DE1217950B - Verfahren zur Herstellung neuer Perhydrate von Aminoalkylphosphonsaeuren - Google Patents
Verfahren zur Herstellung neuer Perhydrate von AminoalkylphosphonsaeurenInfo
- Publication number
- DE1217950B DE1217950B DEH55307A DEH0055307A DE1217950B DE 1217950 B DE1217950 B DE 1217950B DE H55307 A DEH55307 A DE H55307A DE H0055307 A DEH0055307 A DE H0055307A DE 1217950 B DE1217950 B DE 1217950B
- Authority
- DE
- Germany
- Prior art keywords
- active oxygen
- acid
- hydrogen peroxide
- oxygen content
- aminotri
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002253 acid Substances 0.000 title claims description 21
- 150000007513 acids Chemical class 0.000 title claims description 13
- 238000000034 method Methods 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 35
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 26
- 229910052760 oxygen Inorganic materials 0.000 claims description 26
- 239000001301 oxygen Substances 0.000 claims description 26
- 150000003839 salts Chemical class 0.000 claims description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 9
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 229960002449 glycine Drugs 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 125000001476 phosphono group Chemical group [H]OP(*)(=O)O[H] 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
- -1 oxyl group Chemical group 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims 7
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims 6
- 235000013905 glycine and its sodium salt Nutrition 0.000 claims 3
- YACKEPLHDIMKIO-UHFFFAOYSA-N methylphosphonic acid Chemical compound CP(O)(O)=O YACKEPLHDIMKIO-UHFFFAOYSA-N 0.000 claims 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- FJKFUXNMDLMIRM-UHFFFAOYSA-N aminooxy(methyl)phosphinic acid Chemical class CP(O)(=O)ON FJKFUXNMDLMIRM-UHFFFAOYSA-N 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- GFVMLYBCWPLMTF-UHFFFAOYSA-N disodiomagnesium Chemical compound [Na][Mg][Na] GFVMLYBCWPLMTF-UHFFFAOYSA-N 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- DKPHLYCEFBDQKM-UHFFFAOYSA-H hexapotassium;1-phosphonato-n,n-bis(phosphonatomethyl)methanamine Chemical compound [K+].[K+].[K+].[K+].[K+].[K+].[O-]P([O-])(=O)CN(CP([O-])([O-])=O)CP([O-])([O-])=O DKPHLYCEFBDQKM-UHFFFAOYSA-H 0.000 claims 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims 1
- 239000000347 magnesium hydroxide Substances 0.000 claims 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims 1
- 238000003860 storage Methods 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 230000007717 exclusion Effects 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 230000010933 acylation Effects 0.000 description 1
- 238000005917 acylation reaction Methods 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 150000004965 peroxy acids Chemical group 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000003918 potentiometric titration Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEH55307A DE1217950B (de) | 1965-02-25 | 1965-02-25 | Verfahren zur Herstellung neuer Perhydrate von Aminoalkylphosphonsaeuren |
| US497484A US3394172A (en) | 1965-02-25 | 1965-10-18 | Perhydrates of nitrogen-containing phosphonic acids and process for their manufacture |
| FR49177A FR1468016A (fr) | 1965-02-25 | 1966-02-10 | Procédé pour la fabrication de nouveaux perhydrates d'acides phosphoniques aminés, ainsi que produits conformes à ceux obtenus par ledit procédé ou procédé similaire |
| GB8074/66A GB1072827A (en) | 1965-02-25 | 1966-02-24 | New perhydrates of phosphonic acids containing nitrogen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEH55307A DE1217950B (de) | 1965-02-25 | 1965-02-25 | Verfahren zur Herstellung neuer Perhydrate von Aminoalkylphosphonsaeuren |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE1217950B true DE1217950B (de) | 1966-06-02 |
| DE1217950C2 DE1217950C2 (US06815460-20041109-C00097.png) | 1966-12-15 |
Family
ID=7158991
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEH55307A Granted DE1217950B (de) | 1965-02-25 | 1965-02-25 | Verfahren zur Herstellung neuer Perhydrate von Aminoalkylphosphonsaeuren |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3394172A (US06815460-20041109-C00097.png) |
| DE (1) | DE1217950B (US06815460-20041109-C00097.png) |
| FR (1) | FR1468016A (US06815460-20041109-C00097.png) |
| GB (1) | GB1072827A (US06815460-20041109-C00097.png) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1264687B (de) * | 1965-11-24 | 1968-03-28 | Therachemie Chem Therapeut | Mittel zur Verminderung der Schaedigung von Haaren beim Bleichen und Faerben |
| US4840659A (en) * | 1971-03-10 | 1989-06-20 | Monsanto Company | N-Phosphonomethylglycine phytotoxicant compositions |
| BE787173A (fr) * | 1971-08-04 | 1973-02-05 | Monsanto Co | Amines tertiaires substituees et procedes pour les preparer |
| US4659860A (en) * | 1971-08-09 | 1987-04-21 | Monsanto Company | Thioester of n-phosphonomethylglycine |
| US3914162A (en) * | 1973-06-25 | 1975-10-21 | Monsanto Co | Compositions and process for the electrodeposition of metals |
| US3969398A (en) * | 1974-05-01 | 1976-07-13 | Monsanto Company | Process for producing N-phosphonomethyl glycine |
| US4073700A (en) * | 1975-03-10 | 1978-02-14 | Weisberg Alfred M | Process for producing by electrodeposition bright deposits of gold and its alloys |
| US4405531A (en) * | 1975-11-10 | 1983-09-20 | Monsanto Company | Salts of N-phosphonomethylglycine |
| US4106923A (en) * | 1975-11-10 | 1978-08-15 | Monsanto Company | Phosphonomethyl glycine ester anhydrides, herbicidal composition containing same and use thereof |
| US4495363A (en) * | 1975-11-10 | 1985-01-22 | Monsanto Co. | Esters of N-phosphonomethylglycine |
| US4110100A (en) * | 1977-08-12 | 1978-08-29 | Monsanto Company | Phosphinylmethylimino-acetic acid N-oxide compounds and the sucrose increasing use thereof |
| US4655975A (en) * | 1986-01-27 | 1987-04-07 | The Dow Chemical Company | Solid chelating poly(carboxylate and/or sulfonate)peroxyhydrate bleaches |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1133726B (de) * | 1960-03-22 | 1962-07-26 | Henkel & Cie Gmbh | Verfahren zur Herstellung neuer Perhydrate von Acylierungsprodukten der phosphorigen Saeure |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB852102A (en) * | 1958-02-17 | 1960-10-26 | Prod Chim Et De Synthese Soc D | Improvements in or relating to the stabilisation of hydrogen peroxide |
| NL285361A (US06815460-20041109-C00097.png) * | 1961-11-13 | 1900-01-01 | ||
| US3234140A (en) * | 1964-06-05 | 1966-02-08 | Monsanto Co | Stabilization of peroxy solutions |
-
1965
- 1965-02-25 DE DEH55307A patent/DE1217950B/de active Granted
- 1965-10-18 US US497484A patent/US3394172A/en not_active Expired - Lifetime
-
1966
- 1966-02-10 FR FR49177A patent/FR1468016A/fr not_active Expired
- 1966-02-24 GB GB8074/66A patent/GB1072827A/en not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1133726B (de) * | 1960-03-22 | 1962-07-26 | Henkel & Cie Gmbh | Verfahren zur Herstellung neuer Perhydrate von Acylierungsprodukten der phosphorigen Saeure |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1072827A (en) | 1967-06-21 |
| US3394172A (en) | 1968-07-23 |
| DE1217950C2 (US06815460-20041109-C00097.png) | 1966-12-15 |
| FR1468016A (fr) | 1967-02-03 |
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