CN114732767A - Liquid foundation and preparation method thereof - Google Patents

Liquid foundation and preparation method thereof Download PDF

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Publication number
CN114732767A
CN114732767A CN202210396848.5A CN202210396848A CN114732767A CN 114732767 A CN114732767 A CN 114732767A CN 202210396848 A CN202210396848 A CN 202210396848A CN 114732767 A CN114732767 A CN 114732767A
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China
Prior art keywords
oil
foundation
water
emulsifier
phase
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Pending
Application number
CN202210396848.5A
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Chinese (zh)
Inventor
田勇
沈洁
袁菊懋
田云才
申福澈
付东会
刘书艳
陈锦海
王国伟
周立晓
张鑑锋
牟沛松
江忠梅
余涛
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Shanghai Zhenchen Cosmetics Co Ltd
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Shanghai Zhenchen Cosmetics Co Ltd
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Priority to CN202210396848.5A priority Critical patent/CN114732767A/en
Publication of CN114732767A publication Critical patent/CN114732767A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9789Magnoliopsida [dicotyledons]
    • AHUMAN NECESSITIES
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    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/23Sulfur; Selenium; Tellurium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26Aluminium; Compounds thereof
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    • A61K8/27Zinc; Compounds thereof
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    • A61K8/34Alcohols
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    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
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    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • A61K8/368Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
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    • A61K8/37Esters of carboxylic acids
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    • A61K8/39Derivatives containing from 2 to 10 oxyalkylene groups
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    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/4953Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom containing pyrimidine ring derivatives, e.g. minoxidil
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    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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    • A61K8/73Polysaccharides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
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    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/735Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
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    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
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    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
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    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • AHUMAN NECESSITIES
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    • A61K8/98Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
    • A61K8/987Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin of species other than mammals or birds
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    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
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    • A61K2800/20Chemical, physico-chemical or functional or structural properties of the composition as a whole
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Abstract

The application relates to a liquid foundation and a preparation method thereof, wherein the liquid foundation comprises the following components in percentage by mass: 2-8% of a water-in-oil type emulsifier; 32-60% of a water phase; 35-60% of an oil phase; 0.3-1% of preservative, wherein the water phase comprises deionized water, a humectant, an antiallergic agent and a thickening agent; the oil phase comprises emollient grease, toner, a dispersant and filling powder. The liquid foundation provided by the invention contains no chemical synthetic substances, does not cause skin aging, is prepared from natural raw materials, has no pollution and no heavy metal components, and is safe and healthy.

Description

Liquid foundation and preparation method thereof
Technical Field
The application belongs to the technical field of cosmetics, and particularly relates to a foundation liquid and a preparation method thereof.
Background
The foundation liquid is light and thin in texture, easy to apply and less greasy in feeling, is a foundation cosmetic which is popular at present, and is suitable for most skins, especially oily skins and rapid makeup and modification in summer.
The foundation liquid is one kind of face beautifying cosmetics, and is one kind of emulsion cosmetics with added powder, and it has excellent compatibility between pigment powder and glycerin and water to form smooth covering layer on the surface for covering and masking some facial flaws, such as freckle, acne, scar, etc. Can also adjust the texture, color and luster of the skin, play a role in homogenizing the complexion and make the complexion look natural and close.
Although the traditional foundation liquid formula has good skin feel and good concealing power, the formula is not all natural, but wax, grease, emulsifier, preservative, dispersant and the like from chemical synthetic substances, and the chemical synthetic substances are easy to generate certain adverse effects after being used. For example, conventional foundation solutions contain a relatively large amount of silicone oil, which is easily absorbed by the skin of the user, causing skin aging.
Disclosure of Invention
The application provides a foundation liquid and a preparation method thereof, aiming at solving the problem that the chemical synthetic substances contained in the traditional foundation liquid are easy to cause skin aging.
On one hand, the embodiment of the application provides a foundation solution, which comprises the following components in percentage by mass:
2-8% of a water-in-oil type emulsifier;
32-60% of a water phase;
35-60% of an oil phase;
0.3 to 1 percent of preservative,
wherein the water phase comprises deionized water, a humectant, an antiallergic agent and a thickening agent; the oil phase comprises emollient oil, toner, dispersant and filling powder.
Preferably, the liquid foundation comprises the following components in percentage by mass:
4-6% of a water-in-oil type emulsifier;
40-50% of a water phase;
45-55% of an oil phase;
0.5-0.8% of preservative.
Preferably, the water-in-oil emulsifier comprises a primary emulsifier and a secondary emulsifier, wherein the primary emulsifier comprises polyglycerol-2 dipolyhydroxystearate and/or polyglycerol-3 diisostearate; the auxiliary emulsifier comprises one or more of magnesium stearate, zinc stearate, calcium stearate, aluminum stearate, glyceryl stearate, polyglyceryl-4 isostearate, sorbitan oleate, glyceryl oleate, polyglyceryl-2 caprate oleum Armeniacae amarum polyglycerol-6 esters, polyglyceryl-3 polyricinoleate and polyglyceryl-6 polyricinoleate.
Preferably, the preservative comprises one or more of 1, 2-pentanediol, anisic acid, magnolol, peony root bark extract, and potassium sorbate.
Preferably, the deionized water has a resistivity >1M Ω.
Preferably, the moisturizer comprises one or more of glycerin, 1, 3-butanediol, 1, 2-hexanediol, sodium hyaluronate, tremella polysaccharide, and trehalose;
or the antiallergic agent is one or more of ectoin, bisabolol, herba Portulacae extract, dipotassium glycyrrhizinate, and herba Centellae extract.
Preferably, the thickener comprises one or more of magnesium sulfate heptahydrate, carbomer and xanthan gum.
Preferably, the emollient oil comprises one or more of the plants squalane, jojoba oil, sunflower seed oil, castor oil, meadowfoam seed oil, coconut oil, shea butter, grape seed oil, macadamia nut oil, olive oil, palm oil, and glycolipids;
or the toner comprises one or more of pearl powder, zinc oxide, curcumin, radish red and plant carbon black.
Preferably, the dispersant is one or more of octyldodecanol, caprylic/capric triglyceride, and cocol-caprylic capric triglyceride;
or the filling powder is one or more of mica, corn starch and rice starch.
On the other hand, the embodiment of the application also provides a preparation method of the foundation liquid, which comprises the following steps:
(1) grinding the toner, and adding a dispersing agent for dispersing to obtain color paste;
(2) under the heating condition, mixing deionized water, a humectant, an antiallergic agent and a thickening agent to obtain an aqueous phase mixture;
(3) under the heating condition, mixing the skin moistening grease with the filling powder, and adding the color paste and the water-in-oil type emulsifier under stirring to obtain an oil phase mixture;
(4) mixing the water phase mixture and the oil phase mixture to obtain a mixture;
(5) and after the mixture is cooled, adding a preservative into the mixture, and forming and filling to obtain the liquid foundation.
Compared with the prior art, the invention has the advantages that:
(1) the liquid foundation provided by the invention contains no chemical synthetic substances, cannot cause skin aging, is prepared from natural raw materials (plant sources or mineral sources), has no pollution, contains no heavy metal components, and is safe and healthy.
(2) Compared with the traditional foundation solution containing silicone oil, the foundation solution provided by the invention adopts silicon-free skin moistening grease, so that skin aging is not easy to cause.
(3) Compared with the traditional starch base solution containing the lake, the starch base solution provided by the invention adopts water-soluble plant pigment as the toner, has various colors and does not harm the health of users.
Detailed Description
Embodiments of the present application are described in further detail below with reference to examples. The following detailed description of the embodiments is intended to be illustrative of the principles of the application and is not intended to limit the scope of the application, i.e., the application is not limited to the embodiments described.
For the sake of brevity, only some numerical ranges are explicitly disclosed herein. However, any lower limit may be combined with any upper limit to form ranges not explicitly recited; and any lower limit may be combined with any other lower limit to form a range not explicitly recited, and similarly any upper limit may be combined with any other upper limit to form a range not explicitly recited. Also, although not explicitly recited, each point or individual value between endpoints of a range is encompassed within the range. Thus, each point or individual value may, as its lower or upper limit, be combined with any other point or individual value or with other lower or upper limits to form ranges not explicitly recited.
In the description herein, it is to be noted that, unless otherwise specified, "above" and "below" are inclusive, and "a plurality" of "one or more" means two or more.
The common raw materials of the foundation liquid comprise vaseline, liquid paraffin, lanolin and derivatives thereof, oily raw materials such as vegetable oil, silicone oil and the like, aqueous raw materials such as ethanol, glycerol, propylene glycol and the like, surfactants, powdery raw materials such as talcum powder, titanium dioxide, metal soap and the like, pigments, dyes and the like. The kind and characteristics of the powder raw material, and the uniform dispersion of the powder in the matrix directly affect the cosmetic properties such as hiding power and coloring power.
The liquid foundation contains more powder raw materials, and pores and sweat glands are likely to be blocked. If the quality of the mineral powder and the inorganic pigment is poor, harmful substances such as lead, mercury and arsenic can exceed the standard, so that heavy metal poisoning of a human body is caused, and the human body needs to be cleaned.
The foundation liquid has the advantages that the foundation liquid can decorate skin color for people, and the skin color of the whole face is more uniform and has the color of the air. However, the disadvantages are that the foundation is often relatively dry and may cause dusting if the foundation is not made, the makeup may not only be imperfect but also appear dirty, and the incomplete removal of makeup with the foundation over time may also clog the pores, resulting in large or dark pores. However, if the paste-like foundation is used for a long time, pores can be blocked, the paste-like foundation is difficult to be applied uniformly when being applied in a dry way, and the paste-like foundation is difficult to be removed cleanly when being pressed for a plurality of times during makeup removal.
Foundation make-up liquid
The embodiment of the first aspect of the application provides a foundation solution, which comprises the following components in percentage by mass:
2-8% of a water-in-oil type emulsifier;
32-60% of a water phase;
35-60% of an oil phase;
0.3 to 1 percent of preservative,
wherein the water phase comprises deionized water, a humectant, an antiallergic agent and a thickening agent; the oil phase comprises emollient oil, toner, dispersant and filling powder.
The foundation solution provided by the invention consists of a water-in-oil type emulsifier, a water phase, an oil phase and a preservative, wherein the form of the system is that water is dispersed in oil in the form of micro droplets, and the oil phase is an external phase or a dispersion medium, so that the foundation solution is relatively moist when being used, is favorable for locking and moisturizing the skin, and is particularly suitable for dry skin or being used in autumn and winter.
The foundation liquid of the present invention contains 32 to 60% of an aqueous phase, for example, 32%, 35%, 40%, 45%, 50%, 55%, or 60% of an aqueous phase, and the content of the aqueous phase may be in any combination of the above values.
The high or low viscosity of the water phase is not favorable for the uniform and stable dispersion of the oil phase in the water phase, thereby affecting the appearance and stability of the product and simultaneously affecting the extensibility, uniformity and skin feel of the makeup application of the foundation liquid. The water phase of the invention is added with the thickening agent, so that certain viscosity is ensured in the water phase, the foundation liquid is easier to apply, and the makeup is quick, smooth and uniform. The antiallergic agent in water phase has antiallergic effect, and is especially suitable for people with sensitive muscle. The humectant in the water phase can play a role in moisturizing, so that the problem of powder blocking caused by low moisturizing degree is avoided, and the makeup can be more durable.
The foundation liquid of the present invention contains 35 to 60% of an oil phase, for example, 35%, 40%, 45%, 50%, 55% or 60% of an oil phase, and the content of the oil phase may be in any combination of the above values.
The skin moistening oil contained in the oil phase can play a role in moistening the skin, and the oil phase does not contain silicone oil, so that the skin aging is not easy to cause. The toner contained in the oil phase can play a role in toning, and compared with the traditional lake-containing liquid foundation, the liquid foundation provided by the invention adopts water-soluble plant pigment as the toner, has various colors and does not harm the health of users. The dispersant in the oil phase can disperse the toner more uniformly, prevent precipitation and improve the tinting strength of the liquid foundation, and has the function of moistening the skin.
The liquid foundation of the present invention may further contain 2 to 8% of a water-in-oil emulsifier, for example, the content of the water-in-oil emulsifier is 2%, 3%, 4%, 5%, 6%, 7% and 8%, and the content of the water-in-oil emulsifier may be any combination of the above values.
Water-in-oil emulsifiers are surfactants that stabilize emulsions. Thus, after the emulsifier is added to the oil-water system, the water and oil can be mixed with each other to form a fully dispersed emulsion.
The foundation liquid of the present invention may further contain 0.3 to 1% of a preservative, for example, the content of the preservative is 0.3%, 0.5%, 1%, 2%, and 3%, and the content of the preservative may be any combination of the above values. The preservative can prevent the liquid foundation from being polluted by microorganisms in the process of storage and use.
The liquid foundation provided by the invention contains no chemical synthetic substances, does not cause skin aging, is prepared from natural raw materials (plant sources or mineral sources), has no pollution, contains no heavy metal components, and is safe and healthy.
In the embodiment of the application, in order to further improve the using effect of the foundation liquid, the foundation liquid comprises the following components in percentage by mass:
4-6% of a water-in-oil type emulsifier;
40-50% of a water phase;
45-55% of an oil phase;
0.5-0.8% of preservative.
In an embodiment of the present application, the water-in-oil emulsifier comprises a primary emulsifier and a secondary emulsifier, wherein the primary emulsifier comprises polyglyceryl-2 dipolyhydroxystearate and/or polyglyceryl-3 diisostearate; the auxiliary emulsifier comprises one or more of magnesium stearate, zinc stearate, calcium stearate, aluminum stearate, glyceryl stearate, polyglyceryl-4 isostearate, sorbitan oleate, glyceryl oleate, polyglyceryl-2 caprate oleum Armeniacae amarum polyglycerol-6 esters, polyglyceryl-3 polyricinoleate and polyglyceryl-6 polyricinoleate.
According to the embodiment of the application, the main emulsifier is good in oil-water compatibility and strong in action; the auxiliary emulsifier is used for enhancing the effect of the main emulsifier, and the auxiliary emulsifier and the main emulsifier are matched with each other and cannot be used.
In some embodiments, the mass ratio of the main emulsifier to the auxiliary emulsifier is (3-2): 1. for example, the mass ratio of the primary emulsifier to the co-emulsifier is 3:1, or the mass ratio of the primary emulsifier to the co-emulsifier is 2: 1.
In embodiments of the present application, the preservative comprises one or more of 1, 2-pentanediol, anisic acid, magnolol, peony root bark extract, and potassium sorbate.
According to the embodiment of the application, the preservatives are all plant-derived preservatives, and different from the traditional preservatives, the plant preservative used in the invention can not only prevent the liquid foundation from being polluted by microorganisms in the processes of preservation and use, but also has no harm to human health. The hydroxybenzene methyl ester preservative which is common in the traditional preservatives is one of the reasons for the high incidence of female diseases such as breast cancer, uterine diseases and the like for women; for men, it can inhibit male hormone induced infertility.
In an embodiment of the present application, the deionized water has a resistivity >1M Ω.
According to the embodiment of the application, the conductivity of the deionized water in the water phase is selected to be more than 1M omega cm, so that the condition that the viscosity of the system is influenced by ions in the system can be avoided.
In embodiments herein, the humectant comprises one or more of glycerin, 1, 3-butanediol, 1, 2-hexanediol, sodium hyaluronate, tremella polysaccharide, and trehalose; or the antiallergic agent is one or more of ectoin, bisabolol, herba Portulacae extract, dipotassium glycyrrhizinate, and herba Centellae extract.
According to the embodiment of the application, the moisturizing agent is a natural-source moisturizing agent, so that the moisturizing effect can be achieved, the powder blocking problem caused by low moistening degree can be avoided, the makeup can be more durable, and the natural-source moisturizing agent cannot cause harm to skin or body health.
The antiallergic agent is natural antiallergic material, not only can play an antiallergic role, but also can not cause harm to skin or body health.
In embodiments of the present application, the thickener comprises one or more of magnesium sulfate heptahydrate, carbomer, and xanthan gum.
According to the embodiment of the application, the thickening agent is a natural thickening agent, so that a certain viscosity in a water phase can be ensured, the foundation liquid is easier to apply, the makeup is quick, smooth and uniform, and the natural thickening agent cannot cause harm to skin or body health.
In embodiments of the present application, the emollient oils include one or more of the plants squalane, jojoba oil, sunflower seed oil, castor oil, meadowfoam seed oil, coconut oil, shea butter, grape seed oil, macadamia nut oil, olive oil, palm oil, and glycolipids; or the toner comprises one or more of pearl powder, zinc oxide, curcumin, radish red and plant carbon black.
According to the embodiment of the application, the skin moistening oil is of a natural source, so that the effect of moistening the skin can be achieved, and the skin moistening oil of the natural source cannot cause harm to the skin or the health of a human body. In addition, compared with the traditional foundation solution containing silicone oil, the foundation solution provided by the invention adopts silicon-free skin moistening grease, so that skin aging is not easy to cause. The toner is water-soluble plant pigment, has various colors, and does not harm the health of users.
In embodiments herein, the dispersant is one or more of octyldodecanol, caprylic/capric triglyceride, and coco-caprylic capric triglyceride; or the filling powder is one or more of mica, corn starch and rice starch.
According to the embodiment of the application, the dispersing agent and the filling powder are both natural sources and do not harm the health of users.
The natural source foundation liquid (natural definition is plant source or mineral source) provided by the invention not only uses silicon-free skin moistening grease, but also has the significance of safe and environment-friendly product and sustainable development due to the components of the plant and mineral sources, and meets the current requirements of consumers and the trend of 'pure beauty cosmetics' in the market.
Preparation method of foundation liquid
A second aspect of the present application provides a method for preparing a liquid foundation, comprising the steps of:
(1) grinding the toner, and adding a dispersing agent for dispersing to obtain color paste;
(2) under the heating condition, mixing deionized water, a humectant, an antiallergic agent and a thickening agent to obtain an aqueous phase mixture;
(3) under the heating condition, mixing the skin moistening grease with the filling powder, and adding the color paste and the water-in-oil type emulsifier under stirring to obtain an oil phase mixture;
(4) mixing the water phase mixture and the oil phase mixture to obtain a mixture;
(5) and after the mixture is cooled, adding a preservative into the mixture, and forming and filling to obtain the liquid foundation.
In the embodiment of the application, the grinding in the step (1) is specifically grinding at 2000RPM (r/min) for 5min, which can ensure that the identities are fully and uniformly dispersed.
In some embodiments, the heating temperature in step (2) is 70-80 ℃. The components in the water phase can be mixed more uniformly at the temperature.
In some embodiments, the heating temperature in step (3) is 70-80 ℃, the stirring speed is 4000-.
In some embodiments, in step (4), the water phase mixture and the oil phase mixture are mixed and then stirred homogeneously at 4000-.
The preparation method of the foundation liquid provided by the embodiment of the application has simple steps, and the prepared foundation liquid is stable in system and good in effect.
Examples
The present disclosure is more particularly described in the following examples that are intended as illustrative only, since various modifications and changes within the scope of the present disclosure will be apparent to those skilled in the art. Unless otherwise indicated, all parts, percentages, and ratios reported in the following examples are on a weight basis, and all reagents used in the examples are commercially available or synthesized according to conventional methods and can be used directly without further treatment, and the equipment used in the examples is commercially available.
Example 1
The foundation solution provided by the embodiment comprises the following components in percentage by mass:
the emulsifier comprises: 1) 2% of primary emulsifier polyglycerol-2 dipolyhydroxystearate; 2% of polyglycerol-3 diisostearate; 2) 1% of sorbitan isostearate serving as a co-emulsifier; sorbitan oleate 1%
The aqueous phase comprises: 1) 2% of humectant glycerin, 1% of 1, 2-hexanediol, 2% of 1, 2-pentanediol, 1% of bisabolol, 0.1% of ectoin, 0.1% of sodium hyaluronate, 0.7% of magnesium sulfate heptahydrate and 36.38% of deionized water;
the oil phase comprises: 1) color powders: 8% of zinc oxide, 3% of pearl powder, 0.6% of curcumin, 0.09% of radish red and 0.03% of plant carbon black; 2) dispersing agent: 4% of octyl dodecanol, 1% of caprylic/capric triglyceride and 1% of coco-caprylic/capric triglyceride; 3) filling powder: 1% of mica; 4) skin-moistening oil: 10% of octyl dodecanol, 8% of plant squalane, 5% of jojoba oil, 3% of sunflower seed oil, 3% of castor oil and 2% of white chinlon oil;
the preservative comprises: 0.5 percent of 1, 2-pentanediol, 0.3 percent of potassium sorbate and 0.2 percent of anisic acid.
The preparation method of the foundation solution provided by the embodiment comprises the following steps:
(1) dispersing toner:
firstly, mixing and grinding oil color powder for 5min at the rotating speed of 2000RPM (r/min), and then sequentially adding a dispersing agent for artificial stirring and dispersion to obtain the color paste for standby;
(2) preparation of oil and water phases:
sequentially adding the water phase components, stirring, and keeping the temperature at 70-80 deg.C;
sequentially adding the oil phase components, heating to 70-80 ℃, homogenizing and stirring, adding the color paste obtained in the step (1) at the rotation speed of 4000-;
(3) slowly adding the water phase into the oil phase, and homogenizing and stirring at 4000-;
(4) cooling to room temperature, adding antiseptic, molding, and packaging.
Example 2
The foundation solution provided by the embodiment comprises the following components in percentage by mass:
the emulsifier comprises: 1) 6% of primary emulsifier polyglycerol-2 dipolyhydroxystearate; 2) 1% of sorbitan isostearate serving as a co-emulsifier; sorbitan oleate 1%
The aqueous phase comprises: 1) 4% of humectant glycerin, 1% of bisabolol, 0.4% of sodium hyaluronate, 0.7% of magnesium sulfate heptahydrate and 38.18% of deionized water;
the oil phase comprises: 1) color powders: 8% of zinc oxide, 3% of pearl powder, 0.6% of curcumin, 0.09% of radish red and 0.03% of plant carbon black; 2) dispersing agent: 4% of octyl dodecanol, 1% of caprylic/capric triglyceride and 1% of coco-caprylic/capric triglyceride; 3) filling powder: 1% of mica; 4) skin-moisturizing grease: 15% of octyl dodecanol, 5% of plant squalane, 5% of jojoba oil and 3% of sunflower seed oil;
the preservative comprises: 0.5 percent of 1, 2-pentanediol, 0.3 percent of potassium sorbate and 0.2 percent of anisic acid.
The method for preparing the foundation solution provided in this example is the same as in example 1.
Example 3
The foundation solution provided by the embodiment comprises the following components in percentage by mass:
the emulsifier comprises: 1) 6% of primary emulsifier polyglycerol-3 diisostearate; 2) 1% of sorbitan isostearate serving as a co-emulsifier; sorbitan oleate 1%
The aqueous phase comprises: 1) 4% of humectant glycerin, 1% of bisabolol, 0.1% of ectoin, 0.1% of sodium hyaluronate, 0.7% of magnesium sulfate heptahydrate and 33.38% of deionized water;
the oil phase comprises: 1) color powders: 8% of zinc oxide, 3% of pearl powder, 0.6% of curcumin, 0.09% of radish red and 0.03% of plant carbon black; 2) dispersing agent: 4% of octyl dodecanol, 1% of caprylic/capric triglyceride and 1% of coco-caprylic/capric triglyceride; 3) filling powder: 1% of mica; 4) skin-moisturizing grease: 10% of octyl dodecanol, 10% of plant squalane, 8% of jojoba oil and 5% of white chinlon oil;
the preservative comprises: 0.5 percent of 1, 2-pentanediol, 0.3 percent of potassium sorbate and 0.2 percent of anisic acid.
The method for preparing the foundation solution provided in this example is the same as in example 1.
Example 4
The foundation solution provided by the embodiment comprises the following components in percentage by mass:
the emulsifier comprises: 1) 2% of primary emulsifier polyglycerol-2 dipolyhydroxystearate; 2% of polyglycerol-3 diisostearate; 2) 1% of sorbitan isostearate serving as a co-emulsifier; sorbitan oleate 1%
The aqueous phase comprises: 1) 4% of humectant glycerin, 1% of bisabolol, 0.4% of ectoin, 0.4% of sodium hyaluronate, 0.4% of xanthan gum and 39.58% of deionized water;
the oil phase comprises: 1) color powders: 8% of zinc oxide, 3% of pearl powder, 0.6% of curcumin, 0.09% of radish red and 0.03% of plant carbon black; 2) dispersing agent: octyl dodecanol 4%, caprylic/capric triglyceride 1%, cocol-caprylic capric triglyceride 1%; 3) filling powder: 1.5% of corn starch; 4) skin-moisturizing grease: 20% of octyl dodecanol, 5% of jojoba oil and 3% of sunflower seed oil;
the preservative comprises: 0.5 percent of 1, 2-pentanediol, 0.3 percent of potassium sorbate and 0.2 percent of anisic acid.
The method for preparing the foundation solution provided in this example is the same as in example 1.
Example 5
The foundation solution provided by the embodiment comprises the following components in percentage by mass:
the emulsifier comprises: 1) 2% of primary emulsifier polyglycerol-2 dipolyhydroxystearate; 2% of polyglycerol-3 diisostearate; 2) 1% of sorbitan isostearate serving as a co-emulsifier; sorbitan oleate 1%
The aqueous phase comprises: 1) 4% of humectant glycerin, 1.5% of bisabolol, 0.1% of ectoin, 0.1% of sodium hyaluronate, 0.4% of xanthan gum and 39.68% of deionized water;
the oil phase comprises: 1) color powders: 8% of zinc oxide, 3% of pearl powder, 0.6% of curcumin, 0.09% of radish red and 0.03% of plant carbon black; 2) dispersing agent: 4% of octyl dodecanol, 1% of caprylic/capric triglyceride and 1% of coco-caprylic/capric triglyceride; 3) filling powder: 1.5% of rice starch; 4) skin-moisturizing grease: 20% of octyl dodecanol, 5% of jojoba oil and 3% of sunflower seed oil;
the preservative comprises: composition of 0.5% of 1, 2-pentanediol, 0.3% of potassium sorbate and 0.2% of anisic acid the foundation solution provided in this example was prepared in the same manner as in example 1.
Example 6
The foundation solution provided by the embodiment comprises the following components in percentage by mass:
the emulsifier comprises: 1) 4% of primary emulsifier polyglycerol-2 dipolyhydroxystearate; 2) 2% of sorbitan isostearate serving as a co-emulsifier; sorbitan oleate 2%
The aqueous phase comprises: 1) 2% of humectant glycerin, 1.5% of bisabolol, 0.4% of ectoin, 0.1% of sodium hyaluronate, 0.2% of carbomer and 38.08% of deionized water;
the oil phase comprises: 1) color powders: 8% of zinc oxide, 3% of pearl powder, 0.6% of curcumin, 0.09% of radish red and 0.03% of plant carbon black; 2) dispersing agent: octyl dodecanol 4%, caprylic/capric triglyceride 1%, cocol-caprylic capric triglyceride 1%; 3) filling powder: 1% of mica; 4) skin-moisturizing grease: 10% of octyl dodecanol, 8% of plant squalane, 5% of jojoba oil, 3% of sunflower seed oil, 3% of castor oil and 2% of white chinlon oil;
the preservative comprises: composition of 0.5% of 1, 2-pentanediol, 0.3% of potassium sorbate and 0.2% of anisic acid the foundation solution provided in this example was prepared in the same manner as in example 1.
Example 7
The foundation solution provided by the embodiment comprises the following components in percentage by mass:
the emulsifier comprises: 1) 4% of a main emulsifier polyglycerol-3 diisostearate; 2) 2% of sorbitan isostearate serving as a co-emulsifier; sorbitan oleate 2%
The aqueous phase comprises: 1) 2% of humectant glycerin, 0.4% of ectoin, 0.1% of sodium hyaluronate, 0.2% of carbomer and 39.58% of deionized water;
the oil phase comprises: 1) color powders: 8% of zinc oxide, 3% of pearl powder, 0.6% of curcumin, 0.09% of radish red and 0.03% of plant carbon black; 2) dispersing agent: 4% of octyl dodecanol, 1% of caprylic/capric triglyceride and 1% of coco-caprylic/capric triglyceride; 3) filling powder: 1% of mica; 4) skin-moisturizing grease: 10% of octyl dodecanol, 8% of plant squalane, 5% of jojoba oil, 3% of sunflower seed oil, 3% of castor oil and 2% of white chinlon oil;
the preservative comprises: composition of 0.5% of 1, 2-pentanediol, 0.3% of potassium sorbate and 0.2% of anisic acid the foundation solution provided in this example was prepared in the same manner as in example 1.
Performance testing
1. Stability test
Different emulsifier combinations may result in different stabilities, and stability tests in cosmetics include cold, heat and centrifuge tests.
(1) Cold and heat resistance test:
in order to keep the stable performance, no physical and chemical change, no oil leakage, water separation, coarse grain, emulsion breaking and other phenomena of the product in the storage and use processes, the formula is subjected to high-temperature and low-temperature storage stability tests.
The laboratory high-temperature and low-temperature storage stability test can be carried out by adopting the following method:
1) placing in an electric heating constant temperature incubator at 40-50 deg.C for 30-50 days, and observing after recovering room temperature;
2) repeatedly changing at 0-50 deg.C within 24h for 15-30 days, and observing after recovering room temperature;
3) storing at-5 deg.C and 40 deg.C for 3 times, respectively, each time for 24 hr, storing at-5 deg.C for 24 hr, storing at room temperature for 24 hr, storing in 40 deg.C thermostat for 24 hr, sequentially circulating for 3 times, and observing its stability;
4) the stability was observed after storage at-5 ℃ for 1 week.
(2) And (3) centrifugal test:
the centrifugal test is a test for testing the shelf life of emulsion cosmetics and is a necessary test method for an accelerated separation test, the foundation fluid is one kind of emulsion, and the detection method is as follows: the sample is placed in a centrifuge, and after the sample is tested for 30min at the rotating speed of (2000) -4000 RPM, the separation and delamination conditions of the product are observed. The results are shown in Table 1.
Table 1 stability test results for samples in the examples
Sample (I) Cold-resistant Heat resistance Centrifugation
Example 1 Stabilization of Stabilization Without separation or stratification
Example 2 Stabilization Stabilization Without separation and delamination
Example 3 Stabilization of Stabilization Without separation and delamination
Example 4 Stabilization of Stabilization Without separation and delamination
Example 5 Stabilization Stabilization Without separation and delamination
Example 6 Stabilization Stabilization of Without separation and delamination
Example 7 Stabilization Stabilization Without separation and delamination
(3) Patch test
For sensitive skin, the selection of foundation liquid is very careful, and the patent components of the invention are natural, mild and environment-friendly; in particular, the anti-allergy components such as ectoin and bisabolol are also added into the formula.
The patch test is suitable for detecting potential adverse reactions of the cosmetic product to human skin; the purpose is to detect the potential possibility of the test substance causing the adverse reaction of human skin.
Selection of subjects:
1) volunteers from 18 to 60 years old who meet the requirements of the test are selected as subjects.
2) The subject was not selected as the one having the following condition
3) Those who use antihistamines for nearly one week or immunosuppressants for nearly one month;
4) in the last two months, any anti-inflammatory drug is applied to the tested part;
5) the subject has a clinically unvulcanized inflammatory skin condition;
6) insulin-dependent diabetic patients;
7) patients suffering from asthma or other chronic respiratory diseases undergoing treatment;
8) those receiving anti-cancer chemotherapy within approximately 6 months;
9) patients with immunodeficiency or autoimmune disease;
10) lactating or pregnant women;
11) bilateral mastectomy and bilateral underarm lymph node resection;
11) the judgment of the test result is influenced by scars, pigments, atrophy, port wine stains or other flaws on the skin to be tested;
12) participation in other clinical trial investigators;
13) those with high constitutional sensitivity;
14) non-volunteer participants or those who cannot complete the prescribed content as required by the trial.
The detection method comprises the following steps:
the method comprises the following steps: skin seal patch test
1) At least 30 individuals were selected for the trial based on the subject inclusion criteria.
2) The qualified spot test device with the area not more than 50mm2 and the depth of about 1mm is selected. The test substance is placed in the chamber of the plaque tester in an amount of about 0.020g to about 0.025g (solid or semi-solid) or about 0.020mL to about 0.025mL (liquid). When the test substance is the original cosmetic product, the control hole is blank control (no substance is placed), and when the test substance is diluted cosmetic, the diluent of the cosmetic is used in the control hole. The patch test device with the test substance is applied to the back or forearm curvature of the subject with hypoallergenic tape, and is applied to the skin uniformly by pressing with palm for 24 h.
3) The skin reaction was observed according to the second standard of table 30min (after the indentation disappeared), 24h and 48h after the test article plaque removal, respectively, and the observation results were recorded, and the results are shown in table 1.
TABLE 2 skin response grading Standard for skin Enclosed Patch test
Figure BDA0003599352980000131
The skin patch test was performed on seven samples of the examples by 30 support experimenters, and the results are shown in table 3:
table 3 skin seal patch test results
Sample (I) Skin reactions
Example 1 28 people-, 2 people ± -2
Example 2 28 people-, 2 people ± -2
Example 3 29 people-, 1 person ± -1
Example 4 29-man-, 1-man ±)
Example 5 30 people-
Example 6 30 people-
Example 7 25 persons-, 5 persons ± -2
As can be seen from table 3, examples 5 and 6 are the least irritating, almost non-irritating, and example 7 is relatively more irritating; probably as a result of the relatively large amount of bisabolol in examples 5 and 6, whereas example 7 did not contain bisabolol.
The second method comprises the following steps: repetitive open smear test
1) At least 30 individuals were selected for the trial based on the subject inclusion criteria.
2) The area of the forearm flexor is 3X 3cm2, and the test part should be kept dry to avoid contact with other external preparations.
3) About 0.0500.005 g (mL)/test substance was applied to the test site evenly 2 times a day for 7 consecutive days, and the skin reaction was observed, during which time if 3 minutes or more of the skin reaction occurred, it was decided whether to continue the test or not, depending on the case.
4) Skin reactions were observed according to the skin reaction evaluation criteria for the four-fold open smear test shown in table 4, and the results were recorded.
Table 4 skin reaction judgment standard table for skin repetitive open type smearing test
Figure BDA0003599352980000141
Figure BDA0003599352980000151
The results of repeated open-type skin smearing tests on seven samples from the examples were obtained by selecting 30 support experimenters and are shown in table 5:
TABLE 5 skin repetitive open smear test results
Sample (I) Skin reactions
Example 1 Negative reaction in 29 persons, faint erythema in 1 person
Example 2 Negative reaction in 28 persons, faint erythema in 2 persons
Example 3 Negative reaction in 28 persons, faint erythema in 2 persons
Example 4 Negative reaction in 29 persons, faint erythema in 1 person
Example 5 Negative reaction of 30 persons
Example 6 Negative reaction of 30 persons
Example 7 Negative reaction in 27 persons, weak erythema in 2 persons, dryness in 1 person
The results of table 5 show that the samples of example 5 and example 6 are almost non-irritating, while the samples of example 7 are relatively more irritating, and the irritation safety is not as good as that of example 5 and example 6 due to the relatively large contents of bisabolol and ectoine in example 5 and example 6, while the samples of example 7 contain only ectoine.
While the present application has been described with reference to preferred embodiments, various modifications may be made and equivalents may be substituted for elements thereof without departing from the scope of the present application, and in particular, features shown in the various embodiments may be combined in any manner as long as there is no structural conflict. The present application is not intended to be limited to the particular embodiments disclosed herein but is to cover all embodiments that may fall within the scope of the appended claims.

Claims (10)

1. The foundation solution is characterized by comprising the following components in percentage by mass:
2-8% of a water-in-oil type emulsifier;
32-60% of a water phase;
35-60% of an oil phase;
0.3 to 1 percent of preservative,
wherein the water phase comprises deionized water, a humectant, an antiallergic agent and a thickening agent; the oil phase comprises emollient grease, toner, a dispersant and filling powder.
2. The foundation solution of claim 1, which comprises the following components in percentage by mass:
4-6% of a water-in-oil type emulsifier;
40-50% of a water phase;
45-55% of an oil phase;
0.5-0.8% of preservative.
3. The liquid foundation of claim 1, wherein the water-in-oil emulsifier comprises a primary emulsifier and a secondary emulsifier,
wherein the main emulsifier comprises polyglycerol-2 dipolyhydroxystearate and/or polyglycerol-3 diisostearate; the auxiliary emulsifier comprises one or more of magnesium stearate, zinc stearate, calcium stearate, aluminum stearate, glyceryl stearate, polyglyceryl-4 isostearate, sorbitan oleate, glyceryl oleate, polyglyceryl-2 caprate oleum Armeniacae amarum polyglycerol-6 esters, polyglyceryl-3 polyricinoleate and polyglyceryl-6 polyricinoleate.
4. The foundation of claim 1, wherein the preservative comprises one or more of 1, 2-pentanediol, anisic acid, magnolol, peony root bark extract, and potassium sorbate.
5. The foundation liquid of claim 1, wherein the deionized water has a resistivity >1M Ω.
6. The foundation solution of claim 1, wherein the humectant comprises one or more of glycerin, 1, 3-butylene glycol, 1, 2-hexylene glycol, sodium hyaluronate, tremella polysaccharide, and trehalose;
or the antiallergic agent is one or more of ectoin, bisabolol, herba Portulacae extract, dipotassium glycyrrhizinate, and herba Centellae extract.
7. The foundation solution of claim 1, wherein the thickener comprises one or more of magnesium sulfate heptahydrate, carbomer, and xanthan gum.
8. The liquid foundation of claim 1, wherein the emollient oils comprise one or more of the plants squalane, jojoba oil, sunflower seed oil, castor oil, meadowfoam seed oil, coconut oil, shea butter, grape seed oil, macadamia nut oil, olive oil, palm oil, and glycolipids;
or the toner comprises one or more of pearl powder, zinc oxide, curcumin, radish red and plant carbon black.
9. The foundation of claim 1 wherein the dispersant is one or more of octyldodecanol, caprylic/capric triglyceride, and coco-caprylic capric triglyceride;
or the filling powder is one or more of mica, corn starch and rice starch.
10. The preparation method of the foundation liquid is characterized by comprising the following steps:
(1) grinding the toner, and adding a dispersing agent for dispersing to obtain color paste;
(2) under the heating condition, mixing deionized water, a humectant, an antiallergic agent and a thickening agent to obtain an aqueous phase mixture;
(3) under the heating condition, mixing the skin moistening grease with the filling powder, and adding the color paste and the water-in-oil type emulsifier under stirring to obtain an oil phase mixture;
(4) mixing the water phase mixture and the oil phase mixture to obtain a mixture;
(5) and after the mixture is cooled, adding a preservative into the mixture, and forming and filling to obtain the liquid foundation.
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Publication number Priority date Publication date Assignee Title
CN115068399A (en) * 2022-07-22 2022-09-20 上海臻臣化妆品有限公司 Pure natural makeup pre-emulsion and preparation method thereof
CN115227604A (en) * 2022-08-19 2022-10-25 广州东耀化妆品有限公司 Foundation make-up solution with function of improving dispersion of vegetable oil
CN115252516A (en) * 2022-07-25 2022-11-01 上海臻臣化妆品有限公司 Water-feeling blush and preparation method thereof
CN115634185A (en) * 2022-10-31 2023-01-24 苏州安特化妆品股份有限公司 Long-acting make-up-holding oil-controlling plant powder and preparation process thereof
CN115737513A (en) * 2022-11-20 2023-03-07 天津郁美净集团有限公司 Composition with relieving effect, foundation liquid and preparation method

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CN113940899A (en) * 2021-09-29 2022-01-18 广州卓芬化妆品有限公司 Waterproof foundation composition and preparation method thereof
CN114224753A (en) * 2021-12-31 2022-03-25 广东柏俐臣生物科技有限公司 Water-in-oil type emulsified composition, foundation liquid and preparation method thereof
KR20220042013A (en) * 2020-09-25 2022-04-04 주식회사 코스메카코리아 water-in-oil type cosmetic composition and manufacturing method of the same

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CN110876688A (en) * 2019-12-12 2020-03-13 广州丽丰化妆品制造有限公司 Moisturizing and wrinkle-removing foundation and preparation method thereof
KR20220042013A (en) * 2020-09-25 2022-04-04 주식회사 코스메카코리아 water-in-oil type cosmetic composition and manufacturing method of the same
CN113940899A (en) * 2021-09-29 2022-01-18 广州卓芬化妆品有限公司 Waterproof foundation composition and preparation method thereof
CN114224753A (en) * 2021-12-31 2022-03-25 广东柏俐臣生物科技有限公司 Water-in-oil type emulsified composition, foundation liquid and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115068399A (en) * 2022-07-22 2022-09-20 上海臻臣化妆品有限公司 Pure natural makeup pre-emulsion and preparation method thereof
CN115252516A (en) * 2022-07-25 2022-11-01 上海臻臣化妆品有限公司 Water-feeling blush and preparation method thereof
CN115227604A (en) * 2022-08-19 2022-10-25 广州东耀化妆品有限公司 Foundation make-up solution with function of improving dispersion of vegetable oil
CN115634185A (en) * 2022-10-31 2023-01-24 苏州安特化妆品股份有限公司 Long-acting make-up-holding oil-controlling plant powder and preparation process thereof
CN115737513A (en) * 2022-11-20 2023-03-07 天津郁美净集团有限公司 Composition with relieving effect, foundation liquid and preparation method

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