CN115568468B - Synergistic composition containing eugenol for controlling papaya aphids - Google Patents
Synergistic composition containing eugenol for controlling papaya aphids Download PDFInfo
- Publication number
- CN115568468B CN115568468B CN202210390303.3A CN202210390303A CN115568468B CN 115568468 B CN115568468 B CN 115568468B CN 202210390303 A CN202210390303 A CN 202210390303A CN 115568468 B CN115568468 B CN 115568468B
- Authority
- CN
- China
- Prior art keywords
- eugenol
- aphids
- papaya
- synergistic composition
- thiacloprid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 title claims abstract description 110
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 title claims abstract description 55
- 239000005770 Eugenol Substances 0.000 title claims abstract description 55
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 title claims abstract description 55
- 229960002217 eugenol Drugs 0.000 title claims abstract description 55
- 241000219173 Carica Species 0.000 title claims abstract description 25
- 235000009467 Carica papaya Nutrition 0.000 title claims abstract description 24
- 241001124076 Aphididae Species 0.000 title claims abstract description 23
- 230000002195 synergetic effect Effects 0.000 title claims abstract description 22
- 239000000203 mixture Substances 0.000 title claims abstract description 19
- 239000004593 Epoxy Substances 0.000 claims abstract description 10
- 238000013329 compounding Methods 0.000 claims description 3
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 abstract description 31
- 239000005940 Thiacloprid Substances 0.000 abstract description 25
- HOKKPVIRMVDYPB-UVTDQMKNSA-N (Z)-thiacloprid Chemical compound C1=NC(Cl)=CC=C1CN1C(=N/C#N)/SCC1 HOKKPVIRMVDYPB-UVTDQMKNSA-N 0.000 abstract description 24
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 abstract description 16
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 abstract description 16
- 230000004071 biological effect Effects 0.000 abstract description 11
- 239000000575 pesticide Substances 0.000 abstract description 9
- 239000013043 chemical agent Substances 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 7
- 239000005906 Imidacloprid Substances 0.000 abstract description 4
- 229940056881 imidacloprid Drugs 0.000 abstract description 4
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 abstract description 4
- 206010059866 Drug resistance Diseases 0.000 abstract description 3
- 239000000447 pesticide residue Substances 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000003814 drug Substances 0.000 description 11
- 241001600408 Aphis gossypii Species 0.000 description 10
- 241000238631 Hexapoda Species 0.000 description 8
- 241000700605 Viruses Species 0.000 description 7
- 231100000419 toxicity Toxicity 0.000 description 7
- 230000001988 toxicity Effects 0.000 description 7
- 241000196324 Embryophyta Species 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000000341 volatile oil Substances 0.000 description 5
- 241001600407 Aphis <genus> Species 0.000 description 3
- 235000017784 Mespilus germanica Nutrition 0.000 description 3
- 244000182216 Mimusops elengi Species 0.000 description 3
- 235000000560 Mimusops elengi Nutrition 0.000 description 3
- 235000007837 Vangueria infausta Nutrition 0.000 description 3
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- 239000005937 Tebufenozide Substances 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000010413 mother solution Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QYPNKSZPJQQLRK-UHFFFAOYSA-N tebufenozide Chemical compound C1=CC(CC)=CC=C1C(=O)NN(C(C)(C)C)C(=O)C1=CC(C)=CC(C)=C1 QYPNKSZPJQQLRK-UHFFFAOYSA-N 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- WUOACPNHFRMFPN-SECBINFHSA-N (S)-(-)-alpha-terpineol Chemical compound CC1=CC[C@@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-SECBINFHSA-N 0.000 description 1
- UEQZFAGVRGWPDK-UHFFFAOYSA-N 1-[(6-chloropyridin-3-yl)methyl]-4,5-dihydroimidazol-2-amine Chemical compound C1=NC(Cl)=CC=C1CN1C(=N)NCC1 UEQZFAGVRGWPDK-UHFFFAOYSA-N 0.000 description 1
- 108091006112 ATPases Proteins 0.000 description 1
- 102000012440 Acetylcholinesterase Human genes 0.000 description 1
- 108010022752 Acetylcholinesterase Proteins 0.000 description 1
- 102000057290 Adenosine Triphosphatases Human genes 0.000 description 1
- 235000015001 Cucumis melo var inodorus Nutrition 0.000 description 1
- 240000002495 Cucumis melo var. inodorus Species 0.000 description 1
- 208000035240 Disease Resistance Diseases 0.000 description 1
- 241000721621 Myzus persicae Species 0.000 description 1
- 229940022698 acetylcholinesterase Drugs 0.000 description 1
- OVKDFILSBMEKLT-UHFFFAOYSA-N alpha-Terpineol Natural products CC(=C)C1(O)CCC(C)=CC1 OVKDFILSBMEKLT-UHFFFAOYSA-N 0.000 description 1
- 229940088601 alpha-terpineol Drugs 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000010630 cinnamon oil Substances 0.000 description 1
- 239000010632 citronella oil Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- -1 guanidine pentose Chemical class 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000012194 insect media Substances 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 230000009916 joint effect Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 229930000044 secondary metabolite Natural products 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
- A01N31/16—Oxygen or sulfur directly attached to an aromatic ring system with two or more oxygen or sulfur atoms directly attached to the same aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to the technical field of pesticides, in particular to a synergistic composition containing eugenol for controlling papaya aphids. The effective component of the synergistic composition is compounded by eugenol and thiacloprid, epoxy imidacloprid or pendipyryl guanidine. The synergistic composition of the invention has obvious synergistic effect when two effective components are compounded, and can improve the control effect on papaya aphids, thereby reducing the pesticide application amount, reducing the pesticide residue and relieving the environmental pressure; and simultaneously, the drug resistance risk brought by using a single chemical agent can be reduced. In addition, the synergistic composition has good biological activity on papaya aphids, and can provide support for developing novel chemical agents for preventing and controlling the papaya aphids.
Description
Technical Field
The invention relates to the technical field of pesticides, in particular to a synergistic composition containing eugenol for controlling papaya aphids.
Background
Aphids are one of the main insect media of papaya ringspot mosaic disease, and mainly consist of myzus persicae and cotton aphids; adults and nymphs of aphids ingest the juice of young leaves of the young buds, causing new She Zhousu and tortuosity, the honeydew that they discharge can cause soot disease; more serious, the disease of the papaya ringspot mosaic virus can be transmitted, and the pathogenic virus of the papaya ringspot mosaic virus is sucked into aphids along with juice, so that the aphids become the aphids with viruses, and when the aphids with viruses are removed from healthy plants, the viruses are transmitted to the healthy plants, and the loss caused by the transmitted viruses is far more serious than the direct damage of the aphids. The chemical agent is one of the most common means for preventing and controlling papaya aphids, but long-term application of a single chemical agent easily causes drug resistance of pests, and simultaneously causes a plurality of problems such as pesticide residues, environmental pollution and the like.
Essential oil is an important secondary metabolite existing in different tissues of plants, and has the effects of fumigating, contact killing, inhibiting feeding and preventing growth and development of insects. Eugenol, chemical name 4-allyl-2-methoxyphenol, chemical formula C 10 H 12 O 2 Is an important component of many essential oils. The biological activity of four plant essential oil components such as eugenol, cinnamon oil, citronella oil and alpha-terpineol on the cotton aphid of medlar has been studied, and the results show that the eugenol has the strongest poisoning effect on the cotton aphid of medlar among the four plant essential oil components, and the plant essential oil components have the inhibition effect on the acetylcholinesterase and the ATPase activity of the cotton aphid of medlar.
The compounding of pesticide active ingredients with different action mechanisms is an effective and quick way for developing new pesticide products and preventing and controlling pest and disease resistance at present. After the different pesticide active ingredients are compounded, three action types are shown: additive action, synergistic action and antagonistic action. The inventor discovers that eugenol and thiacloprid, epoxy imidacloprid or pendipyr have synergistic effect on papaya aphids when being compounded within a certain mass ratio range through a large number of indoor biological activity tests, and no report of related compounding is found at present.
Disclosure of Invention
The invention aims to provide a synergistic composition containing eugenol for preventing and controlling papaya aphids, which solves the problem of long-term use of a single chemical agent.
In order to achieve the above purpose, the present invention provides the following technical solutions:
the effective component of the synergistic composition is compounded by eugenol and thiacloprid, epoxy imidacloprid or pendipyryl guanidine.
Preferably, the mass ratio of eugenol to thiacloprid is 1-30:30-1;
preferably, the mass ratio of eugenol to epoxy insect is 1-15:40-1;
preferably, the mass ratio of eugenol to pentosan guanidine is 1-9:9-1.
Compared with the prior art, the invention has the following beneficial effects:
(1) The synergistic composition of the invention has obvious synergistic effect when two effective components are compounded, and can improve the control effect on papaya aphids, thereby reducing the pesticide application amount, reducing the pesticide residue and relieving the environmental pressure; and simultaneously, the drug resistance risk brought by using a single chemical agent can be reduced.
(2) The synergistic composition has good biological activity on papaya aphids, and can provide support for developing novel chemical agents for preventing and controlling the papaya aphids.
Detailed Description
The following description of the embodiments of the present invention will be apparent from, and is intended to provide a thorough description of, the embodiments of the present invention, and not a complete description of, the embodiments of the present invention. All other embodiments, which can be made by those skilled in the art based on the embodiments of the present invention without making any inventive effort, are intended to fall within the scope of the present invention.
Examples: indoor Activity test in eugenol Complex
Test agent: 99% eugenol original medicine, 98% thiacloprid original medicine, 95% epoxy imidacloprid original medicine and 96% imidacloprid guanidine original medicine;
test aphids: cotton aphids collected from papaya plants are raised in a laboratory;
test method (refer to NT/T1154.6-2006 pesticide indoor determination test criteria pesticide 6 th part: insecticidal Activity test method for soaking insects)
1. Preparing a single-dose mother solution from raw medicines, setting a plurality of groups of proportions, and preparing 7 gradient mass concentrations of the single-dose mother solution and each group of proportions of the mixture by using a 0.1% Tween-80 solution according to an equal ratio, wherein each mass concentration is 50mL;
2. soaking cotton aphid nymphs in the same age into the liquid medicine for 10s, sucking redundant liquid medicine by using filter paper, and transferring to normal conditions for continuous feeding; repeating each treatment for 4 times, soaking 20 heads each time, and setting treatment without medicament as blank control;
3.24h later, checking the death condition of the tested aphids, respectively recording the total number of insects and the death number of insects, calculating the corrected death rate of each treatment, carrying out treatment analysis on the test data by DPS software, and calculating the LC of each medicament 50 And the co-toxicity coefficient (CTC value) of the mixture was calculated according to the grand cloud Pei method.
P 1 = (K/N) ×100, where P 1 Mortality (%), K is the number of dead insects, N is the total number of insects treated;
P 2 ＝(P t －P 0 )/(1－P 0 ) Wherein P is 2 To correct mortality (%), P t To treat mortality (%), P 0 Mortality (%) for the blank control;
measured virulence index (ATI) = (standard agent LC 50 Reagent LC 50 )×100；
Theoretical Toxicity Index (TTI) =a agent toxicity index x percentage of agent toxicity index in mixture + B agent toxicity index x percentage of agent toxicity in mixture;
co-toxicity coefficient (CTC) = [ mix measured toxicity index (ATI)/mix Theoretical Toxicity Index (TTI) ]x100;
dividing the standard according to the joint action: the co-toxicity coefficient (CTC) is more than or equal to 120, and the synergistic effect is shown; the cotoxicity coefficient (CTC) is less than or equal to 80 and shows antagonism; 80< co-toxicity coefficient (CTC) <120 shows additive effect, and experimental results are shown in tables 1 to 3.
TABLE 1 results of determination of indoor biological Activity of eugenol and thiacloprid compounded against Aphis papaya
| Medicament name and ratio | LC 50 (mg/L) | ATI | TTI | CTC |
| Eugenol | 0.62 | 100.00 | -- | -- |
| Thiacloprid (Thiacloprid) | 4.76 | 13.03 | -- | -- |
| Eugenol 1: thiacloprid 30 | 2.42 | 25.62 | 15.83 | 161.83 |
| Eugenol 1: thiacloprid 20 | 1.35 | 45.93 | 17.17 | 267.53 |
| Eugenol 1: thiacloprid 10 | 0.63 | 98.41 | 20.93 | 470.15 |
| Eugenol 1: thiacloprid 8 | 0.52 | 119.23 | 22.69 | 525.50 |
| Eugenol 1: thiacloprid 5 | 0.77 | 80.52 | 27.52 | 292.57 |
| Eugenol 1: thiacloprid 2 | 0.35 | 177.14 | 42.02 | 421.60 |
| Eugenol 1: thiacloprid 1 | 0.43 | 144.19 | 56.51 | 255.14 |
| Eugenol 2: thiacloprid 1 | 0.67 | 92.54 | 71.01 | 130.32 |
| Eugenol 5: thiacloprid 1 | 0.54 | 114.81 | 85.50 | 134.28 |
| Eugenol 8: thiacloprid 1 | 0.23 | 269.57 | 90.34 | 298.40 |
| Eugenol 10: thiacloprid 1 | 0.18 | 344.44 | 92.09 | 374.02 |
| Eugenol 20: thiacloprid 1 | 0.36 | 172.22 | 95.86 | 179.66 |
| Eugenol 30: thiacloprid 1 | 0.44 | 140.91 | 97.19 | 144.98 |
As can be seen from table 1, the mass ratio of eugenol to thiacloprid is 1-30: the co-toxicity coefficients within the range of 30-1 are all larger than 120, which indicates that the biological activity of the eugenol and thiacloprid compounded on the papaya cotton aphid shows a synergistic effect.
TABLE 2 results of determination of indoor biological Activity of eugenol and Epoxicillin combinations against Aphis papaya
As can be seen from table 2, the mass ratio of eugenol to epoxy insect is 1-15: the co-toxicity coefficients in the range of 40-1 are all larger than 120, which indicates that the biological activity of the eugenol and the epoxy insect-line after being compounded is synergistic to the papaya cotton aphid.
TABLE 3 results of determination of indoor biological Activity of eugenol and guanidine pentose on Aphis papaya
| Medicament name and ratio | LC 50 (mg/L) | ATI | TTI | CTC |
| Eugenol | 0.62 | 100.00 | -- | -- |
| Pentopiramate guanidine | 4.86 | 12.76 | -- | -- |
| Eugenol 1: pentopiramate guanidine 9 | 2.26 | 27.43 | 21.48 | 127.71 |
| Eugenol 1: pentopiramate guanidine 7 | 1.81 | 34.25 | 23.66 | 144.76 |
| Eugenol 1: pentopiramate guanidine 5 | 0.93 | 66.67 | 27.30 | 244.22 |
| Eugenol 1: pentopiramate guanidine 3 | 0.46 | 134.78 | 34.57 | 389.91 |
| Eugenol 1: pentopiramate guanidine 1 | 0.57 | 108.77 | 56.38 | 192.93 |
| Eugenol 3: pentopiramate guanidine 1 | 0.38 | 163.16 | 78.19 | 208.67 |
| Eugenol 5: pentopiramate guanidine 1 | 0.15 | 413.33 | 85.46 | 483.66 |
| Eugenol 7: pentopiramate guanidine 1 | 0.53 | 116.98 | 89.09 | 131.30 |
| Eugenol 9: pentopiramate guanidine 1 | 0.22 | 281.82 | 91.28 | 308.75 |
As can be seen from table 3, the mass ratio of eugenol to pentosan guanidine is 1-9: the co-toxicity coefficients in the range of 9-1 are all larger than 120, which indicates that the biological activity of eugenol and pentatrichlorfon guanidine on papaya cotton aphid after being compounded is synergistic.
In conclusion, after the eugenol is compounded with the nicotine thiacloprid, the epoxy thiacloprid or the tebufenozide, the biological activities of the eugenol and the tebufenozide are synergistic, and the control effect of the eugenol on the papaya cotton aphid can be effectively improved.
Claims (1)
1. The synergistic composition for controlling papaya aphids and containing eugenol is characterized in that the effective components of the synergistic composition are formed by binary compounding of eugenol and epoxy insect-ine, and the mass ratio of eugenol to epoxy insect-ine is 1-15:40-1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210390303.3A CN115568468B (en) | 2021-08-30 | 2021-08-30 | Synergistic composition containing eugenol for controlling papaya aphids |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210390303.3A CN115568468B (en) | 2021-08-30 | 2021-08-30 | Synergistic composition containing eugenol for controlling papaya aphids |
| CN202111005056.2A CN113545346B (en) | 2021-08-30 | 2021-08-30 | Synergistic composition for preventing and treating papaya aphids |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111005056.2A Division CN113545346B (en) | 2021-08-30 | 2021-08-30 | Synergistic composition for preventing and treating papaya aphids |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115568468A CN115568468A (en) | 2023-01-06 |
| CN115568468B true CN115568468B (en) | 2024-02-20 |
Family
ID=78106211
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111005056.2A Active CN113545346B (en) | 2021-08-30 | 2021-08-30 | Synergistic composition for preventing and treating papaya aphids |
| CN202210390330.0A Active CN115669657B (en) | 2021-08-30 | 2021-08-30 | Composition for preventing and treating papaya aphids and containing guanidine pentosaceus |
| CN202210390303.3A Active CN115568468B (en) | 2021-08-30 | 2021-08-30 | Synergistic composition containing eugenol for controlling papaya aphids |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111005056.2A Active CN113545346B (en) | 2021-08-30 | 2021-08-30 | Synergistic composition for preventing and treating papaya aphids |
| CN202210390330.0A Active CN115669657B (en) | 2021-08-30 | 2021-08-30 | Composition for preventing and treating papaya aphids and containing guanidine pentosaceus |
Country Status (1)
| Country | Link |
|---|---|
| CN (3) | CN113545346B (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107347903A (en) * | 2017-09-13 | 2017-11-17 | 佛山市瑞生通科技有限公司 | A kind of composition pesticide containing cycolxylidin and matrine |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105815350A (en) * | 2016-04-13 | 2016-08-03 | 南通清安健无水印染研究所（普通合伙） | Method for preparing microcapsule pesticide made by compounding insect attractant and insecticide and used for controlling monochamus alternatus |
| CN107646863A (en) * | 2017-10-17 | 2018-02-02 | 张锡林 | A kind of Synergistic insecticidal compositions |
| CN107668061A (en) * | 2017-10-20 | 2018-02-09 | 江西省科学院微生物研究所 | A kind of Pesticidal combination and its application |
| CN108124892A (en) * | 2018-01-31 | 2018-06-08 | 河南淇林园林技术有限公司 | It is a kind of to kill aphid composition containing rotenone and guadipyr |
| CN108651505A (en) * | 2018-06-13 | 2018-10-16 | 惠州市梦芭迪工业产品设计中心(普通合伙) | A kind of composition pesticide containing guadipyr and (R)-4-isopropenyl-1-methyl-1-cyclohexene |
| CN113068698B (en) * | 2021-04-12 | 2021-12-24 | 广西壮族自治区亚热带作物研究所（广西亚热带农产品加工研究所） | Insecticidal composition for preventing and treating macadimia nut aphids |
-
2021
- 2021-08-30 CN CN202111005056.2A patent/CN113545346B/en active Active
- 2021-08-30 CN CN202210390330.0A patent/CN115669657B/en active Active
- 2021-08-30 CN CN202210390303.3A patent/CN115568468B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107347903A (en) * | 2017-09-13 | 2017-11-17 | 佛山市瑞生通科技有限公司 | A kind of composition pesticide containing cycolxylidin and matrine |
Non-Patent Citations (2)
| Title |
|---|
| Disentangling the ecotoxicological selectivity of clove essential oil against aphids and non-target ladybeetles;Pedro F.S. Toledo等;Science of the Total Environment;第718卷;1-12 * |
| 四种植物精油成分对枸杞棉蚜的生物活性;陈新华等;昆虫学报;第62卷(第4期);453-460 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN113545346A (en) | 2021-10-26 |
| CN115669657B (en) | 2024-02-20 |
| CN113545346B (en) | 2022-04-12 |
| CN115669657A (en) | 2023-02-03 |
| CN115568468A (en) | 2023-01-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN115568468B (en) | Synergistic composition containing eugenol for controlling papaya aphids | |
| CN116019101B (en) | Synergistic composition containing thymol for preventing and treating papaya mites | |
| CN114287450B (en) | Pesticide composition for preventing and treating sugarcane thrips | |
| CN111226973B (en) | Pesticide synergistic composition for preventing and controlling armyworm | |
| CN115005227B (en) | Insecticidal composition containing farnesol | |
| CN115968892B (en) | Insecticidal composition for preventing and controlling taro field red spiders | |
| CN113994972B (en) | Composition for treating gummosis of nectarines | |
| CN115005226A (en) | Insecticidal composition for preventing and treating corn armyworm | |
| CN118402527A (en) | Pesticide composition for preventing and treating sugarcane borers | |
| CN113455510B (en) | Biopesticide for preventing and treating pineapple root knot nematode disease | |
| CN113729028B (en) | Pesticide for preventing and treating sugarcane thrips | |
| CN115005221B (en) | Pesticide composition for preventing and controlling wheat aphids | |
| CN116616285A (en) | Pesticide composition for preventing and controlling wheat aphids | |
| CN118160740A (en) | Active pesticide for controlling jackfruit pests | |
| CN116267954A (en) | Insecticidal and acaricidal composition for preventing and controlling cassava red spiders | |
| CN117530296A (en) | Insecticidal composition for preventing and controlling mango thrips | |
| CN116548448A (en) | Insecticidal composition and application thereof in prevention and control of green Chinese onion thrips | |
| CN117562057A (en) | Biological-chemical synergistic insecticidal composition | |
| CN115769821A (en) | Pesticide composition for preventing and treating wormwood aphids | |
| CN116250540A (en) | Biopesticide for preventing and treating macadimia nut thrips | |
| CN117397682A (en) | Pesticide composition for preventing and treating tobacco thrips | |
| CN116649361A (en) | Insecticidal composition, preparation method and application thereof | |
| CN117814233A (en) | Binary compound insecticidal composition and insecticide | |
| CN116548461A (en) | Application method for preventing tea leafhoppers of tea tree | |
| CN116473062A (en) | Sterilization composition for preventing and treating passion fruit stem basal rot |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |