AU2005211495B2 - Alkylation process using a catalyst comprising a solid acid and a hydrogenation metal - Google Patents

Alkylation process using a catalyst comprising a solid acid and a hydrogenation metal Download PDF

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Publication number
AU2005211495B2
AU2005211495B2 AU2005211495A AU2005211495A AU2005211495B2 AU 2005211495 B2 AU2005211495 B2 AU 2005211495B2 AU 2005211495 A AU2005211495 A AU 2005211495A AU 2005211495 A AU2005211495 A AU 2005211495A AU 2005211495 B2 AU2005211495 B2 AU 2005211495B2
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AU
Australia
Prior art keywords
catalyst
water
alkylation
process according
solid acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU2005211495A
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English (en)
Other versions
AU2005211495A1 (en
Inventor
Jan Sant
Emanuel Hermanus Van Broekhoven
Niels Winkler
Stephan Zuijdendorp
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Albemarle Netherlands BV
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Albemarle Netherlands BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Albemarle Netherlands BV filed Critical Albemarle Netherlands BV
Publication of AU2005211495A1 publication Critical patent/AU2005211495A1/en
Application granted granted Critical
Publication of AU2005211495B2 publication Critical patent/AU2005211495B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
    • B01J29/126—Y-type faujasite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/8995—Catalyst and recycle considerations
    • Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
AU2005211495A 2004-02-09 2005-01-26 Alkylation process using a catalyst comprising a solid acid and a hydrogenation metal Ceased AU2005211495B2 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP04075387.3 2004-02-09
EP04075387 2004-02-09
US54792304P 2004-02-26 2004-02-26
US60/547,923 2004-02-26
PCT/EP2005/000929 WO2005075387A1 (en) 2004-02-09 2005-01-26 Alkylation process using a catalyst comprising a solid acid and a hydrogenation metal

Publications (2)

Publication Number Publication Date
AU2005211495A1 AU2005211495A1 (en) 2005-08-18
AU2005211495B2 true AU2005211495B2 (en) 2010-02-18

Family

ID=34928095

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2005211495A Ceased AU2005211495B2 (en) 2004-02-09 2005-01-26 Alkylation process using a catalyst comprising a solid acid and a hydrogenation metal

Country Status (15)

Country Link
US (1) US7750197B2 (enExample)
EP (1) EP1732866B1 (enExample)
JP (1) JP5016927B2 (enExample)
KR (1) KR101156299B1 (enExample)
CN (1) CN1997610B (enExample)
AU (1) AU2005211495B2 (enExample)
CA (1) CA2555197C (enExample)
DK (1) DK1732866T3 (enExample)
EA (1) EA011022B1 (enExample)
ES (1) ES2633798T3 (enExample)
HU (1) HUE034363T2 (enExample)
MX (1) MXPA06008943A (enExample)
PL (1) PL1732866T3 (enExample)
TW (1) TWI344949B (enExample)
WO (1) WO2005075387A1 (enExample)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7425659B2 (en) 2006-01-31 2008-09-16 Exxonmobil Chemical Patents Inc. Alkylaromatics production
TWI433829B (zh) * 2007-01-26 2014-04-11 Albemarle Netherlands Bv 使用含稀土元素之沸石及氫化金屬之催化劑的烷化法
WO2009050067A1 (en) * 2007-10-17 2009-04-23 Albemarle Netherlands, B.V. Alkylation process using a catalyst comprising rare earth containing zeolites and reduced amount of noble metal
US20110313227A1 (en) 2009-02-11 2011-12-22 Albemarle Europe Sprl Alkylation catalyst and related process
CN102574752A (zh) * 2009-08-06 2012-07-11 中国石油大学(北京) 制备烷基化油的方法
AU2015286798B2 (en) * 2014-07-07 2020-03-12 Albemarle Europe Sprl Alkylation process using a catalyst comprising cerium rich rare earth containing zeolites and a hydrogenation metal
WO2018158377A1 (en) 2017-03-01 2018-09-07 Albemarle Europe Sprl Alkylation process with improved octane number
RU188625U1 (ru) * 2018-11-30 2019-04-18 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Устройство для алкилирования изобутана олефинами в реакторе со стационарным слоем катализатора
RU188626U1 (ru) * 2018-11-30 2019-04-18 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Устройство для алкилирования изобутана олефинами в реакторе со стационарным слоем катализатора
CN111482194B (zh) * 2019-01-25 2021-05-14 中国石油化工股份有限公司 一种烷基化催化剂及其应用
CN111482195B (zh) * 2019-01-25 2021-05-14 中国石油化工股份有限公司 一种固体酸催化剂
CN111482193B (zh) * 2019-01-25 2021-08-06 中国石油化工股份有限公司 一种固体酸催化剂的制备方法
US11951461B2 (en) 2019-01-25 2024-04-09 China Petroleum & Chemical Corporation Solid acid catalyst, preparation therefor and use thereof
US11078431B2 (en) 2019-12-16 2021-08-03 Saudi Arabian Oil Company Modified ultra-stable Y (USY) zeolite catalyst for deolefinization of hydrocarbon streams
US11098256B2 (en) 2020-01-08 2021-08-24 Saudi Arabian Oil Company Modified ultra-stable Y (USY) zeolite catalyst for improving cold flow properties of distillates
US11484869B2 (en) 2020-12-09 2022-11-01 Saudi Arabian Oil Company Modified ultra-stable Y (USY) zeolite catalyst for dealkylation of aromatics

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4300015A (en) * 1966-08-25 1981-11-10 Sun Oil Company Of Pennsylvania Crystalline alumino-silicate zeolites containing polyvalent metal cations
US4992616A (en) * 1988-07-15 1991-02-12 Mobil Oil Corporation Heterogeneous isoparaffin/olefin aklylation process
EP0456839A1 (en) * 1989-12-05 1991-11-21 Osaka Gas Co., Ltd. Process for producing 4,4'-diisopropylbiphenyl
EP0842914A1 (en) * 1996-11-18 1998-05-20 Fina Technology, Inc. Alkylation process with enhanced catalyst stability

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3534115A (en) * 1968-08-02 1970-10-13 Sun Oil Co Combination of dy alumino-silicate catalyst and hydrogenation catalyst
US3644565A (en) * 1968-09-18 1972-02-22 Union Oil Co Alkylation process
NL171331C (nl) * 1972-04-25 1983-03-16 Shell Int Research Werkwijze voor het activeren van katalysatoren die geschikt zijn voor het isomeriseren van alifatische verzadigde koolwaterstoffen.
NL171887C (nl) * 1972-04-25 1983-06-01 Shell Int Research Werkwijze voor het isomeriseren van alifatische verzadigde koolwaterstoffen in aanwezigheid van waterstof.
US4604373A (en) * 1984-08-24 1986-08-05 Union Oil Company Of California Hydrocracking catalyst of improved activity
JPH0626948B2 (ja) * 1985-07-30 1994-04-13 マツダ株式会社 車両用点滅装置
DE68924165T2 (de) * 1988-07-15 1996-02-29 Mobil Oil Corp Heterogenes isoparaffin/olefin-alkylierungsverfahren.
DE68910977T2 (de) * 1988-07-15 1994-03-17 Mobil Oil Corp Heterogenes isoparaffin/olefin-alkylierungsverfahren.
US4918255A (en) * 1988-07-15 1990-04-17 Mobil Oil Corp. Heterogeneous isoparaffin/olefin alkylation with isomerization
US5292981A (en) * 1992-06-16 1994-03-08 Mobil Oil Corporation Isoparaffin-olefin alkylation process
US5705729A (en) * 1995-11-22 1998-01-06 Mobil Oil Corporation Isoparaffin-olefin alkylation process
KR100533754B1 (ko) 1996-11-27 2005-12-06 알베마를 네덜란드 비.브이. 탄화수소의 알킬화 방법
WO2001091901A1 (en) * 2000-05-30 2001-12-06 Akzo Nobel N.V. Novel alkylation catalyst and its use in alkylation
EP1308207B1 (en) * 2001-11-06 2011-08-10 Albemarle Netherlands B.V. Sulfur-containing alkylation catalyst and use thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4300015A (en) * 1966-08-25 1981-11-10 Sun Oil Company Of Pennsylvania Crystalline alumino-silicate zeolites containing polyvalent metal cations
US4992616A (en) * 1988-07-15 1991-02-12 Mobil Oil Corporation Heterogeneous isoparaffin/olefin aklylation process
EP0456839A1 (en) * 1989-12-05 1991-11-21 Osaka Gas Co., Ltd. Process for producing 4,4'-diisopropylbiphenyl
EP0842914A1 (en) * 1996-11-18 1998-05-20 Fina Technology, Inc. Alkylation process with enhanced catalyst stability

Also Published As

Publication number Publication date
CN1997610B (zh) 2010-09-15
TWI344949B (en) 2011-07-11
US20070282149A1 (en) 2007-12-06
ES2633798T3 (es) 2017-09-25
EA011022B1 (ru) 2008-12-30
KR20070015134A (ko) 2007-02-01
CA2555197C (en) 2012-10-30
EA200601444A1 (ru) 2007-02-27
HUE034363T2 (en) 2018-02-28
MXPA06008943A (es) 2007-01-26
PL1732866T3 (pl) 2017-10-31
US7750197B2 (en) 2010-07-06
JP5016927B2 (ja) 2012-09-05
WO2005075387A1 (en) 2005-08-18
KR101156299B1 (ko) 2012-06-13
CA2555197A1 (en) 2005-08-18
CN1997610A (zh) 2007-07-11
AU2005211495A1 (en) 2005-08-18
JP2007522140A (ja) 2007-08-09
EP1732866A1 (en) 2006-12-20
TW200606130A (en) 2006-02-16
DK1732866T3 (en) 2017-09-11
EP1732866B1 (en) 2017-05-17

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MK14 Patent ceased section 143(a) (annual fees not paid) or expired