EA008074B1 - Способ каталитического дегидрирования углеводородов - Google Patents
Способ каталитического дегидрирования углеводородов Download PDFInfo
- Publication number
- EA008074B1 EA008074B1 EA200500742A EA200500742A EA008074B1 EA 008074 B1 EA008074 B1 EA 008074B1 EA 200500742 A EA200500742 A EA 200500742A EA 200500742 A EA200500742 A EA 200500742A EA 008074 B1 EA008074 B1 EA 008074B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- stage
- catalyst
- dehydrogenation
- oxygen
- reaction mixture
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 34
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 21
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 21
- 239000003054 catalyst Substances 0.000 claims abstract description 67
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000001301 oxygen Substances 0.000 claims abstract description 31
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 31
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000000203 mixture Substances 0.000 claims abstract description 27
- 239000001257 hydrogen Substances 0.000 claims abstract description 21
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 21
- 239000007789 gas Substances 0.000 claims abstract description 18
- 239000011541 reaction mixture Substances 0.000 claims abstract description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 6
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 5
- 238000010438 heat treatment Methods 0.000 claims abstract description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 3
- 230000001105 regulatory effect Effects 0.000 claims abstract 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims abstract 2
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 49
- 238000001816 cooling Methods 0.000 claims description 15
- 230000003647 oxidation Effects 0.000 claims description 12
- 238000007254 oxidation reaction Methods 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 12
- 150000002431 hydrogen Chemical class 0.000 claims description 9
- 150000004645 aluminates Chemical class 0.000 claims description 4
- 230000000694 effects Effects 0.000 claims description 4
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- 230000018044 dehydration Effects 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 19
- 239000000047 product Substances 0.000 description 15
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 12
- 239000001294 propane Substances 0.000 description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000008929 regeneration Effects 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 206010067484 Adverse reaction Diseases 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000006838 adverse reaction Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/42—Platinum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/56—Platinum group metals
- C07C2523/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10251135A DE10251135B4 (de) | 2002-10-31 | 2002-10-31 | Verfahren zur katalytischen Dehydrierung von leichten Paraffinen zu Olefinen |
| PCT/EP2003/011948 WO2004039920A2 (de) | 2002-10-31 | 2003-10-28 | Verfahren zur katalytischen dehydrierung von kohlenwasserstoffen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA200500742A1 EA200500742A1 (ru) | 2005-08-25 |
| EA008074B1 true EA008074B1 (ru) | 2007-02-27 |
Family
ID=32115153
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA200500742A EA008074B1 (ru) | 2002-10-31 | 2003-10-28 | Способ каталитического дегидрирования углеводородов |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7816576B2 (enExample) |
| EP (1) | EP1562879B1 (enExample) |
| JP (1) | JP4526024B2 (enExample) |
| AT (1) | ATE451343T1 (enExample) |
| AU (1) | AU2003298102A1 (enExample) |
| DE (2) | DE10251135B4 (enExample) |
| DK (1) | DK1562879T3 (enExample) |
| EA (1) | EA008074B1 (enExample) |
| EG (1) | EG23804A (enExample) |
| ES (1) | ES2336667T3 (enExample) |
| IN (1) | IN2005CH00771A (enExample) |
| NO (1) | NO337095B1 (enExample) |
| WO (1) | WO2004039920A2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2486007C2 (ru) * | 2008-08-07 | 2013-06-27 | Уде Гмбх | Высокопористые пенокерамики как носители катализатора для дегидрирования алканов |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004054657A1 (de) | 2004-11-11 | 2006-05-18 | Uhde Gmbh | Verfahren zur katalytischen Dehydrierung von Propan zu Propylen |
| EP1989533B1 (en) * | 2006-02-28 | 2014-10-22 | Servomex Group Limited | System and method of eliminating interference for impurities measurement in noble gases |
| DE102006035718A1 (de) | 2006-07-28 | 2008-01-31 | Basf Ag | Verfahren zum Langzeitbetrieb einer kontinuierlich betriebenen heterogen katalysierten partiellen Dehydrierung eines zu dehydrierenden Kohlenwasserstoffs |
| US20080177117A1 (en) * | 2006-10-16 | 2008-07-24 | Abraham Benderly | Integrated catalytic process for converting alkanes to alkenes and catalysts useful for same |
| DE102007036750A1 (de) * | 2007-08-03 | 2009-02-05 | Uhde Gmbh | Regeneration von Katalysatoren zur Dehydrierung von Alkanen |
| KR20110097953A (ko) * | 2008-12-18 | 2011-08-31 | 우데 게엠베하 | 알칸의 탈수소화를 위한 촉매의 주석 함침에 대한 변형 |
| DE102009012663B3 (de) * | 2009-03-13 | 2010-09-16 | Uhde Gmbh | Verfahren und Vorrichtung zur gleichmäßigen Dampferzeugung aus der Abwärme einer Alkandehydrierung |
| DE102009034464A1 (de) * | 2009-07-22 | 2011-08-18 | Uhde GmbH, 44141 | Verfahren und Vorrichtung zur Dehydrierung von Alkanen mit einer Vergleichmäßigung der Produktzusammensetzung |
| US20160090337A1 (en) * | 2014-09-30 | 2016-03-31 | Uop Llc | Paraffin dehydrogenation with oxidative reheat |
| US9926242B2 (en) | 2015-11-04 | 2018-03-27 | Exxonmobil Chemical Patents Inc. | Integrated gas turbine and conversion system process |
| DE102015121037A1 (de) | 2015-12-03 | 2017-06-08 | Thyssenkrupp Ag | Vorrichtung zur Sauerstoffverteilung in einem Oxidationsreaktor, Oxidationsreaktor und Anlage mit einer solchen Vorrichtung und Betriebsverfahren |
| EP3405449B1 (en) * | 2016-01-21 | 2020-11-25 | SABIC Global Technologies B.V. | Methods for producing propylene by the dehydrogenation of propane |
| MX2019006874A (es) * | 2016-12-19 | 2019-08-22 | Shell Int Research | Deshidrogenacion oxidativa de etano con coproduccion de acetato de vinilo. |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4599471A (en) * | 1985-09-16 | 1986-07-08 | Uop Inc. | Method for oxygen addition to oxidative reheat zone of hydrocarbon dehydrogenation process |
| US4886928A (en) * | 1988-09-26 | 1989-12-12 | Uop | Hydrocarbon dehydrogenation process |
| WO1996019424A1 (en) * | 1994-12-22 | 1996-06-27 | Den Norske Stats Oljeselskap A.S | A reactor for catalytic dehydrogenation of hydrocarbons with selective oxidation of hydrogen |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3972954A (en) * | 1972-02-14 | 1976-08-03 | Phillips Petroleum Company | Process for oxidative dehydrogenation |
| US4739124A (en) * | 1985-09-16 | 1988-04-19 | Uop Inc. | Method for oxygen addition to oxidative reheat zone of ethane dehydrogenation process |
| US4827066A (en) * | 1988-05-23 | 1989-05-02 | Uop Inc. | Dehydrogenation of dehydrogenatable hydrocarbons |
| US5235121A (en) * | 1991-08-02 | 1993-08-10 | Phillips Petroleum Company | Method for reforming hydrocarbons |
| US5321192A (en) * | 1992-12-11 | 1994-06-14 | Uop | Dehydrogenation process |
| US5527979A (en) * | 1993-08-27 | 1996-06-18 | Mobil Oil Corporation | Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen |
| DK171414B1 (da) * | 1993-11-30 | 1996-10-21 | Topsoe Haldor As | Fremgangsmåde til carbonhydrid dehydrogenering |
| DE19858747A1 (de) * | 1998-12-18 | 2000-06-21 | Linde Ag | Verfahren und Katalysatorstation zur Dehydrierung von Alkanen |
-
2002
- 2002-10-31 DE DE10251135A patent/DE10251135B4/de not_active Expired - Lifetime
-
2003
- 2003-10-28 DE DE50312216T patent/DE50312216D1/de not_active Expired - Lifetime
- 2003-10-28 WO PCT/EP2003/011948 patent/WO2004039920A2/de not_active Ceased
- 2003-10-28 AT AT03795802T patent/ATE451343T1/de not_active IP Right Cessation
- 2003-10-28 EA EA200500742A patent/EA008074B1/ru not_active IP Right Cessation
- 2003-10-28 EP EP03795802A patent/EP1562879B1/de not_active Expired - Lifetime
- 2003-10-28 JP JP2004547584A patent/JP4526024B2/ja not_active Expired - Fee Related
- 2003-10-28 ES ES03795802T patent/ES2336667T3/es not_active Expired - Lifetime
- 2003-10-28 AU AU2003298102A patent/AU2003298102A1/en not_active Abandoned
- 2003-10-28 US US10/532,843 patent/US7816576B2/en not_active Expired - Lifetime
- 2003-10-28 DK DK03795802.2T patent/DK1562879T3/da active
-
2005
- 2005-04-28 EG EGNA2005000176 patent/EG23804A/xx active
- 2005-04-28 IN IN771CH2005 patent/IN2005CH00771A/en unknown
- 2005-05-30 NO NO20052592A patent/NO337095B1/no not_active IP Right Cessation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4599471A (en) * | 1985-09-16 | 1986-07-08 | Uop Inc. | Method for oxygen addition to oxidative reheat zone of hydrocarbon dehydrogenation process |
| US4886928A (en) * | 1988-09-26 | 1989-12-12 | Uop | Hydrocarbon dehydrogenation process |
| WO1996019424A1 (en) * | 1994-12-22 | 1996-06-27 | Den Norske Stats Oljeselskap A.S | A reactor for catalytic dehydrogenation of hydrocarbons with selective oxidation of hydrogen |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2486007C2 (ru) * | 2008-08-07 | 2013-06-27 | Уде Гмбх | Высокопористые пенокерамики как носители катализатора для дегидрирования алканов |
Also Published As
| Publication number | Publication date |
|---|---|
| DE10251135B4 (de) | 2006-07-27 |
| ES2336667T3 (es) | 2010-04-15 |
| WO2004039920A2 (de) | 2004-05-13 |
| JP2006504762A (ja) | 2006-02-09 |
| AU2003298102A8 (en) | 2004-05-25 |
| DE50312216D1 (de) | 2010-01-21 |
| ATE451343T1 (de) | 2009-12-15 |
| NO337095B1 (no) | 2016-01-18 |
| DK1562879T3 (da) | 2010-04-26 |
| AU2003298102A1 (en) | 2004-05-25 |
| NO20052592L (no) | 2005-05-30 |
| EP1562879A2 (de) | 2005-08-17 |
| IN224533B (enExample) | 2008-12-05 |
| DE10251135A1 (de) | 2004-05-19 |
| WO2004039920A3 (de) | 2004-06-24 |
| US7816576B2 (en) | 2010-10-19 |
| US20060122448A1 (en) | 2006-06-08 |
| EA200500742A1 (ru) | 2005-08-25 |
| EP1562879B1 (de) | 2009-12-09 |
| IN2005CH00771A (en) | 2007-08-17 |
| EG23804A (en) | 2007-08-28 |
| JP4526024B2 (ja) | 2010-08-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AZ KZ TM RU |