DE1169124B - Formmassen aus Propylenpolymerisaten - Google Patents
Formmassen aus PropylenpolymerisatenInfo
- Publication number
- DE1169124B DE1169124B DEB67163A DEB0067163A DE1169124B DE 1169124 B DE1169124 B DE 1169124B DE B67163 A DEB67163 A DE B67163A DE B0067163 A DEB0067163 A DE B0067163A DE 1169124 B DE1169124 B DE 1169124B
- Authority
- DE
- Germany
- Prior art keywords
- bis
- parts
- tert
- propylene polymers
- plastograph
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000465 moulding Methods 0.000 title claims description 32
- 229920001155 polypropylene Polymers 0.000 title claims description 23
- 150000001875 compounds Chemical class 0.000 title claims description 20
- 239000000203 mixture Substances 0.000 claims description 31
- -1 polyethylene Polymers 0.000 claims description 21
- 239000012965 benzophenone Substances 0.000 claims description 8
- 150000005029 thianthrenes Chemical class 0.000 claims description 8
- 150000008366 benzophenones Chemical class 0.000 claims description 7
- 239000003381 stabilizer Substances 0.000 claims description 7
- 150000003457 sulfones Chemical class 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 229920002367 Polyisobutene Polymers 0.000 claims description 3
- 150000002989 phenols Chemical class 0.000 claims description 3
- 150000003464 sulfur compounds Chemical class 0.000 claims description 2
- 238000004898 kneading Methods 0.000 description 20
- 239000000155 melt Substances 0.000 description 15
- 238000002845 discoloration Methods 0.000 description 12
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 11
- 229910052740 iodine Inorganic materials 0.000 description 11
- 239000011630 iodine Substances 0.000 description 11
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 239000004743 Polypropylene Substances 0.000 description 9
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 6
- XWTUFPFWNHRJNF-UHFFFAOYSA-N 1,2-dimethylthianthrene Chemical class C1=CC=C2SC3=C(C)C(C)=CC=C3SC2=C1 XWTUFPFWNHRJNF-UHFFFAOYSA-N 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 230000000087 stabilizing effect Effects 0.000 description 5
- GVIJJXMXTUZIOD-UHFFFAOYSA-N thianthrene Chemical compound C1=CC=C2SC3=CC=CC=C3SC2=C1 GVIJJXMXTUZIOD-UHFFFAOYSA-N 0.000 description 5
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- LRRMGPGVHYPBPL-UHFFFAOYSA-N 2,6-ditert-butyl-4-[2-(3,5-ditert-butyl-4-hydroxyphenyl)ethyl]phenol Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 LRRMGPGVHYPBPL-UHFFFAOYSA-N 0.000 description 2
- QUWAJPZDCZDTJS-UHFFFAOYSA-N 2-(2-hydroxyphenyl)sulfonylphenol Chemical class OC1=CC=CC=C1S(=O)(=O)C1=CC=CC=C1O QUWAJPZDCZDTJS-UHFFFAOYSA-N 0.000 description 2
- LFKHTSFXKWPEEC-UHFFFAOYSA-N 2-tert-butyl-4-(3-tert-butyl-4-hydroxyphenyl)sulfonylphenol Chemical compound C1=C(O)C(C(C)(C)C)=CC(S(=O)(=O)C=2C=C(C(O)=CC=2)C(C)(C)C)=C1 LFKHTSFXKWPEEC-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 125000001118 alkylidene group Chemical group 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000012778 molding material Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- CKGKXGQVRVAKEA-UHFFFAOYSA-N (2-methylphenyl)-phenylmethanone Chemical compound CC1=CC=CC=C1C(=O)C1=CC=CC=C1 CKGKXGQVRVAKEA-UHFFFAOYSA-N 0.000 description 1
- GAYUSSOCODCSNF-UHFFFAOYSA-N 1-(dodecyldisulfanyl)dodecane Chemical compound CCCCCCCCCCCCSSCCCCCCCCCCCC GAYUSSOCODCSNF-UHFFFAOYSA-N 0.000 description 1
- LGVYQTLHHGYGFA-UHFFFAOYSA-N 3,5-ditert-butyl-4-[4-(2,6-ditert-butyl-4-hydroxyphenyl)butyl]phenol Chemical compound CC(C)(C)c1cc(O)cc(c1CCCCc1c(cc(O)cc1C(C)(C)C)C(C)(C)C)C(C)(C)C LGVYQTLHHGYGFA-UHFFFAOYSA-N 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000000468 ketone group Chemical group 0.000 description 1
- AHXDSVSZEZHDLV-UHFFFAOYSA-N mesulfen Chemical compound CC1=CC=C2SC3=CC(C)=CC=C3SC2=C1 AHXDSVSZEZHDLV-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- 125000004817 pentamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 125000000101 thioether group Chemical group 0.000 description 1
- OPSWAWSNPREEFQ-UHFFFAOYSA-K triphenoxyalumane Chemical compound [Al+3].[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1 OPSWAWSNPREEFQ-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/45—Heterocyclic compounds having sulfur in the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE632080D BE632080A (en:Method) | 1962-05-09 | ||
| DEB67163A DE1169124B (de) | 1962-05-09 | 1962-05-09 | Formmassen aus Propylenpolymerisaten |
| GB1810963A GB1035987A (en) | 1962-05-09 | 1963-05-08 | Stabilised propylene polymers |
| FR934215A FR1357267A (fr) | 1962-05-09 | 1963-05-09 | Poudre à mouler à base de polymères de propylène |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB67163A DE1169124B (de) | 1962-05-09 | 1962-05-09 | Formmassen aus Propylenpolymerisaten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1169124B true DE1169124B (de) | 1964-04-30 |
Family
ID=6975415
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEB67163A Pending DE1169124B (de) | 1962-05-09 | 1962-05-09 | Formmassen aus Propylenpolymerisaten |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE632080A (en:Method) |
| DE (1) | DE1169124B (en:Method) |
| GB (1) | GB1035987A (en:Method) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3386829A (en) * | 1965-03-15 | 1968-06-04 | Eastman Kodak Co | Photoreproduction process utilizing photosensitive thianthrene compositions |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE595794A (en:Method) * | 1959-09-02 |
-
0
- BE BE632080D patent/BE632080A/xx unknown
-
1962
- 1962-05-09 DE DEB67163A patent/DE1169124B/de active Pending
-
1963
- 1963-05-08 GB GB1810963A patent/GB1035987A/en not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE595794A (en:Method) * | 1959-09-02 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1035987A (en) | 1966-07-13 |
| BE632080A (en:Method) |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1234023B (de) | Verfahren zum Stabilisieren von isotaktischem Polypropylen | |
| DE1152540C2 (de) | Verfahren zum Stabilisieren von Homo- oder Mischpolymerisaten von Olefinen durch Benzophenon-verbindungen | |
| DE68924671T2 (de) | Gegen Gammastrahlung beständige Polycarbonatzusammensetzungen. | |
| DE1251020B (de) | Stabilisieren von Polyvinylchlorid, Mischpolymerisaten des Vinylidenchlorid und Vinylchlorids und Halogenaethylenpolymerisaten | |
| DE1153520B (de) | Stabilisierte Formmassen aus stereoregulaeren Polymerisaten von ª-Olefinen | |
| DE1795277C3 (de) | Stabilisierte Formmasse auf der Basis von Polyphenylenoxiden | |
| DE2249680B2 (de) | Stabilisierte polyphenylenaether | |
| DE1161688B (de) | Gegen Alterung stabilisierte Formmassen aus Polyolefinen | |
| DE1169124B (de) | Formmassen aus Propylenpolymerisaten | |
| DE4236142A1 (de) | Gegen gamma-strahlung bestaendige polycarbonat-zusammensetzungen | |
| US3243408A (en) | Stabilized polyolefin compositions | |
| DE1243868B (de) | Verfahren zum Stabilisieren von Olefinpolymerisaten | |
| DE1133884B (de) | Stabilisierte Formmasse aus Polyolefinen | |
| DE1469809B2 (de) | Thermoplastische massen | |
| DE1694402C3 (de) | Warmestabile Formmasse aus Olefin polymeren | |
| DE2338711C2 (de) | Brandschutzmittel-Konzentrat zum Ausrüsten von Polypropylen | |
| DE1694375A1 (de) | Flammabweisende Polymermassen | |
| DE1224924B (de) | Verfahren zum Stabilisieren von Polyolefinen | |
| DE102016112050B4 (de) | Gegen ionisierende Strahlung beständige Polycarbonatharzzusammensetzung und Formteil, das diese enthält | |
| DE1694498A1 (de) | Verfahren zur Stabilisierung von Polymeren | |
| DE1211387B (de) | Stabilisierte Formmassen aus Polyaethylen oder stereoregulaeren Polymerisaten von alpha-Olefinen | |
| DE1643559B1 (de) | Substituierte 2-Hydroxybenzyl-4-hydroxyphenyl-sulfide und ihre Verwendung | |
| DE2338710C2 (de) | Schwerbrennbare Formmassen auf der Basis von Polymerisaten des Propylens | |
| DE1225860B (de) | Stabilisierte Formmassen auf Basis von Niederdruck-, Homo- oder -Mischpolymerisaten von Monoolefinen | |
| DE1234387B (de) | Verfahren zum Stabilisieren von Polyolefinen |