CN1295562C - 可辐射固化树脂组合物以及用其快速原型成形的方法 - Google Patents
可辐射固化树脂组合物以及用其快速原型成形的方法 Download PDFInfo
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- CN1295562C CN1295562C CNB02816184XA CN02816184A CN1295562C CN 1295562 C CN1295562 C CN 1295562C CN B02816184X A CNB02816184X A CN B02816184XA CN 02816184 A CN02816184 A CN 02816184A CN 1295562 C CN1295562 C CN 1295562C
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Classifications
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/26—Processing photosensitive materials; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/0037—Production of three-dimensional images
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/038—Macromolecular compounds which are rendered insoluble or differentially wettable
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polymerisation Methods In General (AREA)
- Epoxy Resins (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
成分 | %(重量) |
3,4-环氧基环己基甲基-3,4-环氧基环己基羧酸酯 | 59.4 |
α-氢化-ω-羟基-聚(氧基-1,4-丁烷二基);Mn~250 | 18 |
Irganox 1035 | 0.2 |
二季戊四醇五丙烯酸酯 | 17 |
1-羟基环己基苯酮 | 2.3 |
三芳基锍六氟锑酸盐 | 3.1 |
成分 | 组合物实例A | 组合物实例B | 实例1 | 实例2 |
基本组合物I(%(重量)) | 100 | 95 | 95 | 95 |
新戊二醇二丙烯酸酯(%(重量)) | 0 | 5 | 0 | 0 |
乙氧基化新戊二醇二丙烯酸酯(1EO/丙烯酸酯)(%(重量)) | 0 | 0 | 5 | 0 |
丙氧基化新戊二醇二丙烯酸酯(1PO/丙烯酸酯)(%(重量)) | 0 | 0 | 0 | 5 |
性质 | ||||
500nm处的透光率(%) | 80 | 81 | 85 | 89 |
透明度(%) | 85.9 | 87.4a | 89.2 | 91.5 |
其透明度除以基本组合物透明度 | 1 | 1.017a | 1.038 | 1.065 |
成分 | 组合物实例A | 组合物实例C | 实例3 | 实例4 |
基本组合物I(%(重量)) | 100 | 90 | 90 | 90 |
新戊二醇二丙烯酸酯(%(重量)) | 0 | 10 | 0 | 0 |
乙氧基化新戊二醇二丙烯酸酯(1EO/丙烯酸酯)(%(重量)) | 0 | 0 | 10 | 0 |
丙氧基化新戊二醇二丙烯酸酯(1PO/丙烯酸酯)(%(重量)) | 0 | 0 | 0 | 10 |
性质 | ||||
500nm处的透光率(%) | 80 | 81 | 89 | 90 |
透明度(%) | 85.9 | 88.5a | 92.1 | 93.3 |
其透明度除以基本组合物透明度 | 1 | 1.030a | 1.072 | 1.086 |
成分 | 组合物实例A | 组合物实例D | 实例5 | 实例6 |
基本组合物I | 100 | 90 | 90 | 90 |
己二醇二丙烯酸酯 | 0 | 10 | 0 | 0 |
乙氧基化己二醇二丙烯酸酯(1EO/丙烯酸酯) | 0 | 0 | 10 | 0 |
丙氧基化己二醇二丙烯酸酯(1PO/丙烯酸酯) | 0 | 0 | 0 | 10 |
性质 | ||||
500nm处的透光率(%) | 80 | 82 | 88 | 88 |
透明度 | 85.9 | 86.8a | 92.0 | 91.8 |
其透明度除以基本组合物透明度 | 1 | 1.010a | 1.071 | 1.069 |
成分 | 组合物实例A | 组合物实例E | 组合物实例F | 实例7 | 实例2 | 实例4 |
基本组合物I | 100 | 99 | 98 | 97 | 95 | 90 |
丙氧基化新戊二醇二丙烯酸酯(1PO/丙烯酸酯) | 0 | 1 | 2 | 3 | 5 | 10 |
性质 | ||||||
500nm处的透光率(%) | 80 | 75 | 81 | 83 | 89 | 90 |
透明度 | 85.9 | 82.2 | 87.1 | 88.7 | 91.5 | 93.3 |
其透明度除以基本组合物透明度 | 1 | 0.957 | 1.014 | 1.033 | 1.065 | 1.086 |
成分 | 组合物实例A | 组合物实例G | 组合物实例H | 实例8 | 实例9 |
基本组合物I | 100 | 90 | 90 | 90 | 90 |
乙氧基化双酚A二丙烯酸酯 | |||||
1EO/丙烯酸酯 | 0 | 10 | 0 | 0 | 0 |
2EO/丙烯酸酯 | 0 | 0 | 10 | 0 | 0 |
4EO/丙烯酸酯 | 0 | 0 | 0 | 10 | 0 |
15EO/丙烯酸酯 | 0 | 0 | 0 | 0 | 10 |
性质 | |||||
500nm处的透光率(%) | 80 | 66 | 77 | 85 | 90 |
透明度 | 85.9 | 76.4 | 83.6 | 89.5 | 92.7 |
其透明度除以基本组合物透明度 | 1 | 0.889 | 0.973 | 1.042 | 1.079 |
成分 | 组合物实例A | 组合物实例H | 组合物实例I |
基本组合物I | 100 | 90 | 90 |
乙氧基化双酚A二丙烯酸酯(2EO/丙烯酸酯) | 0 | 10 | 0 |
乙氧基化双酚A二甲基丙烯酸酯(2EO/甲基丙烯酸酯) | 0 | 0 | 10 |
性质 | |||
500nm处的透光率(%) | 80 | 77 | 41 |
透明度 | 85.9 | 83.6 | 58.5 |
其透明度除以基本组合物透明度 | 1 | 0.973 | 0.681 |
成分 | %(重量) |
3,4-环氧基环己基甲基-3,4-环氧基环己基羧酸酯 | 46 |
聚四氢呋喃二环氧甘油醚(分子量约780) | 26 |
双酚A型环氧基的丙烯酸酯 | 21.5 |
抗氧化剂(Irganox 1035,Ciba Geigy) | 0.2 |
自由基光敏引发剂(Irgacure 184,Ciba Geigy) | 3.2 |
阳离子光敏引发剂(Cyracure UVI-6974,Union Carbide) | 2.7 |
碳酸钠 | <0.5 |
成分 | 组合物实例R | 实例20 | 实例21 |
基本组合物II(%(重量)) | 100 | 90 | 90 |
丙氧基化新戊二醇二丙烯酸酯(1PO/丙烯酸酯)(%(重量)) | 0 | 10 | 0 |
聚四氢呋喃二丙烯酸酯(分子量~1000g/mol)(%(重量)) | 0 | 0 | 10 |
性质 | |||
500nm处的透光率(%) | 80 | 90 | |
透明度(%) | 27.2 | 35.0 | 67.6 |
其透明度除以基本组合物透明度 | 1 | 1.29 | 2.49 |
成分 | 组合物实例A | 实例10 | 实例11 | 实例12 | 实例13 | 实例14 |
基本组合物I | 100 | 90 | 90 | 90 | ||
基本组合物II | 90 | 95 | ||||
三丙二醇二丙烯酸酯 | 0 | 10 | 0 | 0 | 0 | 0 |
聚丙二醇二甲基丙烯酸酯(分子量~375) | 0 | 0 | 10 | 0 | 0 | 0 |
聚四氢呋喃二丙烯酸酯(分子量~1000g/mol) | 0 | 0 | 0 | 10 | 5 | 0 |
己内酯丙烯酸酯 | 0 | 0 | 0 | 0 | 0 | 10 |
性质 | ||||||
500nm处的透光率(%) | 80 | 95 | 95 | 94 | 90 | 91 |
透明度 | 85.9 | 96.0 | 96.0 | 95.9 | 93.6 | 93.5 |
其透明度除以基本组合物透明度 | 1 | 1.118 | 1.118 | 1.116 | 1.090 | 1.088 |
成分 | 组合物实例A | 组合物实例J | 组合物实例K | 组合物实例L | 组合物实例M | 组合物实例N | 组合物实例O | 组合物实例P |
基本组合物I | 100 | 90 | 90 | 95 | 90 | 90 | ||
基本组合物II | 95 | 95 | ||||||
双酚A丙三醇化二丙烯酸酯(1丙三醇/Acr) | 0 | 10 | 0 | 0 | 0 | 0 | 0 | 0 |
双酚A丙三醇化二甲基丙烯酸酯(1丙三醇/M-Acr) | 0 | 0 | 10 | 0 | 0 | 0 | 0 | 0 |
乙氧基化双酚A二丙烯酸酯(1.5EO/Acr) | 0 | 0 | 0 | 5 | 0 | 0 | 0 | 0 |
4-羟丁烷 | 0 | 0 | 0 | 0 | 10 | 0 | 0 | 0 |
丙烯酸酯 | ||||||||
己二醇二丙烯酸酯 | 0 | 0 | 0 | 0 | 0 | 5 | 0 | 0 |
丁二醇二丙烯酸酯 | 0 | 0 | 0 | 0 | 0 | 0 | 5 | 10 |
性质 | ||||||||
500nm处的透光率(%) | 80 | 76 | 65 | 70 | 82 | 75 | 80 | 84 |
透明度 | 85.9 | 83.2 | 76.3 | 80.4 | 87.8 | 86.0 | 83.0 | 87.9a |
其透明度除以基本组合物透明度 | 1 | 0.967 | 0.876 | 0.924 | 1.022 | 1.001 | 0.966 | 1.023a |
成分 | 组合物实例A | 组合物实例Q | 实例16 | 实例17 | 实例18 | 实例19 | 组合物实例R |
基本组合物I | 100 | 95 | 90 | 95 | 90 | ||
基本组合物II | 95 | 90 | |||||
乙氧基化三羟甲基丙烷三丙烯酸酯(1EO/Acr.) | 0 | 5 | 0 | 0 | 0 | 0 | 0 |
丙氧基化三羟甲基丙烷三丙烯酸酯(1PO/Acr.) | 0 | 0 | 5 | 10 | 0 | 0 | 0 |
四乙二醇二丙烯酸酯 | 0 | 0 | 0 | 0 | 10 | 0 | 0 |
新戊二醇甲醚丙烯酸酯(2PO/OH) | 0 | 0 | 0 | 0 | 0 | 5 | 10 |
性质 | |||||||
500nm处的透光率(%) | 80 | 82 | 88 | 89 | 86 | 85 | 79 |
透明度 | 85.9 | 87.9 | 91.8 | 92.0 | 88.9 | 89.0 | 87.8 |
其透明度除以基本组合物透明度 | 1 | 1.023 | 1.069 | 1.071 | 1.035 | 1.036 | 1.022 |
Claims (26)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US29947001P | 2001-06-21 | 2001-06-21 | |
US60/299,470 | 2001-06-21 |
Publications (2)
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CN1543590A CN1543590A (zh) | 2004-11-03 |
CN1295562C true CN1295562C (zh) | 2007-01-17 |
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CNB02816184XA Expired - Lifetime CN1295562C (zh) | 2001-06-21 | 2002-06-20 | 可辐射固化树脂组合物以及用其快速原型成形的方法 |
Country Status (7)
Country | Link |
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US (1) | US6811937B2 (zh) |
EP (1) | EP1397725B1 (zh) |
JP (1) | JP2004530773A (zh) |
KR (1) | KR20040030694A (zh) |
CN (1) | CN1295562C (zh) |
HK (1) | HK1070142A1 (zh) |
WO (1) | WO2003001295A1 (zh) |
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CN1543590A (zh) | 2004-11-03 |
KR20040030694A (ko) | 2004-04-09 |
EP1397725A1 (en) | 2004-03-17 |
WO2003001295A1 (en) | 2003-01-03 |
JP2004530773A (ja) | 2004-10-07 |
US20030104313A1 (en) | 2003-06-05 |
US6811937B2 (en) | 2004-11-02 |
HK1070142A1 (en) | 2005-06-10 |
EP1397725B1 (en) | 2017-12-20 |
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