DE112017003141A5 - Vernetzte hochstabile Anionenaustauscherblendmembranen mit Polyethylenglycolen als hydrophiler Membranphase - Google Patents

Vernetzte hochstabile Anionenaustauscherblendmembranen mit Polyethylenglycolen als hydrophiler Membranphase Download PDF

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Publication number
DE112017003141A5
DE112017003141A5 DE112017003141.9T DE112017003141T DE112017003141A5 DE 112017003141 A5 DE112017003141 A5 DE 112017003141A5 DE 112017003141 T DE112017003141 T DE 112017003141T DE 112017003141 A5 DE112017003141 A5 DE 112017003141A5
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Prior art keywords
anion exchange
polyethylene glycols
highly stable
hydrophilic membrane
membrane phase
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DE112017003141.9T
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English (en)
Inventor
Jochen Kerres
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Universitaet Stuttgart
Between Lizenz GmbH
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Universitaet Stuttgart
Between Lizenz GmbH
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2256—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/12—Macromolecular compounds
    • B01J41/13—Macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/28—Polymers of vinyl aromatic compounds
    • B01D71/281—Polystyrene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/30—Polyalkenyl halides
    • B01D71/32—Polyalkenyl halides containing fluorine atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/52—Polyethers
    • B01D71/521—Aliphatic polyethers
    • B01D71/5211—Polyethylene glycol or polyethyleneoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/52—Polyethers
    • B01D71/522—Aromatic polyethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/52—Polyethers
    • B01D71/522—Aromatic polyethers
    • B01D71/5222—Polyetherketone, polyetheretherketone, or polyaryletherketone
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/66—Polymers having sulfur in the main chain, with or without nitrogen, oxygen or carbon only
    • B01D71/68—Polysulfones; Polyethersulfones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/12—Macromolecular compounds
    • B01J41/14—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B13/00—Diaphragms; Spacing elements
    • C25B13/04—Diaphragms; Spacing elements characterised by the material
    • C25B13/08—Diaphragms; Spacing elements characterised by the material based on organic materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1025—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • H01M8/184—Regeneration by electrochemical means
    • H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/42—Ion-exchange membranes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/18—Homopolymers or copolymers of aromatic monomers containing elements other than carbon and hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2471/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
    • C08J2471/02—Polyalkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2479/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2461/00 - C08J2477/00
    • C08J2479/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2481/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
    • C08J2481/06—Polysulfones; Polyethersulfones

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  • Chemical & Material Sciences (AREA)
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  • Electrochemistry (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Metallurgy (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Fuel Cell (AREA)
  • Cell Separators (AREA)
  • Conductive Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
DE112017003141.9T 2016-06-22 2017-06-22 Vernetzte hochstabile Anionenaustauscherblendmembranen mit Polyethylenglycolen als hydrophiler Membranphase Withdrawn DE112017003141A5 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102016007815.4 2016-06-22
DE102016007815.4A DE102016007815A1 (de) 2016-06-22 2016-06-22 Vernetzte hochstabile Anionenaustauscherblendmembranen mit Polyethylenglycolen als hydrophiler Membranphase
PCT/DE2017/000179 WO2017220065A1 (de) 2016-06-22 2017-06-22 Vernetzte hochstabile anionenaustauscherblendmembranen mit polyethylenglycolen als hydrophiler membranphase

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DE112017003141A5 true DE112017003141A5 (de) 2019-03-07

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DE102016007815.4A Withdrawn DE102016007815A1 (de) 2016-06-22 2016-06-22 Vernetzte hochstabile Anionenaustauscherblendmembranen mit Polyethylenglycolen als hydrophiler Membranphase
DE112017003141.9T Withdrawn DE112017003141A5 (de) 2016-06-22 2017-06-22 Vernetzte hochstabile Anionenaustauscherblendmembranen mit Polyethylenglycolen als hydrophiler Membranphase

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US (2) US11278879B2 (de)
EP (1) EP3478750A1 (de)
JP (2) JP2019522887A (de)
AU (1) AU2017280451A1 (de)
DE (2) DE102016007815A1 (de)
WO (1) WO2017220065A1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111359453A (zh) * 2020-03-21 2020-07-03 山东科技大学 一种掺杂咪唑类离子液体/改性壳聚糖均相阴离子交换膜及其制备方法

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Publication number Priority date Publication date Assignee Title
DE102016007815A1 (de) * 2016-06-22 2017-12-28 Universität Stuttgart Vernetzte hochstabile Anionenaustauscherblendmembranen mit Polyethylenglycolen als hydrophiler Membranphase
CN109316979B (zh) * 2018-11-02 2021-04-16 绿邦膜分离技术（江苏）有限公司 一种高致密性聚苯乙烯系阳离子交换膜的连续制备方法
CN109701400A (zh) * 2019-03-11 2019-05-03 福州大学 一种基于聚醚砜的多孔阴离子交换膜的制备方法
CN110280149A (zh) * 2019-07-02 2019-09-27 中国科学院宁波材料技术与工程研究所 超亲水聚合物微孔膜、其制备方法及应用
PL3770201T3 (pl) * 2019-07-22 2023-09-25 Evonik Operations Gmbh Membrana polimerowa przewodząca aniony
CN110560181B (zh) * 2019-09-04 2022-08-02 中国科学技术大学先进技术研究院 一种阴离子交换膜的制备方法
CN110550788A (zh) * 2019-09-12 2019-12-10 欧润吉生态环保(浙江)有限公司 一种零排放水处理装置
CN111040156B (zh) * 2019-11-28 2022-05-31 李南文 一种耐溶剂且高尺寸稳定性的交联型聚酰亚胺薄膜
CN111303436B (zh) * 2020-03-06 2022-03-18 珠海冠宇电池股份有限公司 一种聚烯烃-g-超支化聚苯并咪唑接枝共聚物及其制备方法与应用
CN112316988A (zh) * 2020-10-23 2021-02-05 天津市大陆制氢设备有限公司 一种高效的阴离子交换膜及其制备方法
CN113041850A (zh) * 2021-04-07 2021-06-29 福州大学 一种用于扩散渗析的多孔交联阴离子交换膜的制备方法
CN113600026B (zh) * 2021-09-09 2022-07-22 浙江工业大学 一种基于聚乙烯醇抗污染交联型阴离子交换膜的制备方法
CN114456393B (zh) * 2022-01-19 2023-06-27 武汉理工大学 一种sebs接枝聚苯醚阴离子交换膜的制备方法
DE102022120196A1 (de) 2022-08-10 2024-02-15 Forschungszentrum Jülich GmbH Seitenkettenfunktionalisierte Polystyrole als Membranmaterialien für alkalische Wasserelektrolyseure, Brennstoffzellen und Flow-Batterien

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WO2009081841A1 (ja) * 2007-12-21 2009-07-02 Tokuyama Corporation 固体高分子型燃料電池用隔膜、及び隔膜－触媒電極接合体
JP5959046B2 (ja) * 2012-03-07 2016-08-02 国立研究開発法人日本原子力研究開発機構 アニオン伝導電解質膜およびその製造方法
EP3106476A4 (de) * 2014-02-14 2017-07-12 Tokuyama Corporation Teilweise quaternisiertes styrol-basiertes copolymer, ionenleitfähigkeitsvermittler, katalytische elektrodenschicht, membran-/elektrodenanordnung und verfahren zur herstellung davon, gasdiffusionselektrode und verfahren zur herstellung davon sowie brennstoffzelle mit anionenaustauschmembrane
DE102014009170A1 (de) 2014-06-12 2015-12-17 Universität Stuttgart Kombinatorisches Materialsystem für Ionenaustauschermembranen und dessen Verwendung in elektrochemischen Prozessen
DE102016007815A1 (de) * 2016-06-22 2017-12-28 Universität Stuttgart Vernetzte hochstabile Anionenaustauscherblendmembranen mit Polyethylenglycolen als hydrophiler Membranphase

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111359453A (zh) * 2020-03-21 2020-07-03 山东科技大学 一种掺杂咪唑类离子液体/改性壳聚糖均相阴离子交换膜及其制备方法

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JP2019522887A (ja) 2019-08-15
JP2022160413A (ja) 2022-10-19
US20200023348A1 (en) 2020-01-23
EP3478750A1 (de) 2019-05-08
WO2017220065A1 (de) 2017-12-28
US20220212183A1 (en) 2022-07-07
US11278879B2 (en) 2022-03-22
DE102016007815A1 (de) 2017-12-28
AU2017280451A1 (en) 2019-02-14

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