CN1238394C - 阻燃的韧性聚氨酯泡沫材料及其制造方法 - Google Patents
阻燃的韧性聚氨酯泡沫材料及其制造方法 Download PDFInfo
- Publication number
- CN1238394C CN1238394C CNB018119727A CN01811972A CN1238394C CN 1238394 C CN1238394 C CN 1238394C CN B018119727 A CNB018119727 A CN B018119727A CN 01811972 A CN01811972 A CN 01811972A CN 1238394 C CN1238394 C CN 1238394C
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- Prior art keywords
- foam materials
- component
- active hydrogen
- molecular weight
- glycol
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- Expired - Fee Related
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/30—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by mixing gases into liquid compositions or plastisols, e.g. frothing with air
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
- C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
- C08G18/0861—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers
- C08G18/0871—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being organic
- C08G18/0876—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being organic the dispersing or dispersed phase being a polyol
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/088—Removal of water or carbon dioxide from the reaction mixture or reaction components
- C08G18/0885—Removal of water or carbon dioxide from the reaction mixture or reaction components using additives, e.g. absorbing agents
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/222—Catalysts containing metal compounds metal compounds not provided for in groups C08G18/225 - C08G18/26
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
- C08G18/3842—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
- C08G18/3851—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing three nitrogen atoms in the ring
- C08G18/3853—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing three nitrogen atoms in the ring containing cyanurate and/or isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4072—Mixtures of compounds of group C08G18/63 with other macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/409—Dispersions of polymers of C08G in organic compounds having active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4266—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
- C08G18/4269—Lactones
- C08G18/4277—Caprolactone and/or substituted caprolactone
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
- C08G18/632—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2101/00—Manufacture of cellular products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0066—≥ 150kg/m3
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2290/00—Compositions for creating anti-fogging
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US21450200P | 2000-06-28 | 2000-06-28 | |
US60/214,502 | 2000-06-28 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1454227A CN1454227A (zh) | 2003-11-05 |
CN1238394C true CN1238394C (zh) | 2006-01-25 |
Family
ID=22799325
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB018119727A Expired - Fee Related CN1238394C (zh) | 2000-06-28 | 2001-06-28 | 阻燃的韧性聚氨酯泡沫材料及其制造方法 |
Country Status (7)
Country | Link |
---|---|
US (1) | US6559196B2 (fr) |
EP (1) | EP1519973B2 (fr) |
JP (1) | JP2004501998A (fr) |
CN (1) | CN1238394C (fr) |
AU (1) | AU2001271571A1 (fr) |
GB (1) | GB2381528B (fr) |
WO (1) | WO2002000750A2 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101240055B (zh) * | 2008-03-13 | 2011-08-24 | 北京市丰信德科技发展有限公司 | 低voc含量聚氨酯泡沫的制备方法及用途 |
CN108250388A (zh) * | 2017-12-29 | 2018-07-06 | 浙江省三门中鑫实业有限公司 | 一种低气味低voc全水发泡材料及其制造方法 |
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US6806441B2 (en) * | 2001-09-24 | 2004-10-19 | Polyneer, Inc. | Process for laser-cutting parts and removing flashing |
US20040152796A1 (en) * | 2003-01-31 | 2004-08-05 | Crompton Corporation | Process for preparing polyurethane foams having reduced VOC emissions |
US20070185250A1 (en) * | 2003-12-04 | 2007-08-09 | Ciba Specialty Chemicals Holding Inc. | Stabilization of polyether polyols, polyester polyols and polyurethanes |
US8127764B2 (en) | 2004-11-05 | 2012-03-06 | Ric Investments Llc | Respiratory mask cushion and mask using same |
US7459488B2 (en) * | 2005-03-03 | 2008-12-02 | Polyfoam Products, Inc. | Composition and process for recovery of spilled hydrocarbons from aqueous environments |
CA2675153C (fr) * | 2007-01-19 | 2016-03-01 | Huntsman Petrochemical Corporation | Amines tertiaires bloquees au moyen d'acides polymeres |
US20090226696A1 (en) | 2008-02-06 | 2009-09-10 | World Properties, Inc. | Conductive Polymer Foams, Method of Manufacture, And Uses Thereof |
KR101606070B1 (ko) * | 2007-07-16 | 2016-03-24 | 에프알엑스 폴리머스, 인코포레이티드 | 난연성 엔지니어링 중합체 조성물 |
US8124665B2 (en) * | 2008-08-29 | 2012-02-28 | Bayer Materialscience Llc | Decorative molded foams with good impact resistance and fire retardant properties |
US8097658B2 (en) * | 2009-11-18 | 2012-01-17 | Bayer Materialscience Llc | Process for the production of medium density decorative molded foams having good fire retardant properties with reduced mold times, fire retardant compositions and foams produced by this process |
WO2011094324A2 (fr) * | 2010-01-27 | 2011-08-04 | Intellectual Property Holdings, Llc | Mousse de poluréthane ignifuge et procédé pour préparer celle-ci |
EP2365013A1 (fr) * | 2010-03-12 | 2011-09-14 | Rhein Chemie Rheinau GmbH | Nouvelles masses de coulée de polyuréthane résistant aux intempéries, un procédé de fabrication et d'utilisation de celles-ci |
JP5555121B2 (ja) * | 2010-10-08 | 2014-07-23 | 株式会社イノアックコーポレーション | 難燃性ポリウレタン発泡体、及びその製造方法 |
US10066047B2 (en) | 2012-02-02 | 2018-09-04 | Covestro Llc | Polyurethane foams with decreased aldehyde emissions, a process for preparing these foams and a method for decreasing aldehyde in polyurethane foams |
JP2016510355A (ja) | 2013-01-22 | 2016-04-07 | エフアールエックス ポリマーズ、インク. | リン含有エポキシ化合物およびそれからなる組成物 |
CN103804890B (zh) | 2014-02-18 | 2016-01-27 | 山东美瑞新材料有限公司 | 一种挤出发泡热塑性聚氨酯弹性体粒子及其制备方法 |
JP2017513993A (ja) * | 2014-04-24 | 2017-06-01 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag | ポリエーテルカーボネートポリオール系ポリウレタンフォーム |
CN104109227B (zh) * | 2014-08-05 | 2015-09-02 | 北京李尔岱摩斯汽车系统有限公司 | 一种聚氨酯软泡材料及其制备方法 |
CN104448198B (zh) * | 2014-12-16 | 2017-08-25 | 山东一诺威聚氨酯股份有限公司 | 用于聚氨酯拳击手套填充物的组合物及其制备方法 |
WO2018075302A1 (fr) | 2016-10-17 | 2018-04-26 | Rogers Corporation | Procédé destiné à retarder le durcissement dans du polyuréthane et compositions et articles fabriqués à partir de celui-ci |
EP3649334A1 (fr) * | 2017-07-07 | 2020-05-13 | Covestro Deutschland AG | Isolation anti-flamme pour moteurs à combustion interne |
CN107501516A (zh) * | 2017-09-08 | 2017-12-22 | 张家港长泰汽车饰件材料有限公司 | 低醛含量聚氨酯板材及其制备方法 |
CN108395521A (zh) * | 2018-03-30 | 2018-08-14 | 南宁可煜能源科技有限公司 | 一种保温水箱用聚氨酯复合保温材料 |
CN109096462B (zh) * | 2018-07-09 | 2020-11-10 | 江苏长顺高分子材料研究院有限公司 | 低醛型聚醚多元醇的组合物及其制备方法 |
EP3921350A1 (fr) * | 2019-02-07 | 2021-12-15 | Dow Global Technologies LLC | Procédé pour la préparation d'un polyol copolymère |
US20220073739A1 (en) * | 2019-02-28 | 2022-03-10 | Lamkin Corporation | Composition and manufacturing methods for grips |
CN109971161A (zh) * | 2019-03-26 | 2019-07-05 | 上海馨源新材料科技有限公司 | 一种低气味汽车用聚氨酯材料及其制备方法 |
CN112409559B (zh) * | 2019-08-21 | 2022-08-02 | 万华化学(北京)有限公司 | 一种聚氨酯微孔弹性体及其制备方法 |
CN111072890B (zh) * | 2019-12-25 | 2022-04-22 | 万华化学(北京)有限公司 | 半硬质聚氨酯泡沫及其制备方法、聚氨酯泡沫夹层部件及用途 |
US20230102722A1 (en) * | 2021-09-01 | 2023-03-30 | Covestro Llc | Processes for producing filled polyol compositions |
CN117965018A (zh) * | 2023-04-06 | 2024-05-03 | 北京金博轩科技发展有限公司 | 一种隔氧夜光塑料的制备方法 |
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-
2001
- 2001-06-28 JP JP2002505872A patent/JP2004501998A/ja active Pending
- 2001-06-28 AU AU2001271571A patent/AU2001271571A1/en not_active Abandoned
- 2001-06-28 CN CNB018119727A patent/CN1238394C/zh not_active Expired - Fee Related
- 2001-06-28 EP EP01950597.3A patent/EP1519973B2/fr not_active Expired - Lifetime
- 2001-06-28 US US09/893,744 patent/US6559196B2/en not_active Expired - Lifetime
- 2001-06-28 GB GB0301952A patent/GB2381528B/en not_active Expired - Fee Related
- 2001-06-28 WO PCT/US2001/020589 patent/WO2002000750A2/fr active Application Filing
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101240055B (zh) * | 2008-03-13 | 2011-08-24 | 北京市丰信德科技发展有限公司 | 低voc含量聚氨酯泡沫的制备方法及用途 |
CN108250388A (zh) * | 2017-12-29 | 2018-07-06 | 浙江省三门中鑫实业有限公司 | 一种低气味低voc全水发泡材料及其制造方法 |
Also Published As
Publication number | Publication date |
---|---|
WO2002000750A3 (fr) | 2002-05-30 |
WO2002000750A2 (fr) | 2002-01-03 |
US6559196B2 (en) | 2003-05-06 |
GB2381528A (en) | 2003-05-07 |
EP1519973A2 (fr) | 2005-04-06 |
GB2381528B (en) | 2004-10-13 |
JP2004501998A (ja) | 2004-01-22 |
AU2001271571A1 (en) | 2002-01-08 |
US20020040978A1 (en) | 2002-04-11 |
EP1519973B2 (fr) | 2016-07-06 |
GB0301952D0 (en) | 2003-02-26 |
EP1519973B1 (fr) | 2012-09-26 |
CN1454227A (zh) | 2003-11-05 |
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