DE102006048612B4 - Diffusionsmedium für eine PEM-Brennstoffzelle, Verfahren zu seiner Herstellung, Brennstoffzellenstapel und Verfahren zur Verbesserung der Leistung eines PEM-Brennstoffzellenstapels - Google Patents
Diffusionsmedium für eine PEM-Brennstoffzelle, Verfahren zu seiner Herstellung, Brennstoffzellenstapel und Verfahren zur Verbesserung der Leistung eines PEM-Brennstoffzellenstapels Download PDFInfo
- Publication number
- DE102006048612B4 DE102006048612B4 DE102006048612A DE102006048612A DE102006048612B4 DE 102006048612 B4 DE102006048612 B4 DE 102006048612B4 DE 102006048612 A DE102006048612 A DE 102006048612A DE 102006048612 A DE102006048612 A DE 102006048612A DE 102006048612 B4 DE102006048612 B4 DE 102006048612B4
- Authority
- DE
- Germany
- Prior art keywords
- substrate
- fuel cell
- coating
- hydrophobic
- silicone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 111
- 238000009792 diffusion process Methods 0.000 title claims abstract description 94
- 238000000034 method Methods 0.000 title claims description 37
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 230000008569 process Effects 0.000 title description 7
- 239000000758 substrate Substances 0.000 claims abstract description 105
- 229920002313 fluoropolymer Polymers 0.000 claims abstract description 63
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 61
- 238000000576 coating method Methods 0.000 claims abstract description 44
- 239000011248 coating agent Substances 0.000 claims abstract description 41
- 229920005573 silicon-containing polymer Polymers 0.000 claims abstract description 17
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 35
- 229920001296 polysiloxane Polymers 0.000 claims description 35
- 239000000203 mixture Substances 0.000 claims description 33
- 239000004917 carbon fiber Substances 0.000 claims description 32
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 32
- 239000002245 particle Substances 0.000 claims description 31
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 25
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 25
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 20
- 229920002050 silicone resin Polymers 0.000 claims description 18
- 229910052799 carbon Inorganic materials 0.000 claims description 14
- 239000002904 solvent Substances 0.000 claims description 13
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 11
- 239000004447 silicone coating Substances 0.000 claims description 11
- 239000012528 membrane Substances 0.000 claims description 7
- 230000009471 action Effects 0.000 claims description 6
- 238000011068 loading method Methods 0.000 claims description 6
- 238000005507 spraying Methods 0.000 claims description 6
- 229920000867 polyelectrolyte Polymers 0.000 claims description 3
- 238000005245 sintering Methods 0.000 claims 3
- 239000008199 coating composition Substances 0.000 claims 1
- 239000000123 paper Substances 0.000 description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 34
- 239000010410 layer Substances 0.000 description 31
- 229920000642 polymer Polymers 0.000 description 29
- 239000007789 gas Substances 0.000 description 20
- 239000000463 material Substances 0.000 description 20
- 239000006185 dispersion Substances 0.000 description 15
- 239000000243 solution Substances 0.000 description 15
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 9
- 239000001257 hydrogen Substances 0.000 description 9
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- -1 polytetrafluoroethylene Polymers 0.000 description 8
- 239000011148 porous material Substances 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 230000032683 aging Effects 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000004811 fluoropolymer Substances 0.000 description 6
- 229920001600 hydrophobic polymer Polymers 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 5
- 239000003570 air Substances 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 239000003431 cross linking reagent Substances 0.000 description 5
- 238000007598 dipping method Methods 0.000 description 5
- 229910052731 fluorine Inorganic materials 0.000 description 5
- 239000010439 graphite Substances 0.000 description 5
- 229910002804 graphite Inorganic materials 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 238000009736 wetting Methods 0.000 description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 125000003545 alkoxy group Chemical group 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000006230 acetylene black Substances 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 239000004815 dispersion polymer Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002344 surface layer Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 description 2
- BZPCMSSQHRAJCC-UHFFFAOYSA-N 1,2,3,3,4,4,5,5,5-nonafluoro-1-(1,2,3,3,4,4,5,5,5-nonafluoropent-1-enoxy)pent-1-ene Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)=C(F)OC(F)=C(F)C(F)(F)C(F)(F)C(F)(F)F BZPCMSSQHRAJCC-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 230000000875 corresponding effect Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000003487 electrochemical reaction Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000006262 metallic foam Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000007606 doctor blade method Methods 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000011066 ex-situ storage Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 230000005660 hydrophilic surface Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000011049 pearl Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 description 1
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005067 remediation Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical class [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04291—Arrangements for managing water in solid electrolyte fuel cell systems
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/023—Porous and characterised by the material
- H01M8/0234—Carbonaceous material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/023—Porous and characterised by the material
- H01M8/0239—Organic resins; Organic polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/023—Porous and characterised by the material
- H01M8/0241—Composites
- H01M8/0245—Composites in the form of layered or coated products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
- H01M2250/20—Fuel cells in motive systems, e.g. vehicle, ship, plane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T90/00—Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02T90/40—Application of hydrogen technology to transportation, e.g. using fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Fuel Cell (AREA)
- Inert Electrodes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/250,197 | 2005-10-14 | ||
| US11/250,197 US7722979B2 (en) | 2005-10-14 | 2005-10-14 | Fuel cells with hydrophobic diffusion medium |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE102006048612A1 DE102006048612A1 (de) | 2007-04-19 |
| DE102006048612B4 true DE102006048612B4 (de) | 2013-03-21 |
Family
ID=37896646
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE102006048612A Expired - Fee Related DE102006048612B4 (de) | 2005-10-14 | 2006-10-13 | Diffusionsmedium für eine PEM-Brennstoffzelle, Verfahren zu seiner Herstellung, Brennstoffzellenstapel und Verfahren zur Verbesserung der Leistung eines PEM-Brennstoffzellenstapels |
Country Status (4)
| Country | Link |
|---|---|
| US (2) | US7722979B2 (https=) |
| JP (2) | JP5086601B2 (https=) |
| CN (1) | CN100592557C (https=) |
| DE (1) | DE102006048612B4 (https=) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8431284B2 (en) * | 2007-06-26 | 2013-04-30 | GM Global Technology Operations LLC | Low electrical resistance bipolar plate-diffusion media assembly |
| US8278001B2 (en) | 2008-02-15 | 2012-10-02 | Panasonic Corporation | Low-porosity anode diffusion media for high concentration direct methanol fuel cells and method of making |
| US20090208783A1 (en) * | 2008-02-15 | 2009-08-20 | Yongjun Leng | Low porosity anode diffusion media for fuel cells |
| EP2424015A1 (en) * | 2010-08-30 | 2012-02-29 | Solvay SA | Assembly for reversible fuel cell |
| KR101655510B1 (ko) * | 2010-12-31 | 2016-09-07 | 제너럴 일렉트릭 캄파니 | 다공성 지지체 상에 중합체 코팅을 형성시키기 위한 진공 챔버 방법 |
| US20130152612A1 (en) * | 2011-08-16 | 2013-06-20 | Nanopore, Inc. | Sorption cooling systems and climate control using multi-channel thermal swing adsorption |
| KR102102275B1 (ko) * | 2013-02-21 | 2020-04-21 | 아우디 아게 | 천공부를 갖지 않는 연료 전지 가스 확산 층 |
| WO2015009233A1 (en) * | 2013-07-17 | 2015-01-22 | Temasek Polytechnic | Diffusion medium for use in fuel cell, fuel cell and method of making the diffusion medium |
| JP5942952B2 (ja) * | 2013-09-24 | 2016-06-29 | トヨタ自動車株式会社 | 拡散層形成ペーストとその製造方法およびガス拡散層の製造方法 |
| JP5935781B2 (ja) * | 2013-10-11 | 2016-06-15 | トヨタ自動車株式会社 | 燃料電池用ガス拡散層の製造方法および製造装置 |
| KR102591887B1 (ko) * | 2015-10-22 | 2023-10-20 | 도레이 카부시키가이샤 | 탄소 시트, 가스 확산 전극 기재, 권회체 및 연료 전지 |
| CN109256569B (zh) * | 2017-07-14 | 2021-10-15 | 中国科学院青岛生物能源与过程研究所 | 一种质子交换膜燃料电池气体扩散层微孔层及其制备方法 |
| CN111725523A (zh) * | 2020-06-04 | 2020-09-29 | 浙江高成绿能科技有限公司 | 一种薄层疏水的燃料电池膜电极及其制备方法 |
| CN112615018A (zh) * | 2020-12-21 | 2021-04-06 | 上海电气集团股份有限公司 | 阴极催化层及其制备方法、膜电极和燃料电池 |
| KR102590291B1 (ko) * | 2021-12-16 | 2023-10-18 | 자연에너지연구소 주식회사 | 연료전지를 사용하는 드론 |
| CN114976060B (zh) * | 2022-07-04 | 2024-05-28 | 一汽解放汽车有限公司 | 一种气体扩散层的制备方法及其应用 |
| WO2025083484A1 (en) * | 2023-10-19 | 2025-04-24 | 3M Innovative Properties Company | Gas diffusion layer and microporous layer including non-fluorinated hydrophobic material |
| DE102023134950A1 (de) | 2023-12-13 | 2025-06-18 | Ekpo Fuel Cell Technologies Gmbh | Verfahren zur Hydrophobierung einer Gasdiffusionslage und Gasdiffusionslage mit einer hydrophoben Imprägnierung |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6365293B1 (en) * | 1999-06-22 | 2002-04-02 | Sanyo Electric Co., Ltd. | Fuel cell having water permeability adjustment capability |
| US6368751B1 (en) * | 1999-10-08 | 2002-04-09 | Reves, Inc. | Electrochemical electrode for fuel cell |
| US20050064275A1 (en) * | 2003-09-18 | 2005-03-24 | 3M Innovative Properties Company | Fuel cell gas diffusion layer |
Family Cites Families (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3523408A (en) * | 1968-04-02 | 1970-08-11 | Pall Corp | Gas separator |
| JPS57111957A (en) * | 1980-12-27 | 1982-07-12 | Toshiba Corp | Air electrode |
| US5110691A (en) * | 1991-01-16 | 1992-05-05 | International Fuel Cells Corporation | Fuel cell component sealant |
| WO1993013566A1 (en) * | 1991-12-26 | 1993-07-08 | International Fuel Cells, Inc. | Plate-shaped fuel cell component and a method of making the same |
| DE69229177T2 (de) * | 1992-12-31 | 1999-12-02 | Ballard Power Systems Inc., Burnaby | Membranelektrodenzusammenbau und Abdichtung für Brennstoffzellen |
| JPH0845517A (ja) * | 1994-07-28 | 1996-02-16 | Tanaka Kikinzoku Kogyo Kk | 高分子電解質型燃料電池用シール構造及びその製造方法 |
| DE19544323A1 (de) * | 1995-11-28 | 1997-06-05 | Magnet Motor Gmbh | Gasdiffusionselektrode für Polymerelektrolytmembran-Brennstoffzellen |
| JP3583897B2 (ja) * | 1997-04-11 | 2004-11-04 | 三洋電機株式会社 | 燃料電池 |
| DE69804829T2 (de) * | 1997-07-16 | 2002-11-07 | Ballard Power Systems Inc., Burnaby | Elastische dichtung für eine membranelektrodenanordnung in einer elektrochemischen brennstoffzelle und herstellungsverfahren dafür |
| US6045877A (en) | 1997-07-28 | 2000-04-04 | Massachusetts Institute Of Technology | Pyrolytic chemical vapor deposition of silicone films |
| US6258878B1 (en) * | 1999-03-29 | 2001-07-10 | Dow Corning Corporation | One-part moisture-curable hydrocarbon polymer composition |
| JP4470271B2 (ja) * | 2000-03-31 | 2010-06-02 | 株式会社エクォス・リサーチ | 燃料電池および燃料電池装置 |
| AU2001280950A1 (en) * | 2000-08-18 | 2002-03-13 | Muralidharan P. Arikara | Integrated and modular bsp/mea/manifold plates and compliant contacts for fuel cells |
| KR100458783B1 (ko) * | 2000-09-18 | 2004-12-03 | 미츠비시 쥬고교 가부시키가이샤 | 고체 고분자형 연료전지 |
| JP5050294B2 (ja) * | 2000-10-17 | 2012-10-17 | トヨタ自動車株式会社 | 固体高分子電解質型燃料電池の拡散層とその製造方法 |
| GB2374014A (en) * | 2001-04-02 | 2002-10-09 | Cambridge Consultants | Biological sealant storage and dispensing system |
| DE10125360A1 (de) * | 2001-05-23 | 2002-12-05 | Wacker Chemie Gmbh | Verwendung von zu degradationsstabilen Siliconkautschuken vernetzbaren Massen als Dichtungsmassen in Brenntstoffzellen |
| JP5079195B2 (ja) * | 2001-09-27 | 2012-11-21 | パナソニック株式会社 | 燃料電池用ガス拡散電極およびその製造法 |
| US7060384B2 (en) * | 2001-09-28 | 2006-06-13 | Matsushita Electric Industrial Co., Ltd. | Polymer electrolyte fuel cell |
| EP1448807A4 (en) | 2001-10-30 | 2005-07-13 | Massachusetts Inst Technology | FLUORO CARBON ORGANOSILICIUM COPOLYMERS AND COATINGS MADE ACCORDING TO THE HFCVD PROCEDURE |
| US20050181694A1 (en) * | 2002-03-09 | 2005-08-18 | Crook Robert L. | Industrial fabrics |
| US20030198857A1 (en) | 2002-04-05 | 2003-10-23 | Mcmanus Edward C. | Graphite laminate fuel cell plate |
| US7087339B2 (en) * | 2002-05-10 | 2006-08-08 | 3M Innovative Properties Company | Fuel cell membrane electrode assembly with sealing surfaces |
| US7125625B2 (en) * | 2002-05-31 | 2006-10-24 | Lynnetech, Inc. | Electrochemical cell and bipolar assembly for an electrochemical cell |
| JP3951841B2 (ja) * | 2002-07-19 | 2007-08-01 | トヨタ自動車株式会社 | 燃料電池のシール構造とその製造方法 |
| WO2004040681A1 (ja) * | 2002-10-29 | 2004-05-13 | Honda Motor Co., Ltd. | 膜一電極構造体及びその製造方法 |
| US7470483B2 (en) * | 2002-12-11 | 2008-12-30 | Panasonic Corporation | Electrolyte membrane-electrode assembly for fuel cell and operation method of fuel cell using the same |
| WO2004059043A1 (en) * | 2002-12-23 | 2004-07-15 | Anuvu, Inc., A California Corporation | Channel-less proton exchange membrane fuel cell |
| US6928893B2 (en) * | 2003-01-15 | 2005-08-16 | General Motors Corporation | Method of making a gas diffusion media and quality controls for same |
| CA2464204C (en) * | 2003-04-14 | 2009-08-11 | Matsushita Electric Industrial Co., Ltd. | Polymer electrolyte fuel cell and conductive separator for the same |
| JP4514027B2 (ja) * | 2003-04-14 | 2010-07-28 | パナソニック株式会社 | 燃料電池セル、および燃料電池 |
| JP4403448B2 (ja) | 2003-06-24 | 2010-01-27 | 株式会社スリーボンド | 固体高分子型燃料電池のシール構造 |
| AU2004231214A1 (en) * | 2003-07-25 | 2005-02-10 | Albany International Techniweave, Inc. | Control of carbon coating microcrackings in fabrication of fuel cell GDL |
| JP2005085509A (ja) * | 2003-09-04 | 2005-03-31 | Nec Corp | 燃料電池システムおよびその運転方法 |
| US7105242B2 (en) * | 2003-10-17 | 2006-09-12 | General Motors Corporation | Control of polymer surface distribution on diffusion media improved fuel cell performance |
| US7157178B2 (en) * | 2003-11-24 | 2007-01-02 | General Motors Corporation | Proton exchange membrane fuel cell |
| JP4824298B2 (ja) * | 2003-12-04 | 2011-11-30 | パナソニック株式会社 | 燃料電池用ガス拡散層、電極及び膜電極接合体及びその製造方法 |
| DE602005021099D1 (de) * | 2004-03-31 | 2010-06-17 | Corning Inc | Brennstoffzellenvorrichtung mit unterschiedlich grossen aktivbereichen |
| US20050224108A1 (en) * | 2004-04-13 | 2005-10-13 | Cheung Osbert H | Enhanced photovoltaic module |
| JP4691914B2 (ja) * | 2004-06-21 | 2011-06-01 | 日産自動車株式会社 | ガス拡散電極及び固体高分子電解質型燃料電池 |
| US8241818B2 (en) * | 2004-08-06 | 2012-08-14 | GM Global Technology Operations LLC | Diffusion media with hydrophobic and hydrophilic properties |
| KR100661698B1 (ko) * | 2004-12-21 | 2006-12-26 | 마쯔시다덴기산교 가부시키가이샤 | 직접 메탄올형 연료전지 |
| US7569291B2 (en) * | 2005-02-14 | 2009-08-04 | Henkel Corporation | Method and composition for bonding and sealing fuel cell components |
-
2005
- 2005-10-14 US US11/250,197 patent/US7722979B2/en not_active Expired - Fee Related
-
2006
- 2006-10-13 DE DE102006048612A patent/DE102006048612B4/de not_active Expired - Fee Related
- 2006-10-16 CN CN200610135971A patent/CN100592557C/zh not_active Expired - Fee Related
- 2006-10-16 JP JP2006281178A patent/JP5086601B2/ja not_active Expired - Fee Related
-
2010
- 2010-01-22 US US12/692,312 patent/US8835075B2/en not_active Expired - Fee Related
-
2011
- 2011-12-12 JP JP2011271104A patent/JP5415518B2/ja not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6365293B1 (en) * | 1999-06-22 | 2002-04-02 | Sanyo Electric Co., Ltd. | Fuel cell having water permeability adjustment capability |
| US6368751B1 (en) * | 1999-10-08 | 2002-04-09 | Reves, Inc. | Electrochemical electrode for fuel cell |
| US20050064275A1 (en) * | 2003-09-18 | 2005-03-24 | 3M Innovative Properties Company | Fuel cell gas diffusion layer |
Also Published As
| Publication number | Publication date |
|---|---|
| DE102006048612A1 (de) | 2007-04-19 |
| JP5415518B2 (ja) | 2014-02-12 |
| JP2007109664A (ja) | 2007-04-26 |
| CN1949573A (zh) | 2007-04-18 |
| CN100592557C (zh) | 2010-02-24 |
| US8835075B2 (en) | 2014-09-16 |
| US20100129534A1 (en) | 2010-05-27 |
| JP2012099489A (ja) | 2012-05-24 |
| JP5086601B2 (ja) | 2012-11-28 |
| US20070087260A1 (en) | 2007-04-19 |
| US7722979B2 (en) | 2010-05-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE112005002039B4 (de) | Verfahren zum Herstellen eines Diffusionsmediums mit mikroporöser Schicht, Brennstoffzelle, Brennstoffzellenstapel und Verfahren zum Betrieb desselben | |
| DE102006048612B4 (de) | Diffusionsmedium für eine PEM-Brennstoffzelle, Verfahren zu seiner Herstellung, Brennstoffzellenstapel und Verfahren zur Verbesserung der Leistung eines PEM-Brennstoffzellenstapels | |
| DE69527033T2 (de) | Ionenaustauschmembran-Elektrodeneinheit für eine elektrochemische Zelle | |
| DE112004001943B4 (de) | Herstellungsverfahren für ein Diffusionsmedium für eine Brennstoffzelle und Brennstoffzellenstapel mit solch einem Diffusionsmedium | |
| DE60319031T2 (de) | Kohlenstofffaser-Elektrodensubstrat für elektrochemische Zellen | |
| DE112005001910B4 (de) | Verfahren zum Herstellen eines Diffusionsmediums zur Verwendung in einer PEM-Brennstoffzelle | |
| DE102008009724B4 (de) | Diffusionsmedium zur Verwendung in einer PEM-Brennstoffzelle | |
| DE112015001388B4 (de) | Verfahren zur Herstellung einer mit Katalysator beschichteten Membran-Versiegelungs-Anordnung | |
| DE60016924T2 (de) | Elektrochemische anwendungen von amorphen fluoropolymeren | |
| DE112004001385B4 (de) | Brennstoffzellensystem mit einer für verschiedene Betriebsfeuchtigkeiten optimierten Gasdiffusionsschicht und dessen Verwendung | |
| DE10222090A1 (de) | Brennstoffzelle, Elektrode für eine Brennstoffzelle und Herstellungsverfahren einer Elektrode für eine Brennstoffzelle | |
| DE102007012715A1 (de) | Diffusionsmedien mit aufgedampftem Fluorkohlenwasserstoffpolymer | |
| DE112015000657T5 (de) | Gasdiffusionssubstrat | |
| DE112020001053T5 (de) | Kathodenkatalysatorschicht für eine Brennstoffzelle, und Brennstoffzelle | |
| DE112011101367T5 (de) | Membranelektrodenanordnung für eine Brennstoffzelle und Brennstoffzelle, die diese Verwendet | |
| DE102009035961A1 (de) | Geschichtete Elektrode für elektrochemische Zellen | |
| DE102015117925B9 (de) | Katalysatorenelektrodenschicht, Membranelektrodenanordnung und Brennstoffzelle | |
| DE102009009515B4 (de) | Verfahren und System zum Herstellen eines Gasdiffusionsmediums für eine Brennstoffzelle | |
| DE112015001444B4 (de) | Membran-Versiegelungs-Anordnung | |
| DE112015001458B4 (de) | Verfahren zur Herstellung einer verstärkten Membran-Versiegelungs-Anordnung | |
| DE102007031280A1 (de) | Gasdiffusionselektrode und diese enthaltende Membran-Elektroden-Einheit für eine Brennstoffzelle | |
| DE102011120252A1 (de) | Senken von Elektrolytverlust in PEM-Brennstoffzelle | |
| WO2022210069A1 (ja) | 電極基材およびその製造方法 | |
| DE102021108098A1 (de) | Gasdiffusionsschicht, membran-elektroden-baugruppe und brennstoffbatterie | |
| DE102011119901A1 (de) | Brennstoffzellenstapel mit einer undurchlässigen Beschichtung |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OP8 | Request for examination as to paragraph 44 patent law | ||
| 8180 | Miscellaneous part 1 |
Free format text: PFANDRECHT |
|
| 8180 | Miscellaneous part 1 |
Free format text: PFANDRECHT AUFGEHOBEN |
|
| 8180 | Miscellaneous part 1 |
Free format text: PFANDRECHT |
|
| 8127 | New person/name/address of the applicant |
Owner name: GM GLOBAL TECHNOLOGY OPERATIONS LLC , ( N. D. , US |
|
| R081 | Change of applicant/patentee |
Owner name: GM GLOBAL TECHNOLOGY OPERATIONS LLC (N. D. GES, US Free format text: FORMER OWNER: GM GLOBAL TECHNOLOGY OPERATIONS, INC., DETROIT, MICH., US Effective date: 20110323 |
|
| R016 | Response to examination communication | ||
| R016 | Response to examination communication | ||
| R018 | Grant decision by examination section/examining division | ||
| R020 | Patent grant now final |
Effective date: 20130622 |
|
| R119 | Application deemed withdrawn, or ip right lapsed, due to non-payment of renewal fee | ||
| R079 | Amendment of ipc main class |
Free format text: PREVIOUS MAIN CLASS: H01M0008020000 Ipc: H01M0008024500 |