DE102011086451A1 - Methanolsynthesekatalysator auf basis von kupfer, zink und aluminium - Google Patents

Methanolsynthesekatalysator auf basis von kupfer, zink und aluminium Download PDF

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Publication number
DE102011086451A1
DE102011086451A1 DE102011086451A DE102011086451A DE102011086451A1 DE 102011086451 A1 DE102011086451 A1 DE 102011086451A1 DE 102011086451 A DE102011086451 A DE 102011086451A DE 102011086451 A DE102011086451 A DE 102011086451A DE 102011086451 A1 DE102011086451 A1 DE 102011086451A1
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DE
Germany
Prior art keywords
catalyst
catalyst precursor
precursor material
copper
aluminum
Prior art date
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Withdrawn
Application number
DE102011086451A
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German (de)
English (en)
Inventor
Dr. Kniep Benjamin
Martin Hieke
Dr. Kurr Patrick
Malte Behrens
Dr. Schlögel Robert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clariant Produkte Deutschland GmbH
Original Assignee
Sued Chemie IP GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sued Chemie IP GmbH and Co KG filed Critical Sued Chemie IP GmbH and Co KG
Priority to DE102011086451A priority Critical patent/DE102011086451A1/de
Priority to EP12783572.6A priority patent/EP2780110A1/en
Priority to CN201280064200.2A priority patent/CN104039444A/zh
Priority to PCT/EP2012/071581 priority patent/WO2013072197A1/en
Priority to IN985KON2014 priority patent/IN2014KN00985A/en
Priority to RU2014123678/04A priority patent/RU2014123678A/ru
Priority to JP2014541598A priority patent/JP2015502248A/ja
Publication of DE102011086451A1 publication Critical patent/DE102011086451A1/de
Withdrawn legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/392—Metal surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
DE102011086451A 2011-11-16 2011-11-16 Methanolsynthesekatalysator auf basis von kupfer, zink und aluminium Withdrawn DE102011086451A1 (de)

Priority Applications (7)

Application Number Priority Date Filing Date Title
DE102011086451A DE102011086451A1 (de) 2011-11-16 2011-11-16 Methanolsynthesekatalysator auf basis von kupfer, zink und aluminium
EP12783572.6A EP2780110A1 (en) 2011-11-16 2012-10-31 Methanol synthesis catalyst on the basis of copper, zinc and aluminum
CN201280064200.2A CN104039444A (zh) 2011-11-16 2012-10-31 基于铜、锌和铝的甲醇合成催化剂
PCT/EP2012/071581 WO2013072197A1 (en) 2011-11-16 2012-10-31 Methanol synthesis catalyst on the basis of copper, zinc and aluminum
IN985KON2014 IN2014KN00985A (ja) 2011-11-16 2012-10-31
RU2014123678/04A RU2014123678A (ru) 2011-11-16 2012-10-31 Катализатор синтеза метанола на основе меди, цинка и алюминия
JP2014541598A JP2015502248A (ja) 2011-11-16 2012-10-31 銅、亜鉛及びアルミニウムをベースとするメタノール合成触媒

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102011086451A DE102011086451A1 (de) 2011-11-16 2011-11-16 Methanolsynthesekatalysator auf basis von kupfer, zink und aluminium

Publications (1)

Publication Number Publication Date
DE102011086451A1 true DE102011086451A1 (de) 2013-05-16

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DE102011086451A Withdrawn DE102011086451A1 (de) 2011-11-16 2011-11-16 Methanolsynthesekatalysator auf basis von kupfer, zink und aluminium

Country Status (7)

Country Link
EP (1) EP2780110A1 (ja)
JP (1) JP2015502248A (ja)
CN (1) CN104039444A (ja)
DE (1) DE102011086451A1 (ja)
IN (1) IN2014KN00985A (ja)
RU (1) RU2014123678A (ja)
WO (1) WO2013072197A1 (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015144548A1 (de) * 2014-03-26 2015-10-01 Clariant International Ltd Hydrierkatalysator und verfahren zu dessen herstellung
US10035137B2 (en) 2012-09-28 2018-07-31 Clariant International Ltd. Hydrogenation catalyst and process for production thereof by the use of uncalcined starting material
CN112023962A (zh) * 2019-06-03 2020-12-04 国家能源投资集团有限责任公司 用于甲醇合成的催化剂及其制备方法以及合成甲醇的方法

Families Citing this family (14)

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Publication number Priority date Publication date Assignee Title
WO2015070298A1 (pt) * 2013-11-12 2015-05-21 Petróleo Brasileiro S.A. - Petrobras Catalisador para processo de reforma à vapor a baixa temperatura
EP3208258A1 (en) * 2016-02-16 2017-08-23 Fundació Privada Institut Català d'Investigació Química (ICIQ) Methanol production process
US10087355B2 (en) 2016-03-17 2018-10-02 Saudi Arabian Oil Company Oil-based drilling fluids containing an alkaline-earth diamondoid compound as rheology modifier
US10252245B2 (en) 2016-03-17 2019-04-09 Saudi Arabian Oil Company High temperature layered mixed-metal oxide materials with enhanced stability
JP6674068B2 (ja) 2016-03-17 2020-04-01 サウジ アラビアン オイル カンパニーＳａｕｄｉ Ａｒａｂｉａｎ Ｏｉｌ Ｃｏｍｐａｎｙ 遷移金属アダマンタンカルボン酸塩及び酸化物ナノ複合材料の合成
US10138199B2 (en) 2016-03-17 2018-11-27 Saudi Arabian Oil Company High aspect ratio layered double hydroxide materials and methods for preparation thereof
US10106482B2 (en) 2016-03-17 2018-10-23 Saudi Arabian Oil Company Synthesis of magnesium adamantane salts and magnesium oxide nanocomposites, and systems and methods including the salts or the nanocomposites
DE102016225171A1 (de) 2016-12-15 2018-06-21 Clariant International Ltd Tablettierter Katalysator für die Methanolsynthese mit erhöhter mechanischer Stabilität
GB201703558D0 (en) 2017-03-06 2017-04-19 Univ Oxford Innovation Ltd catalysts
US10875092B2 (en) 2017-05-19 2020-12-29 Saudi Arabian Oil Company Methods for preparing mixed-metal oxide diamondoid nanocomposites and catalytic systems including the nanocomposites
JP2020520880A (ja) 2017-05-19 2020-07-16 サウジ アラビアン オイル カンパニーＳａｕｄｉ Ａｒａｂｉａｎ Ｏｉｌ Ｃｏｍｐａｎｙ 遷移金属アダマンタン塩および酸化物ナノ複合体の合成
EP4251316A1 (en) * 2020-11-24 2023-10-04 Topsoe A/S Process and catalyst for the catalytic hydrogenation of organic carbonyl compounds
CN116848065A (zh) * 2022-01-14 2023-10-03 世拓拉斯控股公司 含锌水滑石
CN114660256B (zh) * 2022-04-02 2024-01-05 昆明理工大学 一种铜锌催化剂中各价态铜含量的测定方法

Citations (11)

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GB1010871A (en) 1962-08-24 1965-11-24 Ici Ltd Water-gas conversion and catalysts therefor
GB1159035A (en) 1965-08-18 1969-07-23 Ici Ltd Methanol Synthesis.
GB1296211A (ja) 1969-01-27 1972-11-15
US3850850A (en) 1972-01-21 1974-11-26 Ici Ltd Method of making a methanol synthesis catalyst
US3923694A (en) 1969-03-04 1975-12-02 Ici Ltd Methanol synthesis catalyst
US4279781A (en) 1979-10-09 1981-07-21 United Catalysts Inc. Catalyst for the synthesis of methanol
US4353071A (en) 1981-04-28 1982-10-05 Fairchild Industries, Inc. Self-erecting floatable structure
EP0125689A2 (de) 1983-05-16 1984-11-21 Süd-Chemie Ag Katalysator für die Methanolsynthese
US4598061A (en) 1984-02-02 1986-07-01 Sud-Chemie Aktiengesellschaft Catalyst for the synthesis of methanol and alcohol mixtures containing higher alcohols and method of making the catalyst
EP0522669A2 (en) 1989-10-17 1993-01-13 Engelhard Corporation Process for preparing hydrogenation catalysts
DE10160486A1 (de) 2001-12-08 2003-06-12 Sued Chemie Ag Katalysator für die Methanolsynthese

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GB1159035A (en) 1965-08-18 1969-07-23 Ici Ltd Methanol Synthesis.
GB1296211A (ja) 1969-01-27 1972-11-15
US3923694A (en) 1969-03-04 1975-12-02 Ici Ltd Methanol synthesis catalyst
US3850850A (en) 1972-01-21 1974-11-26 Ici Ltd Method of making a methanol synthesis catalyst
US4279781A (en) 1979-10-09 1981-07-21 United Catalysts Inc. Catalyst for the synthesis of methanol
US4353071A (en) 1981-04-28 1982-10-05 Fairchild Industries, Inc. Self-erecting floatable structure
EP0125689A2 (de) 1983-05-16 1984-11-21 Süd-Chemie Ag Katalysator für die Methanolsynthese
US4598061A (en) 1984-02-02 1986-07-01 Sud-Chemie Aktiengesellschaft Catalyst for the synthesis of methanol and alcohol mixtures containing higher alcohols and method of making the catalyst
EP0522669A2 (en) 1989-10-17 1993-01-13 Engelhard Corporation Process for preparing hydrogenation catalysts
DE10160486A1 (de) 2001-12-08 2003-06-12 Sued Chemie Ag Katalysator für die Methanolsynthese

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10035137B2 (en) 2012-09-28 2018-07-31 Clariant International Ltd. Hydrogenation catalyst and process for production thereof by the use of uncalcined starting material
WO2015144548A1 (de) * 2014-03-26 2015-10-01 Clariant International Ltd Hydrierkatalysator und verfahren zu dessen herstellung
GB2543162A (en) * 2014-03-26 2017-04-12 Clariant Int Ltd Hydrogenation catalyst and method for producing same
US10226760B2 (en) 2014-03-26 2019-03-12 Clariant International Ltd. Hydrogenation catalyst and method for producing same
GB2543162B (en) * 2014-03-26 2020-07-22 Clariant Int Ltd Hydrogenation catalyst and method for producing same
CN112023962A (zh) * 2019-06-03 2020-12-04 国家能源投资集团有限责任公司 用于甲醇合成的催化剂及其制备方法以及合成甲醇的方法
CN112023962B (zh) * 2019-06-03 2023-10-03 国家能源投资集团有限责任公司 用于甲醇合成的催化剂及其制备方法以及合成甲醇的方法

Also Published As

Publication number Publication date
JP2015502248A (ja) 2015-01-22
CN104039444A (zh) 2014-09-10
WO2013072197A1 (en) 2013-05-23
IN2014KN00985A (ja) 2015-10-09
EP2780110A1 (en) 2014-09-24
RU2014123678A (ru) 2015-12-27

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