KR100504055B1 - 중합체 분자량 및 구조의 조절 방법 - Google Patents

중합체 분자량 및 구조의 조절 방법 Download PDF

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Publication number
KR100504055B1
KR100504055B1 KR10-1999-7006234A KR19997006234A KR100504055B1 KR 100504055 B1 KR100504055 B1 KR 100504055B1 KR 19997006234 A KR19997006234 A KR 19997006234A KR 100504055 B1 KR100504055 B1 KR 100504055B1
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KR
South Korea
Prior art keywords
alkyl
substituted
membered ring
aryl
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR10-1999-7006234A
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English (en)
Korean (ko)
Other versions
KR20000070015A (ko
Inventor
앨버트 지. 앤더슨
알렉세이 그리드네브
그램 모드
에지오 리짜르도
산 호아 탕
Original Assignee
이 아이 듀폰 디 네모아 앤드 캄파니
커먼웰쓰 사이언티픽 앤드 인더스트리얼 리서치 오가니제이션
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Application filed by 이 아이 듀폰 디 네모아 앤드 캄파니, 커먼웰쓰 사이언티픽 앤드 인더스트리얼 리서치 오가니제이션 filed Critical 이 아이 듀폰 디 네모아 앤드 캄파니
Publication of KR20000070015A publication Critical patent/KR20000070015A/ko
Application granted granted Critical
Publication of KR100504055B1 publication Critical patent/KR100504055B1/ko
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
    • C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/30—Oxygen or sulfur atoms
    • C07D233/32—One oxygen atom
    • C07D233/38—One oxygen atom with acyl radicals or hetero atoms directly attached to ring nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Graft Or Block Polymers (AREA)
KR10-1999-7006234A 1997-01-10 1998-01-07 중합체 분자량 및 구조의 조절 방법 Expired - Fee Related KR100504055B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US3472797P 1997-01-10 1997-01-10
US60/034,727 1997-01-10
PCT/US1998/000601 WO1998030601A2 (en) 1997-01-10 1998-01-07 Method of controlling polymer molecular weight and structure

Publications (2)

Publication Number Publication Date
KR20000070015A KR20000070015A (ko) 2000-11-25
KR100504055B1 true KR100504055B1 (ko) 2005-07-27

Family

ID=21878221

Family Applications (1)

Application Number Title Priority Date Filing Date
KR10-1999-7006234A Expired - Fee Related KR100504055B1 (ko) 1997-01-10 1998-01-07 중합체 분자량 및 구조의 조절 방법

Country Status (10)

Country Link
US (3) US6271340B1 (enExample)
EP (1) EP0951485B1 (enExample)
JP (1) JP2001508485A (enExample)
KR (1) KR100504055B1 (enExample)
CN (2) CN1280314C (enExample)
AU (1) AU750626B2 (enExample)
BR (1) BR9807104A (enExample)
CA (1) CA2277164C (enExample)
DE (2) DE69812885T2 (enExample)
WO (1) WO1998030601A2 (enExample)

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SG82601A1 (en) 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
CA2337482A1 (en) * 1998-07-31 2000-02-17 Ciba Specialty Chemicals Holding Inc. Open chain alkoxyamine compounds and their use as polymerization regulators
CA2341384A1 (en) * 1998-09-29 2000-04-06 Ciba Specialty Chemicals Holding Inc. Process for the preparation of polymers containing n->o terminal groups
FR2784111B1 (fr) * 1998-10-06 2003-08-01 Atochem Elf Sa Polymerisatin radicalaire en presence de plusieurs radicaux libres stables
TWI225483B (en) * 1998-10-16 2004-12-21 Ciba Sc Holding Ag Heterocyclic alkoxyamines as regulators in controlled radical polymerization process
AU3733800A (en) * 1999-03-09 2000-09-28 Symyx Technologies, Inc. Controlled free radical emulsion and water-based polymerizations and seeded methodologies
US6472486B2 (en) 1999-03-09 2002-10-29 Symyx Technologies, Inc. Controlled stable free radical emulsion polymerization processes
JP4829447B2 (ja) * 1999-07-02 2011-12-07 チバ ホールディング インコーポレーテッド 官能化されたマクロマーの製造のための１および多官能価アルコキシアミン
WO2001002452A1 (en) 1999-07-02 2001-01-11 Symyx Technologies, Inc. Polymer brushes for immobilizing molecules to a surface or substrate, where the polymers have water-soluble or water-dispersible segments and probes bonded thereto
US6716948B1 (en) 1999-07-31 2004-04-06 Symyx Technologies, Inc. Controlled-architecture polymers and use thereof as separation media
WO2001012721A1 (en) * 1999-08-12 2001-02-22 Ciba Specialty Chemicals Holdings Inc. Polymer blends with improved impact resistance
JP4883515B2 (ja) * 1999-09-08 2012-02-22 ポリセリックス リミテッド 均一分子量ポリマー
WO2001023435A1 (en) * 1999-09-30 2001-04-05 Noveon Ip Holdings Corp. Polymerization compositions and methods
TW541303B (en) 2000-03-22 2003-07-11 Ciba Sc Holding Ag 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides
DE10036801A1 (de) 2000-07-28 2002-02-07 Tesa Ag Acrylathaftklebemassen mit enger Molekulargewichtsverteilung
TWI225492B (en) 2000-09-25 2004-12-21 Ciba Sc Holding Ag Composition and process for enhancing controlled free radical polymerization
WO2002056021A2 (en) 2001-01-10 2002-07-18 Symyx Technologies Inc Polymer brushes for immobilizing molecules to a surface
US6547840B2 (en) 2001-04-02 2003-04-15 Ciba Specialty Chemicals Corporation Candle wax stabilized with imidazolidines
US6849679B2 (en) 2001-05-21 2005-02-01 Ciba Specialty Chemicals Corporation Pigment compositions with modified block copolymer dispersants
US20030073835A1 (en) 2001-07-31 2003-04-17 Dario Lazzari Imidazolidinone derivatives
EP1283240A1 (en) * 2001-07-31 2003-02-12 Ciba SC Holding AG Imidazolidinone derivatives
DE10149083A1 (de) 2001-10-05 2003-04-17 Tesa Ag Acrylathaftklebemassen mit enger Molekulargewichtsverteilung
DE10149084A1 (de) 2001-10-05 2003-06-18 Tesa Ag UV-vernetzbare Acrylathaftschmelzhaftkleber mit enger Molekulargewichtsverteilung
US6762263B2 (en) * 2002-02-01 2004-07-13 Atofina Chemicals, Inc. High-solids coatings resins via controlled radical polymerization
US7375175B2 (en) * 2002-08-19 2008-05-20 National Starch And Chemical Investment Holding Corporation Dispersions containing living radicals
US6841636B2 (en) * 2002-08-19 2005-01-11 National Starch And Chemical Investment Holding Corporation Dispersions containing living radicals
FR2852961B1 (fr) * 2003-03-26 2006-07-07 Atofina Nouveau procede de synthese/fabrication de films acryliques
FR2852963A1 (fr) * 2003-03-26 2004-10-01 Atofina Nouveau procede de synthese/fabrication de films acryliques
DE10322830A1 (de) * 2003-05-19 2004-12-09 Tesa Ag Verfahren zur kontinuierlichen Herstellung von Polymeren aus vinylischen Verbindungen durch Substanz-beziehungsweise Lösungsmittelpolymerisation
JP4046678B2 (ja) * 2003-10-15 2008-02-13 横浜ゴム株式会社 タイヤトレッド用ゴム組成物及びそれを用いた空気入りタイヤ
US7652121B2 (en) * 2005-01-13 2010-01-26 E.I. Du Pont De Nemours And Company Rheology control agents for coating compositions
US7741510B2 (en) * 2005-01-13 2010-06-22 E. I. Du Pont De Nemours And Company Rheology control agents
US20060155021A1 (en) * 2005-01-13 2006-07-13 Lenges Christian P Coating compositions containing rheology control agents
US7632882B2 (en) * 2005-01-13 2009-12-15 E.I. Du Pont De Nemours And Company Rheology control agents for coating compositions
JP4046734B2 (ja) 2005-01-18 2008-02-13 横浜ゴム株式会社 ポリマーの変性方法
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US7009011B1 (en) * 2005-05-31 2006-03-07 Xerox Corporation Copolymers of maleic anhydride by stable free redical polymerization
US20070028806A1 (en) * 2005-08-03 2007-02-08 Piro Bonnie D Coating compositions having improved appearance containing coated titanium dioxide pigments
EP1969397B1 (en) * 2005-12-14 2017-11-08 Novartis AG Method for preparing silicone hydrogels
MX325549B (es) * 2006-06-14 2014-11-24 Du Pont Sustrato recubierto que tiene resistencia mejorada contra ralladuras y desgaste.
US9051473B2 (en) * 2006-06-14 2015-06-09 Axalta Coating Systems Ip Co., Llc Clear coating compositions comprising dispersed silica nono-particles and processes for using
US20080021147A1 (en) * 2006-06-14 2008-01-24 Jun Lin Process for forming a dispersion of silica nano-particles
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CN102958993B (zh) 2010-06-29 2015-07-22 巴斯夫欧洲公司 改善聚合物熔体的流动性能的方法
TWI413648B (zh) * 2010-12-31 2013-11-01 Chi Mei Corp 共軛二烯－乙烯基芳香烴共聚物及其製備方法
WO2013060708A1 (en) 2011-10-25 2013-05-02 Basf Se Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes
EP2978786A1 (en) 2013-03-27 2016-02-03 Basf Se Block copolymers as soil release agents in laundry processes
FR3030525B1 (fr) * 2014-12-18 2018-05-11 Arkema France Polymerisation radicalaire d'alcoxyamines a basse temperature
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Also Published As

Publication number Publication date
US6271340B1 (en) 2001-08-07
KR20000070015A (ko) 2000-11-25
DE69829588D1 (de) 2005-05-04
AU6022998A (en) 1998-08-03
WO1998030601A3 (en) 1998-12-03
CA2277164A1 (en) 1998-07-16
CN1280314C (zh) 2006-10-18
DE69829588T2 (de) 2006-01-19
DE69812885T2 (de) 2004-01-29
CN1249759A (zh) 2000-04-05
US20030149208A1 (en) 2003-08-07
US20020061989A1 (en) 2002-05-23
EP0951485B1 (en) 2003-04-02
CA2277164C (en) 2005-11-08
AU750626B2 (en) 2002-07-25
BR9807104A (pt) 2000-04-25
EP0951485A2 (en) 1999-10-27
DE69812885D1 (de) 2003-05-08
CN1824655A (zh) 2006-08-30
WO1998030601A2 (en) 1998-07-16
JP2001508485A (ja) 2001-06-26

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