ES2187717T3 - Procedimiento de alquilacion con estabilidad catalitica mejorada. - Google Patents

Procedimiento de alquilacion con estabilidad catalitica mejorada.

Info

Publication number
ES2187717T3
ES2187717T3 ES97120167T ES97120167T ES2187717T3 ES 2187717 T3 ES2187717 T3 ES 2187717T3 ES 97120167 T ES97120167 T ES 97120167T ES 97120167 T ES97120167 T ES 97120167T ES 2187717 T3 ES2187717 T3 ES 2187717T3
Authority
ES
Spain
Prior art keywords
water
catalyst
pentasil
aromatic
pentasil type
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97120167T
Other languages
English (en)
Inventor
Mark E Kuchenmeister
James R Butler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fina Technology Inc
Original Assignee
Fina Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fina Technology Inc filed Critical Fina Technology Inc
Application granted granted Critical
Publication of ES2187717T3 publication Critical patent/ES2187717T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/03—Catalysts comprising molecular sieves not having base-exchange properties
    • C07C2529/035—Crystalline silica polymorphs, e.g. silicalites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

SE DESCRIBE UN PROCESO DE ALQUILACION DE SUSTRATOS AROMATICOS UTILIZANDO UN CATALIZADOR DE TIPO PENTASIL DONDE EL CATALIZADOR SE ESTABILIZA POR LA PRESENCIA DE AGUA. SE HACE REACCIONAR UN SUSTRATO AROMATICO, TAL COMO BENCENO, CON UN AGENTE DE ALQUILACION, TAL COMO ETILENO, SOBRE UN CATALIZADOR DE TIPO PENTASIL, INCLUYENDO LOS TIPOS ZSM-5 Y SILICALITA. LA ALIMENTACION AROMATICA PUEDE SER UTILIZADA EN EL PROCESO DE LA PRESENTE INVENCION SIN SECADO PARA ELIMINAR EL AGUA. HASTA AHORA HABIA SIDO NECESARIO ELIMINAR EL AGUA DE LA ALIMENTACION, POR EJEMPLO MEDIANTE DESTILACION, PUESTO QUE SE HABIA OBSERVADO QUE AUN CANTIDADES TRAZAS DE AGUA DEGRADABAN ACUSADAMENTE MUCHOS CATALIZADORES DE TIPO PENTASIL. EL PROCESO DE LA PRESENTE INVENCION DESCRIBE EL USO DE CATALIZADORES PENTASIL PARA ALQUILACION EN PRESENCIA DE 100-100.000 PPM DE AGUA PARA OBTENER UNA ESTABILIDAD MEJORADA DEL CATALIZADOR.
ES97120167T 1996-11-18 1997-11-18 Procedimiento de alquilacion con estabilidad catalitica mejorada. Expired - Lifetime ES2187717T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US74952496A 1996-11-18 1996-11-18

Publications (1)

Publication Number Publication Date
ES2187717T3 true ES2187717T3 (es) 2003-06-16

Family

ID=25014101

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97120167T Expired - Lifetime ES2187717T3 (es) 1996-11-18 1997-11-18 Procedimiento de alquilacion con estabilidad catalitica mejorada.

Country Status (7)

Country Link
EP (1) EP0842914B1 (es)
JP (1) JPH10182510A (es)
CN (1) CN1184798A (es)
AT (1) ATE229490T1 (es)
DE (1) DE69717771T2 (es)
ES (1) ES2187717T3 (es)
TW (1) TW408095B (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6670517B1 (en) * 2000-08-24 2003-12-30 Exxon Mobil Chemical Patents Inc. Process for alkylating aromatics
JP2007514702A (ja) * 2003-12-18 2007-06-07 エクソンモービル・ケミカル・パテンツ・インク 触媒反応の改良
CN1997610B (zh) * 2004-02-09 2010-09-15 阿尔伯麦尔荷兰公司 使用含有固体酸和加氢金属的催化剂的烷基化法
US7425659B2 (en) 2006-01-31 2008-09-16 Exxonmobil Chemical Patents Inc. Alkylaromatics production
US7649122B2 (en) 2006-11-15 2010-01-19 Exxonmobile Chemical Patents Inc. Alkylaromatics production

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4599473A (en) * 1983-12-19 1986-07-08 Cosden Technology, Inc. Process for para selective alkylation of aromatic hydrocarbons

Also Published As

Publication number Publication date
EP0842914B1 (en) 2002-12-11
DE69717771T2 (de) 2003-09-04
EP0842914A1 (en) 1998-05-20
JPH10182510A (ja) 1998-07-07
TW408095B (en) 2000-10-11
CN1184798A (zh) 1998-06-17
ATE229490T1 (de) 2002-12-15
DE69717771D1 (de) 2003-01-23

Similar Documents

Publication Publication Date Title
TW374079B (en) Process and system for alkylation of aromatic compounds
CA2264700A1 (en) Alkylation process using zeolite beta
ES2193612T3 (es) Procedimiento de alquilacion aromatica.
ES2098673T3 (es) Procedimiento mejorado para la alquilacion de aromaticos con olefinas lineales obtenidas a partir de una etapa de deshidrogenacion de parafinas lineales.
TW330193B (en) Continuous process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation
ATE228157T1 (de) Herstellung von olefinen
ATE228156T1 (de) Herstellung von olefinen
DE60006191D1 (de) Verfahren zur Alkylierung von Benzol
BR9507370A (pt) Processo para produção de fenol e dos seus derívados
ATE455741T1 (de) Verfahren zur herstellung von sek.-butylbenzol
ATE244288T1 (de) Herstellung von olefinen
CA2300083A1 (en) Propylene oxide purification
TW369543B (en) Process for the preparation of polyalkyl-1-oxa-diazaspirodecane compounds
ES2187717T3 (es) Procedimiento de alquilacion con estabilidad catalitica mejorada.
ATE276221T1 (de) Behandlung einer zusammensetzung enthaltend ein trimethylolalkan-bis-monolineares formal
NO934861D0 (no) Fremgangsmaate ved fremstilling av 2-alkyl-6-metyl-N-(1'-metoksy-2 '-propyl)-anilin, samt tilsvarende kloacetanilider
EP1068898A3 (en) Process for the regeneration of zeolitic catalysts used in (trans)alkylation processes
EP0160145A3 (en) Alkylation of aromatic molecules using wide pore, amorphous silica-alumina catalyst
BR8703039A (pt) Processo para a para-alquilacao seletiva de compostos aromaticos mono-substituidos;processo para a producao seletiva de para-xileno
DE69921269D1 (de) Verfahren zur Herstellung von halogenierten Kohlenwasserstoffen
GB2279661A (en) Nonextractive processes for producing high purity aromatics
CA2265490A1 (en) Alkylation of organic aromatic compounds using beta zeolite catalyst
CA2106028A1 (en) Improved process for alkylation of aromatics with linear olefins derived from a linear paraffin dehydrogenation step
ES8704145A1 (es) Procedimiento para la alquilacion de compuestos aromaticos organicos
US6989469B2 (en) Preparation method