DD208083A5 - Katalysator und verfahren zur gasphasenfluorierung von chlorierten aliphatischen verbindungen - Google Patents
Katalysator und verfahren zur gasphasenfluorierung von chlorierten aliphatischen verbindungen Download PDFInfo
- Publication number
- DD208083A5 DD208083A5 DD81235631A DD23563181A DD208083A5 DD 208083 A5 DD208083 A5 DD 208083A5 DD 81235631 A DD81235631 A DD 81235631A DD 23563181 A DD23563181 A DD 23563181A DD 208083 A5 DD208083 A5 DD 208083A5
- Authority
- DD
- German Democratic Republic
- Prior art keywords
- catalyst
- gas phase
- chromium
- catalysts
- fluorination
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 52
- 238000000034 method Methods 0.000 title claims abstract description 5
- -1 CHLORINE ALIPHATIC COMPOUNDS Chemical class 0.000 title description 7
- 239000000460 chlorine Substances 0.000 title description 6
- 229910052801 chlorine Inorganic materials 0.000 title description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 29
- 238000003682 fluorination reaction Methods 0.000 claims abstract description 24
- 239000011148 porous material Substances 0.000 claims abstract description 8
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 6
- 239000007864 aqueous solution Substances 0.000 claims abstract description 6
- 239000011651 chromium Substances 0.000 claims description 10
- 229910052804 chromium Inorganic materials 0.000 claims description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 5
- 229940117975 chromium trioxide Drugs 0.000 claims description 4
- WGLPBDUCMAPZCE-UHFFFAOYSA-N chromium trioxide Inorganic materials O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 4
- GAMDZJFZMJECOS-UHFFFAOYSA-N chromium(6+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+6] GAMDZJFZMJECOS-UHFFFAOYSA-N 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 28
- 238000006243 chemical reaction Methods 0.000 description 16
- DRUIESSIVFYOMK-UHFFFAOYSA-N Trichloroacetonitrile Chemical compound ClC(Cl)(Cl)C#N DRUIESSIVFYOMK-UHFFFAOYSA-N 0.000 description 7
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 6
- 239000012530 fluid Substances 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- 229950011008 tetrachloroethylene Drugs 0.000 description 6
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 5
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 description 5
- 239000003610 charcoal Substances 0.000 description 5
- 229940087091 dichlorotetrafluoroethane Drugs 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- SFFUEHODRAXXIA-UHFFFAOYSA-N 2,2,2-trifluoroacetonitrile Chemical compound FC(F)(F)C#N SFFUEHODRAXXIA-UHFFFAOYSA-N 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 239000011269 tar Substances 0.000 description 2
- GUIPZCNIFDPABQ-UHFFFAOYSA-N 2-chloro-2,2-difluoroacetonitrile Chemical compound FC(F)(Cl)C#N GUIPZCNIFDPABQ-UHFFFAOYSA-N 0.000 description 1
- 229910021556 Chromium(III) chloride Inorganic materials 0.000 description 1
- 229910021564 Chromium(III) fluoride Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 150000007824 aliphatic compounds Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 229960000359 chromic chloride Drugs 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 description 1
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 125000001153 fluoro group Chemical class F* 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000005826 halohydrocarbons Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- VHHHONWQHHHLTI-UHFFFAOYSA-N hexachloroethane Chemical compound ClC(Cl)(Cl)C(Cl)(Cl)Cl VHHHONWQHHHLTI-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000002006 petroleum coke Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- FTBATIJJKIIOTP-UHFFFAOYSA-K trifluorochromium Chemical compound F[Cr](F)F FTBATIJJKIIOTP-UHFFFAOYSA-K 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/053—Sulfates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/26—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/618—Surface area more than 1000 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8027660A FR2501063A1 (fr) | 1980-12-29 | 1980-12-29 | Catalyseurs de fluoruration en phase gazeuse des derives chlores aliphatiques, a base de charbon actif impregne de sulfate de chrome, et procedes de fluoruration utilisant ces catalyseurs |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DD208083A5 true DD208083A5 (de) | 1984-03-28 |
Family
ID=9249550
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DD81235631A DD208083A5 (de) | 1980-12-29 | 1981-12-10 | Katalysator und verfahren zur gasphasenfluorierung von chlorierten aliphatischen verbindungen |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4418004A (enExample) |
| EP (1) | EP0055651B1 (enExample) |
| JP (1) | JPS57132549A (enExample) |
| AU (1) | AU546244B2 (enExample) |
| BR (1) | BR8108430A (enExample) |
| CA (1) | CA1166624A (enExample) |
| DD (1) | DD208083A5 (enExample) |
| DE (1) | DE3166644D1 (enExample) |
| ES (1) | ES8304904A1 (enExample) |
| FR (1) | FR2501063A1 (enExample) |
| PL (1) | PL132179B1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2748720B2 (ja) * | 1991-05-23 | 1998-05-13 | ダイキン工業株式会社 | ハロゲン化炭化水素のフッ素化方法 |
| US20080207963A1 (en) * | 2007-02-23 | 2008-08-28 | Velliyur Nott Mallikarjuna Rao | Preparation of composition containing chromium, oxygen, and either silver or palladium, and their use as catalysts and catalyst precursors |
| US20080207964A1 (en) * | 2007-02-23 | 2008-08-28 | Velliyur Nott Mallikarjuna Rao | Compositions containing chromium, oxygen and gold, their preparation, and their use as catalysts and catalyst precursors |
| DK2440518T3 (en) | 2009-06-08 | 2014-11-24 | Bayer Cropscience Ag | Method for producing fluoralkylnitriler |
| WO2024062827A1 (ja) * | 2022-09-22 | 2024-03-28 | Ａｇｃ株式会社 | クロロトリフルオロエチレン及びトリフルオロエチレンの製造方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2005705A (en) * | 1930-09-20 | 1935-06-18 | Kinetic Chemicals Inc | Preparation of carbon compounds containing fluorine |
| US2005706A (en) * | 1932-08-10 | 1935-06-18 | Kinetic Chemicals Inc | Organic fluorine compound |
| US2115874A (en) * | 1935-11-09 | 1938-05-03 | Union Carbide & Carbon Corp | Hydration of ethers |
| GB468447A (en) * | 1936-01-03 | 1937-07-05 | Fred Davison Leicester | Improvements in or relating to the manufacture of fluorine derivatives of aliphatic hydrocarbons |
| US2210369A (en) * | 1936-10-26 | 1940-08-06 | Gottlob Widmann K G Elektro Un | Bicycle dynamo with signal lamp |
| US2458551A (en) * | 1947-02-18 | 1949-01-11 | Du Pont | Preparation of carbon tetrafluoride |
| US3600450A (en) * | 1967-08-29 | 1971-08-17 | Franz Kaess | Process for preparing vinylidene fluoride |
| ES362777A1 (es) | 1968-01-24 | 1971-02-16 | Du Pont | Un procedimiento para la preparacion de compuestos de for- mula cf2 cicfxci. |
| NL7114576A (enExample) * | 1970-10-27 | 1972-05-02 | ||
| JPS5527139A (en) * | 1978-08-14 | 1980-02-27 | Daikin Ind Ltd | Preparation of tetrafluoroethane |
-
1980
- 1980-12-29 FR FR8027660A patent/FR2501063A1/fr active Granted
-
1981
- 1981-11-24 US US06/324,439 patent/US4418004A/en not_active Expired - Fee Related
- 1981-12-07 CA CA000391653A patent/CA1166624A/fr not_active Expired
- 1981-12-10 DD DD81235631A patent/DD208083A5/de unknown
- 1981-12-11 EP EP81401979A patent/EP0055651B1/fr not_active Expired
- 1981-12-11 DE DE8181401979T patent/DE3166644D1/de not_active Expired
- 1981-12-23 PL PL1981234422A patent/PL132179B1/pl unknown
- 1981-12-24 AU AU79038/81A patent/AU546244B2/en not_active Ceased
- 1981-12-28 ES ES508386A patent/ES8304904A1/es not_active Expired
- 1981-12-28 BR BR8108430A patent/BR8108430A/pt unknown
- 1981-12-28 JP JP56210071A patent/JPS57132549A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| CA1166624A (fr) | 1984-05-01 |
| AU546244B2 (en) | 1985-08-22 |
| JPS57132549A (en) | 1982-08-16 |
| FR2501063A1 (fr) | 1982-09-10 |
| EP0055651B1 (fr) | 1984-10-10 |
| BR8108430A (pt) | 1982-10-13 |
| PL132179B1 (en) | 1985-02-28 |
| DE3166644D1 (en) | 1984-11-15 |
| US4418004A (en) | 1983-11-29 |
| EP0055651A1 (fr) | 1982-07-07 |
| AU7903881A (en) | 1982-07-08 |
| ES508386A0 (es) | 1983-03-16 |
| JPS6340134B2 (enExample) | 1988-08-09 |
| ES8304904A1 (es) | 1983-03-16 |
| FR2501063B1 (enExample) | 1984-09-21 |
| PL234422A1 (enExample) | 1982-08-16 |
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