AU2001278449A1 - Method for producing acrolein and/or acrylic acid - Google Patents
Method for producing acrolein and/or acrylic acidInfo
- Publication number
- AU2001278449A1 AU2001278449A1 AU2001278449A AU7844901A AU2001278449A1 AU 2001278449 A1 AU2001278449 A1 AU 2001278449A1 AU 2001278449 A AU2001278449 A AU 2001278449A AU 7844901 A AU7844901 A AU 7844901A AU 2001278449 A1 AU2001278449 A1 AU 2001278449A1
- Authority
- AU
- Australia
- Prior art keywords
- propane
- propene
- acrylic acid
- oxidation
- acrolein
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
Acrolein and acrylic acid are produced from propane and propene by absorption/desorption of propane and propene from a gas mixture followed by oxidation, in which no heterogeneously catalyzed dehydrogenation of propane occurs between the desorption and oxidation stages without addition of oxygen. Acrolein and acrylic acid are produced from propane and propene by: (a) separation of propane and propene from a gas mixture (A) by absorption in an absorption medium; (b) separation of propane and propene from the absorbent to give a mixture (B) containing propane and propene; and (c) using mixture (B) for oxidation to the required product(s). In this process, no catalytic dehydrogenation of propane without the addition of oxygen is carried out between stages (b) and (c).
Applications Claiming Priority (21)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10028582 | 2000-06-14 | ||
DE10028582A DE10028582A1 (en) | 2000-06-14 | 2000-06-14 | Production of acrolein or acrylic acid from propane, involves partial gas-phase dehydrogenation, removal of hydrogen and partial gas-phase oxidation of propene with nitrogen as diluent, and recycling of unreacted propane |
DE2000129338 DE10029338A1 (en) | 2000-06-20 | 2000-06-20 | Production of acrolein or acrylic acid involves absorption of propane and propene from a gas mixture followed by desorption and oxidation, with no catalytic dehydrogenation of propane and no added oxygen |
DE10029338 | 2000-06-20 | ||
DE10033121 | 2000-07-07 | ||
DE2000133121 DE10033121A1 (en) | 2000-07-07 | 2000-07-07 | Production of acrolein or acrylic acid involves absorption of propane and propene from a gas mixture followed by desorption and oxidation, with no catalytic dehydrogenation of propane and no added oxygen |
DE2000134825 DE10034825A1 (en) | 2000-07-18 | 2000-07-18 | Production of acrolein or acrylic acid involves absorption of propane and propene from a gas mixture followed by desorption and oxidation, with no catalytic dehydrogenation of propane and no added oxygen |
DE10034825 | 2000-07-18 | ||
DE10046672 | 2000-09-20 | ||
DE2000146672 DE10046672A1 (en) | 2000-09-20 | 2000-09-20 | Production of acrolein or acrylic acid involves absorption of propane and propene from a gas mixture followed by desorption and oxidation, with no catalytic dehydrogenation of propane and no added oxygen |
DE10051419A DE10051419A1 (en) | 2000-10-17 | 2000-10-17 | Production of acrolein or acrylic acid involves absorption of propane and propene from a gas mixture followed by desorption and oxidation, with no catalytic dehydrogenation of propane and no added oxygen |
DE10051419 | 2000-10-17 | ||
DE10118814 | 2001-04-17 | ||
DE10118814A DE10118814A1 (en) | 2001-04-17 | 2001-04-17 | Production of acrolein or acrylic acid involves absorption of propane and propene from a gas mixture followed by desorption and oxidation, with no catalytic dehydrogenation of propane and no added oxygen |
DE10119933 | 2001-04-23 | ||
DE2001119933 DE10119933A1 (en) | 2001-04-23 | 2001-04-23 | Production of acrolein or acrylic acid involves absorption of propane and propene from a gas mixture followed by desorption and oxidation, with no catalytic dehydrogenation of propane and no added oxygen |
DE10121592 | 2001-05-03 | ||
DE2001121592 DE10121592A1 (en) | 2001-05-03 | 2001-05-03 | Production of acrolein or acrylic acid involves absorption of propane and propene from a gas mixture followed by desorption and oxidation, with no catalytic dehydrogenation of propane and no added oxygen |
DE10122027A DE10122027A1 (en) | 2001-05-07 | 2001-05-07 | Production of acrolein or acrylic acid involves absorption of propane and propene from a gas mixture followed by desorption and oxidation, with no catalytic dehydrogenation of propane and no added oxygen |
DE10122027 | 2001-05-07 | ||
PCT/EP2001/006708 WO2001096271A2 (en) | 2000-06-14 | 2001-06-13 | Method for producing acrolein and/or acrylic acid |
Publications (1)
Publication Number | Publication Date |
---|---|
AU2001278449A1 true AU2001278449A1 (en) | 2001-12-24 |
Family
ID=27579201
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU2001278449A Abandoned AU2001278449A1 (en) | 2000-06-14 | 2001-06-13 | Method for producing acrolein and/or acrylic acid |
Country Status (13)
Country | Link |
---|---|
US (1) | US7321058B2 (en) |
EP (2) | EP1289919B1 (en) |
JP (1) | JP5021140B2 (en) |
KR (1) | KR100740728B1 (en) |
CN (1) | CN1209332C (en) |
AT (1) | ATE346835T1 (en) |
AU (1) | AU2001278449A1 (en) |
BR (1) | BR0111702B1 (en) |
CZ (1) | CZ304548B6 (en) |
DE (1) | DE50111556D1 (en) |
ES (2) | ES2276808T3 (en) |
MY (1) | MY140522A (en) |
WO (1) | WO2001096271A2 (en) |
Families Citing this family (65)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10051419A1 (en) * | 2000-10-17 | 2002-04-18 | Basf Ag | Production of acrolein or acrylic acid involves absorption of propane and propene from a gas mixture followed by desorption and oxidation, with no catalytic dehydrogenation of propane and no added oxygen |
DE10118814A1 (en) * | 2001-04-17 | 2002-10-24 | Basf Ag | Production of acrolein or acrylic acid involves absorption of propane and propene from a gas mixture followed by desorption and oxidation, with no catalytic dehydrogenation of propane and no added oxygen |
WO2002006199A2 (en) * | 2000-07-18 | 2002-01-24 | Basf Aktiengesellschaft | Method for producing acrylic acid by the heterogeneously catalysed gas-phase oxidation of propane |
DE10232482A1 (en) | 2002-07-17 | 2004-01-29 | Basf Ag | Process for the safe operation of a continuous heterogeneously catalyzed gas phase partial oxidation of at least one organic compound |
US7038080B2 (en) * | 2002-09-27 | 2006-05-02 | Basf Aktiengesellschaft | Heterogeneously catalyzed gas-phase partial oxidation of acrolein to acrylic acid |
US7238827B2 (en) * | 2002-09-27 | 2007-07-03 | Basf Aktiengesellschaft | Preparation of at least one partial oxidation and/or ammoxidation product of propylene |
EP1411043A1 (en) * | 2002-10-18 | 2004-04-21 | Rohm And Haas Company | Preparation of unsaturated carboxylic acids and unsaturated carboxylic acid esters from alkanes and/or alkenes |
DE10249379A1 (en) | 2002-10-23 | 2004-05-06 | Basf Ag | Process for the continuous recycling of the olefin not reacted in the oxidation of olefins with hydroperoxides by means of solvent washing |
DE10251262A1 (en) * | 2002-11-04 | 2004-05-13 | Basf Ag | Production of saturated aldehydes from alkanes comprises dehydrogenation to yield alkenes with hydroformylation to form aldehyde with at least partial recycle of the alkane |
WO2004099081A1 (en) * | 2003-05-12 | 2004-11-18 | Basf Aktiengesellschaft | Multimetal oxide materials provided in a pure i phase and containing mo, v, and alkali metal |
CA2541794C (en) * | 2003-06-20 | 2017-06-13 | Detroit Edison Company | Device and method for reforming a voc gas |
EP1687249B1 (en) * | 2003-08-06 | 2009-12-02 | Basf Se | Method for operating a continuous heterogeneously catalysed gas-phase partial oxidation of at least one organic compound |
WO2005113123A1 (en) * | 2004-05-07 | 2005-12-01 | Basf Aktiengesellschaft | Method for structurally filling contact tubes of a bank of contact tubes |
JP2005336065A (en) * | 2004-05-25 | 2005-12-08 | Mitsubishi Chemicals Corp | Method for producing (meth)acrolein or (meth)acrylic acid |
DE102004027999A1 (en) * | 2004-06-09 | 2005-01-27 | Basf Ag | Production of multimetal oxide material, useful as an oxidation or ammoxidation catalyst comprises subjecting a mixture of metal oxide sources to hydrothermal treatment |
US7592483B2 (en) * | 2004-07-01 | 2009-09-22 | Basf Aktiengesellschaft | Preparation of acrolein or acrylic acid or a mixture thereof by heterogeneously catalyzed partial gas phase oxidation of propylene |
JP5156375B2 (en) * | 2004-07-01 | 2013-03-06 | ビーエーエスエフ ソシエタス・ヨーロピア | Production of acrolein or acrylic acid or mixtures thereof from propane |
FR2881136B1 (en) * | 2005-01-21 | 2007-03-23 | Arkema Sa | PROCESS FOR THE PREPARATION OF ACRYLIC ACID COMPRISING A PARTIAL OXIDATION OF PROPANE PROPYLENE |
US7439389B2 (en) | 2005-03-01 | 2008-10-21 | Basf Aktiengesellschaft | Process for preparing at least one organic target compound by heterogeneously catalyzed gas phase partial oxidation |
US7705181B2 (en) * | 2005-03-01 | 2010-04-27 | Basf Akiengesellschaft | Process for removing methacrylic acid from liquid phase comprising acrylic acid as a main constituent and target product, and methacrylic acid as a secondary component |
MY140309A (en) * | 2005-03-01 | 2009-12-31 | Basf Ag | Process for preparing at least one organic target compound by heterogeneously catalyzed gas phase partial oxidation |
US7601866B2 (en) | 2005-03-01 | 2009-10-13 | Basf Aktiengesellschaft | Process for removing methacrolein from liquid phase comprising acrylic acid as a main constituent and target product, and methacrolein as a secondary component |
DE102005009882A1 (en) * | 2005-03-01 | 2006-11-16 | Basf Ag | Preparing organic target compound by heterogeneously catalyzed gas phase partial oxidation of organic precursor compound with molecular oxygen in two oxidation reactor lines operated in parallel and removal of compound from gas stream |
DE502006003491D1 (en) * | 2005-11-03 | 2009-05-28 | Basf Se | METHOD FOR THE STABLE OPERATION OF A CONTINUOUS EXTRACTION PROCESS FOR THE PRODUCTION OF ACROLEINE, OR ACRYLIC ACID OR THEIR PROPANE MIXTURE |
KR101370749B1 (en) | 2005-11-24 | 2014-03-06 | 바스프 에스이 | Process for preparing acrolein or acrylic acid or a mixture thereof from propane |
DE102005061626A1 (en) * | 2005-12-21 | 2007-06-28 | Basf Ag | Continuous heterogeneous catalyzed partial dehydrogenation of hydrocarbon involves feeding hydrocarbon to reaction chamber enclosed by shell made of specific steel, passing hydrocarbon through catalyst bed and dehydrogenating feed |
DE102006000996A1 (en) | 2006-01-05 | 2007-07-12 | Basf Ag | Heterogeneously catalyzed gas phase partial oxidation of organic compound in fixed catalyst bed involves recovering quality of catalyst bed by replacing its portion, with a catalyst having activity lower than that of the replaced catalyst |
EP1734030A1 (en) * | 2006-01-18 | 2006-12-20 | BASF Aktiengesellschaft | Method for long term operation of a heterogeneously catalysed gas phase partial oxidation of an organic educt |
CN101405079A (en) * | 2006-03-20 | 2009-04-08 | 旭化成化学株式会社 | Oxidation or ammoxydation catalyst and method of preparing the same |
DE102006024901A1 (en) | 2006-05-24 | 2007-11-29 | Basf Ag | Preparing acrylic acid comprises supplying propane gas to a zone to give a gas containing e.g. propylene, supplying molecular oxygen, feeding oxidation reactor with another gas containing e.g. propylene and subjecting the gas to oxidation |
DE102006029790A1 (en) | 2006-06-27 | 2008-01-03 | Basf Ag | Continuous heterogeneously catalyzed partial dehydrogenation of hydrocarbon involves dehydrogenation through catalyst bed disposed in reaction chamber and with generation of product gas |
US20080003172A1 (en) * | 2006-06-29 | 2008-01-03 | Honeywell International Inc. | Continuous hydrolysis of hexafluoroarsenic acid |
EP2059334A1 (en) * | 2006-11-15 | 2009-05-20 | Basf Se | Process for conducting an exothermic heterogeneously catalyzed partial gas phase oxidation of an organic starting compound to an organic target compound |
DE102007006647A1 (en) * | 2007-02-06 | 2008-08-07 | Basf Se | Process for the regeneration of a catalyst bed deactivated in the context of a heterogeneously catalyzed partial dehydrogenation of a hydrocarbon |
DE102007014603A1 (en) | 2007-03-23 | 2008-09-25 | Basf Se | Method of transporting a withdrawn from a storage container liquid monomer phase in the tank of a tanker or a tanker |
DE102007014606A1 (en) | 2007-03-23 | 2008-09-25 | Basf Se | Process for the storage of a monomer phase which is liquid under the conditions of storage |
DE102007043759A1 (en) | 2007-09-13 | 2008-09-11 | Basf Se | Procedure for continuous separation of target product in the form of fine particle of crystallisate, comprises indirectly operating a heat exchanger having primary and secondary areas, which are spatially separated with one another |
DE102007043748A1 (en) | 2007-09-13 | 2008-09-11 | Basf Se | Method for separating target product i.e. acrylic acid, methacrylic acid, p-xylene or N-vinylpyrrolidone in form of fine crystallized product, involves utilizing heat exchanger, where heat flow is gathered from heat exchanger |
BE1018537A3 (en) | 2007-09-13 | 2011-03-01 | Basf Se | METHOD FOR OPERATING A CONTINUOUS SEPARATION OF TARGET PRODUCT X IN THE FORM OF A FINALLY DIVIDED CRYSTALLISATE |
DE102007043758A1 (en) | 2007-09-13 | 2008-10-23 | Basf Se | Target product continuous separating operation in form of fine crystals from liquid phase, includes heat exchanger having secondary space and primary space |
MX2008015540A (en) * | 2007-12-26 | 2009-06-26 | Rohm Ahd Haas Company | Integrated process for preparing a carboxylic acid from an alkane. |
DE102008041573A1 (en) | 2008-08-26 | 2010-03-04 | Basf Se | Separating acrylic acid and glyoxal from gaseous product mixture of gas phase oxidation of a three carbon-precursor compound of acrylic acid comprises producing a liquid phase containing acrylic acid and glyoxal, and separating glyoxal |
BRPI0916635B1 (en) | 2008-07-28 | 2020-04-14 | Basf Se | process to separate acrylic acid, present as a main product, and glyoxal, present as a by-product in a gas mixture |
DE102008040799A1 (en) | 2008-07-28 | 2008-12-11 | Basf Se | Separating a three carbon precursor compound of acrylic acid as main component containing acrylic acid and as byproduct containing glyoxal, in a product mixture of a heterogeneously catalyzed partial gas phase oxidation |
DE102008044946B4 (en) | 2008-08-29 | 2022-06-15 | Evonik Superabsorber Gmbh | Use of foam bodies in oxidation reactors for the production of unsaturated carboxylic acids |
KR101149050B1 (en) * | 2009-06-11 | 2012-05-24 | 주식회사 엘지화학 | Method for producing unsaturated aldehyde and unsaturatede fatty acid |
DE102009027401A1 (en) | 2009-07-01 | 2010-02-18 | Basf Se | Separating acrylic acid comprises cooling product gas mixture of partial gas phase oxidation of three carbon precursor compound in cooler and providing cooled product gas mixture with (non)evaporated cooling liquid into absorption column |
WO2011000808A2 (en) | 2009-07-01 | 2011-01-06 | Basf Se | Method for separating acrylic acid from the product gas mixture of a heterogeneously catalyzed partial gas phase oxidation of at least one c3-precursor compound |
DE102010001228A1 (en) | 2010-01-26 | 2011-02-17 | Basf Se | Separating acrylic acid from a product gas mixture of heterogeneously catalyzed partial gas phase oxidation of a precursor compound to acrylic acid comprises cooling product gas mixture and adding cooled mixture into absorption column |
US9040763B2 (en) * | 2010-06-28 | 2015-05-26 | Uop Llc | Method for quenching paraffin dehydrogenation reaction in counter-current reactor |
DE102010042216A1 (en) | 2010-10-08 | 2011-06-09 | Basf Se | Inhibiting the unwanted radical polymerization of acrylic acid present in a liquid phase, comprises adding a chemical compound of copper to the liquid phase, and the liquid phase additionally contains propionic acid and glyoxal |
DE102011076931A1 (en) | 2011-06-03 | 2012-12-06 | Basf Se | Aqueous solution containing acrylic acid and its conjugate base |
EP2765127A1 (en) * | 2013-02-06 | 2014-08-13 | Evonik Industries AG | Process for the separation of acrolein from the process gas from the heterogeneously catalyzed oxidation of propene |
CN105263895B (en) * | 2013-05-20 | 2018-04-10 | 沙特基础工业公司 | For purification of acetic acid and acrylic acid |
JP6627484B2 (en) * | 2014-12-19 | 2020-01-08 | 三菱ケミカル株式会社 | Chemical manufacturing equipment and chemical manufacturing operation stop method using chemical manufacturing equipment |
WO2017025391A1 (en) | 2015-08-07 | 2017-02-16 | Basf Se | Process for production of acrylic acid |
RU2715605C1 (en) | 2016-07-25 | 2020-03-03 | Мицубиси Кемикал Корпорейшн | Catalyst, method of producing acrylic acid and method of producing catalyst |
CN106622040B (en) * | 2017-01-18 | 2019-10-18 | 中国科学院过程工程研究所 | A kind of system and preparation method thereof that acrylic acid and/or acrylate are prepared using moving-burden bed reactor |
DE102017000861A1 (en) * | 2017-01-31 | 2018-08-02 | Clariant Produkte (Deutschland) Gmbh | Synthesis of a MoVTeNb catalyst from inexpensive metal oxides |
DE102017000862A1 (en) * | 2017-01-31 | 2018-08-02 | Clariant Produkte (Deutschland) Gmbh | Synthesis of a MoVNbTe catalyst with reduced content of niobium and tellurium and higher activity for the oxidative dehydrogenation of ethane |
DE102017000848A1 (en) * | 2017-01-31 | 2018-08-02 | Clariant Produkte (Deutschland) Gmbh | Process for the preparation of molybdenum-containing mixed oxide materials |
CN108855225B (en) * | 2018-07-13 | 2021-03-05 | 吉林大学 | Preparation method and application of alloy hydride material |
KR20210038593A (en) | 2018-07-26 | 2021-04-07 | 바스프 에스이 | Method for inhibiting unwanted radical polymerization of acrylic acid in liquid P |
CN115335354A (en) | 2020-03-26 | 2022-11-11 | 巴斯夫欧洲公司 | Method for inhibiting the undesired free-radical polymerization of acrylic acid present in the liquid phase P |
CN114054021B (en) * | 2020-07-31 | 2023-05-12 | 中国科学院大连化学物理研究所 | Application of Cu catalyst in alkane dehydrogenation reaction |
Family Cites Families (98)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3161670A (en) | 1960-12-12 | 1964-12-15 | Shell Oil Co | Preparation of olefinic compounds |
BE786398A (en) * | 1971-07-21 | 1973-01-18 | Basf Ag | PROCESS FOR PREPARING ANHYDROUS ACRYLIC ACID |
US3798283A (en) * | 1972-03-08 | 1974-03-19 | Atlantic Richfield Co | Non-catalytic oxidative dehydrogenation process |
US3862256A (en) | 1972-08-07 | 1975-01-21 | Anatoly Lvovich Isailingold | Method for preparing mono- and di-olefine hydrocarbons |
GB1378178A (en) | 1972-11-22 | 1974-12-27 | Davy Powergas Ltd | Hydrocarbon recovery process |
US3887631A (en) | 1973-05-14 | 1975-06-03 | Texaco Inc | Oxidative dehydrogenation of hydrocarbons |
US4203906A (en) | 1977-07-13 | 1980-05-20 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Process for catalytic vapor phase oxidation |
US4220091A (en) | 1978-03-03 | 1980-09-02 | The United States Of America As Represented By The Secretary Of The Army | Delay fuze for explosive charge |
US4255284A (en) | 1978-08-15 | 1981-03-10 | Standard Oil Company (Ohio) | Dehydrogenation catalyst |
DE2909671A1 (en) | 1979-03-12 | 1980-10-02 | Basf Ag | METHOD FOR PRODUCING SHELL CATALYSTS |
US4341664A (en) | 1979-06-15 | 1982-07-27 | Uop Inc. | Hydrocarbon dehydrogenation with an attenuated superactive multimetallic catalytic composite for use therein |
US4532365A (en) * | 1982-09-20 | 1985-07-30 | The Halcon Sd Group, Inc. | Conversion of alkanes to unsaturated aldehydes |
US4413147A (en) * | 1982-04-14 | 1983-11-01 | The Halcon Sd Group, Inc. | Conversion of isobutane to methacrolein |
CA1217502A (en) | 1982-04-14 | 1987-02-03 | Sargis Khoobiar | Conversion of alkanes to unsaturated aldehydes |
DE3461782D1 (en) | 1983-02-22 | 1987-02-05 | Halcon Sd Group Inc | Conversion of propane to acrylic acid |
CA1299193C (en) | 1986-07-17 | 1992-04-21 | Gordon Gene Harkreader | Anhydrous diluents for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid |
US5198578A (en) | 1986-07-17 | 1993-03-30 | Union Carbide Chemicals | Anhydrous diluents for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid |
US5183936A (en) | 1986-08-21 | 1993-02-02 | Union Carbide Chemicals & Plastics Technology Corporation | Anhydrous diluent process for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid |
AU606160B2 (en) | 1987-05-27 | 1991-01-31 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Process for production of acrylic acid |
US4788371A (en) | 1987-12-30 | 1988-11-29 | Uop Inc. | Catalytic oxidative steam dehydrogenation process |
US4886928A (en) | 1988-09-26 | 1989-12-12 | Uop | Hydrocarbon dehydrogenation process |
JPH02256625A (en) * | 1988-12-07 | 1990-10-17 | Asahi Chem Ind Co Ltd | Method for separating and recovering isobutane or propane |
FR2642669B1 (en) | 1989-01-18 | 1993-05-07 | Norsolor Sa | CATALYST AND DEHYDROGENATION METHOD |
US4902849A (en) | 1989-02-06 | 1990-02-20 | Phillips Petroleum Company | Dehydrogenation process |
US4996387A (en) | 1989-07-20 | 1991-02-26 | Phillips Petroleum Company | Dehydrogenation process |
US5073662A (en) | 1990-04-23 | 1991-12-17 | Phillips Petroleum Company | Catalyst and process for dehydrogenation and dehydrocyclization |
SG42912A1 (en) | 1991-08-08 | 1997-10-17 | Mitsubishi Chem Ind | Catalyst and process for producing nitriles |
DE4132263A1 (en) | 1991-09-27 | 1993-04-01 | Basf Ag | METHOD FOR CATALYTIC GAS PHASE OXIDATION FROM ACROLEIN TO ACRYLIC ACID |
US5243122A (en) | 1991-12-30 | 1993-09-07 | Phillips Petroleum Company | Dehydrogenation process control |
EP0575879A2 (en) | 1992-06-24 | 1993-12-29 | E.I. Du Pont De Nemours And Company | Pretreated substrate for slide bead coating |
CN1029915C (en) | 1992-10-19 | 1995-10-04 | 厦门大学 | Catalyst for preparing propene by oxidative dehydrogenation of propane |
EP0608838B1 (en) * | 1993-01-28 | 1997-04-16 | Mitsubishi Chemical Corporation | Method for producing an unsaturated carboxylic acid |
JPH06227819A (en) | 1993-02-02 | 1994-08-16 | Mitsubishi Kasei Corp | Preparation of compound metallic oxide |
DE4308087C2 (en) | 1993-03-13 | 1997-02-06 | Basf Ag | Process for the separation of acrylic acid from the reaction gases of the catalytic oxidation of propylene and / or acrolein |
US5344805A (en) | 1993-05-03 | 1994-09-06 | Phillips Petroleum Company | Platinum and tin-containing catalyst and use thereof in alkane dehydrogenation |
NO179131C (en) | 1993-06-14 | 1996-08-14 | Statoil As | Catalyst, process for its preparation and process for dehydrogenation of light paraffins |
JP3500663B2 (en) | 1993-08-18 | 2004-02-23 | 三菱化学株式会社 | Method for producing acrylic acid |
US5563314A (en) | 1993-08-27 | 1996-10-08 | Agaskar; Pradyot A. | Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen |
US5530171A (en) | 1993-08-27 | 1996-06-25 | Mobil Oil Corporation | Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen |
US5430209A (en) | 1993-08-27 | 1995-07-04 | Mobil Oil Corp. | Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen |
US5527979A (en) | 1993-08-27 | 1996-06-18 | Mobil Oil Corporation | Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen |
DE4335172A1 (en) | 1993-10-15 | 1995-04-20 | Basf Ag | Process for the purification of crude (meth) acrylic acid |
JP3500682B2 (en) | 1994-02-23 | 2004-02-23 | 三菱化学株式会社 | Catalyst for the production of nitriles from alkanes |
JPH0857319A (en) | 1994-08-24 | 1996-03-05 | Mitsubishi Chem Corp | Method for activating metal oxide catalyst |
DE4431949A1 (en) | 1994-09-08 | 1995-03-16 | Basf Ag | Process for the catalytic gas-phase oxidation of acrolein to acrylic acid |
DE4431957A1 (en) | 1994-09-08 | 1995-03-16 | Basf Ag | Process for the catalytic gas-phase oxidation of propene to acrolein |
DE4436243A1 (en) | 1994-10-11 | 1996-04-18 | Basf Ag | Process for the separation of (meth) acrylic acid from the reaction gas mixture of the catalytic gas phase oxidation C¶3¶ / C¶4¶ compounds |
CN1035762C (en) | 1994-11-23 | 1997-09-03 | 大庆石油学院 | Process for producing propenoic acid by homogenization, oxydation and dehydrogenation of propane, and propene oxydation, and apparatus thereof |
ES2139266T3 (en) * | 1995-03-10 | 2000-02-01 | Basf Ag | PROCEDURE FOR THE OBTAINING OF ACROLEIN, ACRYLIC ACID, OR ITS MIXTURE FROM PROPANE. |
DE19508532A1 (en) | 1995-03-10 | 1996-09-12 | Basf Ag | Continuous gas phase oxidn. of propene to acrolein and acrylic acid |
DE19530454A1 (en) | 1995-08-18 | 1997-02-20 | Manfred Prof Dr Baerns | Economical continuous oxidative dehydrogenation of propane to propene in high yield |
US5750760A (en) | 1995-10-05 | 1998-05-12 | Mitsubishi Chemical Corporation | Method for producing a nitrile |
KR20000005139A (en) | 1996-04-01 | 2000-01-25 | 메이허,존,마이클 | Processes for the oxidation of alkanes |
JP3769866B2 (en) | 1996-04-18 | 2006-04-26 | 三菱化学株式会社 | Method for producing catalyst for gas phase catalytic oxidation |
DE19622331A1 (en) * | 1996-06-04 | 1997-12-11 | Basf Ag | Process of heterogeneously catalyzed gas phase oxidation of propane to acrolein |
JPH1036311A (en) | 1996-07-25 | 1998-02-10 | Mitsubishi Chem Corp | Production of alpha, beta-unsaturated carboxylic acid |
JPH1057813A (en) | 1996-08-22 | 1998-03-03 | Mitsubishi Chem Corp | Manufacture of mixed metal oxide catalyst and acrylic acid production using thereof |
US5994580A (en) * | 1996-10-21 | 1999-11-30 | Toagosei Co., Ltd. | Process for producing acrylic acid |
JPH10330343A (en) | 1997-04-04 | 1998-12-15 | Mitsubishi Chem Corp | Production of nitrile |
JPH10310539A (en) | 1997-05-09 | 1998-11-24 | Mitsubishi Chem Corp | Vapor-phase, catalytic oxidation of hydrocarbon |
JPH1142434A (en) | 1997-05-28 | 1999-02-16 | Mitsubishi Chem Corp | Production of vapor phase catalytic oxidation reaction catalyst of hydrocarbon and vapor phase catalytic oxidation reaction method of hydrocarbon using the same |
DE69818268T2 (en) | 1997-07-14 | 2004-06-24 | Mitsubishi Chemical Corp. | METHOD FOR THE CATALYTIC OXYDATION OF HYDROCARBONS IN THE GAS PHASE |
JPH1143314A (en) | 1997-07-25 | 1999-02-16 | Mitsubishi Chem Corp | Production of complex oxide |
EP0895809B1 (en) | 1997-08-05 | 2014-03-19 | Asahi Kasei Kabushiki Kaisha | Process Using Niobium-containing Aqueous Solution in Producing Niobium-containing Oxide Catalyst |
ID20670A (en) | 1997-08-05 | 1999-02-11 | Asahi Chemical Ind | AMOXICATION CATALYST FOR USE IN PRODUCING ACRYLONITRYL OR METACRYLONITRIL FROM PROPANA OR ISOBUTANA WITH AMOXICATION |
JPH1157479A (en) | 1997-08-08 | 1999-03-02 | Mitsubishi Chem Corp | Gas phase catalytic oxidation reaction catalyst for hydrocarbon and preparation thereof |
DE19753817A1 (en) | 1997-12-04 | 1999-06-17 | Basf Ag | Production of acrolein and acrylic acid by catalytic oxidation of propane |
US5877369A (en) | 1997-10-23 | 1999-03-02 | Phillips Petroleum Company | Hydrocarbon conversion catalyst composition and processes therefor and therewith |
JP3948798B2 (en) | 1997-10-27 | 2007-07-25 | 株式会社日本触媒 | Acrylic acid production method |
JPH11263745A (en) | 1997-10-29 | 1999-09-28 | Mitsubishi Chemical Corp | Vapor-phase catalytic oxidation of hydrocarbon |
JPH11169716A (en) | 1997-12-09 | 1999-06-29 | Mitsubishi Chemical Corp | Catalyst for preparing unsaturated nitrile and/or unsaturated carboxylic acid |
DE19756292C2 (en) | 1997-12-10 | 1999-10-28 | Mannesmann Ag | Catalyst for the conversion of paraffinic hydrocarbons into corresponding olefins |
NO307693B1 (en) | 1998-03-13 | 2000-05-15 | Statoil Asa | Improved catalyst support material, process for its preparation, dehydrogenation catalyst, and catalytic dehydrogenation of light alkanes |
JPH11285637A (en) | 1998-04-03 | 1999-10-19 | Toagosei Co Ltd | Catalyst for production of acrylic acid, its production and production of acrylic acid using the same |
CA2271397A1 (en) * | 1998-05-21 | 1999-11-21 | Rohm And Haas Company | A process for preparing a catalyst |
JPH11343262A (en) | 1998-05-28 | 1999-12-14 | Toagosei Co Ltd | Production of acrylic acid |
JP4174852B2 (en) | 1998-05-28 | 2008-11-05 | 東亞合成株式会社 | Acrylic acid production method |
JP2000026123A (en) | 1998-07-08 | 2000-01-25 | Mitsubishi Chemicals Corp | Complex oxide and its production |
JP4166334B2 (en) | 1998-07-24 | 2008-10-15 | 旭化成ケミカルズ株式会社 | Method for preparing oxidation catalyst |
JP2000051693A (en) | 1998-08-07 | 2000-02-22 | Toagosei Co Ltd | Manufacture of catalyst for gas-phase catalytic oxidation for hydrocarbon |
JP3948837B2 (en) | 1998-08-10 | 2007-07-25 | 株式会社日本触媒 | Acrylic acid production method |
DE19837518A1 (en) | 1998-08-19 | 2000-02-24 | Basf Ag | Production of acrolein and/or acrylic acid involves two stage catalytic oxydehydrogenation of propane, using modified air with less nitrogen and more oxygen than normal air as the oxygen source |
DE19837517A1 (en) | 1998-08-19 | 2000-02-24 | Basf Ag | Production of acrolein and/or acrylic acid involves two stage catalytic oxydehydrogenation of propane, using modified air with less nitrogen and more oxygen than normal air as the oxygen source |
DE19837520A1 (en) | 1998-08-19 | 2000-02-24 | Basf Ag | Production of acrolein and/or acrylic acid involves two stage catalytic oxydehydrogenation of propane, using air as the oxygen source and removing nitrogen before the propene oxidation stage |
DE19837519A1 (en) | 1998-08-19 | 2000-02-24 | Basf Ag | Production of acrolein and/or acrylic acid involves two stage catalytic oxydehydrogenation of propane, using air as the oxygen source and removing nitrogen from residual gas before recycling |
DE19838817A1 (en) | 1998-08-26 | 2000-03-02 | Basf Ag | Process for the continuous production of (meth) acrylic acid |
US6384274B1 (en) | 1998-09-27 | 2002-05-07 | Rohm And Haas Company | Single reactor process for preparing acrylic acid from propylene having improved capacity |
US6114278A (en) | 1998-11-16 | 2000-09-05 | Saudi Basic Industries Corporation | Catalysts for catalytic oxidation of propane to acrylic acid, methods of making and using the same |
DE19924532A1 (en) | 1999-05-28 | 2000-11-30 | Basf Ag | Novel separating column used in fractional condensation of acrylic acid-containing partial oxidation gas mixtures contains both dual-flow- and hydraulically-sealed crossflow-plates |
DE19924533A1 (en) | 1999-05-28 | 2000-11-30 | Basf Ag | Fractional condensation of acrylic acid-containing oxidation gas with acrylic acid oligomer drawn off and cracked to give acrylic acid which is fed to the quenching liquid circuit |
DE19910506A1 (en) | 1999-03-10 | 2000-09-14 | Basf Ag | Production of acrolein or acrylic acid by gas-phase oxidation of propene uses two catalyst beds at different temperatures |
DE19910508A1 (en) | 1999-03-10 | 2000-09-21 | Basf Ag | Process of catalytic gas phase oxidation of acrolein to acrylic acid |
DE19937196A1 (en) | 1999-08-06 | 2001-03-01 | Voith Paper Patent Gmbh | Insertion aid device for inserting the start of a material web into a roller machine |
DE19937105A1 (en) | 1999-08-06 | 2001-02-08 | Basf Ag | Oxide catalysts |
DE19937107A1 (en) | 1999-08-06 | 2001-02-08 | Basf Ag | Catalyst with bimodal pore radius distribution |
DE19952964A1 (en) | 1999-11-03 | 2001-05-10 | Basf Ag | Process for the catalytic gas phase oxidation to (meth) acrolein and / or (meth) acrylic acid |
DE10046672A1 (en) | 2000-09-20 | 2002-03-28 | Basf Ag | Production of acrolein or acrylic acid involves absorption of propane and propene from a gas mixture followed by desorption and oxidation, with no catalytic dehydrogenation of propane and no added oxygen |
DE10051419A1 (en) | 2000-10-17 | 2002-04-18 | Basf Ag | Production of acrolein or acrylic acid involves absorption of propane and propene from a gas mixture followed by desorption and oxidation, with no catalytic dehydrogenation of propane and no added oxygen |
-
2001
- 2001-06-13 DE DE50111556T patent/DE50111556D1/en not_active Expired - Lifetime
- 2001-06-13 EP EP01956472A patent/EP1289919B1/en not_active Expired - Lifetime
- 2001-06-13 ES ES01956472T patent/ES2276808T3/en not_active Expired - Lifetime
- 2001-06-13 US US10/297,579 patent/US7321058B2/en not_active Expired - Fee Related
- 2001-06-13 ES ES05025498.6T patent/ES2480302T3/en not_active Expired - Lifetime
- 2001-06-13 AU AU2001278449A patent/AU2001278449A1/en not_active Abandoned
- 2001-06-13 EP EP05025498.6A patent/EP1642879B1/en not_active Expired - Lifetime
- 2001-06-13 KR KR1020027017091A patent/KR100740728B1/en not_active IP Right Cessation
- 2001-06-13 MY MYPI20012767A patent/MY140522A/en unknown
- 2001-06-13 JP JP2002510417A patent/JP5021140B2/en not_active Expired - Fee Related
- 2001-06-13 CN CNB01812822XA patent/CN1209332C/en not_active Expired - Fee Related
- 2001-06-13 BR BRPI0111702-5A patent/BR0111702B1/en not_active IP Right Cessation
- 2001-06-13 WO PCT/EP2001/006708 patent/WO2001096271A2/en active IP Right Grant
- 2001-06-13 CZ CZ2002-4073A patent/CZ304548B6/en not_active IP Right Cessation
- 2001-06-13 AT AT01956472T patent/ATE346835T1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CN1209332C (en) | 2005-07-06 |
CZ20024073A3 (en) | 2003-05-14 |
ATE346835T1 (en) | 2006-12-15 |
BR0111702A (en) | 2003-10-07 |
CZ304548B6 (en) | 2014-07-02 |
ES2276808T3 (en) | 2007-07-01 |
MY140522A (en) | 2009-12-31 |
WO2001096271A3 (en) | 2002-05-02 |
KR100740728B1 (en) | 2007-07-19 |
ES2480302T3 (en) | 2014-07-25 |
EP1642879B1 (en) | 2014-05-21 |
EP1289919A2 (en) | 2003-03-12 |
JP5021140B2 (en) | 2012-09-05 |
EP1289919B1 (en) | 2006-11-29 |
CN1441766A (en) | 2003-09-10 |
DE50111556D1 (en) | 2007-01-11 |
US20030187299A1 (en) | 2003-10-02 |
WO2001096271A2 (en) | 2001-12-20 |
JP2004503517A (en) | 2004-02-05 |
BR0111702B1 (en) | 2012-01-10 |
US7321058B2 (en) | 2008-01-22 |
EP1642879A1 (en) | 2006-04-05 |
KR20030009530A (en) | 2003-01-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
AU2001278449A1 (en) | Method for producing acrolein and/or acrylic acid | |
AU2001281823A1 (en) | Method for the production of acrolein or acrylic acid or the mixture thereof from propane | |
MY140688A (en) | Heterogeneously catalyzed partial gas phase oxidation of propene to acrylic acid | |
TW200500333A (en) | Heterogeneously catalyzed partial gas phase oxidation of propene to acrylic acid | |
MY139342A (en) | Long-term operation of a heterogeneously catalyzed gas phase partial oxidation of propene to acrylic acid | |
MY121878A (en) | Method for the catalytic gas-phase oxidation of propene into acrylic acid | |
MY129153A (en) | Regeneration of a dehydrogenation catalyst | |
MY128386A (en) | Process for operating the epoxidation of ethylene | |
MY121141A (en) | Method for the catalytic gas-phase oxidation of propene into acrolein | |
DE50105418D1 (en) | PROCESS FOR IMPLEMENTING AN ORGANIC COMPOUND WITH A HYDROPEROXIDE | |
MY139360A (en) | Long-term operation of a heterogeneously catalyzed gas phase partial oxidation of acrolein to acrylic acid | |
ATE463474T1 (en) | METHOD FOR PRODUCING ACROLEIN, OR ACRYLIC ACID OR THEIR MIXTURE FROM PROPANE | |
TWI370814B (en) | Preparation of acrylic acid by heterogeneously catalyzed partial gas phase oxidation of propylene | |
MY129762A (en) | Method for the production of acrylic acid by heterogeneously catalyzed partial propane oxidation | |
AU2001252138A1 (en) | Method for the synthesis of aliphatic carboxylic acids from aldehydes | |
BR0103429A (en) | Process for purifying gas streams containing carbon dioxide | |
WO2004085365A3 (en) | Method for the heterogeneously catalyzed partial gas phase oxidation of acrolein into acrylic acid | |
MX240869B (en) | Method for producing propylene oxide. | |
ATE527245T1 (en) | METHOD FOR PRODUCING ETHYLENE OXIDE | |
GB0026243D0 (en) | Process | |
WO2001066503A3 (en) | Method for the synthesis of straight-chain aliphatic carboxylic acids from aldehydes | |
DE50202497D1 (en) | PROCESS FOR PREPARING MALEIC ANHYDRIDE | |
AU2001239267A1 (en) | Method for producing aliphatic carboxylic acids from aldehydes | |
MY136503A (en) | Heterogeneously catalyzed partial gas phase oxidation of acrolein to acrylic acid | |
WO2004108649A3 (en) | Oxidation process for the production of carboxylic acids and alkenes |