DE10251135B4 - Verfahren zur katalytischen Dehydrierung von leichten Paraffinen zu Olefinen - Google Patents

Verfahren zur katalytischen Dehydrierung von leichten Paraffinen zu Olefinen Download PDF

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Publication number
DE10251135B4
DE10251135B4 DE10251135A DE10251135A DE10251135B4 DE 10251135 B4 DE10251135 B4 DE 10251135B4 DE 10251135 A DE10251135 A DE 10251135A DE 10251135 A DE10251135 A DE 10251135A DE 10251135 B4 DE10251135 B4 DE 10251135B4
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DE
Germany
Prior art keywords
stage
oxygen
catalyst
catalyst bed
reaction mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE10251135A
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German (de)
English (en)
Other versions
DE10251135A1 (de
Inventor
Natarajan Dr. Thiagarajan
Max Heinritz-Adrian
Sascha Wenzel
Johannes Menzel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp Industrial Solutions AG
Original Assignee
Uhde GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DE10251135A priority Critical patent/DE10251135B4/de
Application filed by Uhde GmbH filed Critical Uhde GmbH
Priority to DK03795802.2T priority patent/DK1562879T3/da
Priority to PCT/EP2003/011948 priority patent/WO2004039920A2/de
Priority to JP2004547584A priority patent/JP4526024B2/ja
Priority to ES03795802T priority patent/ES2336667T3/es
Priority to EP03795802A priority patent/EP1562879B1/de
Priority to DE50312216T priority patent/DE50312216D1/de
Priority to EA200500742A priority patent/EA008074B1/ru
Priority to AU2003298102A priority patent/AU2003298102A1/en
Priority to AT03795802T priority patent/ATE451343T1/de
Priority to US10/532,843 priority patent/US7816576B2/en
Publication of DE10251135A1 publication Critical patent/DE10251135A1/de
Priority to EGNA2005000176 priority patent/EG23804A/xx
Priority to IN771CH2005 priority patent/IN2005CH00771A/en
Priority to NO20052592A priority patent/NO337095B1/no
Application granted granted Critical
Publication of DE10251135B4 publication Critical patent/DE10251135B4/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56—Platinum group metals
    • C07C2523/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
DE10251135A 2002-10-31 2002-10-31 Verfahren zur katalytischen Dehydrierung von leichten Paraffinen zu Olefinen Expired - Lifetime DE10251135B4 (de)

Priority Applications (14)

Application Number Priority Date Filing Date Title
DE10251135A DE10251135B4 (de) 2002-10-31 2002-10-31 Verfahren zur katalytischen Dehydrierung von leichten Paraffinen zu Olefinen
US10/532,843 US7816576B2 (en) 2002-10-31 2003-10-28 Method for catalytically dehydrating hydrocarbons
JP2004547584A JP4526024B2 (ja) 2002-10-31 2003-10-28 炭化水素を接触的に脱水素化する方法
ES03795802T ES2336667T3 (es) 2002-10-31 2003-10-28 Procedimiento para el deshidrogenado catalitico de hidrocarburos.
EP03795802A EP1562879B1 (de) 2002-10-31 2003-10-28 Verfahren zur katalytischen dehydrierung von kohlenwasserstoffen
DE50312216T DE50312216D1 (de) 2002-10-31 2003-10-28 Verfahren zur katalytischen dehydrierung von kohlenwasserstoffen
EA200500742A EA008074B1 (ru) 2002-10-31 2003-10-28 Способ каталитического дегидрирования углеводородов
AU2003298102A AU2003298102A1 (en) 2002-10-31 2003-10-28 Method for catalytically dehydrating hydrocarbons
DK03795802.2T DK1562879T3 (da) 2002-10-31 2003-10-28 Fremgangsmåde til katalytisk dehydrering af carbonhydrider
PCT/EP2003/011948 WO2004039920A2 (de) 2002-10-31 2003-10-28 Verfahren zur katalytischen dehydrierung von kohlenwasserstoffen
AT03795802T ATE451343T1 (de) 2002-10-31 2003-10-28 Verfahren zur katalytischen dehydrierung von kohlenwasserstoffen
EGNA2005000176 EG23804A (en) 2002-10-31 2005-04-28 Method for catalytically dehydrating hydrocarbons
IN771CH2005 IN2005CH00771A (en) 2002-10-31 2005-04-28 Method for catalytically dehydrating hydrocarbons
NO20052592A NO337095B1 (no) 2002-10-31 2005-05-30 Fremgangsmåte for fremstilling av umettede hydrokarboner

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10251135A DE10251135B4 (de) 2002-10-31 2002-10-31 Verfahren zur katalytischen Dehydrierung von leichten Paraffinen zu Olefinen

Publications (2)

Publication Number Publication Date
DE10251135A1 DE10251135A1 (de) 2004-05-19
DE10251135B4 true DE10251135B4 (de) 2006-07-27

Family

ID=32115153

Family Applications (2)

Application Number Title Priority Date Filing Date
DE10251135A Expired - Lifetime DE10251135B4 (de) 2002-10-31 2002-10-31 Verfahren zur katalytischen Dehydrierung von leichten Paraffinen zu Olefinen
DE50312216T Expired - Lifetime DE50312216D1 (de) 2002-10-31 2003-10-28 Verfahren zur katalytischen dehydrierung von kohlenwasserstoffen

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE50312216T Expired - Lifetime DE50312216D1 (de) 2002-10-31 2003-10-28 Verfahren zur katalytischen dehydrierung von kohlenwasserstoffen

Country Status (13)

Country Link
US (1) US7816576B2 (enExample)
EP (1) EP1562879B1 (enExample)
JP (1) JP4526024B2 (enExample)
AT (1) ATE451343T1 (enExample)
AU (1) AU2003298102A1 (enExample)
DE (2) DE10251135B4 (enExample)
DK (1) DK1562879T3 (enExample)
EA (1) EA008074B1 (enExample)
EG (1) EG23804A (enExample)
ES (1) ES2336667T3 (enExample)
IN (1) IN2005CH00771A (enExample)
NO (1) NO337095B1 (enExample)
WO (1) WO2004039920A2 (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004054657A1 (de) 2004-11-11 2006-05-18 Uhde Gmbh Verfahren zur katalytischen Dehydrierung von Propan zu Propylen
US8239171B2 (en) * 2006-02-28 2012-08-07 Panalytique Inc. System and method of eliminating interference for impurities measurement in noble gases
DE102006035718A1 (de) 2006-07-28 2008-01-31 Basf Ag Verfahren zum Langzeitbetrieb einer kontinuierlich betriebenen heterogen katalysierten partiellen Dehydrierung eines zu dehydrierenden Kohlenwasserstoffs
US20080177117A1 (en) * 2006-10-16 2008-07-24 Abraham Benderly Integrated catalytic process for converting alkanes to alkenes and catalysts useful for same
DE102007036750A1 (de) * 2007-08-03 2009-02-05 Uhde Gmbh Regeneration von Katalysatoren zur Dehydrierung von Alkanen
DE102008036724A1 (de) * 2008-08-07 2010-02-11 Uhde Gmbh Hochporöse Schaumkeramiken als Katalysatorträger zur Dehydrierung von Alkanen
WO2010069548A1 (de) * 2008-12-18 2010-06-24 Uhde Gmbh Variation der zinnimprägnierung eines katalysators zur alkandehydrierung
DE102009012663B3 (de) * 2009-03-13 2010-09-16 Uhde Gmbh Verfahren und Vorrichtung zur gleichmäßigen Dampferzeugung aus der Abwärme einer Alkandehydrierung
DE102009034464A1 (de) * 2009-07-22 2011-08-18 Uhde GmbH, 44141 Verfahren und Vorrichtung zur Dehydrierung von Alkanen mit einer Vergleichmäßigung der Produktzusammensetzung
US20160090337A1 (en) * 2014-09-30 2016-03-31 Uop Llc Paraffin dehydrogenation with oxidative reheat
US9914678B2 (en) 2015-11-04 2018-03-13 Exxonmobil Chemical Patents Inc. Fired tube conversion system and process
DE102015121037A1 (de) 2015-12-03 2017-06-08 Thyssenkrupp Ag Vorrichtung zur Sauerstoffverteilung in einem Oxidationsreaktor, Oxidationsreaktor und Anlage mit einer solchen Vorrichtung und Betriebsverfahren
CN108473389A (zh) * 2016-01-21 2018-08-31 沙特基础全球技术有限公司 通过丙烷脱氢生产丙烯的方法
BR112019012126B1 (pt) * 2016-12-19 2022-11-16 Shell Internationale Research Maatschappij B.V. Processo integrado, e, sistema de reação

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5235121A (en) * 1991-08-02 1993-08-10 Phillips Petroleum Company Method for reforming hydrocarbons
DE19858747A1 (de) * 1998-12-18 2000-06-21 Linde Ag Verfahren und Katalysatorstation zur Dehydrierung von Alkanen

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3972954A (en) * 1972-02-14 1976-08-03 Phillips Petroleum Company Process for oxidative dehydrogenation
US4599471A (en) * 1985-09-16 1986-07-08 Uop Inc. Method for oxygen addition to oxidative reheat zone of hydrocarbon dehydrogenation process
US4739124A (en) 1985-09-16 1988-04-19 Uop Inc. Method for oxygen addition to oxidative reheat zone of ethane dehydrogenation process
US4827066A (en) * 1988-05-23 1989-05-02 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons
US4886928A (en) 1988-09-26 1989-12-12 Uop Hydrocarbon dehydrogenation process
US5321192A (en) * 1992-12-11 1994-06-14 Uop Dehydrogenation process
US5527979A (en) 1993-08-27 1996-06-18 Mobil Oil Corporation Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen
DK171414B1 (da) * 1993-11-30 1996-10-21 Topsoe Haldor As Fremgangsmåde til carbonhydrid dehydrogenering
NO300117B1 (no) 1994-12-22 1997-04-14 Norske Stats Oljeselskap Reaktor for dehydrogenering av hydrokarboner med selektiv oksidasjon av hydrogen

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5235121A (en) * 1991-08-02 1993-08-10 Phillips Petroleum Company Method for reforming hydrocarbons
DE19858747A1 (de) * 1998-12-18 2000-06-21 Linde Ag Verfahren und Katalysatorstation zur Dehydrierung von Alkanen

Also Published As

Publication number Publication date
US20060122448A1 (en) 2006-06-08
JP4526024B2 (ja) 2010-08-18
IN224533B (enExample) 2008-12-05
DK1562879T3 (da) 2010-04-26
EG23804A (en) 2007-08-28
EP1562879B1 (de) 2009-12-09
DE10251135A1 (de) 2004-05-19
WO2004039920A3 (de) 2004-06-24
EP1562879A2 (de) 2005-08-17
AU2003298102A1 (en) 2004-05-25
WO2004039920A2 (de) 2004-05-13
ATE451343T1 (de) 2009-12-15
NO20052592L (no) 2005-05-30
EA008074B1 (ru) 2007-02-27
DE50312216D1 (de) 2010-01-21
EA200500742A1 (ru) 2005-08-25
NO337095B1 (no) 2016-01-18
IN2005CH00771A (en) 2007-08-17
JP2006504762A (ja) 2006-02-09
US7816576B2 (en) 2010-10-19
ES2336667T3 (es) 2010-04-15
AU2003298102A8 (en) 2004-05-25

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8364 No opposition during term of opposition
R081 Change of applicant/patentee

Owner name: THYSSENKRUPP INDUSTRIAL SOLUTIONS AG, DE

Free format text: FORMER OWNER: UHDE GMBH, 44141 DORTMUND, DE

R081 Change of applicant/patentee

Owner name: THYSSENKRUPP INDUSTRIAL SOLUTIONS AG, DE

Free format text: FORMER OWNER: THYSSENKRUPP INDUSTRIAL SOLUTIONS AG, 45143 ESSEN, DE

R071 Expiry of right