DE1141973B - Verfahren zur Verminderung des Quellwertes und zur Erhoehung der Scheuerfestigkeit von Gebilden, wie Fasern, Faeden oder Geweben, aus nativer oder regenerierter Cellulose - Google Patents
Verfahren zur Verminderung des Quellwertes und zur Erhoehung der Scheuerfestigkeit von Gebilden, wie Fasern, Faeden oder Geweben, aus nativer oder regenerierter CelluloseInfo
- Publication number
- DE1141973B DE1141973B DEP22207A DEP0022207A DE1141973B DE 1141973 B DE1141973 B DE 1141973B DE P22207 A DEP22207 A DE P22207A DE P0022207 A DEP0022207 A DE P0022207A DE 1141973 B DE1141973 B DE 1141973B
- Authority
- DE
- Germany
- Prior art keywords
- treated
- cellulose
- cyanuric
- temperature
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 title claims description 22
- 238000000034 method Methods 0.000 title claims description 20
- 238000005299 abrasion Methods 0.000 title claims description 9
- 230000008961 swelling Effects 0.000 title claims description 8
- 239000004744 fabric Substances 0.000 title claims description 5
- 239000004627 regenerated cellulose Substances 0.000 title claims description 4
- 230000008569 process Effects 0.000 title description 6
- 229920002678 cellulose Polymers 0.000 claims description 36
- 239000001913 cellulose Substances 0.000 claims description 35
- 150000004820 halides Chemical class 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 12
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 10
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 9
- 239000004202 carbamide Substances 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 8
- -1 amino compound Chemical class 0.000 claims description 6
- 229920000877 Melamine resin Polymers 0.000 claims description 5
- 238000009833 condensation Methods 0.000 claims description 5
- 230000005494 condensation Effects 0.000 claims description 5
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 claims description 4
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 4
- 150000001299 aldehydes Chemical class 0.000 claims description 3
- 239000012670 alkaline solution Substances 0.000 claims description 3
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 229940015043 glyoxal Drugs 0.000 claims description 2
- 150000004027 organic amino compounds Chemical class 0.000 claims description 2
- 239000007900 aqueous suspension Substances 0.000 claims 1
- 235000010980 cellulose Nutrition 0.000 description 35
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 16
- 229910021538 borax Inorganic materials 0.000 description 11
- 239000004328 sodium tetraborate Substances 0.000 description 11
- 235000010339 sodium tetraborate Nutrition 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 5
- 238000004132 cross linking Methods 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229920000297 Rayon Polymers 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 125000001309 chloro group Chemical group Cl* 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 150000002391 heterocyclic compounds Chemical class 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000012928 buffer substance Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VHYBUUMUUNCHCK-UHFFFAOYSA-N 2,4,6-tribromo-1,3,5-triazine Chemical compound BrC1=NC(Br)=NC(Br)=N1 VHYBUUMUUNCHCK-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 240000000731 Fagus sylvatica Species 0.000 description 1
- 235000010099 Fagus sylvatica Nutrition 0.000 description 1
- WJYIASZWHGOTOU-UHFFFAOYSA-N Heptylamine Chemical compound CCCCCCCN WJYIASZWHGOTOU-UHFFFAOYSA-N 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 229920013820 alkyl cellulose Polymers 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 239000008098 formaldehyde solution Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000006855 networking Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
- D06M13/358—Triazines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL245557D NL245557A (enrdf_load_stackoverflow) | 1959-02-11 | ||
| US3124414D US3124414A (en) | 1959-02-11 | Textile finishing process | |
| DEP22207A DE1141973B (de) | 1959-02-11 | 1959-02-11 | Verfahren zur Verminderung des Quellwertes und zur Erhoehung der Scheuerfestigkeit von Gebilden, wie Fasern, Faeden oder Geweben, aus nativer oder regenerierter Cellulose |
| FR812546A FR1242188A (fr) | 1959-02-11 | 1959-12-09 | Procédé d'ennoblissement d'articles tels que des fibres, des fils ou des tissus en cellulose naturelle ou régénérée |
| GB4425/60A GB940270A (en) | 1959-02-11 | 1960-02-08 | Improvements in or relating to the finishing of cellulose materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP22207A DE1141973B (de) | 1959-02-11 | 1959-02-11 | Verfahren zur Verminderung des Quellwertes und zur Erhoehung der Scheuerfestigkeit von Gebilden, wie Fasern, Faeden oder Geweben, aus nativer oder regenerierter Cellulose |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1141973B true DE1141973B (de) | 1963-01-03 |
Family
ID=7368619
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEP22207A Pending DE1141973B (de) | 1959-02-11 | 1959-02-11 | Verfahren zur Verminderung des Quellwertes und zur Erhoehung der Scheuerfestigkeit von Gebilden, wie Fasern, Faeden oder Geweben, aus nativer oder regenerierter Cellulose |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3124414A (enrdf_load_stackoverflow) |
| DE (1) | DE1141973B (enrdf_load_stackoverflow) |
| FR (1) | FR1242188A (enrdf_load_stackoverflow) |
| GB (1) | GB940270A (enrdf_load_stackoverflow) |
| NL (1) | NL245557A (enrdf_load_stackoverflow) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0903434A1 (de) * | 1997-09-17 | 1999-03-24 | Ciba SC Holding AG | Verfahren zur Behandlung von Cellulosefasern |
| WO1999019555A1 (de) * | 1997-10-15 | 1999-04-22 | Lenzing Aktiengesellschaft | Verfahren zur behandlung von cellulosischen formkörpern |
| TR199801842A3 (tr) * | 1997-09-17 | 1999-10-21 | Ciba Specialty Chemicals Holding Inc. | Selüloz liflerin islem görme yöntemi. |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL6410884A (enrdf_load_stackoverflow) * | 1964-09-18 | 1966-03-21 | ||
| DE4308075A1 (de) * | 1993-03-13 | 1994-09-15 | Pfersee Chem Fab | Verfahren zur Behandlung von Fasermaterialien mittels Triazinderivaten |
| US6036731A (en) * | 1997-06-04 | 2000-03-14 | Ciba Specialty Chemicals Corporation | Crosslinking of cellulosic fiber materials |
| US9416494B2 (en) | 2012-12-26 | 2016-08-16 | Kimberly-Clark Worldwide, Inc. | Modified cellulosic fibers having reduced hydrogen bonding |
| US8834679B2 (en) * | 2012-12-26 | 2014-09-16 | Kimberly-Clark Worldwide, Inc. | Soft tissue having reduced hydrogen bonding |
| US8980054B2 (en) | 2012-12-26 | 2015-03-17 | Kimberly-Clark Worldwide, Inc. | Soft tissue having reduced hydrogen bonding |
| US9410292B2 (en) | 2012-12-26 | 2016-08-09 | Kimberly-Clark Worldwide, Inc. | Multilayered tissue having reduced hydrogen bonding |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB342167A (en) * | 1929-04-11 | 1931-01-29 | Chem Ind Basel | Manufacture of new cellulose derivatives |
| FR1107708A (fr) * | 1953-07-01 | 1956-01-04 | American Cyanamid Co | Perfectionnements à la préparation d'oxyrane triazine polymérisable |
| GB794181A (en) * | 1955-05-27 | 1958-04-30 | Ici Ltd | Treatment of cellulosic textile materials |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2892671A (en) * | 1959-06-30 | Coloring process | ||
| US2892670A (en) * | 1959-06-30 | Table of dyestuffsxcontinued | ||
| US2873269A (en) * | 1956-09-14 | 1959-02-10 | Ciba Ltd | Monoazo-dyestuffs |
-
0
- NL NL245557D patent/NL245557A/xx unknown
- US US3124414D patent/US3124414A/en not_active Expired - Lifetime
-
1959
- 1959-02-11 DE DEP22207A patent/DE1141973B/de active Pending
- 1959-12-09 FR FR812546A patent/FR1242188A/fr not_active Expired
-
1960
- 1960-02-08 GB GB4425/60A patent/GB940270A/en not_active Expired
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB342167A (en) * | 1929-04-11 | 1931-01-29 | Chem Ind Basel | Manufacture of new cellulose derivatives |
| FR1107708A (fr) * | 1953-07-01 | 1956-01-04 | American Cyanamid Co | Perfectionnements à la préparation d'oxyrane triazine polymérisable |
| GB794181A (en) * | 1955-05-27 | 1958-04-30 | Ici Ltd | Treatment of cellulosic textile materials |
| GB794180A (en) * | 1955-05-27 | 1958-04-30 | Ici Ltd | Treatment of cellulosic textile materials |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0903434A1 (de) * | 1997-09-17 | 1999-03-24 | Ciba SC Holding AG | Verfahren zur Behandlung von Cellulosefasern |
| TR199801842A3 (tr) * | 1997-09-17 | 1999-10-21 | Ciba Specialty Chemicals Holding Inc. | Selüloz liflerin islem görme yöntemi. |
| WO1999019555A1 (de) * | 1997-10-15 | 1999-04-22 | Lenzing Aktiengesellschaft | Verfahren zur behandlung von cellulosischen formkörpern |
| US6241933B1 (en) | 1997-10-15 | 2001-06-05 | Lenzing Aktiengesellschaft | Process for the treatment of cellulosic moulded bodies |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1242188A (fr) | 1960-09-23 |
| US3124414A (en) | 1964-03-10 |
| GB940270A (en) | 1963-10-30 |
| NL245557A (enrdf_load_stackoverflow) |
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