CN1997610B - 使用含有固体酸和加氢金属的催化剂的烷基化法 - Google Patents

使用含有固体酸和加氢金属的催化剂的烷基化法 Download PDF

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Publication number
CN1997610B
CN1997610B CN2005800044348A CN200580004434A CN1997610B CN 1997610 B CN1997610 B CN 1997610B CN 2005800044348 A CN2005800044348 A CN 2005800044348A CN 200580004434 A CN200580004434 A CN 200580004434A CN 1997610 B CN1997610 B CN 1997610B
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China
Prior art keywords
catalyst
water
catalyzer
alkylation
solid acid
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Expired - Fee Related
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CN2005800044348A
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English (en)
Chinese (zh)
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CN1997610A (zh
Inventor
E·H·范布洛克霍温
J·桑特
S·祖尔丹多普
N·温克勒
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Albemarle Netherlands BV
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Albemarle Netherlands BV
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
    • B01J29/126—Y-type faujasite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/8995—Catalyst and recycle considerations
    • Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2005800044348A 2004-02-09 2005-01-26 使用含有固体酸和加氢金属的催化剂的烷基化法 Expired - Fee Related CN1997610B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP04075387.3 2004-02-09
EP04075387 2004-02-09
US54792304P 2004-02-26 2004-02-26
US60/547,923 2004-02-26
PCT/EP2005/000929 WO2005075387A1 (en) 2004-02-09 2005-01-26 Alkylation process using a catalyst comprising a solid acid and a hydrogenation metal

Publications (2)

Publication Number Publication Date
CN1997610A CN1997610A (zh) 2007-07-11
CN1997610B true CN1997610B (zh) 2010-09-15

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CN2005800044348A Expired - Fee Related CN1997610B (zh) 2004-02-09 2005-01-26 使用含有固体酸和加氢金属的催化剂的烷基化法

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Country Link
US (1) US7750197B2 (enExample)
EP (1) EP1732866B1 (enExample)
JP (1) JP5016927B2 (enExample)
KR (1) KR101156299B1 (enExample)
CN (1) CN1997610B (enExample)
AU (1) AU2005211495B2 (enExample)
CA (1) CA2555197C (enExample)
DK (1) DK1732866T3 (enExample)
EA (1) EA011022B1 (enExample)
ES (1) ES2633798T3 (enExample)
HU (1) HUE034363T2 (enExample)
MX (1) MXPA06008943A (enExample)
PL (1) PL1732866T3 (enExample)
TW (1) TWI344949B (enExample)
WO (1) WO2005075387A1 (enExample)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7425659B2 (en) 2006-01-31 2008-09-16 Exxonmobil Chemical Patents Inc. Alkylaromatics production
TWI433829B (zh) * 2007-01-26 2014-04-11 Albemarle Netherlands Bv 使用含稀土元素之沸石及氫化金屬之催化劑的烷化法
EP2197817A1 (en) * 2007-10-17 2010-06-23 Albemarle Netherlands B.V. Alkylation process using a catalyst comprising rare earth containing zeolites and reduced amount of noble metal
EP2396291A1 (en) 2009-02-11 2011-12-21 Albemarle Europe Sprl. Alkylation catalyst and related process
CN102574752A (zh) * 2009-08-06 2012-07-11 中国石油大学(北京) 制备烷基化油的方法
US20170203285A1 (en) 2014-07-07 2017-07-20 Albemarle Europe Sprl Alkylation Process Using a Catalyst Comprising Cerium Rich Rare Earth Containing Zeolites and a Hydrogenation Metal
EP3589721A1 (en) 2017-03-01 2020-01-08 Albemarle Europe Srl Alkylation process with improved octane number
RU188625U1 (ru) * 2018-11-30 2019-04-18 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Устройство для алкилирования изобутана олефинами в реакторе со стационарным слоем катализатора
RU188626U1 (ru) * 2018-11-30 2019-04-18 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Устройство для алкилирования изобутана олефинами в реакторе со стационарным слоем катализатора
CN111482195B (zh) * 2019-01-25 2021-05-14 中国石油化工股份有限公司 一种固体酸催化剂
CN111482193B (zh) * 2019-01-25 2021-08-06 中国石油化工股份有限公司 一种固体酸催化剂的制备方法
CN111482194B (zh) * 2019-01-25 2021-05-14 中国石油化工股份有限公司 一种烷基化催化剂及其应用
MY207060A (en) 2019-01-25 2025-01-28 China Petroleum & Chem Corp Solid acid catalyst, preparation therefor and use thereof
US11078431B2 (en) 2019-12-16 2021-08-03 Saudi Arabian Oil Company Modified ultra-stable Y (USY) zeolite catalyst for deolefinization of hydrocarbon streams
US11098256B2 (en) 2020-01-08 2021-08-24 Saudi Arabian Oil Company Modified ultra-stable Y (USY) zeolite catalyst for improving cold flow properties of distillates
US11484869B2 (en) 2020-12-09 2022-11-01 Saudi Arabian Oil Company Modified ultra-stable Y (USY) zeolite catalyst for dealkylation of aromatics

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4918255A (en) * 1988-07-15 1990-04-17 Mobil Oil Corp. Heterogeneous isoparaffin/olefin alkylation with isomerization
EP0456839B1 (en) * 1989-12-05 1994-08-31 Osaka Gas Co., Ltd. Process for producing 4,4'-diisopropylbiphenyl

Family Cites Families (16)

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US4300015A (en) * 1966-08-25 1981-11-10 Sun Oil Company Of Pennsylvania Crystalline alumino-silicate zeolites containing polyvalent metal cations
US3534115A (en) * 1968-08-02 1970-10-13 Sun Oil Co Combination of dy alumino-silicate catalyst and hydrogenation catalyst
US3644565A (en) * 1968-09-18 1972-02-22 Union Oil Co Alkylation process
NL171331C (nl) * 1972-04-25 1983-03-16 Shell Int Research Werkwijze voor het activeren van katalysatoren die geschikt zijn voor het isomeriseren van alifatische verzadigde koolwaterstoffen.
NL171887C (nl) * 1972-04-25 1983-06-01 Shell Int Research Werkwijze voor het isomeriseren van alifatische verzadigde koolwaterstoffen in aanwezigheid van waterstof.
US4604373A (en) * 1984-08-24 1986-08-05 Union Oil Company Of California Hydrocracking catalyst of improved activity
JPH0626948B2 (ja) * 1985-07-30 1994-04-13 マツダ株式会社 車両用点滅装置
AU626091B2 (en) * 1988-07-15 1992-07-23 Mobil Oil Corporation Heterogeneous isoparaffin/olefin alkylation process
US4992616A (en) * 1988-07-15 1991-02-12 Mobil Oil Corporation Heterogeneous isoparaffin/olefin aklylation process
JP2668806B2 (ja) * 1988-07-15 1997-10-27 モービル オイル コーポレーシヨン 不均一系イソパラフィン／オレフィンアルキル化法
US5292981A (en) * 1992-06-16 1994-03-08 Mobil Oil Corporation Isoparaffin-olefin alkylation process
US5705729A (en) * 1995-11-22 1998-01-06 Mobil Oil Corporation Isoparaffin-olefin alkylation process
ES2187717T3 (es) * 1996-11-18 2003-06-16 Fina Technology Procedimiento de alquilacion con estabilidad catalitica mejorada.
AU5750598A (en) 1996-11-27 1998-06-22 Akzo Nobel N.V. Process for alkylating hydrocarbons
EP1286769B1 (en) 2000-05-30 2004-09-29 Akzo Nobel N.V. Use of a catalyst for the alkylation of hydrocarbons
DK1308207T3 (da) 2001-11-06 2011-11-14 Albemarle Netherlands Bv Svovl-holdig alkyleringskatalysator og anvendelse deraf

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4918255A (en) * 1988-07-15 1990-04-17 Mobil Oil Corp. Heterogeneous isoparaffin/olefin alkylation with isomerization
EP0456839B1 (en) * 1989-12-05 1994-08-31 Osaka Gas Co., Ltd. Process for producing 4,4'-diisopropylbiphenyl

Also Published As

Publication number Publication date
CA2555197A1 (en) 2005-08-18
MXPA06008943A (es) 2007-01-26
AU2005211495B2 (en) 2010-02-18
EP1732866A1 (en) 2006-12-20
KR101156299B1 (ko) 2012-06-13
EA011022B1 (ru) 2008-12-30
JP2007522140A (ja) 2007-08-09
US20070282149A1 (en) 2007-12-06
WO2005075387A1 (en) 2005-08-18
AU2005211495A1 (en) 2005-08-18
EP1732866B1 (en) 2017-05-17
PL1732866T3 (pl) 2017-10-31
US7750197B2 (en) 2010-07-06
HUE034363T2 (en) 2018-02-28
CA2555197C (en) 2012-10-30
ES2633798T3 (es) 2017-09-25
KR20070015134A (ko) 2007-02-01
CN1997610A (zh) 2007-07-11
TW200606130A (en) 2006-02-16
TWI344949B (en) 2011-07-11
JP5016927B2 (ja) 2012-09-05
EA200601444A1 (ru) 2007-02-27
DK1732866T3 (en) 2017-09-11

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