CN1659733A - 基于羧酸的离子交联聚合物燃料电池 - Google Patents

基于羧酸的离子交联聚合物燃料电池 Download PDF

Info

Publication number
CN1659733A
CN1659733A CN038133873A CN03813387A CN1659733A CN 1659733 A CN1659733 A CN 1659733A CN 038133873 A CN038133873 A CN 038133873A CN 03813387 A CN03813387 A CN 03813387A CN 1659733 A CN1659733 A CN 1659733A
Authority
CN
China
Prior art keywords
lewis base
fuel cell
fuel
methanol
membrane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN038133873A
Other languages
English (en)
Chinese (zh)
Inventor
D·戴
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of CN1659733A publication Critical patent/CN1659733A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2287—After-treatment
    • C08J5/2293—After-treatment of fluorine-containing membranes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04186—Arrangements for control of reactant parameters, e.g. pressure or concentration of liquid-charged or electrolyte-charged reactants
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • H01M8/04225—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells during start-up
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/043—Processes for controlling fuel cells or fuel cell systems applied during specific periods
    • H01M8/04302—Processes for controlling fuel cells or fuel cell systems applied during specific periods applied during start-up
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1009—Fuel cells with solid electrolytes with one of the reactants being liquid, solid or liquid-charged
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1009—Fuel cells with solid electrolytes with one of the reactants being liquid, solid or liquid-charged
    • H01M8/1011—Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1046—Mixtures of at least one polymer and at least one additive
    • H01M8/1048—Ion-conducting additives, e.g. ion-conducting particles, heteropolyacids, metal phosphate or polybenzimidazole with phosphoric acid
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1053—Polymer electrolyte composites, mixtures or blends consisting of layers of polymers with at least one layer being ionically conductive
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
    • C08J2379/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C08J2379/06—Polyhydrazides; Polytriazoles; Polyamino-triazoles; Polyoxadiazoles
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605—Porous electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/92—Metals of platinum group
    • H01M4/921—Alloys or mixtures with metallic elements
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Development (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Energy (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Fuel Cell (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
CN038133873A 2002-06-10 2003-06-10 基于羧酸的离子交联聚合物燃料电池 Pending CN1659733A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US38746402P 2002-06-10 2002-06-10
US60/387,464 2002-06-10

Publications (1)

Publication Number Publication Date
CN1659733A true CN1659733A (zh) 2005-08-24

Family

ID=29736319

Family Applications (1)

Application Number Title Priority Date Filing Date
CN038133873A Pending CN1659733A (zh) 2002-06-10 2003-06-10 基于羧酸的离子交联聚合物燃料电池

Country Status (5)

Country Link
US (1) US7402351B2 (enExample)
EP (1) EP1512191A2 (enExample)
JP (1) JP2005529465A (enExample)
CN (1) CN1659733A (enExample)
WO (1) WO2003105253A2 (enExample)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101460549B (zh) * 2006-06-01 2012-06-13 纳幕尔杜邦公司 制备含氟聚合物分散体和膜的方法
CN102867929A (zh) * 2011-07-05 2013-01-09 中国科学院大连化学物理研究所 一种复合阴离子交换膜及其制备和应用
CN105720287A (zh) * 2007-05-08 2016-06-29 丰田自动车工程及制造北美公司 使用路易斯酸/布朗斯台德酸络合物的新颖电解质

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006512428A (ja) * 2002-05-13 2006-04-13 ポリフューエル・インコーポレイテッド イオン伝導性ブロックコポリマー
US7402351B2 (en) * 2002-06-10 2008-07-22 E.I. Du Pont De Nemours And Company Carboxylic acid-based ionomer fuel cells
US20070282023A1 (en) * 2006-06-01 2007-12-06 Lousenberg Robert D Fluoropolymer dispersions and membranes
US20070281198A1 (en) * 2006-06-01 2007-12-06 Lousenberg Robert D Membranes electrode assemblies prepared from fluoropolymer dispersions
US8835547B2 (en) * 2008-12-23 2014-09-16 E I Du Pont De Nemours And Company Fluoropolymer particles having a nucleus of fluorinated ionomer
DK3891834T3 (da) * 2018-12-06 2023-06-12 Widex As Direkte alhoholbrændselscelle
KR102659583B1 (ko) * 2021-03-16 2024-04-23 현대모비스 주식회사 고분자 전해질막 및 이를 포함하는 연료전지

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US4358545A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
US4552631A (en) 1983-03-10 1985-11-12 E. I. Du Pont De Nemours And Company Reinforced membrane, electrochemical cell and electrolysis process
US5039389A (en) * 1986-12-19 1991-08-13 The Dow Chemical Company Membrane/electrode combination having interconnected roadways of catalytically active particles
US4940525A (en) 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
US5273694A (en) 1992-08-28 1993-12-28 E. I. Du Pont De Nemours And Company Process for making ion exchange membranes and films
US5773480A (en) 1993-09-21 1998-06-30 Ballard Power Systems Inc. Trifluorostyrene and substituted trifluorostyrene copolymeric compositions and ion-exchange membranes formed therefrom
US5773162A (en) 1993-10-12 1998-06-30 California Institute Of Technology Direct methanol feed fuel cell and system
US5547551A (en) 1995-03-15 1996-08-20 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
DE19632285A1 (de) 1996-08-09 1998-02-19 Hoechst Ag Protonenleiter mit einer Temperaturbeständigkeit in einem weiten Bereich und guten Protonenleitfähigkeiten
US6130175A (en) * 1997-04-29 2000-10-10 Gore Enterprise Holdings, Inc. Integral multi-layered ion-exchange composite membranes
US6110333A (en) 1997-05-02 2000-08-29 E. I. Du Pont De Nemours And Company Composite membrane with highly crystalline porous support
US6248469B1 (en) * 1997-08-29 2001-06-19 Foster-Miller, Inc. Composite solid polymer electrolyte membranes
US6359019B1 (en) 1997-11-12 2002-03-19 Ballard Power Systems Inc. Graft polymeric membranes and ion-exchange membranes formed therefrom
DE10024576A1 (de) * 2000-05-19 2001-11-22 Univ Stuttgart Kovalent und ionisch vernetzte Polymere und Polymermembranen
JP3670565B2 (ja) 2000-09-29 2005-07-13 株式会社東芝 液体供給型メタノール燃料電池用イオン導電性膜およびそれを用いた燃料電池
US6797422B2 (en) 2001-01-25 2004-09-28 Gas Technology Institute Air-breathing direct methanol fuel cell with metal foam current collectors
US6977122B2 (en) 2001-03-27 2005-12-20 The University Of Chicago Proton conducting membrane for fuel cells
US20030044666A1 (en) 2001-09-05 2003-03-06 Qinbai Fan Chemical barriers in electrochemical devices
US7402351B2 (en) * 2002-06-10 2008-07-22 E.I. Du Pont De Nemours And Company Carboxylic acid-based ionomer fuel cells

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101460549B (zh) * 2006-06-01 2012-06-13 纳幕尔杜邦公司 制备含氟聚合物分散体和膜的方法
CN105720287A (zh) * 2007-05-08 2016-06-29 丰田自动车工程及制造北美公司 使用路易斯酸/布朗斯台德酸络合物的新颖电解质
CN102867929A (zh) * 2011-07-05 2013-01-09 中国科学院大连化学物理研究所 一种复合阴离子交换膜及其制备和应用

Also Published As

Publication number Publication date
JP2005529465A (ja) 2005-09-29
EP1512191A2 (en) 2005-03-09
US20040018411A1 (en) 2004-01-29
WO2003105253A3 (en) 2004-12-23
WO2003105253A2 (en) 2003-12-18
US7402351B2 (en) 2008-07-22

Similar Documents

Publication Publication Date Title
CN1174510C (zh) 聚合物基氢氧化物导电膜
CN101379095B (zh) 含有-so3h基的含氟聚合物的制造方法和含有-so3h基的含氟聚合物
US7534516B2 (en) Solid polymer membrane for fuel cell with polyamine imbibed therein for reducing methanol permeability
CN1285630C (zh) 交联的氟化离聚物共聚物
US8802793B2 (en) Polymer electrolyte with aromatic sulfone crosslinking
JP5849148B2 (ja) 高分子電解質膜
JP6034200B2 (ja) レドックスフロー二次電池
US20070281199A1 (en) Crosslinked membrane electrode assemblies
US7074841B2 (en) Polymer electrolyte membranes crosslinked by nitrile trimerization
WO1998022989A1 (en) Novel polymer electrolyte membranes for use in fuel cells
JP2010534274A (ja) ポリスルホン酸ポリマー、及びｆ含有アニオンを有する金属塩を含む、カチオン伝導性膜
JP2009193825A (ja) 複合電解質膜及びその製造方法
CN107108781B (zh) 电解质材料、液态组合物以及固体高分子型燃料电池用膜电极接合体
JP4102299B2 (ja) 燃料電池に用いるイオノマー及びその製造方法
CN101999188B (zh) 质子传导性聚合物电解质膜及其制造方法、以及膜-电极组件和聚合物电解质型燃料电池
CN101048434A (zh) 电解质材料、电解质膜及固体高分子型燃料电池用膜电极接合体
JP4538867B2 (ja) 高分子電解質複合膜
KR20060129213A (ko) 가교 중합체
US20040018410A1 (en) Additive for direct methanol fuel cells
US7402351B2 (en) Carboxylic acid-based ionomer fuel cells
JP2009242688A (ja) 高分子電解質膜
TW200525805A (en) Membrane electrode assembly, manufacturing process therefor and direct type fuel cell therewith
CN1884350A (zh) 复合电解液膜
JP2006164777A (ja) 直接メタノール燃料電池用膜電極接合体及びその製造方法
CN1840582A (zh) 燃料电池用电解质、膜电极接合体以及燃料电池用电解质的制造方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication