CN119954817A - 化合物、发光材料及发光元件 - Google Patents

化合物、发光材料及发光元件 Download PDF

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Publication number
CN119954817A
CN119954817A CN202510123670.0A CN202510123670A CN119954817A CN 119954817 A CN119954817 A CN 119954817A CN 202510123670 A CN202510123670 A CN 202510123670A CN 119954817 A CN119954817 A CN 119954817A
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山下正贵
郑硕贤
U·巴里加帕里
杨沑锡
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Kyushu University NUC
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Kyushu University NUC
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D491/00Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
    • C07D491/02Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
    • C07D491/04Ortho-condensed systems
    • C07D491/044Ortho-condensed systems with only one oxygen atom as ring hetero atom in the oxygen-containing ring
    • C07D491/048Ortho-condensed systems with only one oxygen atom as ring hetero atom in the oxygen-containing ring the oxygen-containing ring being five-membered
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D487/00Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/04Ortho-condensed systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D491/00Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
    • C07D491/12Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains three hetero rings
    • C07D491/14Ortho-condensed systems
    • C07D491/153Ortho-condensed systems the condensed system containing two rings with oxygen as ring hetero atom and one ring with nitrogen as ring hetero atom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D519/00Heterocyclic compounds containing more than one system of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring system not provided for in groups C07D453/00 or C07D455/00
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    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00Luminescent materials, e.g. electroluminescent or chemiluminescent
    • C09K11/06Luminescent materials, e.g. electroluminescent or chemiluminescent containing organic luminescent materials
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60Organic compounds having low molecular weight
    • H10K85/649Aromatic compounds comprising a hetero atom
    • H10K85/657Polycyclic condensed heteroaromatic hydrocarbons
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60Organic compounds having low molecular weight
    • H10K85/649Aromatic compounds comprising a hetero atom
    • H10K85/657Polycyclic condensed heteroaromatic hydrocarbons
    • H10K85/6572Polycyclic condensed heteroaromatic hydrocarbons comprising only nitrogen in the heteroaromatic polycondensed ring system, e.g. phenanthroline or carbazole
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09K2211/00Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10Non-macromolecular compounds
    • C09K2211/1003Carbocyclic compounds
    • C09K2211/1007Non-condensed systems
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09K2211/00Chemical nature of organic luminescent or tenebrescent compounds
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    • C09K2211/00Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10Non-macromolecular compounds
    • C09K2211/1018Heterocyclic compounds
    • C09K2211/1025Heterocyclic compounds characterised by ligands
    • C09K2211/1029Heterocyclic compounds characterised by ligands containing one nitrogen atom as the heteroatom
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09K2211/00Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10Non-macromolecular compounds
    • C09K2211/1018Heterocyclic compounds
    • C09K2211/1025Heterocyclic compounds characterised by ligands
    • C09K2211/1029Heterocyclic compounds characterised by ligands containing one nitrogen atom as the heteroatom
    • C09K2211/1033Heterocyclic compounds characterised by ligands containing one nitrogen atom as the heteroatom with oxygen
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    • C09K2211/00Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10Non-macromolecular compounds
    • C09K2211/1018Heterocyclic compounds
    • C09K2211/1025Heterocyclic compounds characterised by ligands
    • C09K2211/1044Heterocyclic compounds characterised by ligands containing two nitrogen atoms as heteroatoms
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    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K2101/00Properties of the organic materials covered by group H10K85/00
    • H10K2101/20Delayed fluorescence emission
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/10OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/11OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Electroluminescent Light Sources (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
CN202510123670.0A 2020-05-22 2021-05-21 化合物、发光材料及发光元件 Pending CN119954817A (zh)

Applications Claiming Priority (10)

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JP2020090095 2020-05-22
JP2020-090095 2020-05-22
JP2020147167 2020-09-01
JP2020-147167 2020-09-01
JP2020188657 2020-11-12
JP2020-188657 2020-11-12
JP2021074492 2021-04-26
JP2021-074492 2021-04-26
CN202180036659.0A CN115698016B (zh) 2020-05-22 2021-05-21 化合物、发光材料及发光元件
PCT/JP2021/019431 WO2021235549A1 (ja) 2020-05-22 2021-05-21 化合物、発光材料および発光素子

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Publication number Priority date Publication date Assignee Title
WO2021235549A1 (ja) * 2020-05-22 2021-11-25 株式会社Kyulux 化合物、発光材料および発光素子
KR20230121081A (ko) * 2020-12-17 2023-08-17 이데미쓰 고산 가부시키가이샤 유기 일렉트로루미네센스 소자 및 전자 기기
JP2024094443A (ja) * 2021-03-15 2024-07-10 出光興産株式会社 有機エレクトロルミネッセンス素子及び電子機器
JP7733388B2 (ja) * 2021-12-22 2025-09-03 株式会社Kyulux 化合物、発光材料および発光素子
JP7752866B2 (ja) * 2022-01-24 2025-10-14 株式会社Kyulux 化合物、発光材料および発光素子
JP2025087933A (ja) * 2022-03-08 2025-06-11 出光興産株式会社 化合物、有機エレクトロルミネッセンス素子用材料、有機エレクトロルミネッセンス素子及び電子機器
JPWO2024106261A1 (https=) * 2022-11-15 2024-05-23

Family Cites Families (58)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103688384B (zh) 2011-07-15 2016-03-09 国立大学法人九州大学 迟滞荧光材料及使用其的有机电致发光元件
JP5828518B2 (ja) 2011-07-15 2015-12-09 国立大学法人九州大学 遅延蛍光材料、それを用いた有機エレクトロルミネッセンス素子および化合物
EP2733762B1 (en) 2011-07-15 2018-11-28 Kyulux, Inc. Organic electroluminescence element and compound used therein
EP2787549A4 (en) 2011-12-02 2015-09-23 Univ Kyushu Nat Univ Corp ORGANIC LIGHT-EMITTING COMPONENT AND DELAYED FLUORESCENCE MATERIAL AND COMPOUND USED THEREFROM
JP2013116975A (ja) 2011-12-02 2013-06-13 Kyushu Univ 遅延蛍光材料、有機発光素子および化合物
US9985215B2 (en) 2012-03-09 2018-05-29 Kyulux, Inc. Light-emitting material, and organic light-emitting element
JP2014135466A (ja) 2012-04-09 2014-07-24 Kyushu Univ 有機発光素子ならびにそれに用いる発光材料および化合物
WO2013161437A1 (ja) 2012-04-25 2013-10-31 国立大学法人九州大学 発光材料および有機発光素子
JP5594750B2 (ja) 2012-05-17 2014-09-24 国立大学法人九州大学 化合物、発光材料および有機発光素子
JP2014009352A (ja) 2012-07-03 2014-01-20 Kyushu Univ 発光材料、化合物および有機発光素子
JP2014009224A (ja) 2012-07-03 2014-01-20 Kyushu Univ 発光材料、化合物および有機発光素子
WO2014034535A1 (ja) 2012-08-30 2014-03-06 国立大学法人九州大学 発光材料、化合物、およびそれらを用いた有機発光素子
KR102151294B1 (ko) 2013-01-23 2020-09-02 가부시키가이샤 큐럭스 발광 재료 및 그것을 사용한 유기 발광 소자
JP5614568B1 (ja) 2013-02-07 2014-10-29 保土谷化学工業株式会社 ジアザトリフェニレン環構造を有する化合物および有機エレクトロルミネッセンス素子
WO2014126200A1 (ja) 2013-02-18 2014-08-21 国立大学法人九州大学 化合物、発光材料および有機発光素子
TWI615389B (zh) 2013-03-01 2018-02-21 九州有機光材股份有限公司 化合物、發光材料及有機發光元件
WO2014136758A1 (ja) 2013-03-05 2014-09-12 国立大学法人九州大学 電荷輸送材料、ホスト材料、薄膜および有機発光素子
JP6293417B2 (ja) 2013-03-08 2018-03-14 株式会社Kyulux 化合物、発光材料および有機発光素子
JP2016516085A (ja) * 2013-03-22 2016-06-02 メルク パテント ゲーエムベーハー 電子素子のための材料
JP6430370B2 (ja) 2013-04-10 2018-11-28 株式会社Kyulux 発光材料、有機発光素子および化合物
TW201509920A (zh) 2013-05-24 2015-03-16 Univ Kyushu Nat Univ Corp 化合物、發光材料及有機發光元件
JP6367189B2 (ja) 2013-06-05 2018-08-01 株式会社Kyulux 発光材料、有機発光素子および化合物
WO2014203840A1 (ja) 2013-06-21 2014-12-24 国立大学法人九州大学 赤色発光材料、有機発光素子および化合物
JP6148731B2 (ja) 2013-06-26 2017-06-14 出光興産株式会社 化合物、有機エレクトロルミネッセンス素子用材料、有機エレクトロルミネッセンス素子、および電子機器
US9685615B2 (en) 2013-07-03 2017-06-20 Kyulux, Inc. Light emitting material, delayed fluorescent emitter, organic light emitting device, and compound
US10461261B2 (en) 2013-07-16 2019-10-29 Kyushu University, National University Corporation Compound, light emitting material, and organic light emitting device
CN105531271B (zh) 2013-08-01 2019-04-12 国立大学法人九州大学 化合物、发光材料及有机发光元件
JP6542122B2 (ja) 2013-08-09 2019-07-10 国立大学法人九州大学 有機金属錯体、発光材料、遅延蛍光体および有機発光素子
US10862047B2 (en) 2013-08-14 2020-12-08 Kyushu University, National University Corporation Organic electroluminescent device
TW201522326A (zh) 2013-11-12 2015-06-16 Univ Kyushu Nat Univ Corp 發光材料與使用其之延遲螢光體及有機發光元件
JP6392240B2 (ja) 2013-11-18 2018-09-19 株式会社Kyulux 発光材料、有機発光素子および化合物
TW201529565A (zh) 2013-11-28 2015-08-01 Univ Kyushu Nat Univ Corp 發光材料、有機發光元件及化合物
TWI637944B (zh) 2013-11-28 2018-10-11 九州有機光材股份有限公司 發光材料、有機發光元件及化合物
JP6383538B2 (ja) 2014-01-08 2018-08-29 株式会社Kyulux 発光材料、有機発光素子および化合物
JP6284370B2 (ja) 2014-01-17 2018-02-28 株式会社Kyulux 発光材料、有機発光素子および化合物
JP6469076B2 (ja) 2014-02-28 2019-02-13 株式会社Kyulux 発光材料、有機発光素子および化合物
CN106062126B (zh) 2014-02-28 2019-01-11 九州有机光材股份有限公司 发光材料、有机发光元件及化合物
WO2015133501A1 (ja) 2014-03-07 2015-09-11 国立大学法人九州大学 発光材料、有機発光素子および化合物
CN106103441B (zh) 2014-03-11 2019-03-26 保土谷化学工业株式会社 具有氮杂芴环结构的螺环化合物、发光材料和有机电致发光器件
JP6466913B2 (ja) 2014-03-11 2019-02-06 株式会社Kyulux 発光材料、有機発光素子および化合物
CN106165138B (zh) 2014-03-11 2019-07-09 九州有机光材股份有限公司 有机发光元件、主体材料、发光材料及化合物
JP6326251B2 (ja) 2014-03-12 2018-05-16 株式会社カネカ 発光材料及びそれを用いた有機el素子
US10256415B2 (en) 2014-03-27 2019-04-09 Kyulux, Inc. Light-emitting material, organic light-emitting device, and compound
CN106103440B (zh) 2014-04-18 2019-03-26 保土谷化学工业株式会社 具有四氮杂苯并菲环结构的化合物、发光材料和有机电致发光器件
JP6829547B2 (ja) 2015-12-28 2021-02-10 株式会社Kyulux 化合物、発光材料および有機発光素子
JP6668152B2 (ja) 2015-12-28 2020-03-18 株式会社Kyulux 化合物、発光材料および有機発光素子
JP2017222623A (ja) 2016-06-17 2017-12-21 株式会社Kyulux 化合物および有機発光素子
JP7023452B2 (ja) 2016-06-17 2022-02-22 株式会社Kyulux 発光材料、有機発光素子および化合物
WO2018047853A1 (ja) 2016-09-06 2018-03-15 株式会社Kyulux 有機発光素子
EP3561023B1 (en) 2016-12-21 2022-10-12 Kyushu University National University Corporation Light-emitting material, coumpound, and organic light-emitting element
WO2018237389A1 (en) 2017-06-23 2018-12-27 Kyulux Inc. Composition of matter for use in organic light-emitting diodes
KR102187980B1 (ko) 2018-03-28 2020-12-07 주식회사 엘지화학 화합물 및 이를 포함하는 유기 발광 소자
WO2019195104A1 (en) * 2018-04-02 2019-10-10 Kyulux, Inc. Composition of matter for use in organic light-emitting diodes
WO2020085765A1 (ko) * 2018-10-22 2020-04-30 주식회사 엘지화학 다환 화합물 및 이를 포함하는 유기발광소자
WO2020085446A1 (ja) 2018-10-25 2020-04-30 出光興産株式会社 化合物、有機エレクトロルミネッセンス素子用材料、有機エレクトロルミネッセンス素子、および電子機器
JPWO2021066059A1 (https=) 2019-10-01 2021-04-08
WO2021235549A1 (ja) * 2020-05-22 2021-11-25 株式会社Kyulux 化合物、発光材料および発光素子
WO2022254965A1 (ja) * 2021-06-03 2022-12-08 株式会社Kyulux 化合物、発光材料および発光素子

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CN115698016B (zh) 2025-02-21
WO2021235549A1 (ja) 2021-11-25
CN115698016A (zh) 2023-02-03
US20230210000A1 (en) 2023-06-29
JP7406260B2 (ja) 2023-12-27
KR20230015360A (ko) 2023-01-31
JP7674766B2 (ja) 2025-05-12
EP4155309A4 (en) 2023-10-25
EP4155309A1 (en) 2023-03-29
JP2024026324A (ja) 2024-02-28
JP2022008106A (ja) 2022-01-13

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