CN1315886C - 制造氟聚合物的方法 - Google Patents

制造氟聚合物的方法 Download PDF

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Publication number
CN1315886C
CN1315886C CNB988038102A CN98803810A CN1315886C CN 1315886 C CN1315886 C CN 1315886C CN B988038102 A CNB988038102 A CN B988038102A CN 98803810 A CN98803810 A CN 98803810A CN 1315886 C CN1315886 C CN 1315886C
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China
Prior art keywords
carbon dioxide
polymer
polymerization
fluoropolymer
freon
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Expired - Fee Related
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CNB988038102A
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English (en)
Chinese (zh)
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CN1251594A (zh
Inventor
约瑟夫·M·德西蒙
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University of North Carolina at Chapel Hill
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University of North Carolina at Chapel Hill
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • C08F20/22Esters containing halogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/02Processes for applying liquids or other fluent materials performed by spraying
    • B05D1/025Processes for applying liquids or other fluent materials performed by spraying using gas close to its critical state
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/08Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
    • B05D5/083Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface involving the use of fluoropolymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02Monomers containing only one unsaturated aliphatic radical
    • C08F12/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/14Monomers containing only one unsaturated aliphatic radical containing one ring substituted by hetero atoms or groups containing heteroatoms
    • C08F12/16Halogens
    • C08F12/20Fluorine
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18Monomers containing fluorine
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F16/12Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F16/14Monomers containing only one unsaturated aliphatic radical
    • C08F16/16Monomers containing no hetero atoms other than the ether oxygen
    • C08F16/22Carbocyclic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F16/12Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F16/14Monomers containing only one unsaturated aliphatic radical
    • C08F16/24Monomers containing halogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00Post-polymerisation treatments
    • C08F6/06Treatment of polymer solutions
    • C08F6/12Separation of polymers from solutions
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/54Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Polymerisation Methods In General (AREA)
CNB988038102A 1997-02-07 1998-02-06 制造氟聚合物的方法 Expired - Fee Related CN1315886C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/797,592 1997-02-07
US08/797,592 US5863612A (en) 1992-03-27 1997-02-07 Method of making fluoropolymers

Publications (2)

Publication Number Publication Date
CN1251594A CN1251594A (zh) 2000-04-26
CN1315886C true CN1315886C (zh) 2007-05-16

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Family Applications (1)

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CNB988038102A Expired - Fee Related CN1315886C (zh) 1997-02-07 1998-02-06 制造氟聚合物的方法

Country Status (5)

Country Link
US (1) US5863612A (enExample)
EP (2) EP0960143A1 (enExample)
JP (1) JP2001511210A (enExample)
CN (1) CN1315886C (enExample)
WO (1) WO1998034967A1 (enExample)

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US6127000A (en) * 1997-10-10 2000-10-03 North Carolina State University Method and compositions for protecting civil infrastructure
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US6497921B1 (en) * 1998-11-06 2002-12-24 North Carolina State University Method for meniscus coating with liquid carbon dioxide
US6083565A (en) * 1998-11-06 2000-07-04 North Carolina State University Method for meniscus coating with liquid carbon dioxide
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US20020077435A1 (en) * 2000-10-09 2002-06-20 Desimone Joseph M. Methods for preparing polymers in carbon dioxide having reactive functionality
DE10054114A1 (de) 2000-10-31 2002-05-16 Dupont Performance Coatings Verfahren zur Herstellung von Pulverlackzusammensetzungen
US6656258B2 (en) 2001-03-20 2003-12-02 3M Innovative Properties Company Compositions comprising fluorinated silanes and compressed fluid CO2
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US6832699B2 (en) * 2002-02-22 2004-12-21 Terrasimco Inc. Direct pressure apparatus and method for dispensing coatings
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US7407703B2 (en) * 2002-09-20 2008-08-05 Bha Group, Inc. Composite membrane having oleophobic properties
US7771818B2 (en) * 2002-09-20 2010-08-10 Bha Group, Inc. Treatment of porous article
TWI270555B (en) * 2003-02-25 2007-01-11 President Of Shizuoka Universi Method of manufacturing polymer
US6951769B2 (en) 2003-06-04 2005-10-04 Texas Instruments Incorporated Method for stripping sacrificial layer in MEMS assembly
US6806993B1 (en) 2003-06-04 2004-10-19 Texas Instruments Incorporated Method for lubricating MEMS components
US7652115B2 (en) * 2003-09-08 2010-01-26 3M Innovative Properties Company Fluorinated polyether isocyanate derived silane compositions
US7141537B2 (en) * 2003-10-30 2006-11-28 3M Innovative Properties Company Mixture of fluorinated polyethers and use thereof as surfactant
US7803894B2 (en) * 2003-12-05 2010-09-28 3M Innovatie Properties Company Coating compositions with perfluoropolyetherisocyanate derived silane and alkoxysilanes
WO2006009942A1 (en) 2004-06-21 2006-01-26 Exxonmobil Chemical Patents Inc. Polymerization process
US7858736B2 (en) * 2004-06-21 2010-12-28 Exxonmobil Chemical Patents Inc. Polymer recovery method
US7604818B2 (en) * 2004-12-22 2009-10-20 Advanced Cardiovascular Systems, Inc. Polymers of fluorinated monomers and hydrocarbon monomers
CN1332992C (zh) * 2005-06-07 2007-08-22 中国石油化工股份有限公司 含氟嵌段共聚物及其制备方法和应用
CN1308360C (zh) * 2005-07-20 2007-04-04 上海三爱富新材料股份有限公司 聚偏氟乙烯的合成方法及其制得的聚偏氟乙烯
CN100436497C (zh) * 2005-11-04 2008-11-26 王志军 聚丙烯酸酯的制备方法及由该方法得到的氟改性的聚丙烯酸酯
JP2015117356A (ja) * 2013-11-18 2015-06-25 株式会社リコー ポリマーの製造方法、ポリマー生成物、粒子、フィルム、成形品、及び繊維
JP6545187B2 (ja) * 2014-04-11 2019-07-17 ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. α−ヨードパーフルオロアルカンおよびα,ω−ジヨードパーフルオロアルカンを製造する方法
CN104861116B (zh) * 2015-05-29 2017-05-17 陕西省石油化工研究设计院 一种含氟无皂乳液防护剂制备方法
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CN105524236B (zh) * 2016-02-20 2018-10-23 北京化工大学 一种利用超临界二氧化碳光聚合技术制备含氟高分子颗粒的方法
US10876041B2 (en) * 2018-04-13 2020-12-29 University of Pittsburgh—of the Commonwealth System of Higher Education Carbon dioxide and polymer compositions for permeability control and sealing
CN111440255B (zh) * 2020-03-26 2021-03-02 东莞东阳光科研发有限公司 一种含氟树脂乳液的后处理方法及含氟树脂

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WO1996028477A1 (en) * 1995-03-10 1996-09-19 The University Of North Carolina At Chapel Hill Nonaqueous polymerization of fluoromonomers

Also Published As

Publication number Publication date
US5863612A (en) 1999-01-26
JP2001511210A (ja) 2001-08-07
WO1998034967A1 (en) 1998-08-13
EP1416002A3 (en) 2004-09-29
EP1416002A2 (en) 2004-05-06
EP0960143A1 (en) 1999-12-01
CN1251594A (zh) 2000-04-26

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