DE102009001775A1 - (Meth)acrylatpolymere und deren Verwendung als polymergebundene UV-Initiatoren oder Zusatz zu UV-härtbaren Harzen - Google Patents

(Meth)acrylatpolymere und deren Verwendung als polymergebundene UV-Initiatoren oder Zusatz zu UV-härtbaren Harzen Download PDF

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Publication number
DE102009001775A1
DE102009001775A1 DE102009001775A DE102009001775A DE102009001775A1 DE 102009001775 A1 DE102009001775 A1 DE 102009001775A1 DE 102009001775 A DE102009001775 A DE 102009001775A DE 102009001775 A DE102009001775 A DE 102009001775A DE 102009001775 A1 DE102009001775 A1 DE 102009001775A1
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Germany
Prior art keywords
meth
polymer
acrylate
weight
polymer according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE102009001775A
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German (de)
English (en)
Inventor
Gerold Dr. Schmitt
Reinhold Martin
Patrik Hartmann
Wolfgang Dr. Klesse
Joachim Dr. Knebel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Roehm GmbH Darmstadt
Original Assignee
Evonik Roehm GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Roehm GmbH filed Critical Evonik Roehm GmbH
Priority to DE102009001775A priority Critical patent/DE102009001775A1/de
Priority to CN201080012598.6A priority patent/CN102361893B/zh
Priority to KR1020117022237A priority patent/KR20110139234A/ko
Priority to JP2012501217A priority patent/JP5901515B2/ja
Priority to EP10705371.2A priority patent/EP2411426B1/de
Priority to US13/203,993 priority patent/US20120010317A1/en
Priority to HK12105574.9A priority patent/HK1164905B/xx
Priority to PCT/EP2010/052384 priority patent/WO2010108752A1/de
Priority to RU2011142635/04A priority patent/RU2553661C2/ru
Priority to TW099108188A priority patent/TWI478947B/zh
Publication of DE102009001775A1 publication Critical patent/DE102009001775A1/de
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C08F20/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F20/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F20/30—Esters containing oxygen in addition to the carboxy oxygen containing aromatic rings in the alcohol moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/30—Esters containing oxygen in addition to the carboxy oxygen containing aromatic rings in the alcohol moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/30—Esters containing oxygen in addition to the carboxy oxygen containing aromatic rings in the alcohol moiety
    • C08F220/302—Esters containing oxygen in addition to the carboxy oxygen containing aromatic rings in the alcohol moiety and two or more oxygen atoms in the alcohol moiety
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/10—Homopolymers or copolymers of methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
DE102009001775A 2009-03-24 2009-03-24 (Meth)acrylatpolymere und deren Verwendung als polymergebundene UV-Initiatoren oder Zusatz zu UV-härtbaren Harzen Withdrawn DE102009001775A1 (de)

Priority Applications (10)

Application Number Priority Date Filing Date Title
DE102009001775A DE102009001775A1 (de) 2009-03-24 2009-03-24 (Meth)acrylatpolymere und deren Verwendung als polymergebundene UV-Initiatoren oder Zusatz zu UV-härtbaren Harzen
CN201080012598.6A CN102361893B (zh) 2009-03-24 2010-02-25 (甲基)丙烯酸酯聚合物和其作为聚合物键接的uv引发剂或可uv固化树脂的添加剂的用途
KR1020117022237A KR20110139234A (ko) 2009-03-24 2010-02-25 (메트)아크릴레이트 중합체 및 ｕｖ-경화성 수지에 대한 중합체-결합된 ｕｖ 개시제 또는 첨가제로서의 그의 용도
JP2012501217A JP5901515B2 (ja) 2009-03-24 2010-02-25 （メタ）アクリレートポリマー並びに前記ポリマーを、ポリマーに結合された紫外線開始剤として又は紫外線硬化性樹脂への添加剤として用いる使用
EP10705371.2A EP2411426B1 (de) 2009-03-24 2010-02-25 (meth)acrylatpolymere und deren verwendung als polymergebundene uv-initiatoren oder zusatz zu uv-härtbaren harzen
US13/203,993 US20120010317A1 (en) 2009-03-24 2010-02-25 (meth)acrylate polymers and the use thereof as polymer-bound uv initiators or additive to uv-curable resins
HK12105574.9A HK1164905B (en) 2009-03-24 2010-02-25 (meth)acrylate polymers and the use thereof as polymer-bound uv initiators or additive to uv-curable resins
PCT/EP2010/052384 WO2010108752A1 (de) 2009-03-24 2010-02-25 (meth)acrylatpolymere und deren verwendung als polymergebundene uv-initiatoren oder zusatz zu uv-härtbaren harzen
RU2011142635/04A RU2553661C2 (ru) 2009-03-24 2010-02-25 (мет) акрилатные полимеры и применение их в качестве связанных с полимерами уф-инициаторов или в качестве добавки к отверждаемым уф-светом смолам
TW099108188A TWI478947B (zh) 2009-03-24 2010-03-19 （甲基）丙烯酸酯聚合物及其作為與聚合物結合的ｕｖ引發劑或ｕｖ可固化樹脂的添加劑之用途

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102009001775A DE102009001775A1 (de) 2009-03-24 2009-03-24 (Meth)acrylatpolymere und deren Verwendung als polymergebundene UV-Initiatoren oder Zusatz zu UV-härtbaren Harzen

Publications (1)

Publication Number Publication Date
DE102009001775A1 true DE102009001775A1 (de) 2010-09-30

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DE102009001775A Withdrawn DE102009001775A1 (de) 2009-03-24 2009-03-24 (Meth)acrylatpolymere und deren Verwendung als polymergebundene UV-Initiatoren oder Zusatz zu UV-härtbaren Harzen

Country Status (9)

Country Link
US (1) US20120010317A1 (https=)
EP (1) EP2411426B1 (https=)
JP (1) JP5901515B2 (https=)
KR (1) KR20110139234A (https=)
CN (1) CN102361893B (https=)
DE (1) DE102009001775A1 (https=)
RU (1) RU2553661C2 (https=)
TW (1) TWI478947B (https=)
WO (1) WO2010108752A1 (https=)

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EP2585496A2 (en) * 2010-06-22 2013-05-01 Coloplast A/S Hydrophilic gels derived from grafted photoinitiators
WO2012145857A1 (en) * 2011-04-25 2012-11-01 Evonik Röhm Gmbh Aqueous dispersion of preferably benzophenone-containing (meth)acrylate polymers for leather coating
WO2013052105A2 (en) 2011-10-03 2013-04-11 Biomimedica, Inc. Polymeric adhesive for anchoring compliant materials to another surface
CN103087234A (zh) * 2011-11-08 2013-05-08 广州市博兴化工科技有限公司 具有光引发活性端基的丙烯酸酯官能性聚合物及其制备方法
BE1020472A5 (nl) * 2012-03-16 2013-11-05 Arets Graphics Verbeterde deklagen en werkwijze om deklagen te maken.
EP2850111B1 (en) * 2012-05-16 2018-11-21 Coloplast A/S Novel polymeric photoinitiators and photoinitiator monomers
US9034938B2 (en) * 2012-09-12 2015-05-19 Basf Se Photoreactive polymer
DE102012216170A1 (de) * 2012-09-12 2014-03-13 Basf Se Photoreaktives Polymer
TWI585144B (zh) * 2014-10-21 2017-06-01 Mitsubishi Rayon Co (Meth) acrylic resin composition and a resin molded product
KR101921013B1 (ko) 2015-01-05 2018-11-21 아이지엠 몰타 리미티드 Led-경화성 저 이동 광개시제
JP6791615B2 (ja) * 2015-03-06 2020-11-25 スリーエム イノベイティブ プロパティズ カンパニー 紫外線架橋性組成物
BR112017019963A2 (pt) * 2015-03-20 2018-06-19 Henkel IP & Holding GmbH fotoiniciadores que são poliméricos ou polimerizáveis para uso em adesivos sensíveis à pressão curáveis por uv
RU2741435C2 (ru) * 2016-08-12 2021-01-26 Дау Глоубл Текнолоджиз Ллк Чувствительные к давлению адгезивные композиции на водной основе и способы их получения
JP7225530B2 (ja) * 2017-10-30 2023-02-21 株式会社レゾナック 無溶剤型樹脂組成物
JP7596656B2 (ja) * 2020-07-29 2024-12-10 三菱ケミカル株式会社 硬化性組成物、硬化物及び積層体
CN112851845B (zh) * 2021-01-20 2022-04-29 东华大学 一种共聚高分子光引发剂及其制备方法
CN114855295B (zh) * 2021-01-20 2024-04-05 东华大学 一种纺丝原液、耐热抗蠕变纤维及其制备方法
CN114854114B (zh) * 2021-01-20 2024-10-18 东华大学 一种交联聚烯烃及其制备方法
CN113336882B (zh) * 2021-05-24 2022-11-04 博立尔化工（扬州）有限公司 一种采用间歇式本体聚合法制备窄分子量分布的pmma树脂的工艺

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EP0346734B1 (de) * 1988-06-16 1993-11-03 BASF Aktiengesellschaft Benzophenonderivate und deren Herstellung
US5073611A (en) * 1989-04-29 1991-12-17 Basf Aktiengesellschaft Copolymers crosslinkable by ultraviolet radiation in the atmosphere
EP0445641A1 (de) * 1990-03-08 1991-09-11 BASF Aktiengesellschaft Ethylenisch ungesättigte Verbindungen
US5439970A (en) * 1992-11-04 1995-08-08 Rhone-Poulenc Chimie Paint latices comprising benzophenone/acrylic copolymerizates
US5900472A (en) 1996-12-23 1999-05-04 Sartomer Technology Copolymerizable benzophenone photoinitiators
EP1316597A2 (de) * 2001-11-29 2003-06-04 Basf Aktiengesellschaft Glycidyl(meth)acrylat enthaltende Klebstoff
WO2008049932A1 (de) * 2006-10-27 2008-05-02 Basf Se Strahlungshärtbare mischung, enthaltend niedermolekulare, ethylenisch ungesättigte verbindungen mit nicht-aromatischen ringsystemen

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DIN EN/SO 6721-2
EN ISO 11357
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EP2411426B1 (de) 2016-08-17
JP5901515B2 (ja) 2016-04-13
EP2411426A1 (de) 2012-02-01
JP2012521453A (ja) 2012-09-13
US20120010317A1 (en) 2012-01-12
HK1164905A1 (en) 2012-09-28
WO2010108752A1 (de) 2010-09-30
RU2553661C2 (ru) 2015-06-20
CN102361893A (zh) 2012-02-22
TW201105685A (en) 2011-02-16
CN102361893B (zh) 2015-06-17
TWI478947B (zh) 2015-04-01
KR20110139234A (ko) 2011-12-28
RU2011142635A (ru) 2013-04-27

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