ES2633798T3 - Proceso de alquilación que usa un catalizador que comprende un ácido sólido y un metal de hidrogenación - Google Patents

Proceso de alquilación que usa un catalizador que comprende un ácido sólido y un metal de hidrogenación Download PDF

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Publication number
ES2633798T3
ES2633798T3 ES05701274.2T ES05701274T ES2633798T3 ES 2633798 T3 ES2633798 T3 ES 2633798T3 ES 05701274 T ES05701274 T ES 05701274T ES 2633798 T3 ES2633798 T3 ES 2633798T3
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ES
Spain
Prior art keywords
catalyst
solid acid
hydrogenation metal
alkylation process
hydrogenation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES05701274.2T
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English (en)
Inventor
Emanuel Hermanus Van Broekhoven
Jan Sant
Stephan Zuijdendorp
Niels Winkler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Albemarle Netherlands BV
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Albemarle Netherlands BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Albemarle Netherlands BV filed Critical Albemarle Netherlands BV
Application granted granted Critical
Publication of ES2633798T3 publication Critical patent/ES2633798T3/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
    • B01J29/126—Y-type faujasite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/8995—Catalyst and recycle considerations
    • Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

poner en contacto la alimentación de hidrocarburo a alquilar con un agente de alquilación que comprende una olefina que tiene 2-6 átomos de carbono en presencia de un catalizador que comprende una zeolita de ácido sólido, platino como metal de hidrogenación, caracterizado por que el catalizador comprende el 1,5 - 6 % en peso de agua, medida como la pérdida por ignición a 600 ºC.

Description

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Claims (1)

  1. imagen1
ES05701274.2T 2004-02-09 2005-01-26 Proceso de alquilación que usa un catalizador que comprende un ácido sólido y un metal de hidrogenación Active ES2633798T3 (es)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP04075387 2004-02-09
EP04075387 2004-02-09
US54792304P 2004-02-26 2004-02-26
US547923P 2004-02-26
PCT/EP2005/000929 WO2005075387A1 (en) 2004-02-09 2005-01-26 Alkylation process using a catalyst comprising a solid acid and a hydrogenation metal

Publications (1)

Publication Number Publication Date
ES2633798T3 true ES2633798T3 (es) 2017-09-25

Family

ID=34928095

Family Applications (1)

Application Number Title Priority Date Filing Date
ES05701274.2T Active ES2633798T3 (es) 2004-02-09 2005-01-26 Proceso de alquilación que usa un catalizador que comprende un ácido sólido y un metal de hidrogenación

Country Status (15)

Country Link
US (1) US7750197B2 (es)
EP (1) EP1732866B1 (es)
JP (1) JP5016927B2 (es)
KR (1) KR101156299B1 (es)
CN (1) CN1997610B (es)
AU (1) AU2005211495B2 (es)
CA (1) CA2555197C (es)
DK (1) DK1732866T3 (es)
EA (1) EA011022B1 (es)
ES (1) ES2633798T3 (es)
HU (1) HUE034363T2 (es)
MX (1) MXPA06008943A (es)
PL (1) PL1732866T3 (es)
TW (1) TWI344949B (es)
WO (1) WO2005075387A1 (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7425659B2 (en) 2006-01-31 2008-09-16 Exxonmobil Chemical Patents Inc. Alkylaromatics production
TWI433829B (zh) * 2007-01-26 2014-04-11 Albemarle Netherlands Bv 使用含稀土元素之沸石及氫化金屬之催化劑的烷化法
CN101827802A (zh) * 2007-10-17 2010-09-08 雅宝荷兰有限责任公司 使用包括含稀土元素的沸石和减少量的贵金属的催化剂的烷基化工艺
CN102333744A (zh) 2009-02-11 2012-01-25 阿尔比马尔欧洲有限公司 烷基化催化剂和相关方法
CN102574752A (zh) * 2009-08-06 2012-07-11 中国石油大学(北京) 制备烷基化油的方法
DK3167026T3 (da) * 2014-07-07 2019-07-01 Albemarle Europe Sprl Alkyleringsfremgangsmåde der anvender en katalysator, som omfatter sjælden jord rigt på cerium, der indeholder zeolitter og et hydrogeneringsmetal.
AU2018226543B2 (en) * 2017-03-01 2023-03-30 Albemarle Europe Srl Alkylation process with improved octane number
RU188626U1 (ru) * 2018-11-30 2019-04-18 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Устройство для алкилирования изобутана олефинами в реакторе со стационарным слоем катализатора
RU188625U1 (ru) * 2018-11-30 2019-04-18 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Устройство для алкилирования изобутана олефинами в реакторе со стационарным слоем катализатора
EP3915681A4 (en) 2019-01-25 2022-11-09 China Petroleum & Chemical Corporation SOLID ACID CATALYST, ITS PREPARATION AND USE
CN111482195B (zh) * 2019-01-25 2021-05-14 中国石油化工股份有限公司 一种固体酸催化剂
CN111482194B (zh) * 2019-01-25 2021-05-14 中国石油化工股份有限公司 一种烷基化催化剂及其应用
CN111482193B (zh) * 2019-01-25 2021-08-06 中国石油化工股份有限公司 一种固体酸催化剂的制备方法
US11078431B2 (en) 2019-12-16 2021-08-03 Saudi Arabian Oil Company Modified ultra-stable Y (USY) zeolite catalyst for deolefinization of hydrocarbon streams
US11098256B2 (en) 2020-01-08 2021-08-24 Saudi Arabian Oil Company Modified ultra-stable Y (USY) zeolite catalyst for improving cold flow properties of distillates
US11484869B2 (en) 2020-12-09 2022-11-01 Saudi Arabian Oil Company Modified ultra-stable Y (USY) zeolite catalyst for dealkylation of aromatics

Family Cites Families (18)

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US4300015A (en) * 1966-08-25 1981-11-10 Sun Oil Company Of Pennsylvania Crystalline alumino-silicate zeolites containing polyvalent metal cations
US3534115A (en) * 1968-08-02 1970-10-13 Sun Oil Co Combination of dy alumino-silicate catalyst and hydrogenation catalyst
US3644565A (en) * 1968-09-18 1972-02-22 Union Oil Co Alkylation process
NL171331C (nl) * 1972-04-25 1983-03-16 Shell Int Research Werkwijze voor het activeren van katalysatoren die geschikt zijn voor het isomeriseren van alifatische verzadigde koolwaterstoffen.
NL171887C (nl) * 1972-04-25 1983-06-01 Shell Int Research Werkwijze voor het isomeriseren van alifatische verzadigde koolwaterstoffen in aanwezigheid van waterstof.
US4604373A (en) * 1984-08-24 1986-08-05 Union Oil Company Of California Hydrocracking catalyst of improved activity
JPH0626948B2 (ja) * 1985-07-30 1994-04-13 マツダ株式会社 車両用点滅装置
DE68910977T2 (de) * 1988-07-15 1994-03-17 Mobil Oil Corp Heterogenes isoparaffin/olefin-alkylierungsverfahren.
US4918255A (en) * 1988-07-15 1990-04-17 Mobil Oil Corp. Heterogeneous isoparaffin/olefin alkylation with isomerization
US4992616A (en) * 1988-07-15 1991-02-12 Mobil Oil Corporation Heterogeneous isoparaffin/olefin aklylation process
WO1990000533A1 (en) * 1988-07-15 1990-01-25 Mobil Oil Corporation Heterogeneous isoparaffin/olefin alkylation process
WO1991008181A1 (en) * 1989-12-05 1991-06-13 Osaka Gas Company Limited Process for producing 4,4'-diisopropylbiphenyl
US5292981A (en) * 1992-06-16 1994-03-08 Mobil Oil Corporation Isoparaffin-olefin alkylation process
US5705729A (en) * 1995-11-22 1998-01-06 Mobil Oil Corporation Isoparaffin-olefin alkylation process
DE69717771T2 (de) * 1996-11-18 2003-09-04 Fina Technology, Inc. Alkylierungsverfahren mit höherer Katalysatorstabilität
JP4278067B2 (ja) 1996-11-27 2009-06-10 アルベマーレ ネザーランズ ビー．ブイ． 炭化水素のアルキル化法
AU2001266005A1 (en) 2000-05-30 2001-12-11 Akzo Nobel N.V. Novel alkylation catalyst and its use in alkylation
ES2371238T3 (es) * 2001-11-06 2011-12-28 Albemarle Netherlands B.V. Catalizador de alquilación que contiene azufre y su uso.

Also Published As

Publication number Publication date
EP1732866A1 (en) 2006-12-20
TWI344949B (en) 2011-07-11
US7750197B2 (en) 2010-07-06
EA200601444A1 (ru) 2007-02-27
WO2005075387A1 (en) 2005-08-18
TW200606130A (en) 2006-02-16
CN1997610A (zh) 2007-07-11
MXPA06008943A (es) 2007-01-26
EP1732866B1 (en) 2017-05-17
AU2005211495A1 (en) 2005-08-18
JP5016927B2 (ja) 2012-09-05
CN1997610B (zh) 2010-09-15
KR101156299B1 (ko) 2012-06-13
KR20070015134A (ko) 2007-02-01
HUE034363T2 (en) 2018-02-28
CA2555197C (en) 2012-10-30
CA2555197A1 (en) 2005-08-18
JP2007522140A (ja) 2007-08-09
DK1732866T3 (en) 2017-09-11
AU2005211495B2 (en) 2010-02-18
US20070282149A1 (en) 2007-12-06
PL1732866T3 (pl) 2017-10-31
EA011022B1 (ru) 2008-12-30

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