CN1249300A - 由丙烯生产丙烯酸功效改进的单反应器法 - Google Patents
由丙烯生产丙烯酸功效改进的单反应器法 Download PDFInfo
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- CN1249300A CN1249300A CN99104024A CN99104024A CN1249300A CN 1249300 A CN1249300 A CN 1249300A CN 99104024 A CN99104024 A CN 99104024A CN 99104024 A CN99104024 A CN 99104024A CN 1249300 A CN1249300 A CN 1249300A
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- described method
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- propylene
- heat
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- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 97
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 19
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/067—Heating or cooling the reactor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00212—Plates; Jackets; Cylinders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00212—Plates; Jackets; Cylinders
- B01J2208/00221—Plates; Jackets; Cylinders comprising baffles for guiding the flow of the heat exchange medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00256—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles in a heat exchanger for the heat exchange medium separate from the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
- B01J2208/023—Details
- B01J2208/024—Particulate material
- B01J2208/025—Two or more types of catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Description
Claims (38)
Applications Claiming Priority (3)
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US10221998P | 1998-09-27 | 1998-09-27 | |
US102219 | 1998-09-29 | ||
US102,219 | 1998-09-29 |
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CN1249300A true CN1249300A (zh) | 2000-04-05 |
CN1312104C CN1312104C (zh) | 2007-04-25 |
Family
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CNB991040244A Expired - Lifetime CN1312104C (zh) | 1998-09-27 | 1999-03-17 | 由丙烯生产丙烯酸功效改进的单反应器法 |
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Country | Link |
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US (1) | US6384274B1 (zh) |
EP (1) | EP0990636B1 (zh) |
JP (1) | JP2000103761A (zh) |
KR (1) | KR100650037B1 (zh) |
CN (1) | CN1312104C (zh) |
BR (1) | BR9900847A (zh) |
DE (1) | DE69910930T2 (zh) |
MX (1) | MXPA99001856A (zh) |
TW (1) | TWI239328B (zh) |
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Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH493811A (de) | 1967-09-06 | 1970-07-15 | Basf Ag | Wärmetauschvorrichtung |
JPS4924898B1 (zh) | 1970-12-26 | 1974-06-26 | ||
BE793928A (fr) | 1972-01-13 | 1973-05-02 | Deggendorfer Werft Eisenbau | Appareil pour la mise en oeuvre de processus chimiques exothermiques et endothermiques |
DE2231557A1 (de) | 1972-06-28 | 1974-01-17 | Rheinstahl Ag | Reaktor fuer katalytische gasphaseoxydation |
JPS52108917A (en) | 1976-03-11 | 1977-09-12 | Nippon Shokubai Kagaku Kogyo Co Ltd | Preparation of acrylic acid by vapor-phase catalytic oxidation of prop ylene |
US4203906A (en) | 1977-07-13 | 1980-05-20 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Process for catalytic vapor phase oxidation |
US4317926A (en) | 1978-01-19 | 1982-03-02 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Process for preparing and recovering acrylic acid |
JPS55102536A (en) | 1979-01-30 | 1980-08-05 | Mitsubishi Petrochem Co Ltd | Preparation of acrylic acid |
JPS5673041A (en) | 1979-11-19 | 1981-06-17 | Mitsubishi Petrochem Co Ltd | Preparation of acrylic acid |
US5198578A (en) | 1986-07-17 | 1993-03-30 | Union Carbide Chemicals | Anhydrous diluents for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid |
US5218146A (en) | 1987-05-27 | 1993-06-08 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Process for production of acrylic acid |
AU606160B2 (en) * | 1987-05-27 | 1991-01-31 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Process for production of acrylic acid |
DE3874759D1 (de) | 1988-12-13 | 1992-10-22 | Deggendorfer Werft Eisenbau | Rohrbuendelreaktor. |
DE4023239A1 (de) | 1990-07-21 | 1992-01-23 | Basf Ag | Verfahren zur katalytischen gasphasenoxidation von propen oder iso-buten zu acrolein oder methacrolein |
DE4132263A1 (de) | 1991-09-27 | 1993-04-01 | Basf Ag | Verfahren zur katalytischen gasphasenoxidation von acrolein zu acrylsaeure |
TW295580B (zh) | 1992-01-09 | 1997-01-11 | Nippon Catalytic Chem Ind | |
DE4431957A1 (de) | 1994-09-08 | 1995-03-16 | Basf Ag | Verfahren zur katalytischen Gasphasenoxidation von Propen zu Acrolein |
DE4431949A1 (de) | 1994-09-08 | 1995-03-16 | Basf Ag | Verfahren zur katalytischen Gasphasenoxidation von Acrolein zu Acrylsäure |
CA2261268A1 (en) | 1996-04-01 | 1997-10-09 | Jonathan Lester Brockwell | Processes for the oxidation of alkanes |
JP3476307B2 (ja) | 1996-05-09 | 2003-12-10 | 三菱レイヨン株式会社 | 不飽和アルデヒド及び不飽和カルボン酸合成用触媒の充填方法 |
JP3948798B2 (ja) | 1997-10-27 | 2007-07-25 | 株式会社日本触媒 | アクリル酸の製造方法 |
-
1999
- 1999-02-04 US US09/244,182 patent/US6384274B1/en not_active Expired - Lifetime
- 1999-02-24 EP EP99301356A patent/EP0990636B1/en not_active Revoked
- 1999-02-24 DE DE69910930T patent/DE69910930T2/de not_active Revoked
- 1999-02-25 MX MXPA99001856A patent/MXPA99001856A/es active IP Right Grant
- 1999-02-26 TW TW088102944A patent/TWI239328B/zh not_active IP Right Cessation
- 1999-03-02 BR BR9900847-5A patent/BR9900847A/pt not_active Application Discontinuation
- 1999-03-09 KR KR1019990007699A patent/KR100650037B1/ko not_active IP Right Cessation
- 1999-03-17 CN CNB991040244A patent/CN1312104C/zh not_active Expired - Lifetime
- 1999-06-09 JP JP11162225A patent/JP2000103761A/ja active Pending
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7119227B2 (en) | 2002-03-11 | 2006-10-10 | Mitsubishi Chemical Corporation | Process for catalytic vapor phase oxidation |
CN1330618C (zh) * | 2002-03-11 | 2007-08-08 | 三菱化学株式会社 | 催化气相氧化法 |
CN100341841C (zh) * | 2002-08-08 | 2007-10-10 | 株式会社日本触媒 | 生产丙烯酸的方法 |
CN100347144C (zh) * | 2003-03-25 | 2007-11-07 | 巴斯福股份公司 | 将丙烯非均相催化部分气相氧化成丙烯酸的方法 |
CN1781594B (zh) * | 2004-11-22 | 2010-05-05 | 罗门哈斯公司 | 反应器非正常停车方法 |
CN104661738A (zh) * | 2012-09-24 | 2015-05-27 | 阿科玛股份有限公司 | 具有改进的抗污损性的反应器 |
CN104661738B (zh) * | 2012-09-24 | 2017-03-29 | 阿科玛股份有限公司 | 具有改进的抗污损性的反应器 |
CN103542984A (zh) * | 2013-10-30 | 2014-01-29 | 天津市化工设计院 | 5万吨/年蛋氨酸丙烯氧化反应器模拟工况检验方法 |
Also Published As
Publication number | Publication date |
---|---|
EP0990636A1 (en) | 2000-04-05 |
BR9900847A (pt) | 2000-05-09 |
KR20000022591A (ko) | 2000-04-25 |
DE69910930T2 (de) | 2004-07-22 |
EP0990636B1 (en) | 2003-09-03 |
DE69910930D1 (de) | 2003-10-09 |
KR100650037B1 (ko) | 2006-11-27 |
MXPA99001856A (es) | 2005-07-15 |
TWI239328B (en) | 2005-09-11 |
US6384274B1 (en) | 2002-05-07 |
JP2000103761A (ja) | 2000-04-11 |
CN1312104C (zh) | 2007-04-25 |
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