CN1441822A - 可尤其用作厚浆涂料或油漆的基于可通过缩合而交联成粘合剂弹性体的粘稠硅油的水分散体,及其制备方法 - Google Patents
可尤其用作厚浆涂料或油漆的基于可通过缩合而交联成粘合剂弹性体的粘稠硅油的水分散体,及其制备方法 Download PDFInfo
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- CN1441822A CN1441822A CN01812788.6A CN01812788A CN1441822A CN 1441822 A CN1441822 A CN 1441822A CN 01812788 A CN01812788 A CN 01812788A CN 1441822 A CN1441822 A CN 1441822A
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- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- VPMWDFRZSIMDKW-YJYMSZOUSA-N Salmefamol Chemical compound C1=CC(OC)=CC=C1C[C@@H](C)NC[C@H](O)C1=CC=C(O)C(CO)=C1 VPMWDFRZSIMDKW-YJYMSZOUSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- ODFJOVXVLFUVNQ-UHFFFAOYSA-N acetarsol Chemical compound CC(=O)NC1=CC([As](O)(O)=O)=CC=C1O ODFJOVXVLFUVNQ-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000004520 agglutination Effects 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229910001423 beryllium ion Inorganic materials 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- JJFAJTXZGDAWTR-UHFFFAOYSA-N butyl 2-chloroprop-2-enoate Chemical compound CCCCOC(=O)C(Cl)=C JJFAJTXZGDAWTR-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- OOCCDEMITAIZTP-UHFFFAOYSA-N cinnamyl alcohol Chemical compound OCC=CC1=CC=CC=C1 OOCCDEMITAIZTP-UHFFFAOYSA-N 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- JSIRWKUDLWXOJO-UHFFFAOYSA-N dioctyltin;dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O.CCCCCCCC[Sn]CCCCCCCC JSIRWKUDLWXOJO-UHFFFAOYSA-N 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 229960000878 docusate sodium Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-M ethenesulfonate Chemical compound [O-]S(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-M 0.000 description 1
- YCUBDDIKWLELPD-UHFFFAOYSA-N ethenyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OC=C YCUBDDIKWLELPD-UHFFFAOYSA-N 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- GLVVKKSPKXTQRB-UHFFFAOYSA-N ethenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC=C GLVVKKSPKXTQRB-UHFFFAOYSA-N 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- CVUNPKSKGHPMSY-UHFFFAOYSA-N ethyl 2-chloroprop-2-enoate Chemical compound CCOC(=O)C(Cl)=C CVUNPKSKGHPMSY-UHFFFAOYSA-N 0.000 description 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate Substances CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 1
- 125000000031 ethylamino group Chemical group [H]C([H])([H])C([H])([H])N([H])[*] 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002193 fatty amides Chemical class 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 125000005816 fluoropropyl group Chemical group [H]C([H])(F)C([H])([H])C([H])([H])* 0.000 description 1
- FATAVLOOLIRUNA-UHFFFAOYSA-N formylmethyl Chemical compound [CH2]C=O FATAVLOOLIRUNA-UHFFFAOYSA-N 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229920000591 gum Polymers 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- MOYKHGMNXAOIAT-JGWLITMVSA-N isosorbide dinitrate Chemical compound [O-][N+](=O)O[C@H]1CO[C@@H]2[C@H](O[N+](=O)[O-])CO[C@@H]21 MOYKHGMNXAOIAT-JGWLITMVSA-N 0.000 description 1
- 229960000201 isosorbide dinitrate Drugs 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- AWJZTPWDQYFQPQ-UHFFFAOYSA-N methyl 2-chloroprop-2-enoate Chemical class COC(=O)C(Cl)=C AWJZTPWDQYFQPQ-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 229960002900 methylcellulose Drugs 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 1
- DVYVMJLSUSGYMH-UHFFFAOYSA-N n-methyl-3-trimethoxysilylpropan-1-amine Chemical compound CNCCC[Si](OC)(OC)OC DVYVMJLSUSGYMH-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 125000005447 octyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- QIWKUEJZZCOPFV-UHFFFAOYSA-N phenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=CC=C1 QIWKUEJZZCOPFV-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- IFUUJJJOOHDTAT-UHFFFAOYSA-N propan-2-yl 2-chloroprop-2-enoate Chemical compound CC(C)OC(=O)C(Cl)=C IFUUJJJOOHDTAT-UHFFFAOYSA-N 0.000 description 1
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 229950001879 salmefamol Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/205—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase
- C08J3/21—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the polymer being premixed with a liquid phase
- C08J3/215—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the polymer being premixed with a liquid phase at least one additive being also premixed with a liquid phase
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2383/04—Polysiloxanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Sealing Material Composition (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
实施例1(CaCO3的淤浆 | 实施例2(粉末形式的憎水CaCO3) | 实施例2a(粉末形式的亲水CaCO3) | |
残余乳液含量T | 88.8% | 37% | 65% |
凝聚乳液含量C | 11.2% | 63% | 35% |
Brookfield粘度A7V5(Pa.s) | 56 | 46.4 | 28.4 |
2mm膜的外观 | 光滑 | 轻微粒状 | 粒状 |
在盒中15天和干燥7天之后测定的机械性能 | |||
硬度(Shore A) | 28 | 45 | 28 |
断裂强度(MPa) | 1.27 | 0.85 | 0.63 |
断裂伸长率(%) | 902 | 427 | 180 |
在100%伸长率下的模量(MPa) | 0.38 | 0.57 | 0.53 |
在盒中3个月和干燥7天之后测定的机械性能 | |||
硬度(Shore A) | 29 | 不可测(内聚差的膜) | 29 |
断裂强度(MPa) | 0.60 | 不可测(内聚差的膜) | 0.63 |
断裂伸长率(%) | 356 | 不可测(内聚差的膜) | 200 |
在100%伸长率下的模量(MPa) | 0.43 | 不可测(内聚差的膜) | 0.5 |
使用无空气枪的涂布 | 光滑膜 | 变差的外观 | 不可能 |
与PUR泡沫材料的粘附性(通过手工剥离而评估) | 良好 | 一般 | 中等 |
实施例3(CaCO3淤浆) | 实施例4(粉状处理的CaCO3) | |
残余乳液含量T | 98% | 97% |
凝聚乳液含量C | 2% | 3% |
Boeing流动性(mm) | 0 | 0 |
2mm膜的外观 | 光滑 | 光滑 |
在盒中1个月和干燥7天之后测定的机械性能 | ||
硬度(Shore A) | 23 | 16 |
断裂强度(MPa) | 0.92 | 0.65 |
断裂伸长率(%) | 402 | 523 |
在100%伸长率下的模量(MPa) | 0.47 | 0.30 |
通过在盒中1个月和干燥7天之后在载体上剥离而评估的粘附性(2-3mm厚的硅氧烷膜): | ||
与玻璃的粘附性 | 良好 | 良好 |
与木材的粘附性 | 良好 | 良好 |
与阳极化铝的粘附性 | 良好 | 良好 |
与混凝土的粘附性 | 良好 | 良好 |
与PVC的粘附性 | 轻微 | 无 |
与PUR泡沫材料的粘附性 | 良好 | 一般 |
实施例5 | 实施例6 | 实施例7 | |
Boeing流动性(mm) | 0 | 0 | |
2mm膜的外观 | 光滑 | 光滑 | |
在盒中1个月和干燥7天之后测定的机械性能 | 产物仍从盒中挤出,但它不再能够用刮刀铺展,因为它是弹性的 | ||
硬度(Shore A) | 10 | 19 | 不可测 |
断裂强度(MPa) | 0.61 | 1.15 | 不可测 |
断裂伸长率(%) | 379 | 494 | 不可测 |
在100%伸长率下的模量(MPa) | 0.20 | 0.34 | 不可测 |
通过在盒中1个月和干燥7天之后在载体上剥离而评估的粘附性(2-3mm厚的硅氧烷膜): | |||
与玻璃的粘附性 | 良好 | 良好 | 不可测 |
与木材的粘附性 | 良好 | 良好 | 不可测 |
与阳极化铝的粘附性 | 良好 | 良好 | 不可测 |
与混凝土的粘附性 | 平均 | 平均 | 不可测 |
与PVC的粘附性 | 良好 | 良好 | 不可测 |
Claims (26)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR00/08551 | 2000-06-30 | ||
FR0008551A FR2810989A1 (fr) | 2000-06-30 | 2000-06-30 | Dispersion aqueuse a base base d'huiles silicone visqueuses reticulables par condensation en un elastomere, adherent utilisable notamment comme mastics ou peintures, procede de preparation |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1441822A true CN1441822A (zh) | 2003-09-10 |
CN1249129C CN1249129C (zh) | 2006-04-05 |
Family
ID=8851992
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN01812788.6A Expired - Fee Related CN1249129C (zh) | 2000-06-30 | 2001-06-29 | 可尤其用作厚浆涂料或油漆的基于可通过缩合而交联成粘合剂弹性体的粘稠硅油的水分散体,及其制备方法 |
Country Status (10)
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US (1) | US6995210B2 (zh) |
EP (1) | EP1299458B1 (zh) |
CN (1) | CN1249129C (zh) |
AT (1) | ATE535562T1 (zh) |
AU (1) | AU2001270727A1 (zh) |
BR (1) | BR0112273A (zh) |
ES (1) | ES2377853T3 (zh) |
FR (1) | FR2810989A1 (zh) |
PT (1) | PT1299458E (zh) |
WO (1) | WO2002000770A1 (zh) |
Cited By (5)
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CN102256592A (zh) * | 2008-12-22 | 2011-11-23 | 道康宁东丽株式会社 | 生产乳液的方法 |
CN102317338A (zh) * | 2009-03-27 | 2012-01-11 | 卡尔·弗罗伊登伯格公司 | 制备反应性聚氨酯乳液的方法 |
CN101389740B (zh) * | 2005-06-29 | 2013-01-16 | 蓝星有机硅法国公司 | 用于轮胎的模塑/脱模的基于硅氧烷的组合物 |
US8686174B2 (en) | 2008-12-22 | 2014-04-01 | Dow Corning Toray Co. Ltd. | Partially hydrocarbon group-blocked (poly)glycerol-modified polysiloxane, method for producing the same, and cosmetic composition containing the same |
CN108102604A (zh) * | 2018-01-23 | 2018-06-01 | 苏州世华新材料科技有限公司 | 一种高剥离力低硅残留有机硅压敏胶、压敏胶带及其制备方法 |
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US8012544B2 (en) * | 2003-10-08 | 2011-09-06 | Dow Corning Corporation | Silicone MQ resin reinforced silicone elastomer emulsions |
FR2861722B1 (fr) * | 2003-11-04 | 2007-05-11 | Rhodia Chimie Sa | Procede de traitement de surface d'un support contenant de l'amiante et entrant dans la constitution d'un batiment, support ainsi obtenu |
FR2881748B1 (fr) * | 2005-02-07 | 2007-03-09 | Rhodia Chimie Sa | Dispersions silicones aqueuses, formulations notamment de peintures les comprenant et l'un de leurs procedes de preparation |
FR2883452A1 (fr) * | 2005-03-23 | 2006-09-29 | Rhodia Chimie Sa | Procede de traitement de vegetaux a l'aide d'une dispersion silicone aqueuse contenant un additif phytosanitaire |
DE102005053071A1 (de) * | 2005-11-04 | 2007-05-16 | Degussa | Verfahren zur Herstellung von ultrafeinen Pulvern auf Basis Polymaiden, ultrafeinen Polyamidpulver sowie deren Verwendung |
JP2007231030A (ja) * | 2006-02-27 | 2007-09-13 | Shin Etsu Chem Co Ltd | 皮膜形成シリコーンエマルジョン組成物 |
WO2009077389A1 (de) * | 2007-12-14 | 2009-06-25 | Henkel Ag & Co. Kgaa | Härtbare zusammensetzungen enthaltend wässrige dispersionen von organopolysiloxanen |
DE102007060919A1 (de) * | 2007-12-14 | 2009-06-18 | Henkel Ag & Co. Kgaa | Härtbare Zusammensetzungen enthaltend wässrige Dispersionen von Organopolysiloxanen |
CN102171308B (zh) * | 2008-08-20 | 2014-03-12 | 汉高公司 | 制备模具封孔剂的方法、模具封孔剂组件及其组合物 |
EP2513215B1 (en) | 2009-12-17 | 2019-06-05 | 3M Innovative Properties Company | High magnesium surface concentration nanocalcite composites |
WO2015077912A1 (en) * | 2013-11-26 | 2015-06-04 | Dow Corning (China) Holding Co., Ltd. | Novel silicone emulsion, water-based anchorage additive thereof and silicone release coating composition |
US10533124B2 (en) | 2014-07-28 | 2020-01-14 | Halliburton Energy Services, Inc. | Foamed curable resin fluids |
CN109320937A (zh) * | 2018-09-11 | 2019-02-12 | 铨盛(云浮)新型聚合物有限公司 | 一种基于孔状无机物的有机硅阻燃剂及其制备方法 |
Family Cites Families (9)
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US4221688A (en) * | 1978-04-28 | 1980-09-09 | Dow Corning Corporation | Silicone emulsion which provides an elastomeric product and methods for preparation |
US4567231A (en) * | 1984-06-26 | 1986-01-28 | Dow Corning Corporation | Emulsions of reinforced polydiorganosiloxane latex |
CA1340036C (en) * | 1988-08-05 | 1998-09-08 | Donald Taylor Liles | Silicone water based elastomers |
US5851594A (en) * | 1992-10-20 | 1998-12-22 | Rhone Poulenc Chimie | Aqueous dispersions based on viscous silicone oils capable of cross-linking on removal of water |
FR2697021B1 (fr) * | 1992-10-20 | 1994-12-02 | Rhone Poulenc Chimie | Dispersions aqueuses à base d'huiles silicones visqueuses pouvant réticuler par élimination de l'eau et leur utilisation à la réalisation de joints élastomères silicones. |
US5449712A (en) * | 1993-01-13 | 1995-09-12 | Thoro System Products, Inc. | Organosilicon emulsions for rendering porous substrates water repellent |
US5895794A (en) * | 1993-08-30 | 1999-04-20 | Dow Corning Corporation | Shelf stable cross-linked emulsions with optimum consistency and handling without the use of thickeners |
FR2753708B1 (fr) * | 1996-09-26 | 1998-12-31 | Dispersion silicone aqueuse, reticulable par condensation en un elastomere adherent sur de nombreux supports et mastic constitue par ledit elastomere | |
US6521699B2 (en) * | 1996-09-26 | 2003-02-18 | Rhodia Chimie | Aqueous silicone dispersion |
-
2000
- 2000-06-30 FR FR0008551A patent/FR2810989A1/fr active Pending
-
2001
- 2001-06-29 ES ES01949602T patent/ES2377853T3/es not_active Expired - Lifetime
- 2001-06-29 WO PCT/FR2001/002105 patent/WO2002000770A1/fr active Application Filing
- 2001-06-29 AT AT01949602T patent/ATE535562T1/de active
- 2001-06-29 PT PT01949602T patent/PT1299458E/pt unknown
- 2001-06-29 AU AU2001270727A patent/AU2001270727A1/en not_active Abandoned
- 2001-06-29 EP EP01949602A patent/EP1299458B1/fr not_active Expired - Lifetime
- 2001-06-29 US US10/312,425 patent/US6995210B2/en not_active Expired - Lifetime
- 2001-06-29 CN CN01812788.6A patent/CN1249129C/zh not_active Expired - Fee Related
- 2001-06-29 BR BR0112273-8A patent/BR0112273A/pt not_active Withdrawn
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101389740B (zh) * | 2005-06-29 | 2013-01-16 | 蓝星有机硅法国公司 | 用于轮胎的模塑/脱模的基于硅氧烷的组合物 |
CN102256592A (zh) * | 2008-12-22 | 2011-11-23 | 道康宁东丽株式会社 | 生产乳液的方法 |
US8686174B2 (en) | 2008-12-22 | 2014-04-01 | Dow Corning Toray Co. Ltd. | Partially hydrocarbon group-blocked (poly)glycerol-modified polysiloxane, method for producing the same, and cosmetic composition containing the same |
US8835555B2 (en) | 2008-12-22 | 2014-09-16 | Dow Corning Toray Co. Ltd. | Method for producing emulsion |
CN102256592B (zh) * | 2008-12-22 | 2014-09-17 | 道康宁东丽株式会社 | 生产乳液的方法 |
CN102317338A (zh) * | 2009-03-27 | 2012-01-11 | 卡尔·弗罗伊登伯格公司 | 制备反应性聚氨酯乳液的方法 |
CN102317338B (zh) * | 2009-03-27 | 2014-11-26 | 卡尔·弗罗伊登伯格公司 | 制备反应性聚氨酯乳液的方法 |
CN108102604A (zh) * | 2018-01-23 | 2018-06-01 | 苏州世华新材料科技有限公司 | 一种高剥离力低硅残留有机硅压敏胶、压敏胶带及其制备方法 |
CN108102604B (zh) * | 2018-01-23 | 2018-09-18 | 苏州世华新材料科技股份有限公司 | 一种高剥离力低硅残留有机硅压敏胶、压敏胶带及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
WO2002000770A1 (fr) | 2002-01-03 |
ATE535562T1 (de) | 2011-12-15 |
CN1249129C (zh) | 2006-04-05 |
US6995210B2 (en) | 2006-02-07 |
EP1299458A1 (fr) | 2003-04-09 |
US20040054070A1 (en) | 2004-03-18 |
EP1299458B1 (fr) | 2011-11-30 |
PT1299458E (pt) | 2012-03-06 |
ES2377853T3 (es) | 2012-04-02 |
AU2001270727A1 (en) | 2002-01-08 |
BR0112273A (pt) | 2003-06-10 |
FR2810989A1 (fr) | 2002-01-04 |
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