ES2611128T3 - Agentes protectores en forma de nanopartículas contra UV con recubrimiento de dióxido de silicio - Google Patents
Agentes protectores en forma de nanopartículas contra UV con recubrimiento de dióxido de silicio Download PDFInfo
- Publication number
- ES2611128T3 ES2611128T3 ES04763094.2T ES04763094T ES2611128T3 ES 2611128 T3 ES2611128 T3 ES 2611128T3 ES 04763094 T ES04763094 T ES 04763094T ES 2611128 T3 ES2611128 T3 ES 2611128T3
- Authority
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- Spain
- Prior art keywords
- acid
- polyethylene glycol
- oil
- phase
- red
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 239000002105 nanoparticle Substances 0.000 title claims abstract description 44
- 239000000377 silicon dioxide Substances 0.000 title claims abstract description 30
- 235000012239 silicon dioxide Nutrition 0.000 title claims abstract description 28
- 239000003223 protective agent Substances 0.000 title claims abstract description 25
- 238000000576 coating method Methods 0.000 title claims abstract description 23
- 239000011248 coating agent Substances 0.000 title claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 claims abstract description 42
- 238000000034 method Methods 0.000 claims abstract description 31
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 29
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 29
- 238000010335 hydrothermal treatment Methods 0.000 claims abstract description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 195
- 239000004408 titanium dioxide Substances 0.000 claims description 84
- 239000000725 suspension Substances 0.000 claims description 12
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 7
- 238000003980 solgel method Methods 0.000 claims description 4
- 230000029219 regulation of pH Effects 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 abstract description 8
- -1 their coatings Substances 0.000 description 111
- 229920001223 polyethylene glycol Polymers 0.000 description 99
- 239000002202 Polyethylene glycol Substances 0.000 description 95
- 239000012071 phase Substances 0.000 description 90
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 84
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 82
- 239000000203 mixture Substances 0.000 description 80
- 238000002360 preparation method Methods 0.000 description 77
- 239000003921 oil Substances 0.000 description 73
- 235000019198 oils Nutrition 0.000 description 69
- 235000010215 titanium dioxide Nutrition 0.000 description 66
- 239000000049 pigment Substances 0.000 description 50
- 238000003756 stirring Methods 0.000 description 45
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 42
- 239000002253 acid Substances 0.000 description 38
- 239000000126 substance Substances 0.000 description 38
- 150000001875 compounds Chemical class 0.000 description 37
- 239000000047 product Substances 0.000 description 36
- NKEQOUMMGPBKMM-UHFFFAOYSA-N 2-hydroxy-2-[2-(2-hydroxy-3-octadecanoyloxypropoxy)-2-oxoethyl]butanedioic acid Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COC(=O)CC(O)(C(O)=O)CC(O)=O NKEQOUMMGPBKMM-UHFFFAOYSA-N 0.000 description 32
- 238000009472 formulation Methods 0.000 description 32
- 239000002537 cosmetic Substances 0.000 description 31
- NZZIMKJIVMHWJC-UHFFFAOYSA-N dibenzoylmethane Chemical class C=1C=CC=CC=1C(=O)CC(=O)C1=CC=CC=C1 NZZIMKJIVMHWJC-UHFFFAOYSA-N 0.000 description 31
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 30
- 239000000839 emulsion Substances 0.000 description 30
- 235000013772 propylene glycol Nutrition 0.000 description 29
- 229960004063 propylene glycol Drugs 0.000 description 29
- 239000004904 UV filter Substances 0.000 description 28
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 28
- 238000003860 storage Methods 0.000 description 27
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 25
- 235000014113 dietary fatty acids Nutrition 0.000 description 25
- 239000000194 fatty acid Substances 0.000 description 25
- 229930195729 fatty acid Natural products 0.000 description 25
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 25
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 24
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 24
- 239000011049 pearl Substances 0.000 description 23
- 210000003491 skin Anatomy 0.000 description 23
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- 239000001993 wax Substances 0.000 description 22
- 235000011187 glycerol Nutrition 0.000 description 21
- 230000037072 sun protection Effects 0.000 description 21
- WSSJONWNBBTCMG-UHFFFAOYSA-N 2-hydroxybenzoic acid (3,3,5-trimethylcyclohexyl) ester Chemical compound C1C(C)(C)CC(C)CC1OC(=O)C1=CC=CC=C1O WSSJONWNBBTCMG-UHFFFAOYSA-N 0.000 description 19
- 150000004665 fatty acids Chemical class 0.000 description 19
- 230000005855 radiation Effects 0.000 description 19
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 18
- 239000003995 emulsifying agent Substances 0.000 description 18
- 229940075529 glyceryl stearate Drugs 0.000 description 18
- 150000003254 radicals Chemical class 0.000 description 18
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 16
- 239000000499 gel Substances 0.000 description 16
- 239000006210 lotion Substances 0.000 description 16
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 description 16
- 239000000975 dye Substances 0.000 description 15
- 150000002148 esters Chemical class 0.000 description 15
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 14
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 14
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 14
- 229960002216 methylparaben Drugs 0.000 description 14
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 13
- WQXNXVUDBPYKBA-YFKPBYRVSA-N ectoine Chemical compound CC1=[NH+][C@H](C([O-])=O)CCN1 WQXNXVUDBPYKBA-YFKPBYRVSA-N 0.000 description 13
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 13
- 229940049964 oleate Drugs 0.000 description 13
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- 235000014692 zinc oxide Nutrition 0.000 description 13
- NLMKTBGFQGKQEV-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hexadecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO NLMKTBGFQGKQEV-UHFFFAOYSA-N 0.000 description 12
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- ZAKOWWREFLAJOT-UHFFFAOYSA-N d-alpha-Tocopheryl acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-UHFFFAOYSA-N 0.000 description 12
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 12
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical class CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 12
- 229960001679 octinoxate Drugs 0.000 description 12
- 239000002245 particle Substances 0.000 description 12
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 12
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 12
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 12
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- 239000002994 raw material Substances 0.000 description 12
- 229920006395 saturated elastomer Polymers 0.000 description 12
- 239000011787 zinc oxide Substances 0.000 description 12
- 208000002874 Acne Vulgaris Diseases 0.000 description 11
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 11
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 description 11
- 150000007513 acids Chemical class 0.000 description 11
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- FOYKKGHVWRFIBD-UHFFFAOYSA-N gamma-tocopherol acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 FOYKKGHVWRFIBD-UHFFFAOYSA-N 0.000 description 11
- 239000002932 luster Substances 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 11
- 239000011734 sodium Substances 0.000 description 11
- 229910052708 sodium Inorganic materials 0.000 description 11
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 10
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- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 9
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
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- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 239000011686 zinc sulphate Substances 0.000 description 1
- 235000009529 zinc sulphate Nutrition 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y5/00—Nanobiotechnology or nanomedicine, e.g. protein engineering or drug delivery
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3653—Treatment with inorganic compounds
- C09C1/3661—Coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
- C09C3/063—Coating
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/413—Nanosized, i.e. having sizes below 100 nm
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
- C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
- C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Crystallography & Structural Chemistry (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Organic Chemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Biotechnology (AREA)
- Materials Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Dispersion Chemistry (AREA)
- Composite Materials (AREA)
- Dermatology (AREA)
- Physics & Mathematics (AREA)
- Biophysics (AREA)
- General Physics & Mathematics (AREA)
- General Engineering & Computer Science (AREA)
- Medical Informatics (AREA)
- Medicinal Chemistry (AREA)
- Molecular Biology (AREA)
- Pharmacology & Pharmacy (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10333029 | 2003-07-21 | ||
| DE10333029A DE10333029A1 (de) | 2003-07-21 | 2003-07-21 | Nanopartikuläres UV-Schutzmittel |
| PCT/EP2004/007311 WO2005019348A1 (de) | 2003-07-21 | 2004-07-05 | Nanopartikuläres uv-schutzmittel mit siliciumdioxidbeschichtung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2611128T3 true ES2611128T3 (es) | 2017-05-05 |
Family
ID=34071799
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES04763094.2T Expired - Lifetime ES2611128T3 (es) | 2003-07-21 | 2004-07-05 | Agentes protectores en forma de nanopartículas contra UV con recubrimiento de dióxido de silicio |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US20060194057A1 (enExample) |
| EP (1) | EP1660592B1 (enExample) |
| JP (1) | JP4740845B2 (enExample) |
| CN (1) | CN100519666C (enExample) |
| DE (1) | DE10333029A1 (enExample) |
| ES (1) | ES2611128T3 (enExample) |
| TW (1) | TW200505495A (enExample) |
| WO (1) | WO2005019348A1 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004003000A1 (de) * | 2004-01-19 | 2005-08-04 | Beiersdorf Ag | Kosmetische und dermatologische Lichtschutzformulierungen |
| US20080318825A1 (en) * | 2004-11-24 | 2008-12-25 | The Proctor & Gamble Company | Hair Treatment Agent |
| DE102005007482A1 (de) * | 2005-02-17 | 2006-09-14 | Merck Patent Gmbh | Zubereitung enthaltend nanopartikuläres UV-Schutzmittel |
| US20090291107A1 (en) * | 2005-03-23 | 2009-11-26 | Volker Schehlmann | Chromophore Coated Metal Oxide Particles |
| DE102005026005A1 (de) * | 2005-06-03 | 2006-12-07 | Beiersdorf Ag | Kosmetische Zubereitungen mit einem Gehalt an einem besonderen Anisfruchtextrakt und bestimmten Emulgatoren |
| DE102005026035A1 (de) * | 2005-06-03 | 2006-12-07 | Beiersdorf Ag | Kosmetische Zubereitungen mit einem Gehalt an einem besonderen Anisfruchtextrakt und Füllstoffen |
| DE102005026006A1 (de) * | 2005-06-03 | 2006-12-07 | Beiersdorf Ag | Kosmetische Zubereitungen mit einem Gehalt an einem besonderen Anisfruchtextrakt und Triazin-Lichtfiltern |
| DE102005026007A1 (de) * | 2005-06-03 | 2006-12-07 | Beiersdorf Ag | Kosmetische Zubereitungen mit einem Gehalt an einem besonderen Anisfruchtextrakt und sulfonierten Lichtfiltern |
| EP1911437B1 (en) * | 2005-08-05 | 2010-07-14 | Shiseido Company, Limited | Self-tanning cosmetic |
| US20070098803A1 (en) * | 2005-10-27 | 2007-05-03 | Primet Precision Materials, Inc. | Small particle compositions and associated methods |
| US20080305133A1 (en) | 2005-12-09 | 2008-12-11 | Dsm Ip Assets B.V. | Novel Cosmetic or Dermatological Combinations Comprising Modified Titanium Dioxide Particles |
| DE102006025057A1 (de) * | 2006-05-24 | 2007-11-29 | Beiersdorf Ag | Kosmetische Lichtschutzzubereitung mit besonderer Textur |
| JP5207426B2 (ja) * | 2006-06-30 | 2013-06-12 | 学校法人神奈川大学 | 化粧料及びその製造方法 |
| US8512467B2 (en) | 2006-08-21 | 2013-08-20 | Air Products And Chemicals, Inc. | Zinc oxide nanoparticle dispersions |
| JP4581093B2 (ja) * | 2006-09-14 | 2010-11-17 | 国立大学法人 新潟大学 | 酸化チタンの製造法 |
| US20080081024A1 (en) * | 2006-10-02 | 2008-04-03 | Beasley Donathan G | Photoprotective compositions comprising synergistic combination of sunscreen active compounds |
| DE102007005186A1 (de) * | 2007-01-29 | 2008-07-31 | Merck Patent Gmbh | Partikuläres UV-Schutzmittel |
| US8580860B2 (en) * | 2007-02-23 | 2013-11-12 | Gojo Industries, Inc. | Foamable alcoholic composition |
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| EP2111851B1 (de) * | 2008-04-22 | 2011-06-15 | Azelis Deutschland Kosmetik GmbH | Emulgatorgemisch |
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| DE102008049955A1 (de) * | 2008-10-02 | 2010-04-08 | Merck Patent Gmbh | Titandioxid-Partikel |
| US8642991B2 (en) * | 2008-11-11 | 2014-02-04 | Samsung Electronics Co., Ltd. | Photosensitive quantum dot, composition comprising the same and method of forming quantum dot-containing pattern using the composition |
| JP5794755B2 (ja) * | 2009-05-21 | 2015-10-14 | 石原産業株式会社 | 赤外線反射材料及びその製造方法並びにそれを含有した塗料、樹脂組成物 |
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| GB2477931A (en) * | 2010-02-17 | 2011-08-24 | Tioxide Europe Ltd | A titanium dioxide-containing composition |
| US9125411B2 (en) | 2010-04-15 | 2015-09-08 | Basf Se | UV absorbers for reducing the E/Z isomerization of pesticides |
| US11116792B1 (en) * | 2010-12-22 | 2021-09-14 | Biocurity Holdings, Inc. | Cerium oxide nanoparticle formulation for use in skin radioprotection and associated methods |
| CN102391744B (zh) * | 2011-09-02 | 2013-07-10 | 张小勇 | 纳米隐形艺术品复制专用淋膜液及其制备方法 |
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| JP5942701B2 (ja) * | 2012-08-27 | 2016-06-29 | 住友大阪セメント株式会社 | 酸化亜鉛複合粉体及び酸化亜鉛複合粉体含有分散液並びに化粧料 |
| EP2705828B1 (de) | 2012-09-05 | 2018-02-14 | Deb IP Limited | Schnell einziehende, hautpflegende Softcreme |
| WO2016142026A1 (de) | 2015-03-06 | 2016-09-15 | Merck Patent Gmbh | Fluortenside in emulsionen |
| CZ306068B6 (cs) * | 2015-05-26 | 2016-07-20 | Precheza A.S. | Částice TiO2 s rutilovou strukturou pro použití jako UV absorbér |
| JP6689517B2 (ja) * | 2015-05-29 | 2020-04-28 | テイカ株式会社 | 油性分散体およびこの油性分散体を用いた乳化組成物並びにこの乳化組成物を用いた化粧料 |
| US11389536B2 (en) | 2015-07-17 | 2022-07-19 | BioCurity Pharmaceuticals Inc. | Treatment of cancer with a combination of radiation, cerium oxide nanoparticles, and a chemotherapeutic agent |
| FR3041528A1 (fr) | 2015-09-25 | 2017-03-31 | Rhodia Operations | Composition cosmetique photoprotectrice |
| EP3464184A1 (en) | 2016-06-06 | 2019-04-10 | Venator Germany GmbH | Process for reducing the sulphur content of anatase titania and the so-obtained product |
| US20170348671A1 (en) | 2016-06-06 | 2017-12-07 | Huntsman P&A Germany Gmbh | Process for reducing the sulphur content of anatase titania and the so-obtained product |
| EP3584221B1 (en) * | 2017-02-14 | 2024-10-16 | M. Technique Co., Ltd. | Silicon-doped metal oxide particles, and uv-absorbing composition containing silicon-doped metal oxide particles |
| JP6979644B2 (ja) * | 2017-08-30 | 2021-12-15 | 株式会社 ナチュラル | 紫外線遮蔽性化粧用組成物 |
| FR3074162A1 (fr) | 2017-11-24 | 2019-05-31 | Rhodia Operations | Particules d'oxyde de cerium / silice |
| CN109736075A (zh) * | 2018-12-28 | 2019-05-10 | 杭州蓝色倾情服饰有限公司 | 抗紫外线面料及其制作方法 |
| CN110255613B (zh) * | 2019-03-04 | 2022-02-15 | 厦门威亮光学涂层技术有限公司 | 一种金属氧化物溶胶及其制备方法 |
| EP4021988B1 (en) * | 2019-08-29 | 2023-08-09 | Société BIC | Process of preparation of an aqueous gel ink with fixed color comprising gold nanoparticles |
| CA3164397A1 (en) * | 2020-02-06 | 2021-11-11 | Seshagiri RAGHUKUMAR | Protection from ionizing radiation |
| CN111150677B (zh) * | 2020-02-25 | 2022-09-13 | 广州玮弘祺生物科技有限公司 | 一种防晒化妆品及其制备方法 |
| CN111847461A (zh) * | 2020-07-30 | 2020-10-30 | 山东联科科技股份有限公司 | 一种沉淀法二氧化硅制备新工艺 |
| DE102021200944A1 (de) * | 2021-02-02 | 2022-08-04 | Beiersdorf Aktiengesellschaft | Kosmetikum mit Titandioxid in der wässrigen Phase |
| CN113234336A (zh) * | 2021-05-18 | 2021-08-10 | 浙江天女集团制漆有限公司 | 一种无机复合紫外线吸收剂的制备方法 |
| CN114437566A (zh) * | 2022-03-03 | 2022-05-06 | 河南凌宝新材料科技有限公司 | 一种抗黄变珠光颜料及其制备方法 |
| EP4502085A1 (en) * | 2022-03-31 | 2025-02-05 | Titan Kogyo Kabushiki Kaisha | Powder of titanium(iv) oxide composed of particles having peanut-like twin shape, and cosmetic containing same |
| CN115721580A (zh) * | 2022-11-15 | 2023-03-03 | 清华大学深圳国际研究生院 | 具有金属氧化物微纳米片的防晒产品及其制备方法 |
| US20240287732A1 (en) | 2023-02-27 | 2024-08-29 | Ascend Performance Materials Operations Llc | Chem/bio fabric or layer with metal oxide content |
| FR3150107A1 (fr) | 2023-06-22 | 2024-12-27 | L'oreal | Utilisation d’un matériau composite d’oxycarbonate de bismuth et de composés inorganiques pour la filtration des rayonnements ultra-violets |
| CN117070120B (zh) * | 2023-06-30 | 2024-05-24 | 山东建筑大学 | 一种水性环氧防腐涂料及其涂覆方法 |
| CN119637887B (zh) * | 2023-09-18 | 2025-09-19 | 中国石油天然气股份有限公司 | 光化学改性高表面活性纳米球形二氧化硅及其制备方法 |
| CN118561284B (zh) * | 2024-06-13 | 2025-06-17 | 江西师范大学 | 生物还原硅砂除铁方法和系统 |
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| US2885366A (en) * | 1956-06-28 | 1959-05-05 | Du Pont | Product comprising a skin of dense, hydrated amorphous silica bound upon a core of another solid material and process of making same |
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| GB8908995D0 (en) | 1989-04-20 | 1989-06-07 | Tioxide Group Plc | Particulate material |
| US5180585A (en) * | 1991-08-09 | 1993-01-19 | E. I. Du Pont De Nemours And Company | Antimicrobial compositions, process for preparing the same and use |
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| JPH0675086A (ja) * | 1992-08-25 | 1994-03-18 | Toshiba Corp | インターナルポンプ用ロックスリーブの脱着機 |
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| WO1997015526A1 (en) * | 1995-10-27 | 1997-05-01 | E.I. Du Pont De Nemours And Company | Hydrothermal process for making ultrafine metal oxide powders |
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| ES2225366T3 (es) * | 2001-08-08 | 2005-03-16 | Degussa Aktiengesellschaft | Particulas de oxido metalico recubiertas con dioxido de silicio. |
| DE10260718A1 (de) | 2002-12-23 | 2004-07-08 | Degussa Ag | Mit Siliziumdioxid umhülltes Titandioxid |
| US20060210500A1 (en) * | 2003-04-18 | 2006-09-21 | Merck Patent Gmbh | Formulations |
-
2003
- 2003-07-21 DE DE10333029A patent/DE10333029A1/de not_active Withdrawn
-
2004
- 2004-06-24 TW TW093118249A patent/TW200505495A/zh unknown
- 2004-07-05 ES ES04763094.2T patent/ES2611128T3/es not_active Expired - Lifetime
- 2004-07-05 US US10/565,214 patent/US20060194057A1/en not_active Abandoned
- 2004-07-05 WO PCT/EP2004/007311 patent/WO2005019348A1/de not_active Ceased
- 2004-07-05 CN CNB2004800207603A patent/CN100519666C/zh not_active Expired - Lifetime
- 2004-07-05 EP EP04763094.2A patent/EP1660592B1/de not_active Expired - Lifetime
- 2004-07-05 JP JP2006520709A patent/JP4740845B2/ja not_active Expired - Lifetime
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2009
- 2009-04-30 US US12/432,949 patent/US8758501B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| TW200505495A (en) | 2005-02-16 |
| DE10333029A1 (de) | 2005-02-17 |
| US8758501B2 (en) | 2014-06-24 |
| JP4740845B2 (ja) | 2011-08-03 |
| EP1660592B1 (de) | 2016-10-19 |
| EP1660592A1 (de) | 2006-05-31 |
| US20060194057A1 (en) | 2006-08-31 |
| US20090220441A1 (en) | 2009-09-03 |
| CN100519666C (zh) | 2009-07-29 |
| WO2005019348A1 (de) | 2005-03-03 |
| JP2006528706A (ja) | 2006-12-21 |
| CN1826389A (zh) | 2006-08-30 |
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