DE1281683B - Verfahren zur Gewinnung von Nickel und weiteren Nichteisenmetallen aus reichem eisenhaltigem Nickelstein - Google Patents
Verfahren zur Gewinnung von Nickel und weiteren Nichteisenmetallen aus reichem eisenhaltigem NickelsteinInfo
- Publication number
- DE1281683B DE1281683B DES97925A DES0097925A DE1281683B DE 1281683 B DE1281683 B DE 1281683B DE S97925 A DES97925 A DE S97925A DE S0097925 A DES0097925 A DE S0097925A DE 1281683 B DE1281683 B DE 1281683B
- Authority
- DE
- Germany
- Prior art keywords
- nickel
- solution
- leaching
- arsenic
- stone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims description 129
- 229910052759 nickel Inorganic materials 0.000 title claims description 63
- 238000000034 method Methods 0.000 title claims description 39
- 239000004575 stone Substances 0.000 title claims description 35
- 229910052751 metal Inorganic materials 0.000 title claims description 27
- 239000002184 metal Substances 0.000 title claims description 27
- 238000000605 extraction Methods 0.000 title claims description 14
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 title claims description 12
- -1 ferrous metals Chemical class 0.000 title claims description 12
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 46
- 229910052785 arsenic Inorganic materials 0.000 claims description 45
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 42
- 238000002386 leaching Methods 0.000 claims description 35
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 27
- 239000010949 copper Substances 0.000 claims description 26
- 229910052802 copper Inorganic materials 0.000 claims description 25
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 24
- 229910052742 iron Inorganic materials 0.000 claims description 21
- 239000003518 caustics Substances 0.000 claims description 20
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 12
- 229910017052 cobalt Inorganic materials 0.000 claims description 12
- 239000010941 cobalt Substances 0.000 claims description 12
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 12
- 229910052717 sulfur Inorganic materials 0.000 claims description 12
- 239000011593 sulfur Substances 0.000 claims description 12
- 239000010970 precious metal Substances 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 239000010802 sludge Substances 0.000 claims description 9
- 229910052787 antimony Inorganic materials 0.000 claims description 8
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 8
- 230000029087 digestion Effects 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 230000001590 oxidative effect Effects 0.000 claims description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- 229910000510 noble metal Inorganic materials 0.000 claims description 4
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 239000000706 filtrate Substances 0.000 claims description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 239000000243 solution Substances 0.000 claims 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 1
- PQTCMBYFWMFIGM-UHFFFAOYSA-N gold silver Chemical compound [Ag].[Au] PQTCMBYFWMFIGM-UHFFFAOYSA-N 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 239000002253 acid Substances 0.000 description 9
- 150000002739 metals Chemical class 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Substances [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 230000002378 acidificating effect Effects 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 3
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 241000283725 Bos Species 0.000 description 2
- 229910000570 Cupronickel Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 2
- 238000009854 hydrometallurgy Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000020477 pH reduction Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 150000004763 sulfides Chemical class 0.000 description 2
- YSCNMFDFYJUPEF-OWOJBTEDSA-N 4,4'-diisothiocyano-trans-stilbene-2,2'-disulfonic acid Chemical compound OS(=O)(=O)C1=CC(N=C=S)=CC=C1\C=C\C1=CC=C(N=C=S)C=C1S(O)(=O)=O YSCNMFDFYJUPEF-OWOJBTEDSA-N 0.000 description 1
- 229910017709 Ni Co Inorganic materials 0.000 description 1
- 244000078856 Prunus padus Species 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- FHKPLLOSJHHKNU-INIZCTEOSA-N [(3S)-3-[8-(1-ethyl-5-methylpyrazol-4-yl)-9-methylpurin-6-yl]oxypyrrolidin-1-yl]-(oxan-4-yl)methanone Chemical compound C(C)N1N=CC(=C1C)C=1N(C2=NC=NC(=C2N=1)O[C@@H]1CN(CC1)C(=O)C1CCOCC1)C FHKPLLOSJHHKNU-INIZCTEOSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- UIFOTCALDQIDTI-UHFFFAOYSA-N arsanylidynenickel Chemical compound [As]#[Ni] UIFOTCALDQIDTI-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 230000036651 mood Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000009853 pyrometallurgy Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/255—Details, e.g. use of specially adapted sources, lighting or optical systems
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0407—Leaching processes
- C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
- C22B23/043—Sulfurated acids or salts thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Pathology (AREA)
- Manufacturing & Machinery (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Health & Medical Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Handcart (AREA)
- Agricultural Machines (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA906694 | 1964-07-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1281683B true DE1281683B (de) | 1968-10-31 |
Family
ID=4142026
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DES97925A Withdrawn DE1281683B (de) | 1964-07-08 | 1965-07-01 | Verfahren zur Gewinnung von Nickel und weiteren Nichteisenmetallen aus reichem eisenhaltigem Nickelstein |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE1281683B (enrdf_load_stackoverflow) |
| FI (1) | FI44960C (enrdf_load_stackoverflow) |
| GB (1) | GB1067007A (enrdf_load_stackoverflow) |
| NO (1) | NO115066B (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3001080A1 (de) * | 1980-01-14 | 1981-07-23 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur laugung von uran aus armerzen |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2140461C1 (ru) * | 1999-03-10 | 1999-10-27 | Открытое акционерное общество "Комбинат Североникель" | Способ растворения металлизированного материала, содержащего никель и кобальт |
| CA2931118C (en) * | 2013-12-03 | 2023-02-14 | Bhp Billiton Nickel West Pty Ltd | Process for producing refined nickel and other products from a mixed hydroxide intermediate |
| CN107630146B (zh) * | 2017-08-07 | 2019-12-20 | 中国恩菲工程技术有限公司 | 镍回收方法 |
| CN111411222B (zh) * | 2020-03-30 | 2022-02-01 | 东北大学秦皇岛分校 | 铜镍硫化物过硫酸铵-硫酸氧化浸出提取有价金属方法 |
| CN112708760B (zh) * | 2020-12-29 | 2022-11-25 | 金川集团股份有限公司 | 一种镍精炼系统中除锑的方法 |
| CN113416843A (zh) * | 2021-06-18 | 2021-09-21 | 国家电投集团黄河上游水电开发有限责任公司 | 一种硫化镍精矿的超细磨-氧压浸出工艺 |
-
1965
- 1965-06-22 GB GB2637165A patent/GB1067007A/en not_active Expired
- 1965-07-01 DE DES97925A patent/DE1281683B/de not_active Withdrawn
- 1965-07-06 FI FI158965A patent/FI44960C/fi active
- 1965-07-08 NO NO158857A patent/NO115066B/no unknown
Non-Patent Citations (1)
| Title |
|---|
| None * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3001080A1 (de) * | 1980-01-14 | 1981-07-23 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur laugung von uran aus armerzen |
Also Published As
| Publication number | Publication date |
|---|---|
| FI44960C (fi) | 1972-02-10 |
| FI44960B (enrdf_load_stackoverflow) | 1971-11-01 |
| NO115066B (enrdf_load_stackoverflow) | 1968-07-15 |
| GB1067007A (en) | 1967-04-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2540641C2 (de) | Verfahren zum Laugen von zinkferrithaltigen Rückständen | |
| DE2559219C2 (enrdf_load_stackoverflow) | ||
| EP0428194B1 (de) | Verfahren zur Aufarbeitung von Jarosit-haltigen Rückständen | |
| DE2357280C2 (de) | Verfahren zur Gewinnung von Zink aus zink- und eisenhaltigen Sulfiden | |
| DE2647601C2 (de) | Verfahren zur Gewinnung von Zink aus zink- und eisenhaltigen Mineralsulfiden | |
| DE2257519C3 (de) | Verfahren zur Gewinnung von Edelmetallen | |
| DE2352125A1 (de) | Verfahren zur gewinnung von nickelpulver aus unreinen nickelverbindungen | |
| DD232933A5 (de) | Verfahren zum gewinnen von zink und kupfer | |
| DE2917751A1 (de) | Verfahren zur gewinnung von kupfer aus hochtoxischem, arsenhaltigem flugstaub aus schmelzoefen und bzw. oder aus raffinerieschlaemmen | |
| DE1939342C3 (de) | Verfahren zur selektiven Gewinnung von Nickel, Kupfer und Schwefel aus nickel- und kupferhaltigen sulfidischen Vorstoffen | |
| DE3105445A1 (de) | Verfahren zur laugung von sulfidischen rohsteinen mit einem gehalt an eisen und nichteisenmetallen | |
| DE2557399C2 (de) | Verfahren zum Auslaugen von Nickel aus einem Sulfidstein | |
| DE2624658C3 (de) | Verfahren zur Aufarbeitung von bei der Laugung gerösteter Zinkblende verbleibender Rückstände | |
| DE2502006C3 (de) | Abtrennung von Selen aus kupferhaltigen Lösungen | |
| DE1281683B (de) | Verfahren zur Gewinnung von Nickel und weiteren Nichteisenmetallen aus reichem eisenhaltigem Nickelstein | |
| DE1947535B1 (de) | Verfahren zum Aufschluss von Metalle und Sulfidschwefel enthaltenden Ausgangsstoffen | |
| DE2616623A1 (de) | Verfahren zur gewinnung von kupfer, silber, kobalt und zink | |
| DE2014470A1 (de) | Verfahren zur Aufbereitung von Molybdänit enthaltenden Haufwerken mit unlöslichen nichtsulfidischen Anteilen | |
| DE2311242A1 (de) | Verfahren zur gewinnung von kupfer, zink oder nickel aus erzen | |
| DE2202298A1 (de) | Verfahren zur Gewinnung und Trennung von Kupfer- und Nickelanteilen aus Rohschmelzen u.ae. Ausgangsprodukten | |
| DE876463C (de) | Verfahren zur Gewinnung der in eisenhaltigen Erzen oder Konzentraten anwesenden Metalle, insbesondere Nichteisenmetalle | |
| DE2050947C (de) | Verfahren zur selektiven Abtrennung von Nichteisenmetallen aus diese enthaltenden Pyriterzen | |
| DE2949706A1 (de) | Verfahren zur behandlung von bleikonzentrat | |
| DE1792335C3 (de) | Verfahren zur Aufbereitung von Eisensulfiden | |
| DE1947535C (de) | Verfahren zum Aufschluß von Metalle und Sulfidschwefel enthaltenden Ausgangs stoffen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| E77 | Valid patent as to the heymanns-index 1977 | ||
| EHJ | Ceased/non-payment of the annual fee |