CN1221497C - 异丁烯的选择性二聚方法 - Google Patents

异丁烯的选择性二聚方法 Download PDF

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Publication number
CN1221497C
CN1221497C CNB008175659A CN00817565A CN1221497C CN 1221497 C CN1221497 C CN 1221497C CN B008175659 A CNB008175659 A CN B008175659A CN 00817565 A CN00817565 A CN 00817565A CN 1221497 C CN1221497 C CN 1221497C
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CN
China
Prior art keywords
isobutene
weight
process according
butene
zeolite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB008175659A
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English (en)
Chinese (zh)
Other versions
CN1433390A (zh
Inventor
J·M·达卡
M·吉尔伦
P·W·艾伦
G·M·K·马希斯
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ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
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Publication date
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Publication of CN1433390A publication Critical patent/CN1433390A/zh
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Publication of CN1221497C publication Critical patent/CN1221497C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C9/00Aliphatic saturated hydrocarbons
    • C07C9/14Aliphatic saturated hydrocarbons with five to fifteen carbon atoms
    • C07C9/16Branched-chain hydrocarbons
    • C07C9/212, 2, 4-Trimethylpentane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007Zeolite Beta
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/12Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/16After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/36Steaming
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CNB008175659A 1999-12-23 2000-12-20 异丁烯的选择性二聚方法 Expired - Fee Related CN1221497C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB9930402.4A GB9930402D0 (en) 1999-12-23 1999-12-23 Selective removal of isobutene from C4 olefinic feedstocks
GB9930402.4 1999-12-23

Publications (2)

Publication Number Publication Date
CN1433390A CN1433390A (zh) 2003-07-30
CN1221497C true CN1221497C (zh) 2005-10-05

Family

ID=10866875

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB008175659A Expired - Fee Related CN1221497C (zh) 1999-12-23 2000-12-20 异丁烯的选择性二聚方法

Country Status (14)

Country Link
EP (1) EP1242342B1 (https=)
JP (1) JP4691303B2 (https=)
KR (1) KR100635314B1 (https=)
CN (1) CN1221497C (https=)
AR (1) AR027087A1 (https=)
AT (1) ATE273259T1 (https=)
AU (1) AU782012B2 (https=)
BR (1) BR0016719A (https=)
CA (1) CA2394030C (https=)
DE (1) DE60012979T2 (https=)
GB (1) GB9930402D0 (https=)
MX (1) MXPA02006200A (https=)
MY (1) MY125097A (https=)
WO (1) WO2001046095A1 (https=)

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* Cited by examiner, † Cited by third party
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EP1184361B1 (en) * 2000-08-29 2004-05-19 BP Köln GmbH Process for the selective preparation of di-isobutylene from an i-butene-containing C4 stream
DE10250468A1 (de) * 2002-10-30 2004-05-19 Basf Ag Verfahren zur Herstellung von Oligomeren abgeleitet von Butenen
DE10302457B3 (de) * 2003-01-23 2004-10-07 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Butenoligomeren und tert.-Butylethern aus Isobuten-haltigen C4-Strömen
US7196238B2 (en) 2003-03-10 2007-03-27 Fortum Oyj Process for dimerizing light olefins
US7227047B2 (en) 2003-08-22 2007-06-05 Exxonmobil Chemical Patents Inc. Butadiene and isobutylene removal from olefinic streams
US7012167B2 (en) * 2003-10-08 2006-03-14 Lyondell Chemical Technology, L.P. Diisobutylene process
US7329788B2 (en) 2003-12-22 2008-02-12 Neste Oil Oyj Process for producing gasoline components
US20060111598A1 (en) * 2004-11-22 2006-05-25 Shaw-Chan Lin Diisobutylene process
US8299312B2 (en) 2005-10-28 2012-10-30 Neste Oil Oyj Process for dimerizing olefins
CN100430353C (zh) * 2006-12-26 2008-11-05 南京石油化工股份有限公司 从c4馏分中分离丁烯-1的方法
JP5767875B2 (ja) * 2011-06-29 2015-08-26 出光興産株式会社 混合c4留分を原料とするジイソブチレンの製造方法
US8999013B2 (en) * 2011-11-01 2015-04-07 Saudi Arabian Oil Company Method for contemporaneously dimerizing and hydrating a feed having butene
US11613717B2 (en) 2017-07-27 2023-03-28 Sabic Global Technologies B.V. Method of producing a fuel additive
SG11202008332SA (en) 2018-03-19 2020-09-29 Sabic Global Technologies Bv Method of producing a fuel additive
SG11202008334VA (en) 2018-03-19 2020-09-29 Sabic Global Technologies Bv Method of producing a fuel additive
CN111989387B (zh) 2018-04-19 2022-09-06 沙特基础工业全球技术有限公司 生产燃油添加剂的方法
SG11202009410PA (en) 2018-05-07 2020-10-29 Sabic Global Technologies Bv Method of producing a fuel additive
EP3790854B1 (en) 2018-05-07 2025-11-05 SABIC Global Technologies B.V. Method of producing a fuel additive
US11697626B2 (en) 2018-05-18 2023-07-11 Sabic Global Technologies B.V. Method of producing a fuel additive with a hydration unit
KR102569585B1 (ko) 2018-09-18 2023-08-23 사빅 글로벌 테크놀러지스 비.브이. 하나 이상의 연료 첨가제를 효율적으로 제조하기 위한 시스템 및 방법
US20210395178A1 (en) * 2018-10-31 2021-12-23 Lummus Technology Llc Selective dimerization and etherification of isobutylene via catalytic distillation
CN113165996A (zh) 2018-11-20 2021-07-23 沙特基础工业全球技术有限公司 用于生产乙烯以及丁醇和烷基叔丁基醚中的至少一种的方法和系统
CN113365965A (zh) * 2019-01-31 2021-09-07 巴斯夫欧洲公司 用于烯烃二聚的催化法
CN113544238B (zh) 2019-03-08 2023-02-28 沙特基础工业全球技术有限公司 生产燃料添加剂的方法
CN111675592A (zh) * 2020-05-31 2020-09-18 南京克米斯璀新能源科技有限公司 一种碳四烯烃中异丁烯选择性叠合的方法及设备
EP4622942A1 (en) * 2022-11-23 2025-10-01 Braskem, S.A. Use of proton-form zeolite catalyst to produce light-polyisobutylene

Family Cites Families (15)

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Publication number Priority date Publication date Assignee Title
US2276199A (en) * 1940-11-22 1942-03-10 Universal Oil Prod Co Production of iso-octane
JPS54138507A (en) * 1978-04-17 1979-10-27 Kuraray Co Ltd Preparation of diisobutene
US4324940A (en) * 1980-04-09 1982-04-13 Mobil Oil Corporation Shape selective acid catalyzed reactions of olefins over crystalline zeolites
JPS57108023A (en) * 1980-12-26 1982-07-05 Toa Nenryo Kogyo Kk Oligomerization catalyst for isobutene
JPS58164523A (ja) * 1982-03-26 1983-09-29 Toa Nenryo Kogyo Kk イソブテンの低重合方法
JPS59227830A (ja) * 1983-06-10 1984-12-21 Toa Nenryo Kogyo Kk イソブテンの低重合法
JPH03152242A (ja) * 1989-11-06 1991-06-28 Nissan Motor Co Ltd 複数幅取り織機の緯糸張力緩和装置
GB9012725D0 (en) * 1990-06-07 1990-08-01 Exxon Chemical Patents Inc Process for catalytic conversion of olefins
US5091590A (en) * 1990-08-22 1992-02-25 Mobil Oil Corporation Ether production with staged reaction of olefins
CA2128624C (en) * 1992-01-30 2001-11-20 Georges M. K. Mathys Alkene oligomerization
US5401429A (en) * 1993-04-01 1995-03-28 Minnesota Mining And Manufacturing Company Azeotropic compositions containing perfluorinated cycloaminoether
US5618878A (en) * 1995-04-07 1997-04-08 Dow Corning Corporation Hydrogen silsesquioxane resin coating composition
AU2680497A (en) * 1996-03-27 1997-10-17 Airedale Sports & Technology, Inc. Table tennis rubber solvent and adhesive systems
KR20000068089A (ko) * 1996-09-09 2000-11-25 캐털리틱 디스틸레이션 테크놀로지스 베타 제올라이트 촉매를 사용한 유기 방향족 화합물의 알킬화
EP0994088B1 (en) * 1998-10-16 2004-06-16 Fortum Oil and Gas Oy Process for producing a fuel component

Also Published As

Publication number Publication date
CN1433390A (zh) 2003-07-30
AR027087A1 (es) 2003-03-12
AU782012B2 (en) 2005-06-30
DE60012979D1 (de) 2004-09-16
BR0016719A (pt) 2002-09-03
JP2004505008A (ja) 2004-02-19
EP1242342B1 (en) 2004-08-11
MXPA02006200A (es) 2004-02-26
ATE273259T1 (de) 2004-08-15
DE60012979T2 (de) 2005-07-28
GB9930402D0 (en) 2000-02-16
KR20020081231A (ko) 2002-10-26
CA2394030C (en) 2009-01-20
KR100635314B1 (ko) 2006-10-18
EP1242342A1 (en) 2002-09-25
MY125097A (en) 2006-07-31
JP4691303B2 (ja) 2011-06-01
AU2447601A (en) 2001-07-03
CA2394030A1 (en) 2001-06-28
WO2001046095A1 (en) 2001-06-28

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