CN1699636A - 一维单晶二氧化钛纳米材料的制备方法 - Google Patents
一维单晶二氧化钛纳米材料的制备方法 Download PDFInfo
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- CN1699636A CN1699636A CN 200410038073 CN200410038073A CN1699636A CN 1699636 A CN1699636 A CN 1699636A CN 200410038073 CN200410038073 CN 200410038073 CN 200410038073 A CN200410038073 A CN 200410038073A CN 1699636 A CN1699636 A CN 1699636A
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- Prior art keywords
- titanium dioxide
- parts
- single crystal
- alcohol
- dimensional single
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 104
- 239000004408 titanium dioxide Substances 0.000 title claims abstract description 46
- 239000013078 crystal Substances 0.000 title claims abstract description 37
- 239000002086 nanomaterial Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 51
- 238000003756 stirring Methods 0.000 claims abstract description 26
- 239000000203 mixture Substances 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000008367 deionised water Substances 0.000 claims abstract description 20
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 20
- 239000002071 nanotube Substances 0.000 claims abstract description 20
- 239000002070 nanowire Substances 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 14
- 239000006228 supernatant Substances 0.000 claims abstract description 11
- 238000005406 washing Methods 0.000 claims abstract description 11
- 238000001035 drying Methods 0.000 claims abstract description 9
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims abstract description 9
- 239000002253 acid Substances 0.000 claims abstract description 5
- 239000003960 organic solvent Substances 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 29
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 21
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- 239000013049 sediment Substances 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 206010013786 Dry skin Diseases 0.000 claims description 8
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical group CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 5
- 150000002825 nitriles Chemical class 0.000 claims description 5
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 150000008431 aliphatic amides Chemical group 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 150000004982 aromatic amines Chemical class 0.000 claims description 4
- 229910017604 nitric acid Inorganic materials 0.000 claims description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 3
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical group CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 claims description 3
- NWPNXBQSRGKSJB-UHFFFAOYSA-N 2-methylbenzonitrile Chemical compound CC1=CC=CC=C1C#N NWPNXBQSRGKSJB-UHFFFAOYSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- JPYHHZQJCSQRJY-UHFFFAOYSA-N Phloroglucinol Natural products CCC=CCC=CCC=CCC=CCCCCC(=O)C1=C(O)C=C(O)C=C1O JPYHHZQJCSQRJY-UHFFFAOYSA-N 0.000 claims description 2
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- 230000002045 lasting effect Effects 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims description 2
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 claims description 2
- 229960001553 phloroglucinol Drugs 0.000 claims description 2
- 229940095064 tartrate Drugs 0.000 claims description 2
- 238000012546 transfer Methods 0.000 claims description 2
- 239000003643 water by type Substances 0.000 claims description 2
- 239000000047 product Substances 0.000 abstract description 5
- 239000002904 solvent Substances 0.000 abstract description 4
- 239000002073 nanorod Substances 0.000 abstract description 3
- 238000001816 cooling Methods 0.000 abstract description 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 239000002244 precipitate Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- -1 nanometer rod Substances 0.000 description 13
- 239000002994 raw material Substances 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- 150000004703 alkoxides Chemical class 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 238000007429 general method Methods 0.000 description 2
- 238000001027 hydrothermal synthesis Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- MIHINWMALJZIBX-UHFFFAOYSA-N cyclohexa-2,4-dien-1-ol Chemical compound OC1CC=CC=C1 MIHINWMALJZIBX-UHFFFAOYSA-N 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002196 fatty nitriles Chemical group 0.000 description 1
- XTVHTJKQKUOEQA-UHFFFAOYSA-N heptane-2,5-diol Chemical compound CCC(O)CCC(C)O XTVHTJKQKUOEQA-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 238000013033 photocatalytic degradation reaction Methods 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
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CNB2004100380736A CN1307328C (zh) | 2004-05-18 | 2004-05-18 | 一维单晶二氧化钛纳米材料的制备方法 |
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CNB2004100380736A CN1307328C (zh) | 2004-05-18 | 2004-05-18 | 一维单晶二氧化钛纳米材料的制备方法 |
Publications (2)
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CN1699636A true CN1699636A (zh) | 2005-11-23 |
CN1307328C CN1307328C (zh) | 2007-03-28 |
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CNB2004100380736A Expired - Fee Related CN1307328C (zh) | 2004-05-18 | 2004-05-18 | 一维单晶二氧化钛纳米材料的制备方法 |
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008014690A1 (fr) * | 2006-07-27 | 2008-02-07 | Beijing Xianxundongtai Technology Co., Ltd. | Nano-fil de dioxyde de titane, procédé d'élaboration correspondant, son utilisation, et procédé de dégradation de contaminants organiques |
CN100441751C (zh) * | 2005-12-20 | 2008-12-10 | 中国科学院兰州化学物理研究所 | 油溶性二氧化钛纳米棒的制备方法 |
CN101845664A (zh) * | 2010-06-18 | 2010-09-29 | 西安交通大学 | 一种高取向单晶二氧化钛纳米线阵列薄膜的低温制备方法 |
CN101091111B (zh) * | 2005-12-23 | 2010-12-01 | 韩国科学技术研究院 | 超灵敏的金属氧化物气体传感器及其制作方法 |
CN101920990A (zh) * | 2010-07-23 | 2010-12-22 | 上海师范大学 | 一种高压微波法制备二氧化钛纳米线的方法 |
CN101994154A (zh) * | 2010-11-26 | 2011-03-30 | 浙江大学 | 一种腰鼓形单晶锐钛矿二氧化钛及其聚集微球的制备方法 |
CN101550595B (zh) * | 2009-04-03 | 2011-07-20 | 哈尔滨工业大学 | 无模板低温制备纯金红石相二氧化钛单晶纳米棒的方法 |
CN102241414A (zh) * | 2011-05-25 | 2011-11-16 | 东华大学 | 一种制备亲水亲油可控锐钛矿型二氧化钛纳米颗粒的方法 |
CN102897831A (zh) * | 2012-10-30 | 2013-01-30 | 东华大学 | 油水界面法制备油溶性锐钛矿型纳米二氧化钛颗粒的方法 |
CN103553127A (zh) * | 2013-10-22 | 2014-02-05 | 渤海大学 | 锐钛矿型二氧化钛纳米管的制备方法 |
CN101952202B (zh) * | 2008-02-11 | 2014-07-23 | 道尼亚太阳能电池有限责任公司 | 具有纳米尺寸和可控形状的二氧化钛的制备方法 |
CN110947410A (zh) * | 2019-12-11 | 2020-04-03 | 信阳师范学院 | 一种氮掺杂TiO2微米束的温和制备方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1257841C (zh) * | 2002-02-26 | 2006-05-31 | 舟山明日纳米材料有限公司 | 纳米金红石型氧化钛的制备方法 |
CN1200881C (zh) * | 2002-08-19 | 2005-05-11 | 西安华创纳米化合物技术研究发展有限责任公司 | 氧化钛纳米纤维的制备方法 |
-
2004
- 2004-05-18 CN CNB2004100380736A patent/CN1307328C/zh not_active Expired - Fee Related
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100441751C (zh) * | 2005-12-20 | 2008-12-10 | 中国科学院兰州化学物理研究所 | 油溶性二氧化钛纳米棒的制备方法 |
CN101091111B (zh) * | 2005-12-23 | 2010-12-01 | 韩国科学技术研究院 | 超灵敏的金属氧化物气体传感器及其制作方法 |
WO2008014690A1 (fr) * | 2006-07-27 | 2008-02-07 | Beijing Xianxundongtai Technology Co., Ltd. | Nano-fil de dioxyde de titane, procédé d'élaboration correspondant, son utilisation, et procédé de dégradation de contaminants organiques |
CN101952202B (zh) * | 2008-02-11 | 2014-07-23 | 道尼亚太阳能电池有限责任公司 | 具有纳米尺寸和可控形状的二氧化钛的制备方法 |
CN101550595B (zh) * | 2009-04-03 | 2011-07-20 | 哈尔滨工业大学 | 无模板低温制备纯金红石相二氧化钛单晶纳米棒的方法 |
CN101845664A (zh) * | 2010-06-18 | 2010-09-29 | 西安交通大学 | 一种高取向单晶二氧化钛纳米线阵列薄膜的低温制备方法 |
CN101920990A (zh) * | 2010-07-23 | 2010-12-22 | 上海师范大学 | 一种高压微波法制备二氧化钛纳米线的方法 |
CN101994154B (zh) * | 2010-11-26 | 2012-06-06 | 浙江大学 | 一种腰鼓形单晶锐钛矿二氧化钛及其聚集微球的制备方法 |
CN101994154A (zh) * | 2010-11-26 | 2011-03-30 | 浙江大学 | 一种腰鼓形单晶锐钛矿二氧化钛及其聚集微球的制备方法 |
CN102241414A (zh) * | 2011-05-25 | 2011-11-16 | 东华大学 | 一种制备亲水亲油可控锐钛矿型二氧化钛纳米颗粒的方法 |
CN102241414B (zh) * | 2011-05-25 | 2013-11-13 | 东华大学 | 一种制备亲水亲油可控锐钛矿型二氧化钛纳米颗粒的方法 |
CN102897831A (zh) * | 2012-10-30 | 2013-01-30 | 东华大学 | 油水界面法制备油溶性锐钛矿型纳米二氧化钛颗粒的方法 |
CN102897831B (zh) * | 2012-10-30 | 2015-01-07 | 东华大学 | 油水界面法制备油溶性锐钛矿型纳米二氧化钛颗粒的方法 |
CN103553127A (zh) * | 2013-10-22 | 2014-02-05 | 渤海大学 | 锐钛矿型二氧化钛纳米管的制备方法 |
CN103553127B (zh) * | 2013-10-22 | 2015-11-25 | 渤海大学 | 锐钛矿型二氧化钛纳米管的制备方法 |
CN110947410A (zh) * | 2019-12-11 | 2020-04-03 | 信阳师范学院 | 一种氮掺杂TiO2微米束的温和制备方法 |
CN110947410B (zh) * | 2019-12-11 | 2023-10-24 | 信阳师范学院 | 一种氮掺杂TiO2微米束的温和制备方法 |
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