DE1568816C3 - Verfahren zur selektiven Hydrierung eines Diolefins - Google Patents

Verfahren zur selektiven Hydrierung eines Diolefins

Info

Publication number
DE1568816C3
DE1568816C3 DE1568816A DE1568816A DE1568816C3 DE 1568816 C3 DE1568816 C3 DE 1568816C3 DE 1568816 A DE1568816 A DE 1568816A DE 1568816 A DE1568816 A DE 1568816A DE 1568816 C3 DE1568816 C3 DE 1568816C3
Authority
DE
Germany
Prior art keywords
catalyst
percent
volume
pores
diolefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE1568816A
Other languages
German (de)
English (en)
Other versions
DE1568816A1 (de
DE1568816B2 (de
Inventor
Jean Cosyns
Michel Derrien
Jean-Francois Lepage
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies nouvelles
Original Assignee
IFP Energies nouvelles
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies nouvelles filed Critical IFP Energies nouvelles
Publication of DE1568816A1 publication Critical patent/DE1568816A1/de
Publication of DE1568816B2 publication Critical patent/DE1568816B2/de
Application granted granted Critical
Publication of DE1568816C3 publication Critical patent/DE1568816C3/de
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C07C5/05—Partial hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/36—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/38—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE1568816A 1965-02-13 1966-02-14 Verfahren zur selektiven Hydrierung eines Diolefins Expired DE1568816C3 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR78005522 1965-02-13

Publications (3)

Publication Number Publication Date
DE1568816A1 DE1568816A1 (de) 1970-05-21
DE1568816B2 DE1568816B2 (de) 1975-05-22
DE1568816C3 true DE1568816C3 (de) 1976-01-02

Family

ID=9696327

Family Applications (1)

Application Number Title Priority Date Filing Date
DE1568816A Expired DE1568816C3 (de) 1965-02-13 1966-02-14 Verfahren zur selektiven Hydrierung eines Diolefins

Country Status (6)

Country Link
US (1) US3472763A (enExample)
BE (1) BE676321A (enExample)
DE (1) DE1568816C3 (enExample)
GB (1) GB1129325A (enExample)
NL (1) NL148028B (enExample)
OA (1) OA02047A (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3008191A1 (de) * 1979-03-05 1980-09-11 Inst Francais Du Petrol Verfahren zur gleichzeitigen und selektiven hydrierung einer ungesaettigten c tief 4 -kohlenwasserstoff-fraktion und einer ungesaettigten benzin-fraktion

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3696160A (en) * 1970-03-26 1972-10-03 Exxon Research Engineering Co Selective hydrogenation of diolefins
GB1369676A (en) * 1971-02-19 1974-10-09 Int Synthetic Rubber Cyclopentene preparation
US3793186A (en) * 1971-07-19 1974-02-19 Chevron Res Lube oil improvement
US4131537A (en) * 1977-10-04 1978-12-26 Exxon Research & Engineering Co. Naphtha hydrofining process
JPS5513748A (en) * 1978-07-17 1980-01-30 Nippon Oil Co Ltd Hydrogenation of thermally cracked gasoline
FR2552078B1 (fr) * 1983-09-19 1986-05-02 Inst Francais Du Petrole Procede d'hydrogenation selective de l'acetylene contenu dans un melange d'acetylene et d'ethylene
US4523045A (en) * 1984-04-04 1985-06-11 Uop Inc. Process for converting paraffins to olefins
US4520214A (en) * 1984-04-04 1985-05-28 Uop Inc. High selectivity process for dehydrogenation of paraffinic hydrocarbons
US4523048A (en) * 1984-04-04 1985-06-11 Uop Inc. Process for the selective production of alkylbenzenes
US4695560A (en) * 1985-10-01 1987-09-22 Uop Inc. Catalyst for the selective hydrogenation of diolefinic hydrocarbons
US4734540A (en) * 1986-12-22 1988-03-29 Uop Inc. Catalyst for the selective hydrogenation of polyunsaturated organics
IN171787B (enExample) * 1986-12-22 1993-01-09 Uop Inc
US4761509A (en) * 1987-02-24 1988-08-02 Uop Inc. High selectivity process for dehydrogenation of paraffinic hydrocarbons
ES2022366B3 (es) * 1987-09-14 1991-12-01 Uop (A New York General Partnership) Catalizador de hidrogenacion selectiva de alta macrosporas
DE3736557A1 (de) * 1987-10-28 1989-05-11 Sued Chemie Ag Katalysator zur selektiven hydrierung von mehrfach ungesaettigten kohlenwasserstoffen
FR2664610A1 (fr) * 1990-07-13 1992-01-17 Inst Francais Du Petrole Hydrogenation selective des essences de vapocraquage sur des catalyseurs a base d'un metal supporte dans lesquels un compose organique a ete incorpore avant chargement dans le reacteur.
FR2785833B1 (fr) * 1998-11-18 2000-12-08 Inst Francais Du Petrole Catalyseur comprenant du nickel et son utilisation dans un procede d'hydrodesulfuration de charges hydrocarbonees
US6417135B1 (en) 1999-08-27 2002-07-09 Huntsman Petrochemical Corporation Advances in dehydrogenation catalysis
US6676606B2 (en) * 2002-06-11 2004-01-13 Koninklijke Philips Electronics N.V. Ultrasonic diagnostic micro-vascular imaging
US7081555B2 (en) * 2002-08-07 2006-07-25 Shell Oil Company Process for hydrogenation of aromatics in hydrocarbon feedstocks containing thiopheneic compounds
US7745372B2 (en) * 2003-12-22 2010-06-29 China Petroleum & Chemical Corporation Catalyst for selective hydrogenation of olefins and its preparation as well as use
US7449167B2 (en) * 2004-07-08 2008-11-11 Air Products And Chemicals, Inc. Catalyst and process for improving the adiabatic steam-reforming of natural gas
FR2895416B1 (fr) * 2005-12-22 2011-08-26 Inst Francais Du Petrole Procede d'hydrogenation selective mettant en oeuvre un catalyseur sulfure
FR2895415B1 (fr) * 2005-12-22 2011-07-15 Inst Francais Du Petrole Procede d'hydrogenation selective mettant en oeuvre un catalyseur presentant un support specifique
FR2895414B1 (fr) * 2005-12-22 2011-07-29 Inst Francais Du Petrole Procede d'hydrogenation selective mettant en oeuvre un catalyseur presentant une porosite controlee
CN100487086C (zh) * 2006-01-06 2009-05-13 中国石油天然气股份有限公司 一种选择性镍系加氢催化剂及其制备方法、应用
TWI445575B (zh) * 2006-09-20 2014-07-21 China Petro Chemical Technology Dev Company Ltd A nickel catalyst for selective hydrogenation
CN101423775B (zh) * 2007-11-01 2010-05-12 中国石油天然气股份有限公司 一种选择性镍系加氢催化剂及其制备方法
CN101433841B (zh) * 2007-12-13 2010-04-14 中国石油天然气股份有限公司 一种选择性加氢催化剂及其制备方法
FI128142B (fi) * 2010-02-02 2019-10-31 Upm Kymmene Corp Menetelmä ja laitteisto hiilivetyjen tuottamiseksi
FR2990882B1 (fr) * 2012-05-24 2015-05-15 IFP Energies Nouvelles Procede de preparation d'un catalyseur a base d'un metal du groupe viii et contenant du silicium et procede d'hydrogenation selective mettant en oeuvre ledit catalyseur
KR101979132B1 (ko) 2015-01-29 2019-05-15 루머스 테크놀로지 엘엘씨 스팀 크래커 c5 공급물로부터 c5 올레핀류의 제조

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3067128A (en) * 1958-08-29 1962-12-04 Exxon Research Engineering Co Metal oxide containing catalyst base
US3205281A (en) * 1959-03-02 1965-09-07 Chemetron Corp Method of selectively hydrogenating acetylenic compounds in a gas consisting predominately of olefins
FR1250000A (fr) * 1959-11-27 1961-01-06 Pechiney Support de catalyseur
NL103710C (enExample) * 1960-01-14
NL257123A (enExample) * 1960-10-21
US3242101A (en) * 1962-07-24 1966-03-22 Sinclair Research Inc Nickel-molybdenum-alumina hydrocarbon conversion catalyst

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3008191A1 (de) * 1979-03-05 1980-09-11 Inst Francais Du Petrol Verfahren zur gleichzeitigen und selektiven hydrierung einer ungesaettigten c tief 4 -kohlenwasserstoff-fraktion und einer ungesaettigten benzin-fraktion

Also Published As

Publication number Publication date
GB1129325A (en) 1968-10-02
DE1568816A1 (de) 1970-05-21
OA02047A (fr) 1970-05-05
NL6600092A (enExample) 1966-08-15
US3472763A (en) 1969-10-14
NL148028B (nl) 1975-12-15
DE1568816B2 (de) 1975-05-22
BE676321A (enExample) 1966-08-10

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Legal Events

Date Code Title Description
C3 Grant after two publication steps (3rd publication)
E77 Valid patent as to the heymanns-index 1977
8339 Ceased/non-payment of the annual fee