CN1492781A - 管式反应器、制备催化剂的方法以及制备不饱和醛和不饱和羧酸的方法 - Google Patents
管式反应器、制备催化剂的方法以及制备不饱和醛和不饱和羧酸的方法 Download PDFInfo
- Publication number
- CN1492781A CN1492781A CNA02805153XA CN02805153A CN1492781A CN 1492781 A CN1492781 A CN 1492781A CN A02805153X A CNA02805153X A CN A02805153XA CN 02805153 A CN02805153 A CN 02805153A CN 1492781 A CN1492781 A CN 1492781A
- Authority
- CN
- China
- Prior art keywords
- catalyst
- temperature
- catalyst precarsor
- additive
- tubular reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
- B01J23/8885—Tungsten containing also molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/067—Heating or cooling the reactor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00212—Plates; Jackets; Cylinders
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8875—Germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/28—Phosphorising
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Description
Claims (13)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001043576A JP4995373B2 (ja) | 2001-02-20 | 2001-02-20 | 反応管、触媒の製造方法、不飽和アルデヒドおよび不飽和カルボン酸の製造方法 |
JP043576/2001 | 2001-02-20 | ||
JP043576/01 | 2001-02-20 | ||
PCT/JP2002/001395 WO2002066160A1 (fr) | 2001-02-20 | 2002-02-19 | Tube de reaction, procede de production de catalyseur et procede de production d'aldehyde et d'acide carboxylique insatures |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1492781A true CN1492781A (zh) | 2004-04-28 |
CN1492781B CN1492781B (zh) | 2010-10-06 |
Family
ID=18905714
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN02805153XA Expired - Lifetime CN1492781B (zh) | 2001-02-20 | 2002-02-19 | 制备催化剂的方法以及制备不饱和醛和不饱和羧酸的方法 |
Country Status (4)
Country | Link |
---|---|
US (1) | US6919478B2 (zh) |
JP (1) | JP4995373B2 (zh) |
CN (1) | CN1492781B (zh) |
WO (1) | WO2002066160A1 (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108514882A (zh) * | 2013-05-24 | 2018-09-11 | Lg化学株式会社 | 用于制备丙烯醛和丙烯酸的环状催化剂及所述催化剂的应用 |
CN113613785A (zh) * | 2019-03-28 | 2021-11-05 | 三菱化学株式会社 | 催化剂成型体以及使用其的不饱和醛和不饱和羧酸的制造方法 |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5063055B2 (ja) * | 2006-08-04 | 2012-10-31 | 三菱レイヨン株式会社 | 固体触媒の充填方法並びに不飽和アルデヒド及び不飽和カルボン酸を製造する方法 |
US20090250653A1 (en) * | 2006-08-07 | 2009-10-08 | Kiely Donald E | Hydroxycarboxylic Acids and Salts |
CA2660389C (en) | 2006-08-07 | 2014-12-02 | The University Of Montana | Method for the preparation of organic acids via oxidization using nitric acid |
WO2009065143A2 (en) * | 2007-11-15 | 2009-05-22 | The University Of Montana | Hydroxypolyamide gel forming agents |
BR112013011627A2 (pt) | 2010-11-11 | 2017-08-01 | Rivertop Renewables | composição de inibição da corrosão |
ES2548405T3 (es) | 2011-04-21 | 2015-10-16 | Rivertop Renewables, Inc. | Composición fijadora de calcio |
SG11201501592QA (en) | 2012-09-28 | 2015-05-28 | Asahi Kasei Chemicals Corp | Oxide catalyst and method for producing the same, and methods for producing unsaturated aldehyde, diolefin, and unsaturated nitrile |
CA2892939A1 (en) | 2012-11-28 | 2014-06-05 | Rivertop Renewables | Corrosion inhibiting, freezing point lowering compositions |
US9670124B2 (en) | 2013-03-13 | 2017-06-06 | Rivertop Renewables, Inc. | Nitric acid oxidation process |
WO2014159694A1 (en) | 2013-03-13 | 2014-10-02 | Rivertop Renewables, Inc. | Improved nitric acid oxidation processes |
US9346736B2 (en) | 2013-03-13 | 2016-05-24 | Rivertop Renewables, Inc. | Oxidation process |
JP6271317B2 (ja) * | 2014-03-27 | 2018-01-31 | 旭化成株式会社 | 酸化物触媒及びその製造方法、並びにアクリロニトリルの製造方法 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT294018B (de) * | 1969-03-15 | 1971-11-10 | Basf Ag | Reaktionsrohr für Röhrenöfen sowie Verfahren zu seiner Herstellung |
DE2153437B2 (de) * | 1971-10-27 | 1974-11-21 | Metallgesellschaft Ag, 6000 Frankfurt | Reaktor zur Herstellung von Methanol |
US3990858A (en) * | 1974-11-19 | 1976-11-09 | The Lummus Company | Device for retaining particulate material in upflow tubes |
JPS56161841A (en) * | 1980-05-19 | 1981-12-12 | Mitsubishi Petrochem Co Ltd | Manufacture of composite oxide catalyst |
JPH0283042A (ja) * | 1988-09-20 | 1990-03-23 | Mitsubishi Heavy Ind Ltd | 触媒の焼成方法 |
JPH044048A (ja) * | 1990-04-19 | 1992-01-08 | Mitsubishi Rayon Co Ltd | 不飽和アルデヒド及び不飽和酸合成用触媒の製造法 |
US5425924A (en) * | 1993-09-07 | 1995-06-20 | Finley; Charles M. | Compact fixed-bed reactor with folded reaction path |
JPH08182933A (ja) | 1994-12-28 | 1996-07-16 | Japan Energy Corp | 機械的強度に優れた固体触媒及びその製造方法 |
DE19717165A1 (de) * | 1997-04-23 | 1998-10-29 | Basf Ag | Vorrichtung und Verfahren zur Temperaturmessung in Rohrreaktoren |
US5877331A (en) * | 1997-11-12 | 1999-03-02 | Huntsman Petrochemical Corporation | Prevention of catalyst attrition and tar formation in manufacture of maleic anhydride |
KR100531988B1 (ko) * | 1998-04-23 | 2005-11-30 | 미쯔비시 레이온 가부시끼가이샤 | 불포화 니트릴 제조용 촉매 |
JP2000070719A (ja) | 1998-09-01 | 2000-03-07 | Mitsubishi Rayon Co Ltd | 不飽和アルデヒドおよび不飽和カルボン酸合成用触媒、その製造方法、およびその触媒を用いた不飽和アルデヒドおよび不飽和カルボン酸の合成方法 |
JP3559456B2 (ja) * | 1998-09-18 | 2004-09-02 | 株式会社日本触媒 | 接触気相酸化方法及び多管式反応器 |
US6417376B1 (en) * | 1998-10-09 | 2002-07-09 | Abb Lummus Global Inc. | Selective oxidation process and catalyst therefor |
JP4004048B2 (ja) * | 2003-04-11 | 2007-11-07 | Tdk株式会社 | 高周波伝送線路 |
-
2001
- 2001-02-20 JP JP2001043576A patent/JP4995373B2/ja not_active Expired - Lifetime
-
2002
- 2002-02-19 WO PCT/JP2002/001395 patent/WO2002066160A1/ja active Application Filing
- 2002-02-19 CN CN02805153XA patent/CN1492781B/zh not_active Expired - Lifetime
- 2002-02-19 US US10/467,343 patent/US6919478B2/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108514882A (zh) * | 2013-05-24 | 2018-09-11 | Lg化学株式会社 | 用于制备丙烯醛和丙烯酸的环状催化剂及所述催化剂的应用 |
CN113613785A (zh) * | 2019-03-28 | 2021-11-05 | 三菱化学株式会社 | 催化剂成型体以及使用其的不饱和醛和不饱和羧酸的制造方法 |
CN113613785B (zh) * | 2019-03-28 | 2023-12-29 | 三菱化学株式会社 | 催化剂成型体以及使用其的不饱和醛和不饱和羧酸的制造方法 |
Also Published As
Publication number | Publication date |
---|---|
WO2002066160A1 (fr) | 2002-08-29 |
US6919478B2 (en) | 2005-07-19 |
JP2002239386A (ja) | 2002-08-27 |
US20040116280A1 (en) | 2004-06-17 |
CN1492781B (zh) | 2010-10-06 |
JP4995373B2 (ja) | 2012-08-08 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Huizhou Hui Ling Chemical Co., Ltd. Assignor: Mitsubishi Reiyon Co., Ltd. Contract fulfillment period: From September 30, 2004 to February 19, 2022 Contract record no.: 051000030009 Denomination of invention: A tubular reactor, a process for preparing a catalyst, and a process for preparing a saturated aldehyde and an unsaturated antelope License type: General permission Record date: 20050114 |
|
LIC | Patent licence contract for exploitation submitted for record |
Free format text: COMMON LICENCE; TIME LIMIT OF IMPLEMENTING CONTACT: 2004.9.30 TO 2022.2.19 Name of requester: HUIZHOU MMA CO., LTD. Effective date: 20050114 |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CP01 | Change in the name or title of a patent holder | ||
CP01 | Change in the name or title of a patent holder |
Address after: Tokyo, Japan, Japan Patentee after: Mitsubishi Kasei Corporation Address before: Tokyo, Japan, Japan Patentee before: Mitsubishi Reiyon Co., Ltd. |
|
CX01 | Expiry of patent term | ||
CX01 | Expiry of patent term |
Granted publication date: 20101006 |