DE1421838B1 - Phototroper Glasgegenstand - Google Patents
Phototroper GlasgegenstandInfo
- Publication number
- DE1421838B1 DE1421838B1 DE19611421838 DE1421838A DE1421838B1 DE 1421838 B1 DE1421838 B1 DE 1421838B1 DE 19611421838 DE19611421838 DE 19611421838 DE 1421838 A DE1421838 A DE 1421838A DE 1421838 B1 DE1421838 B1 DE 1421838B1
- Authority
- DE
- Germany
- Prior art keywords
- percent
- weight
- silver
- glass
- photochromic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims description 108
- 229910052709 silver Inorganic materials 0.000 claims description 81
- 239000004332 silver Substances 0.000 claims description 81
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 47
- -1 silver halide Chemical class 0.000 claims description 41
- 239000013078 crystal Substances 0.000 claims description 37
- 239000000203 mixture Substances 0.000 claims description 27
- 229910052736 halogen Inorganic materials 0.000 claims description 17
- 150000002367 halogens Chemical class 0.000 claims description 17
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 13
- 229910021607 Silver chloride Inorganic materials 0.000 claims description 10
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims description 10
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 9
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 8
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 8
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 6
- 239000005368 silicate glass Substances 0.000 claims description 5
- 239000004615 ingredient Substances 0.000 claims description 4
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 claims description 3
- 239000005751 Copper oxide Substances 0.000 claims description 3
- 229910021612 Silver iodide Inorganic materials 0.000 claims description 3
- 229910000431 copper oxide Inorganic materials 0.000 claims description 3
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 claims description 3
- 229940045105 silver iodide Drugs 0.000 claims description 3
- 229910018068 Li 2 O Inorganic materials 0.000 claims description 2
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 2
- 229910000413 arsenic oxide Inorganic materials 0.000 claims description 2
- KTTMEOWBIWLMSE-UHFFFAOYSA-N diarsenic trioxide Chemical compound O1[As](O2)O[As]3O[As]1O[As]2O3 KTTMEOWBIWLMSE-UHFFFAOYSA-N 0.000 claims description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 2
- 229910001887 tin oxide Inorganic materials 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 238000002844 melting Methods 0.000 description 9
- 230000008018 melting Effects 0.000 description 9
- 230000035699 permeability Effects 0.000 description 9
- 230000005855 radiation Effects 0.000 description 9
- 239000000460 chlorine Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 7
- 150000004820 halides Chemical class 0.000 description 7
- 101710134784 Agnoprotein Proteins 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 5
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 229910052731 fluorine Inorganic materials 0.000 description 5
- 239000011737 fluorine Substances 0.000 description 5
- 239000004576 sand Substances 0.000 description 5
- 239000000292 calcium oxide Substances 0.000 description 4
- 239000003638 chemical reducing agent Substances 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- 230000002441 reversible effect Effects 0.000 description 4
- 238000002845 discoloration Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000006121 base glass Substances 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 150000004673 fluoride salts Chemical class 0.000 description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 238000010309 melting process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000011022 opal Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000008707 rearrangement Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- 238000012619 stoichiometric conversion Methods 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000006060 molten glass Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000006089 photosensitive glass Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229940100890 silver compound Drugs 0.000 description 1
- 150000003379 silver compounds Chemical class 0.000 description 1
- 229940096017 silver fluoride Drugs 0.000 description 1
- REYHXKZHIMGNSE-UHFFFAOYSA-M silver monofluoride Chemical compound [F-].[Ag+] REYHXKZHIMGNSE-UHFFFAOYSA-M 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/22—Absorbing filters
- G02B5/23—Photochromic filters
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/04—Compositions for glass with special properties for photosensitive glass
- C03C4/06—Compositions for glass with special properties for photosensitive glass for phototropic or photochromic glass
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7961460A | 1960-12-30 | 1960-12-30 | |
| US15327261A | 1961-11-24 | 1961-11-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1421838B1 true DE1421838B1 (de) | 1970-05-27 |
Family
ID=26762211
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19611421838 Pending DE1421838B1 (de) | 1960-12-30 | 1961-12-27 | Phototroper Glasgegenstand |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE612171A (es) |
| CH (1) | CH418538A (es) |
| DE (1) | DE1421838B1 (es) |
| DK (1) | DK129572B (es) |
| FI (1) | FI40837B (es) |
| GB (1) | GB950906A (es) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3406085A (en) * | 1964-05-11 | 1968-10-15 | Corning Glass Works | Photochromic window |
| CH472344A (fr) * | 1965-10-27 | 1969-05-15 | Glaverbel | Matériau composite ayant la propriété d'uniformiser l'action d'un rayonnement électromagnétique variable du spectre visible |
| US3615761A (en) * | 1968-01-31 | 1971-10-26 | Ppg Industries Inc | Phototropic articles containing thallous halide |
| US3656923A (en) * | 1968-05-27 | 1972-04-18 | Corning Glass Works | Method for strengthening photochromic glass articles |
| US3836809A (en) * | 1971-07-19 | 1974-09-17 | Corning Glass Works | Fiber optic plate with dense opal glass cladding |
| DE3020357A1 (de) * | 1980-05-29 | 1981-12-03 | Jenaer Glaswerk Schott & Gen., 6500 Mainz | Verfahren zur verstaerkung des phototropen effekts in phototropen glaesern |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE844648C (de) * | 1950-07-07 | 1952-07-24 | Corning Glass Works | Lichtempfindliches Glas |
-
1961
- 1961-12-22 GB GB4607461A patent/GB950906A/en not_active Expired
- 1961-12-27 DE DE19611421838 patent/DE1421838B1/de active Pending
- 1961-12-29 BE BE612171A patent/BE612171A/fr unknown
- 1961-12-29 CH CH1511461A patent/CH418538A/de unknown
- 1961-12-29 FI FI230561A patent/FI40837B/fi active
- 1961-12-30 DK DK525361A patent/DK129572B/da unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE844648C (de) * | 1950-07-07 | 1952-07-24 | Corning Glass Works | Lichtempfindliches Glas |
Also Published As
| Publication number | Publication date |
|---|---|
| CH418538A (de) | 1966-08-15 |
| DK129572C (es) | 1975-03-24 |
| GB950906A (en) | 1964-02-26 |
| DK129572B (da) | 1974-10-28 |
| FI40837B (es) | 1969-02-28 |
| BE612171A (fr) | 1962-06-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69333593T2 (de) | Ultraviolett absorbierende Gläser | |
| DE1496091B2 (de) | Glaskörper aus Silikatglas, der Metallhalogenide, jedoch kein Silberhalogenid enthält, und dessen optische Durchlässigkeit im umgekehrten Verhältnis zu der auf ihn auftreffenden aktinischen Strahlung steht, sowie Verfahren zu seiner Herstellung | |
| DE1596764B1 (de) | Glaskoerper mit photochromatischer oberflaechenschicht und verfahren seiner herstellung | |
| DE3206958C2 (de) | Phototropes Glas mit einem Brechungsindex ≥ 1,59, einer Abbezahl ≥ 44 und einer Dichte ≦ 3,0 g/cm↑3↑ | |
| DE3030692C2 (es) | ||
| DE3117000C2 (de) | Phototropes Glas mit einem Brechungsindex ≥ 1,59, einer Abbezahl ≥ 40 und einer Dichte ≦ 3,2 g/cm↑3↑ | |
| DE2800144A1 (de) | Verfahren zur herstellung opak- durchsichtiger glaeser | |
| DE2800145A1 (de) | Verfahren zur herstellung photosensitiver farbglaeser | |
| DE2911796A1 (de) | Photochrome glaeser | |
| DE844648C (de) | Lichtempfindliches Glas | |
| DE2218142C3 (de) | Phototropes Glas des Systems SiO tief 2 -B tief 2 O tief 3- Al tief 2 O tief 3 -BaO-K tief 2 O und Silberhalogenen mit erhöhter optischer Dichte und erhöhter Geschwindigkeit der Lichtdurchlässigkeitsänderung sowie Verfahren zu seiner Herstellung | |
| DE1496092A1 (de) | Waermeabsorbierende Glaeser mit verbesserten physikalischen Eigenschaften | |
| DE1496093C3 (de) | Phototroper Glasgegenstand und Verfahren zu seiner Herstellung | |
| DE2436464B2 (de) | Fotochromes Glas des Systems SiO2 -B2 O3 -BaO-R2 O sowie CuO und Ag mit einem stöchiometrischen Überschuß an Cl, Br und/oder J gegenüber Ag und einem BaO-R2 O-Gewichtsverhältnis von 0,035 bis 0,65 | |
| DE2436516A1 (de) | Reversibel lichtempfindliches glas | |
| DE1496082A1 (de) | Phototropischer Silikatglaskoerper | |
| DE1924493C3 (de) | Schnell reagierendes phototropes Glas hoher Stabilität auf Borat- oder Borosilikatbasis sowie Verfahren zu seiner Herstellung | |
| DE1421838B1 (de) | Phototroper Glasgegenstand | |
| DE1596917C3 (de) | Schnell umschlagendes phototropes Glas auf der Basis eines Tonerde-Boratglases mit Zusätzen an Silberhalogeniden und Kupferoxid und Verfahren zu seiner Herstellung | |
| DE1421838C (de) | Phototroper Glasgegenstand | |
| DE2140914A1 (de) | Thermisch dunkelbares, photochromes Glas | |
| AT255678B (de) | Phototroper Glaskörper und Verfahren zu dessen Herstellung | |
| DE1496091C (de) | Glaskörper aus Sihkatglas, der Metall halogenide, jedoch kein Silberhalogenid ent halt, und dessen optische Durchlässigkeit im umgekehrten Verhältnis zu der auf ihn auftreffenden aktinischen Strahlung steht, sowie Verfahren zu seiner Herstellung | |
| DE2805481C2 (de) | Fotochromes, silberfreies Glas | |
| DE1949684B2 (de) | Fuer uv-strahlen nicht durchlaessiges optisches farbglas fuer die farbfotografie mit hoher wiedergabetreue der farben und verfahren zu seiner herstellung |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| E77 | Valid patent as to the heymanns-index 1977 |