IN2014KN00985A - - Google Patents

Info

Publication number
IN2014KN00985A
IN2014KN00985A IN985KON2014A IN2014KN00985A IN 2014KN00985 A IN2014KN00985 A IN 2014KN00985A IN 985KON2014 A IN985KON2014 A IN 985KON2014A IN 2014KN00985 A IN2014KN00985 A IN 2014KN00985A
Authority
IN
India
Prior art keywords
catalyst
carbonates
oxides
aluminum
homogeneous phase
Prior art date
Application number
Inventor
Malte Behrens
Benjamin Kniep
Patrick Kurr
Robert Schlögl
Martin Hieke
Original Assignee
Clariant Produkte Deutschland
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant Produkte Deutschland filed Critical Clariant Produkte Deutschland
Publication of IN2014KN00985A publication Critical patent/IN2014KN00985A/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/392—Metal surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The present invention relates to a catalyst precursor material comprising oxides and carbonates of copper zinc and aluminium wherein Cu and En are present together in a greater molar amount than aluminum and said carbonates and oxides form a homogeneous phase as well as the catalyst material resulting from the reduction of this precursor. The catalyst material comprises discrete crystalline Cu particles partly embedded in a continuous homogeneous phase comprising oxides and carbonates of at least Zn and Al wherein in said catalyst material Cu and Zn are present together in a greater molar amount than aluminum and preferably the molar ratio of Cu and Zn is 0 5/1 to less than 2.8/1 and the Al content is 1 to 30 ¾ by mol based on all metal constituents. The invention also pertains to a specific method of making this catalyst. The catalyst shows an excellent performance and stability in the synthesis of methanol from synthesis gas.
IN985KON2014 2011-11-16 2012-10-31 IN2014KN00985A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102011086451A DE102011086451A1 (en) 2011-11-16 2011-11-16 METHANOL SYNTHESIS CATALYST BASED ON COPPER, ZINC AND ALUMINUM
PCT/EP2012/071581 WO2013072197A1 (en) 2011-11-16 2012-10-31 Methanol synthesis catalyst on the basis of copper, zinc and aluminum

Publications (1)

Publication Number Publication Date
IN2014KN00985A true IN2014KN00985A (en) 2015-10-09

Family

ID=47146375

Family Applications (1)

Application Number Title Priority Date Filing Date
IN985KON2014 IN2014KN00985A (en) 2011-11-16 2012-10-31

Country Status (7)

Country Link
EP (1) EP2780110A1 (en)
JP (1) JP2015502248A (en)
CN (1) CN104039444A (en)
DE (1) DE102011086451A1 (en)
IN (1) IN2014KN00985A (en)
RU (1) RU2014123678A (en)
WO (1) WO2013072197A1 (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012019123B4 (en) 2012-09-28 2021-10-21 Clariant International Ltd. Hydrogenation catalyst and process for its preparation using uncalcined starting material
WO2015070298A1 (en) * 2013-11-12 2015-05-21 Petróleo Brasileiro S.A. - Petrobras Catalyst for low-temperature steam reforming processes
DE102014004413A1 (en) * 2014-03-26 2015-10-01 Clariant International Ltd. Hydrogenation catalyst and process for its preparation
EP3208258A1 (en) * 2016-02-16 2017-08-23 Fundació Privada Institut Català d'Investigació Química (ICIQ) Methanol production process
EP3429963B1 (en) 2016-03-17 2023-09-20 Saudi Arabian Oil Company Synthesis of transition-metal adamantane carboxylic salts and oxide nanocomposites
US10252245B2 (en) 2016-03-17 2019-04-09 Saudi Arabian Oil Company High temperature layered mixed-metal oxide materials with enhanced stability
US10138199B2 (en) 2016-03-17 2018-11-27 Saudi Arabian Oil Company High aspect ratio layered double hydroxide materials and methods for preparation thereof
US10087355B2 (en) 2016-03-17 2018-10-02 Saudi Arabian Oil Company Oil-based drilling fluids containing an alkaline-earth diamondoid compound as rheology modifier
US10106482B2 (en) 2016-03-17 2018-10-23 Saudi Arabian Oil Company Synthesis of magnesium adamantane salts and magnesium oxide nanocomposites, and systems and methods including the salts or the nanocomposites
DE102016225171A1 (en) 2016-12-15 2018-06-21 Clariant International Ltd Tableted catalyst for methanol synthesis with increased mechanical stability
GB201703558D0 (en) * 2017-03-06 2017-04-19 Univ Oxford Innovation Ltd catalysts
CN110678419B (en) 2017-05-19 2022-03-29 沙特阿拉伯石油公司 Synthesis of transition metal adamantane salt and oxide nanocomposites
US10875092B2 (en) 2017-05-19 2020-12-29 Saudi Arabian Oil Company Methods for preparing mixed-metal oxide diamondoid nanocomposites and catalytic systems including the nanocomposites
CN112023962B (en) * 2019-06-03 2023-10-03 国家能源投资集团有限责任公司 Catalyst for methanol synthesis, preparation method thereof and method for synthesizing methanol
EP4251316A1 (en) * 2020-11-24 2023-10-04 Topsoe A/S Process and catalyst for the catalytic hydrogenation of organic carbonyl compounds
JPWO2023135927A1 (en) * 2022-01-14 2023-07-20
CN114660256B (en) * 2022-04-02 2024-01-05 昆明理工大学 Method for measuring content of copper in each valence state in copper-zinc catalyst

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1010871A (en) 1962-08-24 1965-11-24 Ici Ltd Water-gas conversion and catalysts therefor
GB1159035A (en) 1965-08-18 1969-07-23 Ici Ltd Methanol Synthesis.
GB1296211A (en) 1969-01-27 1972-11-15
GB1296212A (en) 1969-03-04 1972-11-15
DE2056612C3 (en) * 1970-11-18 1979-09-13 Basf Ag, 6700 Ludwigshafen Process for the production of methanol
GB1405012A (en) 1972-01-21 1975-09-03 Ici Ltd Method of making composition convertible to a catalyst precursor and catalyst and methanol synthesis using the catalyst
US4279781A (en) 1979-10-09 1981-07-21 United Catalysts Inc. Catalyst for the synthesis of methanol
US4353071A (en) 1981-04-28 1982-10-05 Fairchild Industries, Inc. Self-erecting floatable structure
DE3317725A1 (en) 1983-05-16 1984-11-22 Süd-Chemie AG, 8000 München CATALYST FOR METHANOL SYNTHESIS
FR2558738B1 (en) * 1984-01-27 1987-11-13 Inst Francais Du Petrole PROCESS FOR THE MANUFACTURE OF CATALYSTS CONTAINING COPPER, ZINC AND ALUMINUM FOR USE IN THE PRODUCTION OF METHANOL FROM SYNTHESIS GAS
DE3403491A1 (en) 1984-02-02 1985-08-14 Süd-Chemie AG, 8000 München CATALYST FOR THE SYNTHESIS OF METHANOL AND ALCOHOL MIXTURES CONTAINING HIGHER ALCOHOLS
CA2026275C (en) 1989-10-17 2000-12-05 Deepak S. Thakur Hydrogenation catalyst, process for preparing and process of using said catalyst
DE69123432D1 (en) * 1990-09-18 1997-01-16 Csir Catalyst for methanol synthesis
US5334779A (en) * 1993-06-01 1994-08-02 Eastman Kodak Company Catalyst compositions and the use thereof in the hydrogenation of carboxylic acid esters
EP0868943B1 (en) * 1997-03-31 2002-10-30 Director-General Of The Agency Of Industrial Science And Technology Copper, zinc and aluminium based catalyst for methanol synthesis and reforming
JP3527972B2 (en) * 1997-06-30 2004-05-17 独立行政法人産業技術総合研究所 Methanol synthesis catalyst
DE10160486A1 (en) * 2001-12-08 2003-06-12 Sued Chemie Ag Copper-zinc-aluminium catalyst for use in methanol synthesis has a relatively low copper to zinc atom ratio and contains the aluminum oxide component in the form of an aluminum hydroxide sol

Also Published As

Publication number Publication date
CN104039444A (en) 2014-09-10
WO2013072197A1 (en) 2013-05-23
JP2015502248A (en) 2015-01-22
RU2014123678A (en) 2015-12-27
EP2780110A1 (en) 2014-09-24
DE102011086451A1 (en) 2013-05-16

Similar Documents

Publication Publication Date Title
IN2014KN00985A (en)
MX2012005996A (en) Hot-dipped steel material and method for producing same.
WO2011139702A3 (en) Modified nucleosides and oligomeric compounds prepared therefrom
NZ596845A (en) Carbon oxides conversion process
WO2012091385A3 (en) High corrosion resistant hot dip zn alloy plated steel sheet and method of manufacturing the same
WO2012146135A3 (en) Hydrogenated alkyl oxalate composite carrier catalyst for synthesizing ethylene glycol and preparation method therefor
MX363092B (en) Copper alloy and copper alloy sheet.
MX361891B (en) Method for producing aluminum alloy heat exchanger.
WO2008036563A3 (en) Methods for conversion of methane to useful hydrocarbons and catalysts for use therein
MY156915A (en) Wire electrode for spark-erosion cutting
MX344422B (en) Steel sheet for hot pressing and method for producing hot pressed member using same.
WO2010077736A3 (en) A method for producing high strength aluminum alloy powder containing l12 intermetallic dispersoids
WO2013025990A3 (en) Lead-free solder compositions
MY167437A (en) Aluminium alloy sheet and method for manufacturing same
IN2014DN10249A (en)
IN2014KN01133A (en)
MX2014002319A (en) Copper alloy sheet and method for producing copper alloy sheet.
WO2012045761A3 (en) Cemented carbide punch
WO2011096990A3 (en) Dehydrogenation catalyst and process
WO2011138643A3 (en) A process for preparation of hydroxyacetone or propylene glycol
BR112014031358B8 (en) METHOD FOR PREPARING A TRANSITION METAL COMPOSITE OF A TRANSITION METAL PRECURSOR
MY162750A (en) Methanol synthesis catalyst
MY159972A (en) Copper catalyst for dehydrogenation application
RU2011121810A (en) COPPER-TIN ALLOY, COMPOSITE MATERIAL AND THEIR APPLICATION
GB201117738D0 (en) Cobalt catalyst