CN117224408A - Moisturizing and skin-adhering foundation liquid for improving makeup effect on dry skin and preparation method thereof - Google Patents
Moisturizing and skin-adhering foundation liquid for improving makeup effect on dry skin and preparation method thereof Download PDFInfo
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- CN117224408A CN117224408A CN202311508689.4A CN202311508689A CN117224408A CN 117224408 A CN117224408 A CN 117224408A CN 202311508689 A CN202311508689 A CN 202311508689A CN 117224408 A CN117224408 A CN 117224408A
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- 230000003020 moisturizing effect Effects 0.000 title claims abstract description 70
- 230000000694 effects Effects 0.000 title claims abstract description 46
- 206010013786 Dry skin Diseases 0.000 title claims abstract description 35
- 230000037336 dry skin Effects 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title abstract description 14
- 239000007788 liquid Substances 0.000 title description 26
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000003086 colorant Substances 0.000 claims abstract description 25
- 239000000945 filler Substances 0.000 claims abstract description 20
- 230000001804 emulsifying effect Effects 0.000 claims abstract description 17
- 239000002537 cosmetic Substances 0.000 claims abstract description 15
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 14
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 14
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 60
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 42
- 238000002156 mixing Methods 0.000 claims description 37
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 36
- 238000003756 stirring Methods 0.000 claims description 31
- 239000004408 titanium dioxide Substances 0.000 claims description 30
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 26
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 23
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 21
- 229920001661 Chitosan Polymers 0.000 claims description 20
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 20
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 18
- 239000008367 deionised water Substances 0.000 claims description 18
- 229910021641 deionized water Inorganic materials 0.000 claims description 18
- 238000001816 cooling Methods 0.000 claims description 14
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 claims description 14
- 238000005406 washing Methods 0.000 claims description 14
- 229920002385 Sodium hyaluronate Polymers 0.000 claims description 13
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 13
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 13
- 229940010747 sodium hyaluronate Drugs 0.000 claims description 13
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 claims description 13
- 238000001914 filtration Methods 0.000 claims description 10
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 10
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 10
- 235000011187 glycerol Nutrition 0.000 claims description 9
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 9
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 9
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 claims description 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 8
- ZAKOWWREFLAJOT-UHFFFAOYSA-N d-alpha-Tocopheryl acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-UHFFFAOYSA-N 0.000 claims description 8
- FOYKKGHVWRFIBD-UHFFFAOYSA-N gamma-tocopherol acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 FOYKKGHVWRFIBD-UHFFFAOYSA-N 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 239000011591 potassium Substances 0.000 claims description 8
- 229910052700 potassium Inorganic materials 0.000 claims description 8
- 230000001954 sterilising effect Effects 0.000 claims description 8
- 239000000454 talc Substances 0.000 claims description 8
- 229910052623 talc Inorganic materials 0.000 claims description 8
- 239000003995 emulsifying agent Substances 0.000 claims description 7
- 239000003999 initiator Substances 0.000 claims description 7
- 239000011261 inert gas Substances 0.000 claims description 6
- 239000003381 stabilizer Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 239000012298 atmosphere Substances 0.000 claims description 4
- 229920001213 Polysorbate 20 Polymers 0.000 claims description 2
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 claims description 2
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 claims description 2
- 229940068977 polysorbate 20 Drugs 0.000 claims description 2
- 239000006210 lotion Substances 0.000 claims 3
- 229940009868 aluminum magnesium silicate Drugs 0.000 claims 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 claims 1
- 229940008099 dimethicone Drugs 0.000 claims 1
- 239000004205 dimethyl polysiloxane Substances 0.000 claims 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract description 4
- 239000006071 cream Substances 0.000 abstract 2
- 210000003491 skin Anatomy 0.000 description 35
- 239000000243 solution Substances 0.000 description 21
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 15
- 239000000843 powder Substances 0.000 description 15
- 238000012360 testing method Methods 0.000 description 14
- 239000000523 sample Substances 0.000 description 13
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 8
- 239000012299 nitrogen atmosphere Substances 0.000 description 8
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 description 8
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 7
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 7
- 229960002446 octanoic acid Drugs 0.000 description 7
- 235000012222 talc Nutrition 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- -1 polytetrafluoroethylene Polymers 0.000 description 5
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 5
- 239000004810 polytetrafluoroethylene Substances 0.000 description 5
- 210000002374 sebum Anatomy 0.000 description 5
- 238000001291 vacuum drying Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 239000003906 humectant Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910010413 TiO 2 Inorganic materials 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 230000028327 secretion Effects 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000005282 brightening Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000000967 suction filtration Methods 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 206010039792 Seborrhoea Diseases 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 230000037312 oily skin Effects 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Cosmetics (AREA)
Abstract
The invention relates to the technical field of cosmetics, and discloses a moisturizing skin-adhering foundation cream for improving the makeup-holding effect of dry skin and a preparation method thereof, wherein the foundation cream comprises the following raw materials in parts by mass: 20-32 parts of water, 10-14 parts of coloring agent, 18-25 parts of modified film forming agent, 15-25 parts of moisturizing component, 3.5-5 parts of emulsifying component, 1-3 parts of antioxidant, 2-3.5 parts of filling agent and 1-3 parts of auxiliary agent.
Description
Technical Field
The invention relates to the technical field of cosmetics, in particular to a moisturizing skin-adhering foundation liquid for improving the makeup-holding effect of dry skin and a preparation method thereof.
Background
With the vigorous development of the cosmetic market, the color cosmetics occupy a significant position in the cosmetic industry, and the market share is increased year by year. The base makeup such as the foundation make-up liquid is an important component of the makeup, mainly plays roles of covering facial flaws and uniformly brightening skin color, endows the skin with smooth and fine feel, and makes consumers face life with more delicate and perfect images. However, the foundation liquid is suitable for neutral, mixed and oily skin groups, dry skin has little sebum secretion and dry skin, and particularly in autumn and winter, the horny layer of the skin can be tilted up, so that powder is unevenly dispersed, the phenomenon of powder sticking and non-fitting occurs, the subsequent makeup holding effect is greatly reduced, and the makeup appearance is influenced.
Chinese patent application CN104434570a discloses a silky skin-feel essence foundation solution and a preparation method thereof, wherein the foundation solution comprises the following components: the foundation liquid has good water resistance and fine skin feel, but no water is added in the formula, the foundation liquid has thick texture, general makeup holding effect, higher cost, poor moisturizing and skin pasting effect and great difficulty in makeup removal. Chinese patent application CN113425627a discloses a durable foundation liquid composition, which is composed of liquid oil, film forming agent, emulsifying agent, thickening agent and coloring agent, and has good make-up effect and anti-darkening effect, but the foundation liquid has general moisturizing effect and is not suitable for dry skin.
Therefore, there is a need to design a foundation solution which has an obvious cosmetic effect on dry skin and is capable of moisturizing and pasting the skin.
Disclosure of Invention
In order to solve the technical problems, the invention provides the moisturizing and skin-pasting type foundation liquid for improving the makeup-holding effect on dry skin and the preparation method thereof, so that the foundation liquid suitable for the dry skin is obtained, after the foundation liquid is used, the moisturizing and skin-pasting type foundation liquid can be kept, and the makeup-holding effect is greatly improved.
In order to achieve the aim, the invention discloses a moisturizing and skin-adhering type foundation liquid for improving the makeup holding effect of dry skin, which is prepared from the following raw materials in parts by mass: 20-32 parts of water, 10-14 parts of colorant, 18-25 parts of modified film forming agent, 15-25 parts of moisturizing component, 3.5-5 parts of emulsifying component, 1-3 parts of antioxidant, 2-3.5 parts of filler and 1-3 parts of auxiliary agent.
Preferably, the colorant comprises CI 77019, CI 77491, CI 77499, CI 77492; the mass ratio of CI 77019, CI 77491, CI 77499, CI 77492 is 105:92:90:100.
preferably, the modified film forming agent is prepared by the following steps:
stirring and mixing titanium tetrachloride, potassium borofluoride, hydrogen peroxide and deionized water, uniformly mixing, transferring into a polytetrafluoroethylene reaction kettle, performing hydrothermal reaction, cooling, suction filtering, washing filter residues with deionized water, and vacuum drying at 60 ℃ for 12 hours to obtain hollow titanium dioxide;
dispersing hollow titanium dioxide into N, N-dimethylformamide by ultrasonic, adding glycidyl methacrylate after uniform dispersion, reacting in an inert gas atmosphere, centrifuging after the reaction is finished, washing with absolute ethyl alcohol and deionized water after centrifuging, and drying at 80 ℃ for 12 hours to obtain modified titanium dioxide; wherein the mass ratio of the hollow titanium dioxide to the N, N-dimethylformamide to the glycidyl methacrylate is 100: (2500-3000): (85-125);
and thirdly, dissolving chitosan in an acetic acid solution, uniformly mixing, adding an initiator ammonium persulfate in an inert gas atmosphere, stirring and mixing, adding allyl methacrylate and modified titanium dioxide, reacting, filtering after the reaction is finished, extracting by using acetone, and drying in vacuum at 60 ℃ for 12 hours to obtain the modified film forming agent.
Further, in the first step, the mass ratio of titanium tetrachloride to potassium borofluoride to hydrogen peroxide to deionized water is 100: (28-35): (40-50): (950-1200).
Further, the temperature of the hydrothermal reaction in the first step is 180-190 ℃, and the time of the hydrothermal reaction is 18-24 hours.
Further, in the second step, the reaction temperature is 65-75 ℃ and the reaction time is 36-42h.
Further, in the second step, the inert gas includes nitrogen.
Further, the temperature of the reaction in the step three is 40-55 ℃, and the reaction time is 3-6h.
Further, in the third step, the acetic acid solution is an aqueous acetic acid solution with a mass concentration of 1%.
Further, in the third step, the mass ratio of the acetic acid solution, chitosan, ammonium persulfate, allyl methacrylate and modified titanium dioxide is (3600-4200): (62-85): (2-5): 100: (25-40).
Further, in the third step, the inert gas includes nitrogen.
Further, in the third step, the stirring and mixing time is 0.5h.
Preferably, the moisturizing component comprises glycerin, sodium hyaluronate, and cyclopentadimethicone; the mass ratio of the glycerol to the sodium hyaluronate to the cyclopentadimethicone is 100: (58-75): (112-130).
Preferably, the emulsifying component comprises an emulsifying agent and an emulsion stabilizer, the emulsifying agent comprises polysorbate-20, the emulsion stabilizer comprises magnesium aluminum silicate, and the mass ratio of the emulsifying agent to the emulsion stabilizer is 2:1.
preferably, the antioxidant comprises tocopheryl acetate.
Preferably, the filler comprises talc and magnesium sulfate.
Further, the mass ratio of the talcum powder to the magnesium sulfate is 100:92.
preferably, the adjuvant comprises caprylic/capric triglyceride.
Preferably, the preparation method of the moisturizing and skin-sticking type foundation solution for improving the makeup effect on dry skin comprises the following steps:
s1, uniformly mixing water, a moisturizing component and an auxiliary agent to obtain a component A;
s2, stirring and mixing the colorant, the modified film forming agent, the emulsifying component and the filler to obtain a component B;
s3, respectively heating the component A and the component B, dropwise adding the component A into the component B under the stirring condition for homogenizing, homogenizing at 75-80 ℃ for 3-6min, cooling after homogenizing, adding an antioxidant, uniformly dispersing, and sterilizing to obtain the moisturizing and skin-adhering type foundation solution for improving the makeup holding effect on dry skin.
Preferably, the vacuum degree of the homogenizing treatment in the step S3 is-0.06 MPa.
Titanium tetrachloride is used as a titanium source in the invention, ti is in a hydrothermal reaction system 4+ Hydrolysis reaction to Ti (OH) 4 Further dehydrated and converted into TiO 2 The surface of the crystal grain is formed in BF due to high surface energy 4 - Under the action of (a) forming stable spherical aggregates, BF in the system 4 - Hydrolysis takes place to release F - Further and TiO 2 The reversible reaction occurs to accelerate TiO 2 The dissolution-adhesion-crystallization self-assembly process of the crystal grains, the decomposition of hydrogen peroxide releases oxygen, and the octahedral TiO is driven by the minimization of interfacial energy 2 The microcrystal is condensed into a hollow sphere around oxygen to obtain hollow titanium dioxide, the hydroxyl on the surface of the hollow titanium dioxide and epoxy on glycidyl methacrylate are subjected to ring-opening reaction to obtain modified titanium dioxide, chitosan and modified titanium dioxide, and allyl methacrylate are subjected to reaction under the action of an initiator ammonium persulfate to obtainTo a modified film former.
Compared with the prior art, the invention has the beneficial effects that: the hollow titanium dioxide prepared by the method has small particle size, can achieve quick and obvious color change effect, has excellent dispersibility and compatibility after surface treatment, ensures that the foundation liquid has better smoothness and extensibility, is lighter and thinner on skin feel, has good whitening concealing and skin color brightening effects, has stronger concealing capability of hollow nano titanium dioxide, can conceal flaws on the surface of skin, ensures that the skin looks smoother and finer, has high transparency, does not influence the skin color when being smeared on the skin, and ensures that the skin looks more natural. After the hollow titanium dioxide is modified, the weather resistance is improved. The chitosan has the functions of moisturizing, stimulating cell regeneration and modifying skin, and the cosmetic containing the chitosan can not only provide nutrients for the skin, but also be filled in dry cracks generated in the epidermis so as to achieve the effect of modifying and beautifying, has good skin nourishing effect and can improve the moisture of the skin. Furthermore, the chitosan can also be used as a thickening agent to improve the viscosity of the foundation liquid, improve the stability of the matrix, and is safe and harmless, and the chitosan can be used for synergistic effect with anions in other component structures in the foundation liquid to protect and moisten skin and improve the face luster. The modified film forming agent is a lipophilic and hydrophobic substance, can selectively absorb sebum but not moisture, has film forming property, can reduce makeup removal caused by skin oil extraction, and can increase the durability of the base makeup. The modified film forming agent has a large number of hydroxyl groups, and molecules are tightly connected through hydrogen bonds, so that a compact and skin-adhering reticular film is formed, toner is firmly locked on the film, and the modified film forming agent has oleophobic property, so that the formed film has good oil resistance and reduces makeup removal caused by sebum secretion.
The humectant disclosed by the invention is prepared from glycerin, sodium hyaluronate and cyclopentadimethicone, and has the advantages of super water locking capacity and obvious moisturizing effect. Through compounding the humectant and the modified film forming agent, a compact three-dimensional network structure can be formed, the deep moisturizing effect from inside to outside is realized, the slow release effect is achieved, and the skin moisturizing agent is more suitable for dry skin. The added auxiliary agent caprylic acid/capric acid triglyceride ensures that powder particles wrapped in the powder base liquid are not too hard, and the powder base liquid is easy to make up and smear uniformly.
The foundation liquid disclosed by the invention has the advantages of moisturizing and nourishing effect, lasting moisturizing and skin-sticking effect, difficulty in makeup removal, strong storage stability and wide application prospect for dry skin, and also has the function of moisturizing and concealing.
Drawings
Fig. 1 is a flowchart of preparing a moisturizing skin-contacting type foundation solution for improving a makeup-holding effect on dry skin in the present invention.
Detailed Description
The technical solutions of the embodiments of the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention, and it is apparent that the described embodiments are only some embodiments of the present invention, but not all embodiments, and all other embodiments obtained by those skilled in the art without making any inventive effort based on the embodiments of the present invention are within the scope of protection of the present invention.
Example 1
A preparation method of a moisturizing and skin-adhering type foundation solution for improving the makeup effect of dry skin comprises the following steps:
s1, uniformly mixing 20 parts by mass of water, 15 parts by mass of moisturizing components and 1 part by mass of auxiliary agent caprylic acid/capric acid triglyceride to obtain a component A, wherein the moisturizing components comprise the following components in percentage by mass: 58:112, sodium hyaluronate and cyclopentadimethicone;
s2, stirring and mixing 10 parts by mass of a colorant, 18 parts by mass of a modified film forming agent, 3.5 parts by mass of an emulsifying component and 2 parts by mass of a filler to obtain a component B, wherein the mass ratio of the colorant is 105:92:90:100, wherein the emulsified components consist of CI 77019, CI 77491, CI 77499 and CI 77492 in a mass ratio of 2:1 and magnesium aluminum silicate, wherein the filler comprises the following components in percentage by mass: 92 talc and magnesium sulfate;
s3, respectively heating the component A and the component B, dropwise adding the component A into the component B under the stirring condition for homogenizing, wherein the vacuum degree of the homogenizing treatment is-0.06 MPa, homogenizing at 75 ℃ for 6min, cooling after homogenizing, adding 1 part of antioxidant tocopheryl acetate, dispersing uniformly, and sterilizing to obtain the moisturizing skin-friendly powder base liquid for improving the makeup holding effect of dry skin; wherein the modified film forming agent is prepared by the following steps:
step one, the mass ratio is 100:28:40:950, uniformly mixing titanium tetrachloride, potassium borofluoride, hydrogen peroxide and deionized water, transferring to a polytetrafluoroethylene reaction kettle after uniformly mixing, performing hydrothermal reaction for 24 hours at 180 ℃, cooling after the reaction is finished, performing suction filtration, washing filter residues with deionized water, and performing vacuum drying for 12 hours at 60 ℃ to obtain hollow titanium dioxide;
step two, ultrasonically dispersing hollow titanium dioxide into N, N-dimethylformamide, and adding glycidyl methacrylate after uniformly dispersing, wherein the mass ratio of the hollow titanium dioxide to the N, N-dimethylformamide to the glycidyl methacrylate is 100:2500:85, stirring and mixing in a nitrogen atmosphere, reacting for 42 hours at 65 ℃, centrifuging at 6000r/min after the reaction is finished, centrifuging for 8min, washing with absolute ethyl alcohol and deionized water after centrifuging, and drying for 12 hours at 80 ℃ to obtain modified titanium dioxide;
step three, dissolving chitosan in an acetic acid aqueous solution with the mass concentration of 1%, uniformly mixing, adding an initiator ammonium persulfate in a nitrogen atmosphere, stirring and mixing for 0.5h, and then adding allyl methacrylate and modified titanium dioxide, wherein the mass ratio of the acetic acid aqueous solution with the mass concentration of 1%, chitosan, ammonium persulfate, allyl methacrylate and modified titanium dioxide is 3600:62:2:100:25, stirring, reacting at 40 ℃ for 6 hours, filtering after the reaction is finished, extracting by using acetone, and drying in vacuum at 60 ℃ for 12 hours to obtain the modified film forming agent.
Example 2
A preparation method of a moisturizing and skin-adhering type foundation solution for improving the makeup effect of dry skin comprises the following steps:
s1, uniformly mixing 24 parts by mass of water, 18 parts by mass of moisturizing components and 1.5 parts by mass of auxiliary agent caprylic acid/capric acid triglyceride to obtain a component A, wherein the moisturizing components comprise the following components in percentage by mass: 62:118, sodium hyaluronate and cyclopentadimethicone;
s2, stirring and mixing 12 parts by mass of a colorant, 20 parts by mass of a modified film forming agent, 4 parts by mass of an emulsifying component and 2.5 parts by mass of a filler to obtain a component B, wherein the mass ratio of the colorant is 105:92:90:100, wherein the emulsified components consist of CI 77019, CI 77491, CI 77499 and CI 77492 in a mass ratio of 2:1 and magnesium aluminum silicate, wherein the filler comprises the following components in percentage by mass: 92 talc and magnesium sulfate;
s3, respectively heating the component A and the component B, dropwise adding the component A into the component B under the stirring condition for homogenizing, wherein the vacuum degree of the homogenizing treatment is-0.06 MPa, homogenizing at 78 ℃ for 4min, cooling after homogenizing, adding 2 parts of antioxidant tocopheryl acetate, dispersing uniformly, and sterilizing to obtain the moisturizing skin-friendly powder base liquid for improving the makeup holding effect of dry skin; wherein the modified film forming agent is prepared by the following steps:
step one, the mass ratio is 100:32:48:1100, uniformly mixing titanium tetrachloride, potassium borofluoride, hydrogen peroxide and deionized water, transferring to a polytetrafluoroethylene reaction kettle after uniformly mixing, performing hydrothermal reaction at 185 ℃ for 22 hours, cooling, filtering, washing filter residues with deionized water, and vacuum drying at 60 ℃ for 12 hours to obtain hollow titanium dioxide;
step two, ultrasonically dispersing hollow titanium dioxide into N, N-dimethylformamide, and adding glycidyl methacrylate after uniformly dispersing, wherein the mass ratio of the hollow titanium dioxide to the N, N-dimethylformamide to the glycidyl methacrylate is 100:2800:105, stirring and mixing in a nitrogen atmosphere, reacting for 40 hours at 70 ℃, centrifuging at 6000r/min after the reaction is finished, centrifuging for 8min, washing with absolute ethyl alcohol and deionized water after centrifuging, and drying for 12 hours at 80 ℃ to obtain modified titanium dioxide;
step three, chitosan is dissolved in acetic acid aqueous solution with the mass concentration of 1%, after being uniformly mixed, initiator ammonium persulfate is added in a nitrogen atmosphere, after being stirred and mixed for 0.5h, allyl methacrylate and modified titanium dioxide are added, and the mass ratio of the acetic acid aqueous solution with the mass concentration of 1%, chitosan, ammonium persulfate, allyl methacrylate and modified titanium dioxide is 4000:75:4:100:35, stirring, reacting for 5 hours at 50 ℃, filtering after the reaction is finished, extracting by using acetone, and drying in vacuum for 12 hours at 60 ℃ to obtain the modified film forming agent.
Example 3
A preparation method of a moisturizing and skin-adhering type foundation solution for improving the makeup effect of dry skin comprises the following steps:
s1, uniformly mixing 30 parts by mass of water, 22 parts by mass of moisturizing components and 2.5 parts by mass of auxiliary agent caprylic acid/capric acid triglyceride to obtain a component A, wherein the moisturizing components comprise the following components in percentage by mass: 70:125 glycerin, sodium hyaluronate and cyclopentadimethicone;
s2, stirring and mixing 13 parts by mass of a colorant, 24 parts by mass of a modified film forming agent, 4.5 parts by mass of an emulsifying component and 3 parts by mass of a filler to obtain a component B, wherein the mass ratio of the colorant is 105:92:90:100, wherein the emulsified components consist of CI 77019, CI 77491, CI 77499 and CI 77492 in a mass ratio of 2:1 and magnesium aluminum silicate, wherein the filler comprises the following components in percentage by mass: 92 talc and magnesium sulfate;
s3, respectively heating the component A and the component B, dropwise adding the component A into the component B under the stirring condition for homogenizing, wherein the vacuum degree of the homogenizing treatment is-0.06 MPa, homogenizing at 78 ℃ for 5min, cooling after homogenizing, adding 2.5 parts of antioxidant tocopheryl acetate, dispersing uniformly, and sterilizing to obtain the moisturizing skin-adhering type powder base liquid for improving the makeup holding effect on dry skin; wherein the preparation process of the modified film forming agent is the same as that of the embodiment 2.
Example 4
A preparation method of a moisturizing and skin-adhering type foundation solution for improving the makeup effect of dry skin comprises the following steps:
s1, uniformly mixing 32 parts by mass of water, 25 parts by mass of moisturizing components and 3 parts by mass of auxiliary agent caprylic acid/capric acid triglyceride to obtain a component A, wherein the moisturizing components comprise the following components in percentage by mass: 75:130, sodium hyaluronate and cyclopentadimethicone;
s2, stirring and mixing 14 parts by mass of a colorant, 25 parts by mass of a modified film forming agent, 5 parts by mass of an emulsifying component and 3.5 parts by mass of a filler to obtain a component B, wherein the mass ratio of the colorant is 105:92:90:100, wherein the emulsified components consist of CI 77019, CI 77491, CI 77499 and CI 77492 in a mass ratio of 2:1 and magnesium aluminum silicate, wherein the filler comprises the following components in percentage by mass: 92 talc and magnesium sulfate;
s3, respectively heating the component A and the component B, dropwise adding the component A into the component B under the stirring condition for homogenizing, wherein the vacuum degree of the homogenizing treatment is-0.06 MPa, homogenizing at 80 ℃ for 3min, cooling after homogenizing, adding 3 parts of antioxidant tocopheryl acetate, dispersing uniformly, and sterilizing to obtain the moisturizing skin-friendly powder base liquid for improving the makeup holding effect of dry skin; wherein the modified film forming agent is prepared by the following steps:
step one, the mass ratio is 100:35:50:1200 titanium tetrachloride, potassium borofluoride, hydrogen peroxide and deionized water are stirred and mixed, after being mixed uniformly, the mixture is transferred into a polytetrafluoroethylene reaction kettle, the hydrothermal reaction is carried out for 18 hours at 190 ℃, after the reaction is finished, cooling and suction filtration are carried out, deionized water is used for washing filter residues, and vacuum drying is carried out for 12 hours at 60 ℃ to obtain hollow titanium dioxide;
step two, ultrasonically dispersing hollow titanium dioxide into N, N-dimethylformamide, and adding glycidyl methacrylate after uniformly dispersing, wherein the mass ratio of the hollow titanium dioxide to the N, N-dimethylformamide to the glycidyl methacrylate is 100:3000:125, stirring and mixing in a nitrogen atmosphere, reacting at 75 ℃ for 36 hours, centrifuging at 6000r/min for 8min after the reaction, washing with absolute ethyl alcohol and deionized water after centrifuging, and drying at 80 ℃ for 12 hours to obtain modified titanium dioxide;
step three, chitosan is dissolved in acetic acid aqueous solution with the mass concentration of 1%, after being uniformly mixed, initiator ammonium persulfate is added in nitrogen atmosphere, after being stirred and mixed for 0.5h, allyl methacrylate and modified titanium dioxide are added, and the mass ratio of acetic acid aqueous solution with the mass concentration of 1%, chitosan, ammonium persulfate, allyl methacrylate and modified titanium dioxide is 4200:85:5:100:40, stirring, reacting for 3 hours at 55 ℃, filtering after the reaction is finished, extracting by using acetone, and drying in vacuum for 12 hours at 60 ℃ to obtain the modified film forming agent.
Comparative example 1
A preparation method of a powder base solution comprises the following steps:
s1, uniformly mixing 30 parts by mass of water, 22 parts by mass of moisturizing components and 2.5 parts by mass of auxiliary agent caprylic acid/capric acid triglyceride to obtain a component A, wherein the moisturizing components comprise the following components in percentage by mass: 70:125 glycerin, sodium hyaluronate and cyclopentadimethicone;
s2, stirring and mixing 13 parts by mass of a colorant, 20 parts by mass of chitosan, 4 parts by mass of hollow titanium dioxide, 4.5 parts by mass of an emulsifying component and 3 parts by mass of a filler to obtain a component B, wherein the mass ratio of the colorant is 105:92:90:100, wherein the emulsified components consist of CI 77019, CI 77491, CI 77499 and CI 77492 in a mass ratio of 2:1 and magnesium aluminum silicate, wherein the filler comprises the following components in percentage by mass: 92 talc and magnesium sulfate;
s3, respectively heating the component A and the component B, dropwise adding the component A into the component B under stirring, homogenizing, wherein the vacuum degree of the homogenizing is-0.06 MPa, homogenizing at 78 ℃ for 5min, cooling after homogenizing, adding 2.5 parts of antioxidant tocopheryl acetate, dispersing uniformly, and sterilizing to obtain a powder base solution; wherein the hollow titanium dioxide is prepared by the following steps: the mass ratio is 100:32:48:1100, uniformly mixing titanium tetrachloride, potassium borofluoride, hydrogen peroxide and deionized water, transferring into a polytetrafluoroethylene reaction kettle, performing hydrothermal reaction at 185 ℃ for 22 hours, cooling, filtering, washing filter residues with deionized water, and vacuum drying at 60 ℃ for 12 hours to obtain hollow titanium dioxide.
Comparative example 2
A preparation method of a powder base solution comprises the following steps:
s1, uniformly mixing 30 parts by mass of water, 22 parts by mass of moisturizing components and 2.5 parts by mass of auxiliary agent caprylic acid/capric acid triglyceride to obtain a component A, wherein the moisturizing components comprise the following components in percentage by mass: 70:125 glycerin, sodium hyaluronate and cyclopentadimethicone;
s2, stirring and mixing 13 parts by mass of a colorant, 24 parts by mass of a modified film forming agent, 4.5 parts by mass of an emulsifying component and 3 parts by mass of a filler to obtain a component B, wherein the mass ratio of the colorant is 105:92:90:100, wherein the emulsified components consist of CI 77019, CI 77491, CI 77499 and CI 77492 in a mass ratio of 2:1 and magnesium aluminum silicate, wherein the filler comprises the following components in percentage by mass: 92 talc and magnesium sulfate;
s3, respectively heating the component A and the component B, dropwise adding the component A into the component B under stirring, homogenizing, wherein the vacuum degree of the homogenizing is-0.06 MPa, homogenizing at 78 ℃ for 5min, cooling after homogenizing, adding 2.5 parts of antioxidant tocopheryl acetate, dispersing uniformly, and sterilizing to obtain a powder base solution; wherein the modified film forming agent is prepared by the following steps:
step one, ultrasonically dispersing nano titanium dioxide into N, N-dimethylformamide, and adding glycidyl methacrylate after uniformly dispersing, wherein the mass ratio of the nano titanium dioxide to the N, N-dimethylformamide to the glycidyl methacrylate is 100:2800:105, stirring and mixing in a nitrogen atmosphere, reacting for 40 hours at 70 ℃, centrifuging at 6000r/min after the reaction is finished, centrifuging for 8min, washing with absolute ethyl alcohol and deionized water after centrifuging, and drying for 12 hours at 80 ℃ to obtain modified titanium dioxide;
step two, dissolving chitosan in an acetic acid aqueous solution with the mass concentration of 1%, uniformly mixing, adding an initiator ammonium persulfate in a nitrogen atmosphere, stirring and mixing for 0.5h, and then adding allyl methacrylate and modified titanium dioxide, wherein the mass ratio of the acetic acid aqueous solution with the mass concentration of 1%, chitosan, ammonium persulfate, allyl methacrylate and modified titanium dioxide is 4000:75:4:100:35, stirring, reacting for 5 hours at 50 ℃, filtering after the reaction is finished, extracting by using acetone, and drying in vacuum for 12 hours at 60 ℃ to obtain the modified film forming agent.
In the above examples and comparative examples, colorant CI 77019 (mica, CAS number 12001-26-2), colorant CI 77491 (iron oxide red, CAS number 1309-37-1), colorant CI 77499 (iron oxide black, CAS number 1317-61-9), colorant CI 77492 (iron oxide yellow, CAS number 1345-27-3) are commercially available products; cyclopentadimethicone was purchased from Guangzhou, inc. of Qiyuan Biotech, inc., brand: american Conning model: PMX-0345Z; sodium hyaluronate was purchased from Guangzhou Minghui chemical technology Co., ltd., product number: SDA963; talcum powder is purchased from Shenzhen Luyue powder technology Co., ltd, and the fineness is 8000 meshes; the magnesium sulfate is anhydrous magnesium sulfate powder, and is purchased from Shandong salt to chemical industry Co., ltd., product number: YDH 2022; the chitosan is water-soluble chitosan, and is purchased from Jiangsu Fusheng biological engineering Co., ltd., product number: 102.
the foundation solutions prepared in examples 1-4 and comparative examples 1-2 were selected as samples, and subjected to corresponding tests, the test methods and test results are as follows:
(1) And (3) moisture preservation effect test: the method comprises the steps of using a Corneometer-capacitance method, representing by setting a humidity measurement value (MMV), wherein the MMV is a value between 0 and 150, almost no current passes through the skin to be tested, the test result is practically free from the effects of polarization effect and ionic conductivity, the influence of active skin on the measurement result is eliminated, the test environment is 20 ℃ and 50% relative humidity, a moisture probe is vertically pressed on the skin surface, the top of the probe is pressed back for a distance, a spring is arranged in the probe to keep the top of the probe pressed on the skin surface by 0.16N pressure, a host computer displays the result in one second and is accompanied by a prompt tone, the test part selects the front end part of the inner side of an arm, 36 volunteer subjects are selected, each group of six volunteer subjects in examples 1 to 4 and comparative examples 1 to 2 are marked on the inner side of the arm after washing, and the test area of the smeared sample is 5X 5cm 2 After sitting still for 30min in a constant temperature and humidity environment, measuring blank values of test parts by using a Corneometer, fixedly measuring five points in each area according to the sequence, taking an average value, smearing the sample during the period, starting timing, and respectively measuring MMV change values of each time, wherein the calculation formula of the skin moisture content increase rate is as follows: skin moisture content increase rate mmv= (MMV t -MMV 0 ）/MMV 0 Of these, x 100% was used,MMV 0 for pre-application skin MMV values, MMV t For MMV values of the skin after 30, 60, 120min, respectively, the test results are shown in table 1:
from the test results of Table 1, it can be seen that the samples corresponding to examples 1-4 have excellent moisturizing efficacy. The humectant is glycerin, sodium hyaluronate and cyclopentadimethicone, and has super-strong water-retaining ability and obvious moisturizing effect. Through compounding the humectant and the modified film forming agent, a compact three-dimensional network structure can be formed, the deep moisturizing effect from inside to outside is realized, the slow release effect is achieved, and the skin moisturizing agent is more suitable for dry skin. The corresponding sample subjects of example 4 had a skin moisture content increase of 64.9% after 30min of application, 60.7% after 60min, and 52.6% after 120 min. In comparative example 1, the hollow titanium dioxide was not modified, the compatibility of the raw materials became poor, the film forming performance was greatly affected, the moisturizing ability was greatly affected, and the moisturizing ability of the sample became poor; the hollow titanium dioxide can wrap the moisturizing component, so that the action time of the moisturizing component is prolonged, the moisturizing effect is improved, when the foundation liquid containing the hollow titanium dioxide is smeared on the skin, the wrapped moisturizing component is gradually released, the lasting moisturizing effect is provided for the skin, the nano titanium dioxide is used for replacing the hollow titanium dioxide in comparative example 2, the moisturizing capability of the skin is greatly reduced along with the increase of the smearing time of a subject, and the moisture content increase rate of the skin is 49.8% after the smearing time is 120 min.
(2) Cosmetic holding ability test: selecting 36 volunteer subjects, six volunteer subjects in each group of examples 1-4 and comparative examples 1-2, washing, marking on the face, and applying sample with test area of 5×5cm 2 Sample application was performed at a sample dose of 0.2g, timing was started, the condition of 36 volunteer subjects after applying the sample for 8 hours was tracked, makeup removal of the foundation solution was observed and sensory scoring was performed, scoring was from 1 (difference) to 10 (excellent), and the average value of the scoring results was calculated to obtainThe sample was evaluated for makeup holding ability and the test results are shown in table 2:
from the test results of Table 2, it can be seen that the samples corresponding to examples 1-4 have excellent makeup holding ability. The modified film forming agent has a large number of hydroxyl groups, and molecules are tightly connected through hydrogen bonds, so that a compact and skin-adhering reticular film is formed, toner is firmly locked on the film, and the modified film forming agent has oleophobic property, so that the formed film has good oil resistance and reduces makeup removal caused by sebum secretion. The modified film forming agent is a lipophilic and hydrophobic substance, can selectively absorb sebum without absorbing moisture, has film forming property, can reduce makeup removal caused by skin oil extraction, increases the durability of base makeup, has no modification on hollow titanium dioxide in comparative example 1, has poor compatibility of raw materials, has no allyl methacrylate introduced, has greatly reduced makeup holding capacity, and has reduced compatibility among materials; the hollow titanium dioxide can delay the dressing effect, the nanometer titanium dioxide is used for replacing the hollow titanium dioxide prepared by synthesis in the comparative example 2 of the efficacy component, the durability of the dressing is poor after the volunteer makes up, the dressing holding capacity is reduced to some extent, and the score is 8.9.
Although embodiments of the present invention have been shown and described, it will be understood by those skilled in the art that various changes, modifications, substitutions and alterations can be made hereto without departing from the spirit and scope of the invention as defined by the appended claims.
Claims (9)
1. A moisturizing and skin-adhering type foundation solution for improving the makeup-holding effect of dry skin is characterized by comprising a component A, a component B and an antioxidant; the component A comprises water, a moisturizing component and an auxiliary agent; the component B comprises a colorant, a modified film forming agent, an emulsifying component and a filler; wherein, 20-32 parts of water, 10-14 parts of colorant, 18-25 parts of modified film forming agent, 15-25 parts of moisturizing component, 3.5-5 parts of emulsifying component, 1-3 parts of antioxidant, 2-3.5 parts of filler and 1-3 parts of auxiliary agent; the modified film forming agent is prepared by the following steps:
stirring and mixing titanium tetrachloride, potassium borofluoride, hydrogen peroxide and deionized water, performing hydrothermal reaction, cooling, filtering, washing and drying after the reaction is finished to obtain hollow titanium dioxide;
dispersing hollow titanium dioxide into N, N-dimethylformamide by ultrasonic, adding glycidyl methacrylate, reacting in an inert gas atmosphere, centrifuging, washing and drying after the reaction is finished to obtain modified titanium dioxide; wherein the mass ratio of the hollow titanium dioxide to the N, N-dimethylformamide to the glycidyl methacrylate is 100: (2500-3000): (85-125);
and thirdly, dissolving chitosan in an acetic acid solution, uniformly mixing, adding an initiator ammonium persulfate in an inert gas atmosphere, stirring and mixing, adding allyl methacrylate and modified titanium dioxide, reacting, filtering and drying to obtain the modified film forming agent.
2. A moisturizing skin-friendly foundation lotion for improving the cosmetic holding effect of dry skin as claimed in claim 1, wherein said coloring agent comprises CI 77019, CI 77491, CI 77499, CI 77492; the mass ratio of CI 77019, CI 77491, CI 77499, CI 77492 is 105:92:90:100.
3. the moisturizing and skin-adhering type foundation solution for improving the cosmetic effect on dry skin according to claim 1, wherein in the first step, the mass ratio of titanium tetrachloride, potassium borofluoride, hydrogen peroxide and deionized water is 100: (28-35): (40-50): (950-1200).
4. The moisturizing and skin-adhering type foundation lotion for improving the cosmetic holding effect on dry skin according to claim 3, wherein the mass ratio of the acetic acid solution, chitosan, ammonium persulfate, allyl methacrylate and modified titanium dioxide in the third step is (3600-4200): (62-85): (2-5): 100: (25-40).
5. The moisturizing and skin-adhering type foundation lotion for improving the cosmetic effect on dry skin according to claim 1, wherein the moisturizing component comprises glycerin, sodium hyaluronate and cyclopenta-dimethicone; the mass ratio of the glycerol to the sodium hyaluronate to the cyclopentadimethicone is 100: (58-75): (112-130).
6. The moisturizing and skin-adhering type foundation solution for improving the cosmetic effect on dry skin according to claim 1, wherein the emulsifying component comprises an emulsifying agent and an emulsifying stabilizer, the emulsifying agent comprises polysorbate-20, the emulsifying stabilizer comprises aluminum magnesium silicate, and the mass ratio of the emulsifying agent to the emulsifying stabilizer is 2:1.
7. a moisturizing skin-contacting foundation for improving the cosmetic effect of dry skin as in claim 1, wherein said antioxidant comprises tocopheryl acetate.
8. The moisturizing and skin-adhering type foundation solution for improving the cosmetic effect on dry skin according to claim 1, wherein the filler comprises talc and magnesium sulfate.
9. A method for preparing a moisturizing skin-contacting foundation solution for improving a make-up effect on dry skin as set forth in any one of claims 1 to 8, comprising the steps of:
s1, uniformly mixing water, a moisturizing component and an auxiliary agent to obtain a component A;
s2, stirring and mixing the colorant, the modified film forming agent, the emulsifying component and the filler to obtain a component B;
and S3, respectively heating the component A and the component B, dropwise adding the component A into the component B under the stirring condition for homogenizing, cooling after homogenizing, adding an antioxidant, uniformly dispersing, and sterilizing to obtain the moisturizing and skin-adhering type foundation solution for improving the makeup holding effect of dry skin.
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