CO5231205A1 - Catalizadores para procesos de esterificacion - Google Patents

Catalizadores para procesos de esterificacion

Info

Publication number
CO5231205A1
CO5231205A1 CO00038297A CO00038297A CO5231205A1 CO 5231205 A1 CO5231205 A1 CO 5231205A1 CO 00038297 A CO00038297 A CO 00038297A CO 00038297 A CO00038297 A CO 00038297A CO 5231205 A1 CO5231205 A1 CO 5231205A1
Authority
CO
Colombia
Prior art keywords
ester
sterification
catalyzers
processes
compound
Prior art date
Application number
CO00038297A
Other languages
English (en)
Inventor
Charles Mark Lindall
John Ridland
Slack Neville
Original Assignee
Acma Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Acma Ltd filed Critical Acma Ltd
Publication of CO5231205A1 publication Critical patent/CO5231205A1/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0257—Phosphorus acids or phosphorus acid esters
    • B01J31/0258—Phosphoric acid mono-, di- or triesters ((RO)(R'O)2P=O), i.e. R= C, R'= C, H
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/84—Boron, aluminium, gallium, indium, thallium, rare-earth metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides, epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Una composición catalítica adecuada para emplearse como catalizador en la preparación de un éster, caracterizada porque comprende:(a) un compuesto organometálico que se prepara reaccionando conjuntamente un orto-éster u orto-éster condensado de titanio, zirconio o aluminio, un alcohol que contiene al menos dos grupos hidroxilo, y un compuesto de organofósforo que contiene al menos un grupo P-OH tal que la relación molar de metal: alcohol: compuesto de organofósforo está dentro del rango de 1 : 1 - 32 : 9,1 - 4,0 respectivamente y(b) por lo menos un compuesto de germanio, antimonio o estaño.
CO00038297A 1999-05-25 2000-05-24 Catalizadores para procesos de esterificacion CO5231205A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB9912210.3A GB9912210D0 (en) 1999-05-25 1999-05-25 Esterification catalysts

Publications (1)

Publication Number Publication Date
CO5231205A1 true CO5231205A1 (es) 2002-12-27

Family

ID=10854167

Family Applications (1)

Application Number Title Priority Date Filing Date
CO00038297A CO5231205A1 (es) 1999-05-25 2000-05-24 Catalizadores para procesos de esterificacion

Country Status (14)

Country Link
US (1) US20020087027A1 (es)
EP (1) EP1181096A1 (es)
JP (1) JP2003500492A (es)
KR (1) KR20020010671A (es)
CN (1) CN1129478C (es)
AR (1) AR024070A1 (es)
AU (1) AU4767200A (es)
BR (1) BR0010883A (es)
CO (1) CO5231205A1 (es)
GB (1) GB9912210D0 (es)
MX (1) MXPA01011984A (es)
UY (1) UY26149A1 (es)
WO (1) WO2000071252A1 (es)
ZA (1) ZA200109202B (es)

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KR100753265B1 (ko) 1999-08-24 2007-08-29 도요 보세키 가부시키가이샤 폴리에스테르 중합촉매 및 이것을 사용하여 제조된폴리에스테르 및 폴리에스테르의 제조방법
TW546330B (en) * 2000-01-07 2003-08-11 Teijin Ltd Biaxially oriented polyester film for metal sheet laminating molding
US6372879B1 (en) 2000-01-07 2002-04-16 Atofina Chemicals, Inc. Polyester polycondensation with catalyst and a catalyst enhancer
GB0002156D0 (en) * 2000-02-01 2000-03-22 Acma Ltd Esterification catalyst compositions
AU2001286193A1 (en) 2000-09-12 2002-03-26 Toyo Boseki Kabushiki Kaisha Polymerization catalyst for polyester, polyester produced with the same, and process for producing polyester
CN1610580A (zh) 2000-11-21 2005-04-27 帝国化学工业公司 酯化催化剂,聚酯方法和聚酯制品
US6914107B2 (en) * 2001-01-24 2005-07-05 E. I. Du Pont De Nemours And Company Catalyst composition and process therewith
EP1400549A4 (en) 2001-02-23 2005-02-09 Toyo Boseki POLYMERIZATION CATALYST FOR POLYESTERS, POLYESTERS MADE THEREFROM AND METHOD FOR THE PREPARATION OF POLYESTERS
US6489433B2 (en) * 2001-02-23 2002-12-03 E. I. Du Pont De Nemours And Company Metal-containing composition and process therewith
JP4930665B2 (ja) * 2001-08-01 2012-05-16 東洋紡績株式会社 ポリエステル重合触媒及びポリエステルの製造方法（オルトエステル）
US6723768B2 (en) * 2002-03-27 2004-04-20 Eastman Chemical Company Polyester/polycarbonate blends with reduced yellowness
KR20030084183A (ko) * 2002-04-25 2003-11-01 켐엔텍 주식회사 폴리에스테르의 제조방법
US6841505B2 (en) 2002-07-26 2005-01-11 E..I. Du Pont De Nemours And Company Titanium-zirconium catalyst compositions and use thereof
US6953768B2 (en) 2002-11-26 2005-10-11 Teck Cominco Metals Ltd. Multi-component catalyst system for the polycondensation manufacture of polyesters
GB0228267D0 (en) 2002-12-04 2003-01-08 Johnson Matthey Plc Catalyst and process
JP4583830B2 (ja) * 2004-07-22 2010-11-17 三洋化成工業株式会社 不飽和モノカルボン酸エステルおよびその製造方法
US8557950B2 (en) 2005-06-16 2013-10-15 Grupo Petrotemex, S.A. De C.V. High intrinsic viscosity melt phase polyester polymers with acceptable acetaldehyde generation rates
US7655746B2 (en) 2005-09-16 2010-02-02 Eastman Chemical Company Phosphorus containing compounds for reducing acetaldehyde in polyesters polymers
US8431202B2 (en) 2005-09-16 2013-04-30 Grupo Petrotemex, S.A. De C.V. Aluminum/alkaline or alkali/titanium containing polyesters having improved reheat, color and clarity
US9267007B2 (en) 2005-09-16 2016-02-23 Grupo Petrotemex, S.A. De C.V. Method for addition of additives into a polymer melt
US7932345B2 (en) 2005-09-16 2011-04-26 Grupo Petrotemex, S.A. De C.V. Aluminum containing polyester polymers having low acetaldehyde generation rates
US7838596B2 (en) 2005-09-16 2010-11-23 Eastman Chemical Company Late addition to effect compositional modifications in condensation polymers
US8309291B2 (en) * 2006-04-21 2012-11-13 Kao Corporation Polyester for toner
US7745368B2 (en) * 2006-07-28 2010-06-29 Eastman Chemical Company Non-precipitating alkali/alkaline earth metal and aluminum compositions made with organic hydroxyacids
US7709593B2 (en) 2006-07-28 2010-05-04 Eastman Chemical Company Multiple feeds of catalyst metals to a polyester production process
US7709595B2 (en) 2006-07-28 2010-05-04 Eastman Chemical Company Non-precipitating alkali/alkaline earth metal and aluminum solutions made with polyhydroxyl ether solvents
US8901272B2 (en) * 2007-02-02 2014-12-02 Grupo Petrotemex, S.A. De C.V. Polyester polymers with low acetaldehyde generation rates and high vinyl ends concentration
JP2008266359A (ja) * 2007-04-16 2008-11-06 Toyobo Co Ltd ポリエステル重合触媒およびこれを用いて製造されたポリエステルならびにポリエステルの製造方法
US20090286907A1 (en) * 2008-01-23 2009-11-19 Beltz Mark W Fumaric Acid/Diol Polyesters and Their Manufacture and Use
US20120053317A1 (en) * 2009-04-23 2012-03-01 Teijin Dupont Films Japan Limited Biaxially oriented polyester film for solar cells
CN101962437B (zh) * 2009-07-24 2013-04-17 常州化学研究所 用酯化缩聚法合成pet的新型铝催化剂
TWI423993B (zh) * 2011-06-16 2014-01-21 Univ Kaohsiung Medical 含錫催化劑用於聚酯化反應之方法
US8653224B1 (en) * 2013-02-08 2014-02-18 Lotte Chemical Corporation Resin composition for manufacturing thermoplastic polyester resin by using green catalyst
TWI537304B (zh) * 2013-08-06 2016-06-11 Shinkong Synthetic Fibers Corp Preparation of copolyester
CN103435792B (zh) * 2013-09-10 2015-05-20 杭州金海湾化工有限公司 一种锑钛组合物及其制备方法和应用
CN107384217B (zh) * 2016-03-31 2021-02-02 荒川化学工业株式会社 松香酯的制造方法和松香酯
CN106349062A (zh) * 2016-08-30 2017-01-25 深圳市普利凯新材料股份有限公司 一种采用复配催化剂合成二甘醇二甲酸酯的方法
CN106975475B (zh) * 2017-04-26 2019-12-20 中国石油化工股份有限公司 一种用于合成三羟甲基丙烷酯的催化剂及其制备方法以及应用
TWI664186B (zh) * 2017-10-05 2019-07-01 遠東新世紀股份有限公司 磷酸酯物質及其製備方法、含磷酸酯物質的聚酯樹脂及其製備方法

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TW381104B (en) * 1996-02-20 2000-02-01 Eastman Chem Co Process for preparing copolyesters of terephthalic acid, ethylene glycol, and 1,4-cyclohexanedimethanol
CN1114643C (zh) * 1997-06-10 2003-07-16 阿科蒂斯工业纤维有限公司 制备聚酯和共聚酯的方法
GB9725419D0 (en) * 1997-12-02 1998-01-28 Tioxide Specialties Ltd Esterification catalysts
WO1999054040A1 (en) * 1998-04-17 1999-10-28 E.I. Du Pont De Nemours And Company Catalytic composition comprising a titanium compound, an amine and a phosphorus compound; preparation and use thereof
US6066714A (en) * 1998-04-17 2000-05-23 E. I. Du Pont De Nemours And Company Titanium-containing catalyst composition and processes therefor and therewith

Also Published As

Publication number Publication date
ZA200109202B (en) 2003-04-30
JP2003500492A (ja) 2003-01-07
CN1351520A (zh) 2002-05-29
AR024070A1 (es) 2002-09-04
BR0010883A (pt) 2002-02-13
US20020087027A1 (en) 2002-07-04
CN1129478C (zh) 2003-12-03
UY26149A1 (es) 2001-11-30
GB9912210D0 (en) 1999-07-28
AU4767200A (en) 2000-12-12
MXPA01011984A (es) 2002-05-06
KR20020010671A (ko) 2002-02-04
WO2000071252A1 (en) 2000-11-30
EP1181096A1 (en) 2002-02-27

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