CN1235665C - 复合陶瓷薄膜分离氧的方法 - Google Patents

复合陶瓷薄膜分离氧的方法 Download PDF

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Publication number
CN1235665C
CN1235665C CN01810834.2A CN01810834A CN1235665C CN 1235665 C CN1235665 C CN 1235665C CN 01810834 A CN01810834 A CN 01810834A CN 1235665 C CN1235665 C CN 1235665C
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China
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layer
oxygen
porous
pore radius
thickness
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Expired - Fee Related
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CN01810834.2A
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English (en)
Chinese (zh)
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CN1434741A (zh
Inventor
A·V·维尔卡
C·F·戈茨曼
R·普拉萨德
B·A·范哈赛尔
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Praxair Technology Inc
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Praxair Technology Inc
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Publication of CN1434741A publication Critical patent/CN1434741A/zh
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12Composite membranes; Ultra-thin membranes
    • B01D69/1216Three or more layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02Inorganic material
    • B01D71/024Oxides
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02Preparation of oxygen
    • C01B13/0229Purification or separation processes
    • C01B13/0248Physical processing only
    • C01B13/0251Physical processing only by making use of membranes
    • C01B13/0255Physical processing only by making use of membranes characterised by the type of membrane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/10Single element gases other than halogens
    • B01D2257/104Oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/26Electrical properties
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2210/00Purification or separation of specific gases
    • C01B2210/0043Impurity removed
    • C01B2210/0046Nitrogen
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2210/00Purification or separation of specific gases
    • C01B2210/0043Impurity removed
    • C01B2210/0051Carbon dioxide

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)
  • Inert Electrodes (AREA)
CN01810834.2A 2000-06-07 2001-05-24 复合陶瓷薄膜分离氧的方法 Expired - Fee Related CN1235665C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/589,425 US6368383B1 (en) 1999-06-08 2000-06-07 Method of separating oxygen with the use of composite ceramic membranes
US09/589,425 2000-06-07

Publications (2)

Publication Number Publication Date
CN1434741A CN1434741A (zh) 2003-08-06
CN1235665C true CN1235665C (zh) 2006-01-11

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN01810834.2A Expired - Fee Related CN1235665C (zh) 2000-06-07 2001-05-24 复合陶瓷薄膜分离氧的方法

Country Status (10)

Country Link
US (1) US6368383B1 (https=)
EP (1) EP1289626A4 (https=)
JP (1) JP2003534906A (https=)
CN (1) CN1235665C (https=)
AU (2) AU2001274925B2 (https=)
BR (1) BR0111331A (https=)
CA (1) CA2411063C (https=)
NO (1) NO20025848D0 (https=)
WO (1) WO2001093987A1 (https=)
ZA (1) ZA200208858B (https=)

Families Citing this family (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7163713B2 (en) * 1999-07-31 2007-01-16 The Regents Of The University Of California Method for making dense crack free thin films
US6682842B1 (en) * 1999-07-31 2004-01-27 The Regents Of The University Of California Composite electrode/electrolyte structure
US7553573B2 (en) 1999-07-31 2009-06-30 The Regents Of The University Of California Solid state electrochemical composite
US6605316B1 (en) * 1999-07-31 2003-08-12 The Regents Of The University Of California Structures and fabrication techniques for solid state electrochemical devices
US6514314B2 (en) * 2000-12-04 2003-02-04 Praxair Technology, Inc. Ceramic membrane structure and oxygen separation method
US6887361B1 (en) 2001-03-22 2005-05-03 The Regents Of The University Of California Method for making thin-film ceramic membrane on non-shrinking continuous or porous substrates by electrophoretic deposition
US20030054154A1 (en) * 2001-09-14 2003-03-20 Hancun Chen Method of making a porous green form and oxygen transport membrane
US6565632B1 (en) * 2001-12-17 2003-05-20 Praxair Technology, Inc. Ion-transport membrane assembly incorporating internal support
US6921557B2 (en) * 2001-12-18 2005-07-26 The Regents Of The University Of California Process for making dense thin films
WO2003052858A1 (en) 2001-12-18 2003-06-26 The Regents Of The University Of California Metal current collect protected by oxide film
AU2003256251A1 (en) * 2002-04-24 2003-11-10 The Regents Of The University Of California Planar electrochemical device assembly
KR100885696B1 (ko) * 2002-05-07 2009-02-26 더 리전트 오브 더 유니버시티 오브 캘리포니아 전기화학 전지 스택 어셈블리
US7338624B2 (en) * 2002-07-31 2008-03-04 Praxair Technology Inc. Ceramic manufacture for a composite ion transport membrane
US7090752B2 (en) * 2002-10-04 2006-08-15 The Regents Of The University Of California Fluorine separation and generation device
US7279027B2 (en) * 2003-03-21 2007-10-09 Air Products And Chemicals, Inc. Planar ceramic membrane assembly and oxidation reactor system
GB0310281D0 (en) * 2003-05-03 2003-06-11 Univ Robert Gordon A membrane apparatus and method of preparing a membrane and a method of producing synthetic gas
DE10325413B4 (de) * 2003-06-05 2015-03-05 Audi Ag Verfahren zum Betreiben einer Brennkraftmaschine eines Fahrzeuges, insbesondere eines Kraftfahtzeuges sowie Vorrichtung zur Durchführung eines derartigen Verfahrens
WO2005009730A1 (en) * 2003-07-10 2005-02-03 Praxair Technology, Inc. Composite oxygen ion transport element
WO2005023407A2 (en) * 2003-07-10 2005-03-17 Praxair Technology, Inc. Method of forming ion transport membrane structure
US7901730B2 (en) * 2004-04-26 2011-03-08 Johnson Research & Development Co., Inc. Thin film ceramic proton conducting electrolyte
JP2008522370A (ja) * 2004-11-30 2008-06-26 ザ、リージェンツ、オブ、ザ、ユニバーシティ、オブ、カリフォルニア 電気化学装置用封止ジョイント構造
CN100574953C (zh) * 2004-11-30 2009-12-30 加州大学评议会 热膨胀系数相匹配的钎焊体系
FR2879185B1 (fr) * 2004-12-10 2007-03-09 Air Liquide Reacteur catalytique membranaire
US7279025B2 (en) * 2004-12-21 2007-10-09 Praxair Technology, Inc. Separation and reaction method utilizing an oxygen ion transport element
US7595019B2 (en) * 2005-03-01 2009-09-29 Air Products And Chemicals, Inc. Method of making an ion transport membrane oxygen separation device
JP2008538543A (ja) * 2005-04-21 2008-10-30 ザ、リージェンツ、オブ、ザ、ユニバーシティ、オブ、カリフォルニア 前駆体物質溶浸およびコーティング方法
JPWO2007052497A1 (ja) * 2005-11-07 2009-04-30 国立大学法人広島大学 複合分離膜およびその製造方法、並びに当該複合分離膜を用いる有機液体混合物の分離方法
JP4745048B2 (ja) * 2005-12-22 2011-08-10 東京瓦斯株式会社 水素透過膜モジュール
JP4745049B2 (ja) * 2005-12-22 2011-08-10 東京瓦斯株式会社 水素透過膜モジュールの作製方法
CA2656460A1 (en) * 2006-07-28 2008-02-07 The Regents Of The University Of California Joined concentric tubes
KR20100065296A (ko) * 2007-07-25 2010-06-16 더 리전트 오브 더 유니버시티 오브 캘리포니아 맞물림 구조를 가지는 고온 전기화학 소자
JP2011517293A (ja) * 2007-11-20 2011-06-02 コーニング インコーポレイテッド 酸素イオン伝導膜構造
DE102008044344A1 (de) * 2007-12-04 2009-09-17 Ceramtec Ag Sperrschicht
US20090145761A1 (en) * 2007-12-11 2009-06-11 Van Hassel Bart A Oxygen separation element and method
DK2250295T3 (da) * 2008-02-04 2012-04-16 Univ California Cu-baseret cermet til højtemperatur-brændstofceller
DE102008016158A1 (de) * 2008-03-28 2009-10-01 Forschungszentrum Jülich GmbH Sauerstoff durchlässige Membran sowie Verfahren zu dessen Herstellung
RU2010147046A (ru) * 2008-04-18 2012-05-27 Члены Правления Университета Калифорнии (Us) Комбинированное уплотнение для высокотемпературного электрохимического устройства
WO2011107898A1 (en) * 2010-03-05 2011-09-09 Koninklijke Philips Electronics N.V. Oxygen separation membrane
JP5817330B2 (ja) * 2010-08-24 2015-11-18 東レ株式会社 分離膜および分離膜エレメント
US8834604B2 (en) * 2010-09-16 2014-09-16 Volt Research, Llc High temperature gas processing system and method for making the same
EP2629880B1 (en) * 2010-10-22 2017-04-05 Koninklijke Philips N.V. Arrangement and method for separating oxygen
KR101780185B1 (ko) 2010-12-10 2017-09-21 삼성전자주식회사 흡착셀 및 그 제조방법
DE102011083501A1 (de) * 2011-09-27 2013-03-28 Siemens Aktiengesellschaft Komposit-Anode für Batterie-Zelle
DE102012006744A1 (de) 2012-04-04 2013-10-10 Forschungszentrum Jülich GmbH Gemischt Ionen und Elektronen leitende Membran zur Gastrennung sowie Verfahren zur Herstellung derselben
KR101471615B1 (ko) * 2012-12-11 2014-12-11 한국에너지기술연구원 수소 분리막 및 그의 제조 방법
KR20160004310A (ko) 2013-04-26 2016-01-12 커틴 유니버시티 오브 테크놀로지 채널화된 물품 및 이를 제작하는 방법
US9797054B2 (en) 2014-07-09 2017-10-24 Carleton Life Support Systems Inc. Pressure driven ceramic oxygen generation system with integrated manifold and tubes
US10441922B2 (en) * 2015-06-29 2019-10-15 Praxair Technology, Inc. Dual function composite oxygen transport membrane
CN109865436B (zh) * 2017-12-01 2021-07-27 中国科学院大连化学物理研究所 一种板状透氧膜组件的制备方法
US11136238B2 (en) 2018-05-21 2021-10-05 Praxair Technology, Inc. OTM syngas panel with gas heated reformer

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1685759A (en) * 1924-05-22 1928-09-25 Ver Fur Chemische Ind Ag Diffusion reaction
US5240480A (en) 1992-09-15 1993-08-31 Air Products And Chemicals, Inc. Composite mixed conductor membranes for producing oxygen
US5534471A (en) * 1994-01-12 1996-07-09 Air Products And Chemicals, Inc. Ion transport membranes with catalyzed mixed conducting porous layer
US5569633A (en) * 1994-01-12 1996-10-29 Air Products And Chemicals, Inc. Ion transport membranes with catalyzed dense layer
US5681373A (en) * 1995-03-13 1997-10-28 Air Products And Chemicals, Inc. Planar solid-state membrane module
JPH09100179A (ja) * 1995-07-26 1997-04-15 Sumitomo Electric Ind Ltd 窒化ケイ素質多孔体およびその製造方法
ID19327A (id) * 1996-12-31 1998-07-02 Praxiar Technology Inc Membran elektrolit padat dengan unsur pokok pemertinggi secara mekanik dan pemertinggi secara katalitik yang bersifat dapat menyerap
US6235187B1 (en) * 1996-12-31 2001-05-22 Praxair Technology Inc. Oxygen separation method using a mixed conducting cubic perovskite ceramic ion transport membrane
US5938822A (en) 1997-05-02 1999-08-17 Praxair Technology, Inc. Solid electrolyte membrane with porous catalytically-enhancing constituents
US5846641A (en) 1997-03-20 1998-12-08 Exxon Research And Engineering Company Multi-layer membrane composites and their use in hydrocarbon partical oxidation
US5888272A (en) * 1997-06-05 1999-03-30 Praxair Technology, Inc. Process for enriched combustion using solid electrolyte ionic conductor systems
US5965010A (en) * 1997-07-15 1999-10-12 Niagara Mohawk Power Corporation Electrochemical autothermal reformer
JP2981884B1 (ja) * 1998-06-29 1999-11-22 工業技術院長 ゼオライト膜の製造方法

Also Published As

Publication number Publication date
WO2001093987A1 (en) 2001-12-13
NO20025848L (no) 2002-12-05
CA2411063C (en) 2006-10-03
AU7492501A (en) 2001-12-17
AU2001274925B2 (en) 2005-11-17
JP2003534906A (ja) 2003-11-25
CN1434741A (zh) 2003-08-06
ZA200208858B (en) 2003-08-19
NO20025848D0 (no) 2002-12-05
EP1289626A1 (en) 2003-03-12
EP1289626A4 (en) 2009-03-11
CA2411063A1 (en) 2001-12-13
US6368383B1 (en) 2002-04-09
BR0111331A (pt) 2003-06-03

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