DE1092201B - Verfahren zur Polymerisation von AEthylen - Google Patents
Verfahren zur Polymerisation von AEthylenInfo
- Publication number
- DE1092201B DE1092201B DEI15172A DEI0015172A DE1092201B DE 1092201 B DE1092201 B DE 1092201B DE I15172 A DEI15172 A DE I15172A DE I0015172 A DEI0015172 A DE I0015172A DE 1092201 B DE1092201 B DE 1092201B
- Authority
- DE
- Germany
- Prior art keywords
- pressure
- ethylene
- pentazdiene
- atmospheres
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 14
- 239000005977 Ethylene Substances 0.000 title claims description 14
- 238000000034 method Methods 0.000 title claims description 11
- 238000006116 polymerization reaction Methods 0.000 title claims description 9
- -1 1,5-Diphenyl-3-methyl-1,4-pentazdiene Chemical compound 0.000 claims description 17
- 239000003054 catalyst Substances 0.000 claims description 14
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 5
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 claims description 5
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 3
- MZVOCNZFJNWWRD-UHFFFAOYSA-N 1-methyl-4-[[2-(4-methylphenyl)iminohydrazinyl]diazenyl]benzene Chemical compound C1=CC(C)=CC=C1N=NNN=NC1=CC=C(C)C=C1 MZVOCNZFJNWWRD-UHFFFAOYSA-N 0.000 claims description 2
- RIRYDBJGXLIEGA-UHFFFAOYSA-N C1(=CC=C(C=C1)N=NN(N=NN(N=NC1=CC=C(C=C1)C)C1=CC=CC=C1)C1=CC=CC=C1)C Chemical compound C1(=CC=C(C=C1)N=NN(N=NN(N=NC1=CC=C(C=C1)C)C1=CC=CC=C1)C1=CC=CC=C1)C RIRYDBJGXLIEGA-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 238000002474 experimental method Methods 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 241001026509 Kata Species 0.000 description 4
- RZXMPPFPUUCRFN-UHFFFAOYSA-N p-toluidine Chemical compound CC1=CC=C(N)C=C1 RZXMPPFPUUCRFN-UHFFFAOYSA-N 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 150000003518 tetracenes Chemical class 0.000 description 3
- ITDKGJIKBWSABM-UHFFFAOYSA-M 4-methylbenzenediazonium;chloride Chemical compound [Cl-].CC1=CC=C([N+]#N)C=C1 ITDKGJIKBWSABM-UHFFFAOYSA-M 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- AFBPFSWMIHJQDM-UHFFFAOYSA-N N-methyl-N-phenylamine Natural products CNC1=CC=CC=C1 AFBPFSWMIHJQDM-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- NYESEEYVQKFGTJ-UHFFFAOYSA-N [(e)-diazenylazo]amine Chemical class NN=NN=N NYESEEYVQKFGTJ-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 210000003298 dental enamel Anatomy 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 150000004655 tetrazenes Chemical class 0.000 description 2
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- MIEPSTDPFQPDEW-UHFFFAOYSA-N aminoazoazoamine Chemical class N\N=N\N=N\N MIEPSTDPFQPDEW-UHFFFAOYSA-N 0.000 description 1
- ICPOUQSUDJWFNX-UHFFFAOYSA-N aminoazoazoazoamine Chemical class N\N=N\N=N\N=N\N ICPOUQSUDJWFNX-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- CLRSZXHOSMKUIB-UHFFFAOYSA-M benzenediazonium chloride Chemical compound [Cl-].N#[N+]C1=CC=CC=C1 CLRSZXHOSMKUIB-UHFFFAOYSA-M 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002897 organic nitrogen compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- IVRIRQXJSNCSPQ-UHFFFAOYSA-N propan-2-yl carbonochloridate Chemical compound CC(C)OC(Cl)=O IVRIRQXJSNCSPQ-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2429357A GB834332A (en) | 1957-07-31 | 1957-07-31 | Polymerisation process for ethylenically unsaturated compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1092201B true DE1092201B (de) | 1960-11-03 |
Family
ID=10209401
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEI15172A Pending DE1092201B (de) | 1957-07-31 | 1958-07-30 | Verfahren zur Polymerisation von AEthylen |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE569886A (en, 2012) |
| DE (1) | DE1092201B (en, 2012) |
| FR (1) | FR1210829A (en, 2012) |
| GB (1) | GB834332A (en, 2012) |
-
0
- BE BE569886D patent/BE569886A/xx unknown
-
1957
- 1957-07-31 GB GB2429357A patent/GB834332A/en not_active Expired
-
1958
- 1958-07-28 FR FR1210829D patent/FR1210829A/fr not_active Expired
- 1958-07-30 DE DEI15172A patent/DE1092201B/de active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| FR1210829A (fr) | 1960-03-10 |
| GB834332A (en) | 1960-05-04 |
| BE569886A (en, 2012) |
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