CN1280314C - 控制聚合物分子量和结构的方法 - Google Patents

控制聚合物分子量和结构的方法 Download PDF

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Publication number
CN1280314C
CN1280314C CNB98803123XA CN98803123A CN1280314C CN 1280314 C CN1280314 C CN 1280314C CN B98803123X A CNB98803123X A CN B98803123XA CN 98803123 A CN98803123 A CN 98803123A CN 1280314 C CN1280314 C CN 1280314C
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CN
China
Prior art keywords
alkyl
group
aryl
formula
replacement
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB98803123XA
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English (en)
Chinese (zh)
Other versions
CN1249759A (zh
Inventor
A·G·安德森
A·格里德内夫
G·莫尔德
E·里扎多
S·H·坦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commonwealth Scientific and Industrial Research Organization CSIRO
EIDP Inc
Original Assignee
Commonwealth Scientific and Industrial Research Organization CSIRO
EI Du Pont de Nemours and Co
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Filing date
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Publication of CN1249759A publication Critical patent/CN1249759A/zh
Application granted granted Critical
Publication of CN1280314C publication Critical patent/CN1280314C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
    • C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/30—Oxygen or sulfur atoms
    • C07D233/32—One oxygen atom
    • C07D233/38—One oxygen atom with acyl radicals or hetero atoms directly attached to ring nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Graft Or Block Polymers (AREA)
CNB98803123XA 1997-01-10 1998-01-07 控制聚合物分子量和结构的方法 Expired - Fee Related CN1280314C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US3472797P 1997-01-10 1997-01-10
US60/034,727 1997-01-10

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CNA2006100681573A Division CN1824655A (zh) 1997-01-10 1998-01-07 控制聚合物分子量和结构的方法

Publications (2)

Publication Number Publication Date
CN1249759A CN1249759A (zh) 2000-04-05
CN1280314C true CN1280314C (zh) 2006-10-18

Family

ID=21878221

Family Applications (2)

Application Number Title Priority Date Filing Date
CNA2006100681573A Pending CN1824655A (zh) 1997-01-10 1998-01-07 控制聚合物分子量和结构的方法
CNB98803123XA Expired - Fee Related CN1280314C (zh) 1997-01-10 1998-01-07 控制聚合物分子量和结构的方法

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CNA2006100681573A Pending CN1824655A (zh) 1997-01-10 1998-01-07 控制聚合物分子量和结构的方法

Country Status (10)

Country Link
US (3) US6271340B1 (enExample)
EP (1) EP0951485B1 (enExample)
JP (1) JP2001508485A (enExample)
KR (1) KR100504055B1 (enExample)
CN (2) CN1824655A (enExample)
AU (1) AU750626B2 (enExample)
BR (1) BR9807104A (enExample)
CA (1) CA2277164C (enExample)
DE (2) DE69829588T2 (enExample)
WO (1) WO1998030601A2 (enExample)

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EP1100772B1 (en) * 1998-07-31 2004-04-14 Ciba SC Holding AG Open chain alkoxyamine compounds and their use as polymerization regulators
BR9914104A (pt) * 1998-09-29 2001-07-31 Ciba Sc Holding Ag Processo para preparação de polìmeros contendo grupos terminais n--o
FR2784111B1 (fr) * 1998-10-06 2003-08-01 Atochem Elf Sa Polymerisatin radicalaire en presence de plusieurs radicaux libres stables
TWI225483B (en) * 1998-10-16 2004-12-21 Ciba Sc Holding Ag Heterocyclic alkoxyamines as regulators in controlled radical polymerization process
US6472486B2 (en) 1999-03-09 2002-10-29 Symyx Technologies, Inc. Controlled stable free radical emulsion polymerization processes
WO2000053640A1 (en) * 1999-03-09 2000-09-14 Symyx Technologies, Inc. Controlled free radical emulsion and water-based polymerizations and seeded methodologies
WO2001002345A2 (en) * 1999-07-02 2001-01-11 Ciba Specialty Chemicals Holding Inc. Mono and multifunctional alkoxyamines for the preparation of functionalized macromers
CA2377739A1 (en) 1999-07-02 2001-01-11 Symyx Technologies, Inc. Polymer brushes for immobilizing molecules to a surface or substrate, where the polymers have water-soluble or water-dispersible segments and probes bonded thereto
US6716948B1 (en) 1999-07-31 2004-04-06 Symyx Technologies, Inc. Controlled-architecture polymers and use thereof as separation media
JP4607403B2 (ja) * 1999-08-12 2011-01-05 チバ ホールディング インコーポレーテッド 改善された耐衝撃性を有するポリマーブレンド
WO2001018080A1 (en) * 1999-09-08 2001-03-15 School Of Pharmacy, University Of London Uniform molecular weight polymers
WO2001023435A1 (en) * 1999-09-30 2001-04-05 Noveon Ip Holdings Corp. Polymerization compositions and methods
TW541303B (en) 2000-03-22 2003-07-11 Ciba Sc Holding Ag 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides
DE10036801A1 (de) 2000-07-28 2002-02-07 Tesa Ag Acrylathaftklebemassen mit enger Molekulargewichtsverteilung
TWI225492B (en) 2000-09-25 2004-12-21 Ciba Sc Holding Ag Composition and process for enhancing controlled free radical polymerization
US7205161B2 (en) 2001-01-10 2007-04-17 Symyx Technologies, Inc. Polymer brushes for immobilizing molecules to a surface or substrate having improved stability
US6547840B2 (en) 2001-04-02 2003-04-15 Ciba Specialty Chemicals Corporation Candle wax stabilized with imidazolidines
US6849679B2 (en) 2001-05-21 2005-02-01 Ciba Specialty Chemicals Corporation Pigment compositions with modified block copolymer dispersants
EP1283240A1 (en) * 2001-07-31 2003-02-12 Ciba SC Holding AG Imidazolidinone derivatives
US20030073835A1 (en) 2001-07-31 2003-04-17 Dario Lazzari Imidazolidinone derivatives
DE10149084A1 (de) 2001-10-05 2003-06-18 Tesa Ag UV-vernetzbare Acrylathaftschmelzhaftkleber mit enger Molekulargewichtsverteilung
DE10149083A1 (de) 2001-10-05 2003-04-17 Tesa Ag Acrylathaftklebemassen mit enger Molekulargewichtsverteilung
US6762263B2 (en) * 2002-02-01 2004-07-13 Atofina Chemicals, Inc. High-solids coatings resins via controlled radical polymerization
US6841636B2 (en) * 2002-08-19 2005-01-11 National Starch And Chemical Investment Holding Corporation Dispersions containing living radicals
US7375175B2 (en) * 2002-08-19 2008-05-20 National Starch And Chemical Investment Holding Corporation Dispersions containing living radicals
FR2852963A1 (fr) * 2003-03-26 2004-10-01 Atofina Nouveau procede de synthese/fabrication de films acryliques
FR2852961B1 (fr) * 2003-03-26 2006-07-07 Atofina Nouveau procede de synthese/fabrication de films acryliques
DE10322830A1 (de) * 2003-05-19 2004-12-09 Tesa Ag Verfahren zur kontinuierlichen Herstellung von Polymeren aus vinylischen Verbindungen durch Substanz-beziehungsweise Lösungsmittelpolymerisation
JP4046678B2 (ja) * 2003-10-15 2008-02-13 横浜ゴム株式会社 タイヤトレッド用ゴム組成物及びそれを用いた空気入りタイヤ
US7632882B2 (en) * 2005-01-13 2009-12-15 E.I. Du Pont De Nemours And Company Rheology control agents for coating compositions
US7652121B2 (en) * 2005-01-13 2010-01-26 E.I. Du Pont De Nemours And Company Rheology control agents for coating compositions
US7741510B2 (en) * 2005-01-13 2010-06-22 E. I. Du Pont De Nemours And Company Rheology control agents
US20060155021A1 (en) * 2005-01-13 2006-07-13 Lenges Christian P Coating compositions containing rheology control agents
JP4046734B2 (ja) 2005-01-18 2008-02-13 横浜ゴム株式会社 ポリマーの変性方法
US20060173142A1 (en) * 2005-02-01 2006-08-03 Hildeberto Nava Functionalized thermosetting resin systems
US7009011B1 (en) * 2005-05-31 2006-03-07 Xerox Corporation Copolymers of maleic anhydride by stable free redical polymerization
US20070028806A1 (en) * 2005-08-03 2007-02-08 Piro Bonnie D Coating compositions having improved appearance containing coated titanium dioxide pigments
WO2007068453A2 (en) * 2005-12-14 2007-06-21 Novartis Ag Method for preparing silicone hydrogels
US20080021147A1 (en) * 2006-06-14 2008-01-24 Jun Lin Process for forming a dispersion of silica nano-particles
MX325549B (es) * 2006-06-14 2014-11-24 Du Pont Sustrato recubierto que tiene resistencia mejorada contra ralladuras y desgaste.
US9051473B2 (en) * 2006-06-14 2015-06-09 Axalta Coating Systems Ip Co., Llc Clear coating compositions comprising dispersed silica nono-particles and processes for using
EP2062311A2 (en) * 2006-09-12 2009-05-27 Ciba Holding Inc. Imidazolidinone nitroxides as electrode materials for energy storage devices
WO2009077396A1 (en) * 2007-12-18 2009-06-25 Basf Se Biodiesel cold flow improver
CN102958993B (zh) 2010-06-29 2015-07-22 巴斯夫欧洲公司 改善聚合物熔体的流动性能的方法
TWI413648B (zh) * 2010-12-31 2013-11-01 Chi Mei Corp 共軛二烯－乙烯基芳香烴共聚物及其製備方法
RU2014120925A (ru) 2011-10-25 2015-12-10 Басф Се Применение гребенчатых или блок-сополимеров в качестве средств против повторного осаждения загрязнения и грязеотталкивающих средств в процессах стирки
US9790452B2 (en) 2013-03-27 2017-10-17 Basf Se Block copolymers as soil release agents in laundry processes
FR3030525B1 (fr) * 2014-12-18 2018-05-11 Arkema France Polymerisation radicalaire d'alcoxyamines a basse temperature
CN104788594B (zh) * 2015-04-16 2018-07-24 厦门大学 一种端氨基聚合物的制备方法
EP3875566B1 (de) 2020-03-06 2023-01-11 Henkel AG & Co. KGaA Nitroxidverbindungen in wasch- oder reinigungsmitteln
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Also Published As

Publication number Publication date
JP2001508485A (ja) 2001-06-26
AU6022998A (en) 1998-08-03
DE69829588T2 (de) 2006-01-19
US6271340B1 (en) 2001-08-07
CN1249759A (zh) 2000-04-05
US20020061989A1 (en) 2002-05-23
DE69812885D1 (de) 2003-05-08
CN1824655A (zh) 2006-08-30
EP0951485A2 (en) 1999-10-27
WO1998030601A3 (en) 1998-12-03
AU750626B2 (en) 2002-07-25
DE69812885T2 (de) 2004-01-29
CA2277164A1 (en) 1998-07-16
KR20000070015A (ko) 2000-11-25
EP0951485B1 (en) 2003-04-02
BR9807104A (pt) 2000-04-25
CA2277164C (en) 2005-11-08
WO1998030601A2 (en) 1998-07-16
KR100504055B1 (ko) 2005-07-27
DE69829588D1 (de) 2005-05-04
US20030149208A1 (en) 2003-08-07

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GR01 Patent grant
C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee