ES2187717T3 - Procedimiento de alquilacion con estabilidad catalitica mejorada. - Google Patents

Procedimiento de alquilacion con estabilidad catalitica mejorada.

Info

Publication number
ES2187717T3
ES2187717T3 ES97120167T ES97120167T ES2187717T3 ES 2187717 T3 ES2187717 T3 ES 2187717T3 ES 97120167 T ES97120167 T ES 97120167T ES 97120167 T ES97120167 T ES 97120167T ES 2187717 T3 ES2187717 T3 ES 2187717T3
Authority
ES
Spain
Prior art keywords
water
catalyst
pentasil
aromatic
pentasil type
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97120167T
Other languages
English (en)
Inventor
Mark E Kuchenmeister
James R Butler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fina Technology Inc
Original Assignee
Fina Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fina Technology Inc filed Critical Fina Technology Inc
Application granted granted Critical
Publication of ES2187717T3 publication Critical patent/ES2187717T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/03—Catalysts comprising molecular sieves not having base-exchange properties
    • C07C2529/035—Crystalline silica polymorphs, e.g. silicalites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

SE DESCRIBE UN PROCESO DE ALQUILACION DE SUSTRATOS AROMATICOS UTILIZANDO UN CATALIZADOR DE TIPO PENTASIL DONDE EL CATALIZADOR SE ESTABILIZA POR LA PRESENCIA DE AGUA. SE HACE REACCIONAR UN SUSTRATO AROMATICO, TAL COMO BENCENO, CON UN AGENTE DE ALQUILACION, TAL COMO ETILENO, SOBRE UN CATALIZADOR DE TIPO PENTASIL, INCLUYENDO LOS TIPOS ZSM-5 Y SILICALITA. LA ALIMENTACION AROMATICA PUEDE SER UTILIZADA EN EL PROCESO DE LA PRESENTE INVENCION SIN SECADO PARA ELIMINAR EL AGUA. HASTA AHORA HABIA SIDO NECESARIO ELIMINAR EL AGUA DE LA ALIMENTACION, POR EJEMPLO MEDIANTE DESTILACION, PUESTO QUE SE HABIA OBSERVADO QUE AUN CANTIDADES TRAZAS DE AGUA DEGRADABAN ACUSADAMENTE MUCHOS CATALIZADORES DE TIPO PENTASIL. EL PROCESO DE LA PRESENTE INVENCION DESCRIBE EL USO DE CATALIZADORES PENTASIL PARA ALQUILACION EN PRESENCIA DE 100-100.000 PPM DE AGUA PARA OBTENER UNA ESTABILIDAD MEJORADA DEL CATALIZADOR.
ES97120167T 1996-11-18 1997-11-18 Procedimiento de alquilacion con estabilidad catalitica mejorada. Expired - Lifetime ES2187717T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US74952496A 1996-11-18 1996-11-18

Publications (1)

Publication Number Publication Date
ES2187717T3 true ES2187717T3 (es) 2003-06-16

Family

ID=25014101

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97120167T Expired - Lifetime ES2187717T3 (es) 1996-11-18 1997-11-18 Procedimiento de alquilacion con estabilidad catalitica mejorada.

Country Status (7)

Country Link
EP (1) EP0842914B1 (es)
JP (1) JPH10182510A (es)
CN (1) CN1184798A (es)
AT (1) ATE229490T1 (es)
DE (1) DE69717771T2 (es)
ES (1) ES2187717T3 (es)
TW (1) TW408095B (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6670517B1 (en) * 2000-08-24 2003-12-30 Exxon Mobil Chemical Patents Inc. Process for alkylating aromatics
EP1694617B1 (en) * 2003-12-18 2011-07-20 ExxonMobil Chemical Patents Inc. Improvements in or relating to catalysed reactions
DK1732866T3 (en) * 2004-02-09 2017-09-11 Albemarle Netherlands Bv ALKYLING PROCESS USING A CATALYST CONTAINER comprising a solid acid and a hydrogenation metal
US7425659B2 (en) * 2006-01-31 2008-09-16 Exxonmobil Chemical Patents Inc. Alkylaromatics production
US7649122B2 (en) 2006-11-15 2010-01-19 Exxonmobile Chemical Patents Inc. Alkylaromatics production

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4599473A (en) * 1983-12-19 1986-07-08 Cosden Technology, Inc. Process for para selective alkylation of aromatic hydrocarbons

Also Published As

Publication number Publication date
DE69717771T2 (de) 2003-09-04
ATE229490T1 (de) 2002-12-15
DE69717771D1 (de) 2003-01-23
CN1184798A (zh) 1998-06-17
JPH10182510A (ja) 1998-07-07
EP0842914B1 (en) 2002-12-11
TW408095B (en) 2000-10-11
EP0842914A1 (en) 1998-05-20

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