DE10333029A1 - Nanopartikuläres UV-Schutzmittel - Google Patents
Nanopartikuläres UV-Schutzmittel Download PDFInfo
- Publication number
- DE10333029A1 DE10333029A1 DE10333029A DE10333029A DE10333029A1 DE 10333029 A1 DE10333029 A1 DE 10333029A1 DE 10333029 A DE10333029 A DE 10333029A DE 10333029 A DE10333029 A DE 10333029A DE 10333029 A1 DE10333029 A1 DE 10333029A1
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- Prior art keywords
- nanoparticulate
- preparation
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- protection
- protection agent
- Prior art date
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 229910044991 metal oxide Inorganic materials 0.000 title claims abstract description 33
- 150000004706 metal oxides Chemical class 0.000 title claims abstract description 33
- 238000000576 coating method Methods 0.000 title claims abstract description 30
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- -1 their coatings Substances 0.000 claims description 89
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- 230000006750 UV protection Effects 0.000 claims description 39
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- NZZIMKJIVMHWJC-UHFFFAOYSA-N dibenzoylmethane Chemical compound C=1C=CC=CC=1C(=O)CC(=O)C1=CC=CC=C1 NZZIMKJIVMHWJC-UHFFFAOYSA-N 0.000 claims description 33
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- ZPWFUIUNWDIYCJ-UHFFFAOYSA-N propan-2-yl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(C)C ZPWFUIUNWDIYCJ-UHFFFAOYSA-N 0.000 description 1
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- 159000000000 sodium salts Chemical class 0.000 description 1
- ODFAPIRLUPAQCQ-UHFFFAOYSA-M sodium stearoyl lactylate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C([O-])=O ODFAPIRLUPAQCQ-UHFFFAOYSA-M 0.000 description 1
- 229940080352 sodium stearoyl lactylate Drugs 0.000 description 1
- NTYZDAJPNNBYED-UHFFFAOYSA-M sodium;2-(2-dodecanoyloxypropanoyloxy)propanoate Chemical compound [Na+].CCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C([O-])=O NTYZDAJPNNBYED-UHFFFAOYSA-M 0.000 description 1
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- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229940098760 steareth-2 Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- ARCJQKUWGAZPFX-UHFFFAOYSA-N stilbene oxide Chemical compound O1C(C=2C=CC=CC=2)C1C1=CC=CC=C1 ARCJQKUWGAZPFX-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 150000001629 stilbenes Chemical class 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-M succinate(1-) Chemical compound OC(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-M 0.000 description 1
- 125000005555 sulfoximide group Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
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- 235000019157 thiamine Nutrition 0.000 description 1
- 229960003495 thiamine Drugs 0.000 description 1
- 239000011721 thiamine Substances 0.000 description 1
- DPJRMOMPQZCRJU-UHFFFAOYSA-M thiamine hydrochloride Chemical compound Cl.[Cl-].CC1=C(CCO)SC=[N+]1CC1=CN=C(C)N=C1N DPJRMOMPQZCRJU-UHFFFAOYSA-M 0.000 description 1
- 229960002663 thioctic acid Drugs 0.000 description 1
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- 108060008226 thioredoxin Proteins 0.000 description 1
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
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- 230000000699 topical effect Effects 0.000 description 1
- QURCVMIEKCOAJU-UHFFFAOYSA-N trans-isoferulic acid Natural products COC1=CC=C(C=CC(O)=O)C=C1O QURCVMIEKCOAJU-UHFFFAOYSA-N 0.000 description 1
- ZCIHMQAPACOQHT-ZGMPDRQDSA-N trans-isorenieratene Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/c1c(C)ccc(C)c1C)C=CC=C(/C)C=Cc2c(C)ccc(C)c2C ZCIHMQAPACOQHT-ZGMPDRQDSA-N 0.000 description 1
- LOIYMIARKYCTBW-OWOJBTEDSA-N trans-urocanic acid Chemical compound OC(=O)\C=C\C1=CNC=N1 LOIYMIARKYCTBW-OWOJBTEDSA-N 0.000 description 1
- 238000004627 transmission electron microscopy Methods 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 description 1
- VLMWBWYAHNRUGC-UHFFFAOYSA-N tridecyl 2-hydroxybenzoate Chemical class CCCCCCCCCCCCCOC(=O)C1=CC=CC=C1O VLMWBWYAHNRUGC-UHFFFAOYSA-N 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- HTJNEBVCZXHBNJ-XCTPRCOBSA-H trimagnesium;(2r)-2-[(1s)-1,2-dihydroxyethyl]-3,4-dihydroxy-2h-furan-5-one;diphosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.OC[C@H](O)[C@H]1OC(=O)C(O)=C1O HTJNEBVCZXHBNJ-XCTPRCOBSA-H 0.000 description 1
- NMEPHPOFYLLFTK-UHFFFAOYSA-N trimethoxy(octyl)silane Chemical compound CCCCCCCC[Si](OC)(OC)OC NMEPHPOFYLLFTK-UHFFFAOYSA-N 0.000 description 1
- OYOGCAUNFUJOMO-UHFFFAOYSA-N trimethyl(octyl)silane Chemical compound CCCCCCCC[Si](C)(C)C OYOGCAUNFUJOMO-UHFFFAOYSA-N 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
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- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 229940116269 uric acid Drugs 0.000 description 1
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- 239000011653 vitamin D2 Substances 0.000 description 1
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- 239000011709 vitamin E Substances 0.000 description 1
- 229940011671 vitamin b6 Drugs 0.000 description 1
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- 235000020234 walnut Nutrition 0.000 description 1
- 230000007279 water homeostasis Effects 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
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- 239000011701 zinc Substances 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y5/00—Nanobiotechnology or nanomedicine, e.g. protein engineering or drug delivery
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3653—Treatment with inorganic compounds
- C09C1/3661—Coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
- C09C3/063—Coating
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/413—Nanosized, i.e. having sizes below 100 nm
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
- C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
- C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Crystallography & Structural Chemistry (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Organic Chemistry (AREA)
- Biophysics (AREA)
- General Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Dispersion Chemistry (AREA)
- Composite Materials (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Physics & Mathematics (AREA)
- Biotechnology (AREA)
- General Physics & Mathematics (AREA)
- Medical Informatics (AREA)
- Medicinal Chemistry (AREA)
- Molecular Biology (AREA)
- Pharmacology & Pharmacy (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10333029A DE10333029A1 (de) | 2003-07-21 | 2003-07-21 | Nanopartikuläres UV-Schutzmittel |
| TW093118249A TW200505495A (en) | 2003-07-21 | 2004-06-24 | Nanoparticulate UV protection agents |
| JP2006520709A JP4740845B2 (ja) | 2003-07-21 | 2004-07-05 | 二酸化ケイ素被覆を有するuv保護ナノ粒子 |
| US10/565,214 US20060194057A1 (en) | 2003-07-21 | 2004-07-05 | Silicon dioxide-coated nanoparticulate uv protectant |
| ES04763094.2T ES2611128T3 (es) | 2003-07-21 | 2004-07-05 | Agentes protectores en forma de nanopartículas contra UV con recubrimiento de dióxido de silicio |
| CNB2004800207603A CN100519666C (zh) | 2003-07-21 | 2004-07-05 | 含有二氧化硅涂层的纳米粒状uv防护剂 |
| EP04763094.2A EP1660592B1 (de) | 2003-07-21 | 2004-07-05 | Nanopartikuläres uv-schutzmittel mit siliciumdioxidbeschichtung |
| PCT/EP2004/007311 WO2005019348A1 (de) | 2003-07-21 | 2004-07-05 | Nanopartikuläres uv-schutzmittel mit siliciumdioxidbeschichtung |
| US12/432,949 US8758501B2 (en) | 2003-07-21 | 2009-04-30 | Nanoparticulate UV protectant with silicon dioxide coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10333029A DE10333029A1 (de) | 2003-07-21 | 2003-07-21 | Nanopartikuläres UV-Schutzmittel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE10333029A1 true DE10333029A1 (de) | 2005-02-17 |
Family
ID=34071799
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE10333029A Withdrawn DE10333029A1 (de) | 2003-07-21 | 2003-07-21 | Nanopartikuläres UV-Schutzmittel |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US20060194057A1 (enExample) |
| EP (1) | EP1660592B1 (enExample) |
| JP (1) | JP4740845B2 (enExample) |
| CN (1) | CN100519666C (enExample) |
| DE (1) | DE10333029A1 (enExample) |
| ES (1) | ES2611128T3 (enExample) |
| TW (1) | TW200505495A (enExample) |
| WO (1) | WO2005019348A1 (enExample) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006128777A1 (de) * | 2005-06-03 | 2006-12-07 | Beiersdorf Ag | Kosmetische zubereitungen mit einem gehalt an einem wässrigen anisfruchtextrakt und sulfonierten lichtfiltern |
| WO2006128780A1 (de) * | 2005-06-03 | 2006-12-07 | Beiersdorf Ag | Kosmetische zubereitungen mit einem gehalt an einem wässrigen anisfruchtextrakt und bestimmten nichtionischen emulgatoren |
| WO2006128778A1 (de) * | 2005-06-03 | 2006-12-07 | Beiersdorf Ag | Kosmetische zubereitungen mit einem gehalt an einem wässrigen anisfruchtextrakt und triazin-lichtfiltern |
| WO2006128779A1 (de) * | 2005-06-03 | 2006-12-07 | Beiersdorf Ag | Kosmetische zubereitungen mit einem gehalt an einem wässrigen anisfruchtextrakt und bestimmten nichtionischen emulgatoren |
| WO2006099952A3 (en) * | 2005-03-23 | 2007-01-25 | Dsm Ip Assets Bv | Chromophore coated metal oxide particles |
| WO2007065574A2 (en) | 2005-12-09 | 2007-06-14 | Dsm Ip Assets B.V. | Cosmetic or dermatological compositions comprising modified titanium dioxide particles |
| DE102007028349A1 (de) | 2007-06-20 | 2008-12-24 | Mitsubishi Polyester Film Gmbh | Transparente Polyesterfolie mit BaSO4-Partikeln |
| WO2010037463A1 (de) * | 2008-10-02 | 2010-04-08 | Merck Patent Gmbh, | Titandioxid-partikel |
| WO2009153231A3 (en) * | 2008-06-20 | 2010-09-16 | Basf Se | Agrochemical formulations comprising a pesticide, an organic uv-photoprotective filter and coated metal-oxide nanoparticles |
| WO2011061133A2 (en) | 2009-11-18 | 2011-05-26 | Dsm Ip Assets B.V. | Topical compositions |
| US9125411B2 (en) | 2010-04-15 | 2015-09-08 | Basf Se | UV absorbers for reducing the E/Z isomerization of pesticides |
| WO2017211710A1 (en) | 2016-06-06 | 2017-12-14 | Huntsman P&A Germany Gmbh | Process for reducing the sulphur content of anatase titania and the so-obtained product |
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| WO2007065574A2 (en) | 2005-12-09 | 2007-06-14 | Dsm Ip Assets B.V. | Cosmetic or dermatological compositions comprising modified titanium dioxide particles |
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| WO2009153231A3 (en) * | 2008-06-20 | 2010-09-16 | Basf Se | Agrochemical formulations comprising a pesticide, an organic uv-photoprotective filter and coated metal-oxide nanoparticles |
| US8404263B2 (en) | 2008-06-20 | 2013-03-26 | Basf Se | Agrochemical formulations comprising a pesticide, an organic UV-photoprotective filter and coated metal-oxide nanoparticles |
| WO2010037463A1 (de) * | 2008-10-02 | 2010-04-08 | Merck Patent Gmbh, | Titandioxid-partikel |
| WO2011061133A2 (en) | 2009-11-18 | 2011-05-26 | Dsm Ip Assets B.V. | Topical compositions |
| US9125411B2 (en) | 2010-04-15 | 2015-09-08 | Basf Se | UV absorbers for reducing the E/Z isomerization of pesticides |
| WO2017211710A1 (en) | 2016-06-06 | 2017-12-14 | Huntsman P&A Germany Gmbh | Process for reducing the sulphur content of anatase titania and the so-obtained product |
| US11135570B2 (en) | 2016-06-06 | 2021-10-05 | Venator Germany Gmbh | Process for reducing the sulphur content of anatase titania and the so-obtained product |
| WO2022167197A1 (de) * | 2021-02-02 | 2022-08-11 | Beiersdorf Ag | Kosmetikum mit titandioxid in der wässrigen phase |
Also Published As
| Publication number | Publication date |
|---|---|
| TW200505495A (en) | 2005-02-16 |
| EP1660592B1 (de) | 2016-10-19 |
| ES2611128T3 (es) | 2017-05-05 |
| EP1660592A1 (de) | 2006-05-31 |
| JP4740845B2 (ja) | 2011-08-03 |
| CN100519666C (zh) | 2009-07-29 |
| WO2005019348A1 (de) | 2005-03-03 |
| CN1826389A (zh) | 2006-08-30 |
| US20090220441A1 (en) | 2009-09-03 |
| US8758501B2 (en) | 2014-06-24 |
| JP2006528706A (ja) | 2006-12-21 |
| US20060194057A1 (en) | 2006-08-31 |
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