DE1296797B - Vulkanisierbare Formmassen - Google Patents
Vulkanisierbare FormmassenInfo
- Publication number
- DE1296797B DE1296797B DEM57589A DEM0057589A DE1296797B DE 1296797 B DE1296797 B DE 1296797B DE M57589 A DEM57589 A DE M57589A DE M0057589 A DEM0057589 A DE M0057589A DE 1296797 B DE1296797 B DE 1296797B
- Authority
- DE
- Germany
- Prior art keywords
- vulcanization
- tert
- tbph
- peroxide
- hexane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000465 moulding Methods 0.000 title claims description 7
- 150000001875 compounds Chemical class 0.000 title claims description 6
- 238000004073 vulcanization Methods 0.000 claims description 29
- 150000002978 peroxides Chemical class 0.000 claims description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 8
- 229910052717 sulfur Inorganic materials 0.000 claims description 8
- 239000011593 sulfur Substances 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 5
- VMAIOJJXKZOYLC-UHFFFAOYSA-N 2,2,5,5-tetrakis(tert-butylperoxy)hexane Chemical compound C(C)(C)(C)OOC(C)(CCC(C)(OOC(C)(C)C)OOC(C)(C)C)OOC(C)(C)C VMAIOJJXKZOYLC-UHFFFAOYSA-N 0.000 claims description 4
- 150000001336 alkenes Chemical class 0.000 claims description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
- 239000003431 cross linking reagent Substances 0.000 claims description 3
- 150000004053 quinones Chemical class 0.000 claims description 3
- 239000000203 mixture Substances 0.000 description 25
- 229920001577 copolymer Polymers 0.000 description 18
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 10
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 7
- 239000006229 carbon black Substances 0.000 description 7
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical class C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 4
- -1 polyethylene Polymers 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- KRDXTHSSNCTAGY-UHFFFAOYSA-N 2-cyclohexylpyrrolidine Chemical compound C1CCNC1C1CCCCC1 KRDXTHSSNCTAGY-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 230000002028 premature Effects 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000004071 soot Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- ZILNZOUQWZZDGS-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)heptane Chemical compound CC(C)(C)OOC(CC)CCC(C)OOC(C)(C)C ZILNZOUQWZZDGS-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 241001441571 Hiodontidae Species 0.000 description 1
- WMVSVUVZSYRWIY-UHFFFAOYSA-N [(4-benzoyloxyiminocyclohexa-2,5-dien-1-ylidene)amino] benzoate Chemical compound C=1C=CC=CC=1C(=O)ON=C(C=C1)C=CC1=NOC(=O)C1=CC=CC=C1 WMVSVUVZSYRWIY-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000001192 hot extrusion Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 150000002976 peresters Chemical class 0.000 description 1
- 238000005502 peroxidation Methods 0.000 description 1
- 125000002081 peroxide group Chemical group 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- CCEKAJIANROZEO-UHFFFAOYSA-N sulfluramid Chemical group CCNS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F CCEKAJIANROZEO-UHFFFAOYSA-N 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/20—Peroxy compounds the —O—O— group being bound to a carbon atom further substituted by singly—bound oxygen atoms
- C07C409/22—Peroxy compounds the —O—O— group being bound to a carbon atom further substituted by singly—bound oxygen atoms having two —O—O— groups bound to the carbon atom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1472262 | 1962-07-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1296797B true DE1296797B (de) | 1969-06-04 |
Family
ID=11145594
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEM57589A Pending DE1296797B (de) | 1962-07-23 | 1963-07-22 | Vulkanisierbare Formmassen |
| DE19631768062 Pending DE1768062A1 (de) | 1962-07-23 | 1963-07-22 | 2,2,5,5-Tetra-(tert.butyl-peroxy)-hexan,seine Herstellung und Verwendung |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19631768062 Pending DE1768062A1 (de) | 1962-07-23 | 1963-07-22 | 2,2,5,5-Tetra-(tert.butyl-peroxy)-hexan,seine Herstellung und Verwendung |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US3477985A (en:Method) |
| AT (1) | AT246420B (en:Method) |
| BE (1) | BE635236A (en:Method) |
| CH (1) | CH427256A (en:Method) |
| DE (2) | DE1296797B (en:Method) |
| DK (1) | DK104432C (en:Method) |
| ES (1) | ES290088A1 (en:Method) |
| FI (2) | FI40834B (en:Method) |
| GB (1) | GB1034266A (en:Method) |
| LU (1) | LU44088A1 (en:Method) |
| NL (2) | NL295444A (en:Method) |
| SE (1) | SE303605B (en:Method) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113976841A (zh) * | 2021-12-24 | 2022-01-28 | 河北钢研德凯科技有限公司北京分公司 | 一种镁合金熔体浇注用保护剂和镁合金铸件及其制备方法 |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1544704B2 (de) * | 1965-05-28 | 1970-07-16 | Chemische Werke Hüls AG, 4370 Mari | Vernetzbare Formmassen aus Polybuten-1 |
| US3878161A (en) * | 1969-08-12 | 1975-04-15 | Goodrich Co B F | Vulcanizing elastomers and crosslinking, plastomers with organic tetraperoxides |
| US4857257A (en) * | 1983-06-13 | 1989-08-15 | Allied-Signal Inc. | Rotationally molding crosslinkable polyethylene composition |
| US4900792A (en) * | 1983-06-13 | 1990-02-13 | Allied-Signal Inc. | Crosslinkable polyethylene composition |
| US4788019A (en) * | 1984-10-02 | 1988-11-29 | Phillips Petroleum Company | Method of molding a polymer composition containing a tetraalkenyl orthosilicate |
| US4661552A (en) * | 1984-10-02 | 1987-04-28 | Phillips Petroleum Company | Polymer composition and process |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1269101A (fr) * | 1959-08-28 | 1961-08-11 | Wallace & Tiernan Inc | Procédé d'obtention de liaisons transversales dans des composés polyéthyléniques, résines obtenues et produits finis, élaborés à partir desdites résines |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| LU38108A1 (en:Method) * | 1959-01-14 |
-
0
- NL NL136863D patent/NL136863C/xx active
- BE BE635236D patent/BE635236A/xx unknown
- NL NL295444D patent/NL295444A/xx unknown
-
1963
- 1963-07-12 GB GB27741/63A patent/GB1034266A/en not_active Expired
- 1963-07-17 ES ES290088A patent/ES290088A1/es not_active Expired
- 1963-07-18 FI FI1423/63A patent/FI40834B/fi active
- 1963-07-18 CH CH898463A patent/CH427256A/de unknown
- 1963-07-18 LU LU44088D patent/LU44088A1/xx unknown
- 1963-07-19 AT AT578163A patent/AT246420B/de active
- 1963-07-22 SE SE8092/63A patent/SE303605B/xx unknown
- 1963-07-22 US US296469A patent/US3477985A/en not_active Expired - Lifetime
- 1963-07-22 DE DEM57589A patent/DE1296797B/de active Pending
- 1963-07-22 DK DK349863AA patent/DK104432C/da active
- 1963-07-22 DE DE19631768062 patent/DE1768062A1/de active Pending
-
1968
- 1968-11-08 FI FI3194/68A patent/FI42327B/fi active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1269101A (fr) * | 1959-08-28 | 1961-08-11 | Wallace & Tiernan Inc | Procédé d'obtention de liaisons transversales dans des composés polyéthyléniques, résines obtenues et produits finis, élaborés à partir desdites résines |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113976841A (zh) * | 2021-12-24 | 2022-01-28 | 河北钢研德凯科技有限公司北京分公司 | 一种镁合金熔体浇注用保护剂和镁合金铸件及其制备方法 |
| CN113976841B (zh) * | 2021-12-24 | 2023-03-21 | 河北钢研德凯科技有限公司北京分公司 | 一种镁合金熔体浇注用保护剂和镁合金铸件及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CH427256A (de) | 1966-12-31 |
| US3477985A (en) | 1969-11-11 |
| NL295444A (en:Method) | |
| BE635236A (en:Method) | |
| LU44088A1 (en:Method) | 1964-07-18 |
| ES290088A1 (es) | 1964-03-01 |
| NL136863C (en:Method) | |
| AT246420B (de) | 1966-04-25 |
| DE1768062A1 (de) | 1971-04-29 |
| SE303605B (en:Method) | 1968-09-02 |
| FI40834B (en:Method) | 1969-02-28 |
| GB1034266A (en) | 1966-06-29 |
| FI42327B (en:Method) | 1970-03-31 |
| DK104432C (da) | 1966-05-16 |
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