CN1178928C - 使用金属氧化物溶胶生产成形体的方法、成形体、及其在生产氧化烯中的应用 - Google Patents

使用金属氧化物溶胶生产成形体的方法、成形体、及其在生产氧化烯中的应用 Download PDF

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Publication number
CN1178928C
CN1178928C CNB998071404A CN99807140A CN1178928C CN 1178928 C CN1178928 C CN 1178928C CN B998071404 A CNB998071404 A CN B998071404A CN 99807140 A CN99807140 A CN 99807140A CN 1178928 C CN1178928 C CN 1178928C
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China
Prior art keywords
metal oxide
metal
preparation
mixture
sol
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Expired - Fee Related
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CNB998071404A
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English (en)
Chinese (zh)
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CN1305395A (zh
Inventor
Gh
G·H·格罗施
U·米勒
M·赫瑟
C·洛克曼
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BASF SE
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BASF SE
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Priority claimed from DE19815879A external-priority patent/DE19815879A1/de
Priority claimed from DE19859561A external-priority patent/DE19859561A1/de
Application filed by BASF SE filed Critical BASF SE
Publication of CN1305395A publication Critical patent/CN1305395A/zh
Application granted granted Critical
Publication of CN1178928C publication Critical patent/CN1178928C/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/04—Silica-rich materials; Silicates
    • C04B14/047—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/033—Using Hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/08—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding porous substances
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Epoxy Compounds (AREA)
  • Saccharide Compounds (AREA)
  • Developing Agents For Electrophotography (AREA)
  • Polarising Elements (AREA)
CNB998071404A 1998-04-08 1999-04-07 使用金属氧化物溶胶生产成形体的方法、成形体、及其在生产氧化烯中的应用 Expired - Fee Related CN1178928C (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE19815879.3 1998-04-08
DE19815879A DE19815879A1 (de) 1998-04-08 1998-04-08 Verfahren zur Herstellung eines Formkörpers
DE19859561A DE19859561A1 (de) 1998-12-22 1998-12-22 Verfahren zur Herstellung eines Formkörpers
DE19859561.1 1998-12-22

Related Child Applications (2)

Application Number Title Priority Date Filing Date
CN200510127013.6A Division CN1781601B (zh) 1998-04-08 1999-04-07 成型体及其作为催化剂的应用
CNB2004100080750A Division CN1240475C (zh) 1998-04-08 1999-04-07 使用金属氧化物溶胶生产成形体的方法

Publications (2)

Publication Number Publication Date
CN1305395A CN1305395A (zh) 2001-07-25
CN1178928C true CN1178928C (zh) 2004-12-08

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CNB998071404A Expired - Fee Related CN1178928C (zh) 1998-04-08 1999-04-07 使用金属氧化物溶胶生产成形体的方法、成形体、及其在生产氧化烯中的应用
CNB2004100080750A Expired - Fee Related CN1240475C (zh) 1998-04-08 1999-04-07 使用金属氧化物溶胶生产成形体的方法

Family Applications After (1)

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CNB2004100080750A Expired - Fee Related CN1240475C (zh) 1998-04-08 1999-04-07 使用金属氧化物溶胶生产成形体的方法

Country Status (13)

Country Link
US (1) US6551546B1 (enExample)
EP (2) EP1071506B1 (enExample)
JP (1) JP4335445B2 (enExample)
KR (1) KR20010052243A (enExample)
CN (2) CN1178928C (enExample)
AT (1) ATE371494T1 (enExample)
AU (1) AU3333699A (enExample)
CA (1) CA2327765A1 (enExample)
DE (1) DE59914480D1 (enExample)
ES (1) ES2289809T3 (enExample)
ID (1) ID26018A (enExample)
MX (2) MX240197B (enExample)
WO (1) WO1999052626A1 (enExample)

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EP1129992A1 (de) 2000-03-02 2001-09-05 Degussa AG Verfahren zur Herstellung eines titanhaltigen Zeolithen
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EP1138386A1 (de) 2000-03-29 2001-10-04 Degussa AG Verfahren zur Herstellung eines Titansilicalitformkörpers
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CN102989502A (zh) * 2012-11-26 2013-03-27 天津大学 一种钛硅分子筛微球催化剂的制备方法
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Publication number Publication date
KR20010052243A (ko) 2001-06-25
MX291849B (en) 2011-11-09
MX240197B (es) 2006-09-12
CN1533837A (zh) 2004-10-06
DE59914480D1 (de) 2007-10-11
ID26018A (id) 2000-11-16
ES2289809T3 (es) 2008-02-01
ATE371494T1 (de) 2007-09-15
MXPA00009872A (es) 2005-09-08
JP2002511335A (ja) 2002-04-16
AU3333699A (en) 1999-11-01
EP1071506B1 (de) 2007-08-29
EP1071506A1 (de) 2001-01-31
US6551546B1 (en) 2003-04-22
CN1305395A (zh) 2001-07-25
CN1240475C (zh) 2006-02-08
WO1999052626A1 (de) 1999-10-21
JP4335445B2 (ja) 2009-09-30
CA2327765A1 (en) 1999-10-21
EP1481728A1 (de) 2004-12-01

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