TWI344949B - Alkylation process using a catalyst comprising a solid acid and a hydrogenation metal - Google Patents
Alkylation process using a catalyst comprising a solid acid and a hydrogenation metal Download PDFInfo
- Publication number
- TWI344949B TWI344949B TW094104053A TW94104053A TWI344949B TW I344949 B TWI344949 B TW I344949B TW 094104053 A TW094104053 A TW 094104053A TW 94104053 A TW94104053 A TW 94104053A TW I344949 B TWI344949 B TW I344949B
- Authority
- TW
- Taiwan
- Prior art keywords
- catalyst
- water
- weight
- solid acid
- doc
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 122
- 239000011973 solid acid Substances 0.000 title claims abstract description 24
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 16
- 239000002184 metal Substances 0.000 title claims abstract description 16
- 238000005984 hydrogenation reaction Methods 0.000 title claims abstract description 11
- 238000005804 alkylation reaction Methods 0.000 title abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 62
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 44
- 230000008569 process Effects 0.000 claims abstract description 22
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 20
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 20
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- 230000002152 alkylating effect Effects 0.000 claims abstract description 3
- 238000006243 chemical reaction Methods 0.000 claims description 35
- 239000010457 zeolite Substances 0.000 claims description 16
- 230000008929 regeneration Effects 0.000 claims description 13
- 238000011069 regeneration method Methods 0.000 claims description 13
- 229910021536 Zeolite Inorganic materials 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 9
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 6
- 238000002485 combustion reaction Methods 0.000 claims description 2
- 229910000510 noble metal Inorganic materials 0.000 claims description 2
- 238000005245 sintering Methods 0.000 claims description 2
- 238000001354 calcination Methods 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 229910052680 mordenite Inorganic materials 0.000 claims 1
- 230000029936 alkylation Effects 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 6
- 230000002829 reductive effect Effects 0.000 description 17
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 12
- 239000002245 particle Substances 0.000 description 12
- 239000007789 gas Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 11
- 238000012812 general test Methods 0.000 description 10
- 230000009467 reduction Effects 0.000 description 10
- 239000002168 alkylating agent Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 229940100198 alkylating agent Drugs 0.000 description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 7
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 239000001282 iso-butane Substances 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000003570 air Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 238000011065 in-situ storage Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 239000000571 coke Substances 0.000 description 3
- 238000004880 explosion Methods 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- -1 mixed oxide of wrong Chemical compound 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- FLTJDUOFAQWHDF-UHFFFAOYSA-N trimethyl pentane Natural products CCCCC(C)(C)C FLTJDUOFAQWHDF-UHFFFAOYSA-N 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000012080 ambient air Substances 0.000 description 2
- 210000004556 brain Anatomy 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- IAQRGUVFOMOMEM-ARJAWSKDSA-N cis-but-2-ene Chemical compound C\C=C/C IAQRGUVFOMOMEM-ARJAWSKDSA-N 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical group CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- UNASZPQZIFZUSI-UHFFFAOYSA-N methylidyneniobium Chemical compound [Nb]#C UNASZPQZIFZUSI-UHFFFAOYSA-N 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- RPAJSBKBKSSMLJ-DFWYDOINSA-N (2s)-2-aminopentanedioic acid;hydrochloride Chemical class Cl.OC(=O)[C@@H](N)CCC(O)=O RPAJSBKBKSSMLJ-DFWYDOINSA-N 0.000 description 1
- SPWDQSXYMZXSIV-UHFFFAOYSA-N 11,12-dimethyldocosane Chemical compound CCCCCCCCCCC(C)C(C)CCCCCCCCCC SPWDQSXYMZXSIV-UHFFFAOYSA-N 0.000 description 1
- XTDQDBVBDLYELW-UHFFFAOYSA-N 2,2,3-trimethylpentane Chemical compound CCC(C)C(C)(C)C XTDQDBVBDLYELW-UHFFFAOYSA-N 0.000 description 1
- HHOSMYBYIHNXNO-UHFFFAOYSA-N 2,2,5-trimethylhexane Chemical compound CC(C)CCC(C)(C)C HHOSMYBYIHNXNO-UHFFFAOYSA-N 0.000 description 1
- OKVWYBALHQFVFP-UHFFFAOYSA-N 2,3,3-trimethylpentane Chemical compound CCC(C)(C)C(C)C OKVWYBALHQFVFP-UHFFFAOYSA-N 0.000 description 1
- XYYMFUCZDNNGFS-UHFFFAOYSA-N 2-methylheptan-3-one Chemical compound CCCCC(=O)C(C)C XYYMFUCZDNNGFS-UHFFFAOYSA-N 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- DZFZYDIYQICXND-UHFFFAOYSA-N C(CCCCCCCCC)C(C)C(CC)CCCCCCCCCC Chemical compound C(CCCCCCCCC)C(C)C(CC)CCCCCCCCCC DZFZYDIYQICXND-UHFFFAOYSA-N 0.000 description 1
- CMCQZHBZLISNNH-UHFFFAOYSA-N C(CCCCCCCCC)C(C)CC(C)(CCCCCCCCCC)CCCCCCCCCC Chemical compound C(CCCCCCCCC)C(C)CC(C)(CCCCCCCCCC)CCCCCCCCCC CMCQZHBZLISNNH-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 235000007106 Crataegus suborbiculata Nutrition 0.000 description 1
- 241000073432 Crataegus suborbiculata Species 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 235000013202 a hawthorn Nutrition 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000002269 analeptic agent Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000011066 ex-situ storage Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000010437 gem Substances 0.000 description 1
- 229910001751 gemstone Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000004081 narcotic agent Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000001558 permutation test Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052851 sillimanite Inorganic materials 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical group 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/56—Addition to acyclic hydrocarbons
- C07C2/58—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/20—Organic compounds not containing metal atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/20—Organic compounds not containing metal atoms
- C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
- B01J29/12—Noble metals
- B01J29/126—Y-type faujasite
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/8995—Catalyst and recycle considerations
- Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04075387 | 2004-02-09 | ||
| US54792304P | 2004-02-26 | 2004-02-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200606130A TW200606130A (en) | 2006-02-16 |
| TWI344949B true TWI344949B (en) | 2011-07-11 |
Family
ID=34928095
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW094104053A TWI344949B (en) | 2004-02-09 | 2005-02-05 | Alkylation process using a catalyst comprising a solid acid and a hydrogenation metal |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US7750197B2 (enExample) |
| EP (1) | EP1732866B1 (enExample) |
| JP (1) | JP5016927B2 (enExample) |
| KR (1) | KR101156299B1 (enExample) |
| CN (1) | CN1997610B (enExample) |
| AU (1) | AU2005211495B2 (enExample) |
| CA (1) | CA2555197C (enExample) |
| DK (1) | DK1732866T3 (enExample) |
| EA (1) | EA011022B1 (enExample) |
| ES (1) | ES2633798T3 (enExample) |
| HU (1) | HUE034363T2 (enExample) |
| MX (1) | MXPA06008943A (enExample) |
| PL (1) | PL1732866T3 (enExample) |
| TW (1) | TWI344949B (enExample) |
| WO (1) | WO2005075387A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7425659B2 (en) | 2006-01-31 | 2008-09-16 | Exxonmobil Chemical Patents Inc. | Alkylaromatics production |
| TWI433829B (zh) * | 2007-01-26 | 2014-04-11 | Albemarle Netherlands Bv | 使用含稀土元素之沸石及氫化金屬之催化劑的烷化法 |
| WO2009050067A1 (en) * | 2007-10-17 | 2009-04-23 | Albemarle Netherlands, B.V. | Alkylation process using a catalyst comprising rare earth containing zeolites and reduced amount of noble metal |
| US20110313227A1 (en) | 2009-02-11 | 2011-12-22 | Albemarle Europe Sprl | Alkylation catalyst and related process |
| CN102574752A (zh) * | 2009-08-06 | 2012-07-11 | 中国石油大学(北京) | 制备烷基化油的方法 |
| AU2015286798B2 (en) * | 2014-07-07 | 2020-03-12 | Albemarle Europe Sprl | Alkylation process using a catalyst comprising cerium rich rare earth containing zeolites and a hydrogenation metal |
| WO2018158377A1 (en) | 2017-03-01 | 2018-09-07 | Albemarle Europe Sprl | Alkylation process with improved octane number |
| RU188625U1 (ru) * | 2018-11-30 | 2019-04-18 | Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) | Устройство для алкилирования изобутана олефинами в реакторе со стационарным слоем катализатора |
| RU188626U1 (ru) * | 2018-11-30 | 2019-04-18 | Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) | Устройство для алкилирования изобутана олефинами в реакторе со стационарным слоем катализатора |
| CN111482194B (zh) * | 2019-01-25 | 2021-05-14 | 中国石油化工股份有限公司 | 一种烷基化催化剂及其应用 |
| CN111482195B (zh) * | 2019-01-25 | 2021-05-14 | 中国石油化工股份有限公司 | 一种固体酸催化剂 |
| CN111482193B (zh) * | 2019-01-25 | 2021-08-06 | 中国石油化工股份有限公司 | 一种固体酸催化剂的制备方法 |
| US11951461B2 (en) | 2019-01-25 | 2024-04-09 | China Petroleum & Chemical Corporation | Solid acid catalyst, preparation therefor and use thereof |
| US11078431B2 (en) | 2019-12-16 | 2021-08-03 | Saudi Arabian Oil Company | Modified ultra-stable Y (USY) zeolite catalyst for deolefinization of hydrocarbon streams |
| US11098256B2 (en) | 2020-01-08 | 2021-08-24 | Saudi Arabian Oil Company | Modified ultra-stable Y (USY) zeolite catalyst for improving cold flow properties of distillates |
| US11484869B2 (en) | 2020-12-09 | 2022-11-01 | Saudi Arabian Oil Company | Modified ultra-stable Y (USY) zeolite catalyst for dealkylation of aromatics |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4300015A (en) * | 1966-08-25 | 1981-11-10 | Sun Oil Company Of Pennsylvania | Crystalline alumino-silicate zeolites containing polyvalent metal cations |
| US3534115A (en) * | 1968-08-02 | 1970-10-13 | Sun Oil Co | Combination of dy alumino-silicate catalyst and hydrogenation catalyst |
| US3644565A (en) * | 1968-09-18 | 1972-02-22 | Union Oil Co | Alkylation process |
| NL171331C (nl) * | 1972-04-25 | 1983-03-16 | Shell Int Research | Werkwijze voor het activeren van katalysatoren die geschikt zijn voor het isomeriseren van alifatische verzadigde koolwaterstoffen. |
| NL171887C (nl) * | 1972-04-25 | 1983-06-01 | Shell Int Research | Werkwijze voor het isomeriseren van alifatische verzadigde koolwaterstoffen in aanwezigheid van waterstof. |
| US4604373A (en) * | 1984-08-24 | 1986-08-05 | Union Oil Company Of California | Hydrocracking catalyst of improved activity |
| JPH0626948B2 (ja) * | 1985-07-30 | 1994-04-13 | マツダ株式会社 | 車両用点滅装置 |
| DE68924165T2 (de) * | 1988-07-15 | 1996-02-29 | Mobil Oil Corp | Heterogenes isoparaffin/olefin-alkylierungsverfahren. |
| DE68910977T2 (de) * | 1988-07-15 | 1994-03-17 | Mobil Oil Corp | Heterogenes isoparaffin/olefin-alkylierungsverfahren. |
| US4992616A (en) * | 1988-07-15 | 1991-02-12 | Mobil Oil Corporation | Heterogeneous isoparaffin/olefin aklylation process |
| US4918255A (en) * | 1988-07-15 | 1990-04-17 | Mobil Oil Corp. | Heterogeneous isoparaffin/olefin alkylation with isomerization |
| DE69012103T2 (de) * | 1989-12-05 | 1995-04-06 | Osaka Gas Co Ltd | Verfahren zur herstellung von 4,4'-diisopropylbiphenyl. |
| US5292981A (en) * | 1992-06-16 | 1994-03-08 | Mobil Oil Corporation | Isoparaffin-olefin alkylation process |
| US5705729A (en) * | 1995-11-22 | 1998-01-06 | Mobil Oil Corporation | Isoparaffin-olefin alkylation process |
| DE69717771T2 (de) * | 1996-11-18 | 2003-09-04 | Fina Technology, Inc. | Alkylierungsverfahren mit höherer Katalysatorstabilität |
| KR100533754B1 (ko) | 1996-11-27 | 2005-12-06 | 알베마를 네덜란드 비.브이. | 탄화수소의 알킬화 방법 |
| WO2001091901A1 (en) * | 2000-05-30 | 2001-12-06 | Akzo Nobel N.V. | Novel alkylation catalyst and its use in alkylation |
| EP1308207B1 (en) * | 2001-11-06 | 2011-08-10 | Albemarle Netherlands B.V. | Sulfur-containing alkylation catalyst and use thereof |
-
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- 2005-01-26 CN CN2005800044348A patent/CN1997610B/zh not_active Expired - Fee Related
- 2005-01-26 EA EA200601444A patent/EA011022B1/ru not_active IP Right Cessation
- 2005-01-26 AU AU2005211495A patent/AU2005211495B2/en not_active Ceased
- 2005-01-26 EP EP05701274.2A patent/EP1732866B1/en not_active Expired - Lifetime
- 2005-01-26 US US10/588,106 patent/US7750197B2/en not_active Expired - Lifetime
- 2005-01-26 WO PCT/EP2005/000929 patent/WO2005075387A1/en not_active Ceased
- 2005-01-26 MX MXPA06008943A patent/MXPA06008943A/es active IP Right Grant
- 2005-01-26 KR KR1020067017504A patent/KR101156299B1/ko not_active Expired - Fee Related
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- 2005-01-26 DK DK05701274.2T patent/DK1732866T3/en active
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Also Published As
| Publication number | Publication date |
|---|---|
| CN1997610B (zh) | 2010-09-15 |
| US20070282149A1 (en) | 2007-12-06 |
| ES2633798T3 (es) | 2017-09-25 |
| EA011022B1 (ru) | 2008-12-30 |
| KR20070015134A (ko) | 2007-02-01 |
| CA2555197C (en) | 2012-10-30 |
| EA200601444A1 (ru) | 2007-02-27 |
| AU2005211495B2 (en) | 2010-02-18 |
| HUE034363T2 (en) | 2018-02-28 |
| MXPA06008943A (es) | 2007-01-26 |
| PL1732866T3 (pl) | 2017-10-31 |
| US7750197B2 (en) | 2010-07-06 |
| JP5016927B2 (ja) | 2012-09-05 |
| WO2005075387A1 (en) | 2005-08-18 |
| KR101156299B1 (ko) | 2012-06-13 |
| CA2555197A1 (en) | 2005-08-18 |
| CN1997610A (zh) | 2007-07-11 |
| AU2005211495A1 (en) | 2005-08-18 |
| JP2007522140A (ja) | 2007-08-09 |
| EP1732866A1 (en) | 2006-12-20 |
| TW200606130A (en) | 2006-02-16 |
| DK1732866T3 (en) | 2017-09-11 |
| EP1732866B1 (en) | 2017-05-17 |
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