DE1096607C2 - Verfahren zur Herstellung von linearem hochkristallinem Kopf-Schwanz-Polypropylen bzw. Poly-α-butylen - Google Patents
Verfahren zur Herstellung von linearem hochkristallinem Kopf-Schwanz-Polypropylen bzw. Poly-α-butylenInfo
- Publication number
- DE1096607C2 DE1096607C2 DE1956M0032091 DEM0032091A DE1096607C2 DE 1096607 C2 DE1096607 C2 DE 1096607C2 DE 1956M0032091 DE1956M0032091 DE 1956M0032091 DE M0032091 A DEM0032091 A DE M0032091A DE 1096607 C2 DE1096607 C2 DE 1096607C2
- Authority
- DE
- Germany
- Prior art keywords
- hydrogen
- polymerization
- butylene
- highly crystalline
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 10
- -1 polypropylene Polymers 0.000 title claims description 7
- 239000004743 Polypropylene Substances 0.000 title claims description 5
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 229920001155 polypropylene Polymers 0.000 title claims description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical group CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 title description 13
- 229920000642 polymer Polymers 0.000 claims description 27
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 25
- 238000006116 polymerization reaction Methods 0.000 claims description 20
- 239000003054 catalyst Substances 0.000 claims description 9
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 6
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 229910052723 transition metal Inorganic materials 0.000 claims 2
- 150000003624 transition metals Chemical class 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 239000002685 polymerization catalyst Substances 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 description 23
- 229910052739 hydrogen Inorganic materials 0.000 description 23
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 20
- 238000002474 experimental method Methods 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 11
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000000605 extraction Methods 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 150000002902 organometallic compounds Chemical class 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910021381 transition metal chloride Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/08—Butenes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1475655 | 1955-10-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE1096607B DE1096607B (de) | 1961-01-05 |
| DE1096607C2 true DE1096607C2 (de) | 1982-12-09 |
Family
ID=11145909
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1956M0032091 Expired DE1096607C2 (de) | 1955-10-19 | 1956-10-18 | Verfahren zur Herstellung von linearem hochkristallinem Kopf-Schwanz-Polypropylen bzw. Poly-α-butylen |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE551905A (enrdf_load_stackoverflow) |
| CH (1) | CH371901A (enrdf_load_stackoverflow) |
| DE (1) | DE1096607C2 (enrdf_load_stackoverflow) |
| FR (1) | FR1161557A (enrdf_load_stackoverflow) |
| GB (1) | GB850585A (enrdf_load_stackoverflow) |
| NL (2) | NL129662C (enrdf_load_stackoverflow) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE594127A (enrdf_load_stackoverflow) * | 1959-08-17 | |||
| DE1520238B1 (de) * | 1960-10-07 | 1970-01-22 | Montedison Spa | Verfahren zur Polymerisation von alpha-Olefinen |
| NL263189A (enrdf_load_stackoverflow) * | 1960-11-03 | |||
| NL277029A (enrdf_load_stackoverflow) * | 1961-04-14 | |||
| US3147241A (en) * | 1961-06-30 | 1964-09-01 | Phillips Petroleum Co | Use of hydrogen and quaternary ammonium halides in organometal catalyzed olefin polymrization |
| NL301746A (enrdf_load_stackoverflow) * | 1962-12-22 | |||
| CA937952A (en) * | 1969-12-30 | 1973-12-04 | Floris Telemaco | Process for the preparation of synthetic lubricating oils from olefines and products so obtained |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL229912A (enrdf_load_stackoverflow) * | 1954-12-24 |
-
0
- NL NL211498D patent/NL211498A/xx unknown
- NL NL129662D patent/NL129662C/xx active
- BE BE551905D patent/BE551905A/xx unknown
-
1956
- 1956-10-15 GB GB3132456A patent/GB850585A/en not_active Expired
- 1956-10-17 CH CH3860756A patent/CH371901A/de unknown
- 1956-10-18 DE DE1956M0032091 patent/DE1096607C2/de not_active Expired
- 1956-10-18 FR FR1161557D patent/FR1161557A/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL129662C (enrdf_load_stackoverflow) | |
| GB850585A (en) | 1960-10-05 |
| FR1161557A (fr) | 1958-09-02 |
| CH371901A (de) | 1963-09-15 |
| NL211498A (enrdf_load_stackoverflow) | |
| DE1096607B (de) | 1961-01-05 |
| BE551905A (enrdf_load_stackoverflow) |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| BI | Miscellaneous see part 2 |