CN1317315C - 一种改性聚酯的制备方法 - Google Patents
一种改性聚酯的制备方法 Download PDFInfo
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- CN1317315C CN1317315C CNB2004100627298A CN200410062729A CN1317315C CN 1317315 C CN1317315 C CN 1317315C CN B2004100627298 A CNB2004100627298 A CN B2004100627298A CN 200410062729 A CN200410062729 A CN 200410062729A CN 1317315 C CN1317315 C CN 1317315C
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- Prior art keywords
- polyester
- esterification
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- modified poly
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- 229920000728 polyester Polymers 0.000 title claims abstract description 95
- 238000000034 method Methods 0.000 title abstract description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 65
- 230000032050 esterification Effects 0.000 claims abstract description 47
- 238000005886 esterification reaction Methods 0.000 claims abstract description 47
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 41
- 238000002360 preparation method Methods 0.000 claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 claims abstract description 16
- 229910052751 metal Inorganic materials 0.000 claims abstract description 15
- 239000002184 metal Substances 0.000 claims abstract description 15
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 12
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920001515 polyalkylene glycol Polymers 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 238000007334 copolymerization reaction Methods 0.000 claims abstract description 3
- 238000006243 chemical reaction Methods 0.000 claims description 29
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 20
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 16
- 239000002002 slurry Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- -1 pentaerythritol ester Chemical class 0.000 claims description 11
- 239000000470 constituent Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 235000019260 propionic acid Nutrition 0.000 claims description 10
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 10
- 150000007942 carboxylates Chemical class 0.000 claims description 9
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 claims description 8
- 238000010009 beating Methods 0.000 claims description 7
- 229940040526 anhydrous sodium acetate Drugs 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 230000003197 catalytic effect Effects 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 abstract description 8
- 230000002159 abnormal effect Effects 0.000 abstract description 4
- 238000012661 block copolymerization Methods 0.000 abstract description 3
- 238000012805 post-processing Methods 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- 238000009987 spinning Methods 0.000 description 20
- 239000000835 fiber Substances 0.000 description 19
- 239000003513 alkali Substances 0.000 description 13
- 229920001223 polyethylene glycol Polymers 0.000 description 11
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
- 238000006068 polycondensation reaction Methods 0.000 description 9
- 239000002585 base Substances 0.000 description 8
- 230000000704 physical effect Effects 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 230000006378 damage Effects 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 238000012423 maintenance Methods 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000002074 melt spinning Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 229920004933 Terylene® Polymers 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- YTRQFSDWAXHJCC-UHFFFAOYSA-N chloroform;phenol Chemical compound ClC(Cl)Cl.OC1=CC=CC=C1 YTRQFSDWAXHJCC-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 229960004249 sodium acetate Drugs 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241001481789 Rupicapra Species 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- JVLRYPRBKSMEBF-UHFFFAOYSA-K diacetyloxystibanyl acetate Chemical compound [Sb+3].CC([O-])=O.CC([O-])=O.CC([O-])=O JVLRYPRBKSMEBF-UHFFFAOYSA-K 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- VNGOYPQMJFJDLV-UHFFFAOYSA-N dimethyl benzene-1,3-dicarboxylate Chemical compound COC(=O)C1=CC=CC(C(=O)OC)=C1 VNGOYPQMJFJDLV-UHFFFAOYSA-N 0.000 description 1
- FCNVPOALDDLXOR-UHFFFAOYSA-L disodium;benzoate;chloride Chemical compound [Na+].[Na+].[Cl-].[O-]C(=O)C1=CC=CC=C1 FCNVPOALDDLXOR-UHFFFAOYSA-L 0.000 description 1
- 238000007922 dissolution test Methods 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- FYIBGDKNYYMMAG-UHFFFAOYSA-N ethane-1,2-diol;terephthalic acid Chemical group OCCO.OC(=O)C1=CC=C(C(O)=O)C=C1 FYIBGDKNYYMMAG-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 229940119177 germanium dioxide Drugs 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Substances OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000013558 reference substance Substances 0.000 description 1
- 238000000646 scanning calorimetry Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000003335 steric effect Effects 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Polyesters Or Polycarbonates (AREA)
Abstract
Description
实施例 | 1 | 2 | 3 |
聚合方法 | 半连续 | 半连续 | 半连续 |
EG/PTA浆料摩尔比 | 1.30 | 1.1 | 1.30 |
SIPE(摩尔%) | 5 | 5 | 9 |
PEG(重量%/分子量) | 6/2000 | 6/4000 | 8/4000 |
无水醋酸钠添加量(%) | 0.01 | 0.01 | 0.01 |
三氧化二锑添加量(%) | 0.03 | 0.03 | 0.03 |
磷酸三甲酯添加量(%) | 0.01 | 0.01 | 0.01 |
2215(%) | 0.4 | 0.4 | 0.2 |
特性粘度(dl/g) | 0.487 | 0.491 | 0.521 |
二甘醇含量(w.t%) | 4.99 | 5.72 | 4.38 |
端羧基含量(mol/t) | 16.3 | 21.1 | 22.6 |
熔点(℃) | 231.71 | 230.18 | 230.75 |
色度b值 | 11 | 6.25 | 6.8 |
色度L值 | 48 | 49.7 | 53.4 |
灰分(%) | 1.55 | 1.51 | 1.66 |
热失重(%) | 2.89 | 2.63 | 2.92 |
碱液溶解性(min) | 135 | 125 | 98 |
纺丝操作性 | 良好 | 良好 | 好 |
耐热性 | 良好 | 良好 | 良好 |
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2004100627298A CN1317315C (zh) | 2004-07-08 | 2004-07-08 | 一种改性聚酯的制备方法 |
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Application Number | Priority Date | Filing Date | Title |
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CNB2004100627298A CN1317315C (zh) | 2004-07-08 | 2004-07-08 | 一种改性聚酯的制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN1587297A CN1587297A (zh) | 2005-03-02 |
CN1317315C true CN1317315C (zh) | 2007-05-23 |
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CNB2004100627298A Expired - Fee Related CN1317315C (zh) | 2004-07-08 | 2004-07-08 | 一种改性聚酯的制备方法 |
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CN (1) | CN1317315C (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102836274B (zh) * | 2012-09-19 | 2014-06-18 | 董晓光 | 治疗脊髓和周围神经损伤引起的功能障碍的中药组合物 |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101525472B (zh) * | 2008-03-04 | 2012-04-11 | 东丽纤维研究所(中国)有限公司 | 一种碱溶性聚酯及其制备方法 |
CN102558527B (zh) * | 2011-12-19 | 2013-11-13 | 东华大学 | 一种以铝化合物为催化剂制备水溶性聚酯的方法 |
CN103483567A (zh) * | 2013-08-15 | 2014-01-01 | 洛阳市柯莱尔清洗材料有限公司 | 一种再生聚酯 |
CN103524720B (zh) * | 2013-09-16 | 2015-07-15 | 厦门翔鹭化纤股份有限公司 | 一种抗菌聚酯材料的制作方法 |
CN105064028B (zh) * | 2015-07-29 | 2017-07-14 | 湖北佳特新材料有限公司 | Dty涤纶低弹丝上浆用水溶性聚酯浆料及其制备方法 |
CN106589329A (zh) * | 2015-10-14 | 2017-04-26 | 中国石化仪征化纤有限责任公司 | 一种低熔融比电阻聚酯及其薄膜的制备方法 |
CN105755568A (zh) * | 2015-11-19 | 2016-07-13 | 厦门翔鹭化纤股份有限公司 | 一种碱溶聚酯纤维及其制备方法 |
CN105601899B (zh) * | 2015-12-29 | 2018-03-06 | 江苏恒力化纤股份有限公司 | 一种瓶用聚酯及其制备方法 |
CN109485841A (zh) * | 2018-09-20 | 2019-03-19 | 浙江恒澜科技有限公司 | 一种不含锑催化剂的碱溶性共聚酯的连续聚合方法 |
CN115181402B (zh) * | 2022-08-17 | 2023-10-27 | 华润化学材料科技股份有限公司 | 一种易挤吹成型的共聚酯组合物及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1438274A (zh) * | 2003-03-20 | 2003-08-27 | 济南正昊化纤新材料有限公司 | 一种易碱解聚酯及其制备方法 |
CN1439751A (zh) * | 2003-03-20 | 2003-09-03 | 济南正昊化纤新材料有限公司 | 一种热碱可溶性聚酯纤维的制备方法 |
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2004
- 2004-07-08 CN CNB2004100627298A patent/CN1317315C/zh not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1438274A (zh) * | 2003-03-20 | 2003-08-27 | 济南正昊化纤新材料有限公司 | 一种易碱解聚酯及其制备方法 |
CN1439751A (zh) * | 2003-03-20 | 2003-09-03 | 济南正昊化纤新材料有限公司 | 一种热碱可溶性聚酯纤维的制备方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102836274B (zh) * | 2012-09-19 | 2014-06-18 | 董晓光 | 治疗脊髓和周围神经损伤引起的功能障碍的中药组合物 |
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Effective date of registration: 20090626 Address after: Fujian province Xiamen City Haicang Taiwan investment area LKeng village postal code: 361026 Co-patentee after: Dragon Special Resin (Xiamen) Co.,Ltd. Patentee after: XIAMEN XIANGLU CHEMICAL FIBER CO.,LTD. Address before: Xiamen, Fujian province Haicang investment zone, reed pit, post code: 361026 Patentee before: XIAMEN XIANGLU CHEMICAL FIBER CO.,LTD. |
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Assignee: Dragon Special Resin (Xiamen) Co.,Ltd. Assignor: Dragon Special Resin (Xiamen) Co.,Ltd.|XIAMEN XIANGLU CHEMICAL FIBER CO.,LTD. Contract fulfillment period: 2009.9.25 to 2014.9.25 Contract record no.: 2009351000075 Denomination of invention: Modified poly ester and its preparing method Granted publication date: 20070523 License type: Exclusive license Record date: 20091102 |
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Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.9.25 TO 2014.9.25; CHANGE OF CONTRACT Name of requester: TENGLONG SPECIAL RESIN (XIAMEN) CO., LTD. Effective date: 20091102 |
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