CN107668061A - A kind of Pesticidal combination and its application - Google Patents
A kind of Pesticidal combination and its application Download PDFInfo
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- CN107668061A CN107668061A CN201710983824.9A CN201710983824A CN107668061A CN 107668061 A CN107668061 A CN 107668061A CN 201710983824 A CN201710983824 A CN 201710983824A CN 107668061 A CN107668061 A CN 107668061A
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- Prior art keywords
- insect
- insect pheromone
- pesticidal combination
- thiacloprid
- combination according
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N27/00—Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aliphatically bound aldehyde or keto groups, or thio analogues thereof; Derivatives thereof, e.g. acetals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/06—Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
Abstract
To include insect pheromone, thiacloprid and Rimon the invention provides the invention provides a kind of Pesticidal combination, the composition.The result of the embodiment of the present invention is shown：After insect pheromone, thiacloprid and Rimon are compounded, after efficacy test result shows insect pheromone, thiacloprid and Rimon compounding, after insect pheromone, thiacloprid and Rimon compounding, there is synergistic effect to the preventing and treating of insect pest, field experiment result shows, for having the target insect for ability of necessarily migrating as adult, especially in aviation plant protection, synergistic effect is even more than 50%.
Description
Technical field
The invention belongs to pesticide production technology field, more particularly to a kind of Pesticidal combination and its application.
Background technology
Thiacloprid is the new chloro nicotinoids by Bayer Bitterfeld GmbH agro-chemical companies and the cooperative development of Japanese Bayer agro-chemical companies
Insecticide, to the small brown rice planthopper on the crops such as rice, vegetables, fruits and vegetables, cotton fleahopper, grain aphid, longicorn beetle, smaller green leaf hopper, three
Changing the pierce-suck types such as snout moth's larva, thrips and pests with chewing mouthparts has special efficacy.Thiacloprid mainly acts on insect nerve engagement caudacoria, passes through
Combined with nAChR, interference insect nervous system normal conduction, cause the obstruction of neural channel, cause acetyl courage
A large amount of accumulation of alkali so that insect exaltation, general spasticity, paralysis and it is dead.
It is conventional at present that Monochamus alternatus Hope is prevented and treated using 48% thiacloprid aqueous suspension agent, the preventive effect to Monochamus alternatus Hope is 70~
76%, obtained prevention effect is undesirable.
The content of the invention
In view of this, in view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to and a kind of insecticide composition is provided, can
Improve the prevention effect to crop pests.
The invention provides a kind of Pesticidal combination, including insect pheromone, thiacloprid and Rimon.
Preferably, the insect pheromone and thiacloprid, the mass ratio of Rimon are (1~55):(1~30):(1~
40)。
Preferably, the insect pheromone is included along 6- heneicosene -11- ketone, along 6, along the carbon -6,9- bis- of 9- 21
Alkene and suitable 6, along the one or more in the carbon -6,9- diene of 9- 23.
Preferably, the insect pheromone is included along 11- hexadecenes ester, along 11- hexadecenals and along the carbon of 11- 16
One or more in enol.
Preferably, the insect pheromone includes acetic acid E-5- ubidecarenones, E-5- decenols, the carbon diene of E-9, Z11- 16
One or more in aldehyde, acetic acid hexadecylene ester and suitable 11- hexadecenols.
Preferably, the insect pheromone include (5R, 6S) -6- acetate -5- hexadecanolides, cis -9- 23 carbene,
It is 10- methyl -9- 23 carbene, cis -2- methyl -8- 22 carbene, cis -9- 22 carbene, cis -8- 22 carbene, suitable
The chloro- 6- methyl isophthalic acids-carboxylic acid tert-butyl ester of formula -10- 23 carbene, 2-, methyl eugenol and the p- acetyl group phenyl -2- fourths of 4-
One or more in ketone.
Preferably, the insect pheromone includes butyl butyrate, trans- 2- butyric acid hexene ester and trans- 4- carbonyls -2- hexenoic aldehydes
In one or more.
Preferably, the insect pheromone includes 1,13- tridecane diols, 2- hendecane epoxide -1- ethanol and trans- 4- carbonyls
One or more in base -2- hexenoic aldehydes.
Preferably, the insect pheromone also include trans -2- hexenoic aldehydes, isothiocyanates, isothiocyanate, leaf-alcohol,
Leaf-alcohol ester, phenylacetaldehyde, gaultherolin, hexyl acetate, n-hexyl alcohol, phenylacetaldehyde dimethyl acetal, cis-blatter alcohol, D- lemons
Lemon alkene, L-citrene, 1- hexene-3-ols, linalool, australene, nopinene, α-carypohyllene, β-carypohyllene, gaultherolin,
Trans-anethole, anethole, anise alcohol, methyl o-anisate, benzyl carbinol, butyl salicylate and by tree brain in one kind
It is or several.
Application of the Pesticidal combination obtained present invention also offers such scheme in insecticidal preparation is prepared, the desinsection
Preparation includes suspending agent, microcapsule suspending agent, oil-suspending agent, low capacity liquor or thermal fog.
The invention provides a kind of Pesticidal combination, the composition includes insect pheromone, thiacloprid and Rimon.
When thiacloprid and Rimon in Pesticidal combination provided by the invention are used for insect control, there is obvious synergistic effect；
Insect pheromone provides precisely orientation, and insect pheromone is added near the attachment point of crop by thiacloprid and Rimon,
The motion frequency of lifting aggregation target insect and increase target insect around the attachment point, so that around the attachment point
Insect density increase, adds the probability that target insect contacts with thiacloprid, Rimon, hence in so that insect pheromone, thiophene
Worm quinoline and Rimon have synergy, improve the effective rate of utilization of agricultural chemicals, realize the preventing and treating purpose precisely oriented.
Pesticidal combination provided by the invention is used for the trapping of target adult, and adult is made according to Insect infestation monitoring result
Curve, the phase occurs in adult, the sex attractant of the present invention is generally discharged in shrub woods, can be by mating of being sought a spouse after emergence
Male worm is trapped and killed in time, the normal mating of effective disturb target insect, is allowed to effectively to raise up seed, and reduces harm.
The result of the embodiment of the present invention is shown：After insect pheromone, thiacloprid and Rimon are compounded, indoor harmacological effect is real
Test result show insect pheromone, thiacloprid and Rimon compounding after, there is synergistic effect, field experiment to the preventing and treating of insect pest
As a result show, for having the target insect for ability of necessarily migrating as adult, especially in aviation plant protection, synergistic effect is even
More than 50%.
Embodiment
The invention provides a kind of Pesticidal combination, including insect pheromone, thiacloprid and Rimon.In the present invention
In, the insect pheromone is attached on crop jointly with thiacloprid, Rimon, improves the quantity of aggregation target insect, with
And increase target insect motion frequency, so as to increase insect density, increase target insect contacts with thiacloprid, Rimon
Probability, and then cause insect pheromone and thiacloprid, Rimon to have synergy, that improves thiacloprid and Rimon has
Utilization rate is imitated, realizes precisely orientation preventing and treating.
In the present invention, the mass ratio of the insect pheromone and thiacloprid, Rimon is preferably (1~55):(1~
30):(1~40), more preferably (5~50):(5~25):(5~35), it is most preferably (10~40):(10~20):(10~
30).The present invention is not particularly limited to the source of the thiacloprid, Rimon, is routinely selected using those skilled in the art
Commercially available prod.
In the present invention, the insect pheromone is included along 6- heneicosene -11- ketone, suitable 6, suitable carbon -6 of 9- 21,
9- diene and suitable 6, along the one or more in carbon -6, the 9- diene of 9- 23, described several specially two or three.Work as institute
State insect pheromone for two kinds when, be preferably along 6- heneicosene -11- ketone and along 6, along carbon -6, the 9- diene of 9- 21, institute
State along 6- heneicosene -11- ketone with being preferably (0.5~3.5) along the mass ratio of 6, the suitable carbon -6,9- diene of 9- 21:(5
~12), more preferably (1~3):(7~10), most preferably 2:8.When the insect pheromone is three kinds, each group is graded matter
Amount mixing.The present invention is not particularly limited to the source of mentioned reagent, is routinely selected using those skilled in the art.
In the present invention, the target insect of the insect pheromone includes Lepidoptera Noctuoidea insect.
In the present invention, the insect pheromone is included along 11- hexadecenes ester, along 11- hexadecenals and along 11- ten
One or more in six carbene alcohol, described several specially two or three.When the insect pheromone is two kinds, each group
Grade mass mixing.When the insect pheromone is three kinds, suitable the 11- hexadecenes ester, suitable 11- hexadecenals and suitable
The mass ratio of 11- hexadecenols is preferably (5~15):(5~15):(0.5~1.5), more preferably (8~12):(8~
12):(0.8~1.2), most preferably 10:10:1.0.The present invention is not particularly limited to the source of mentioned reagent, using ability
Field technique personnel routinely select.In the present invention, the target insect of the insect pheromone include lepidoptera diamond-back moth section,
Gelechidae and Pyralidae insect.
In the present invention, the insect pheromone is included along 11- hexadecenes ester, along 11- hexadecenals and along 11- ten
One or more in six carbene alcohol, described several specially two or three.When the insect pheromone is two kinds, each group
Grade mass mixing.When the insect pheromone is three kinds, suitable the 11- hexadecenes ester, suitable 11- hexadecenals and suitable
The mass ratio of 11- hexadecenols is preferably (5~15):(5~15):(0.5~1.5), more preferably (8~12):(8~
12):(0.8~1.2), most preferably 10:10:1.0.The present invention is not particularly limited to the source of mentioned reagent, using ability
Field technique personnel routinely select.In the present invention, the target insect of the insect pheromone include lepidoptera diamond-back moth section,
Gelechidae and Pyralidae insect.
In the present invention, the insect pheromone includes (5R, 6S) -6- acetate -5- hexadecanolides, cis -9- 23
Carbene, 10- methyl -9- 23 carbene, cis -2- methyl -8- 22 carbene, cis -9- 22 carbene, cis -8- 22 carbon
Alkene, cis -10- 23 carbene, the chloro- 6- methyl isophthalic acids-carboxylic acid tert-butyl esters of 2-, methyl eugenol and the p- acetyl group phenyls of 4- -
One or more in 2- butanone, several specially two kinds, the three kinds or more.When the insect pheromone is two
Kind, three kinds or more when, each group is graded mass mixing.The present invention is not particularly limited to the source of mentioned reagent, is used
Those skilled in the art routinely select.In the present invention, the target insect of the insect pheromone is dived including Diptera
Nuscidae and Dulicidae insect.
In the present invention, the insect pheromone include butyl butyrate, trans- 2- butyric acid hexene ester and trans- 4- carbonyls -2- oneself
One or more in olefine aldehydr, described several specially two or three.When the insect pheromone is two kinds, each group is graded
Mass mixing.When the insect pheromone is three kinds, the butyl butyrate, trans- 2- butyric acid hexene ester and trans- 4- carbonyls -2-
The mass ratio of hexenoic aldehyde is preferably (0.8~1.6):(0.1~0.4):(0.5~1.5), more preferably (1.0~1.4):(0.2
~0.3):(0.8~1.2), most preferably 1.25:2.5:1.0.The present invention is not particularly limited to the source of mentioned reagent, is adopted
Routinely selected with those skilled in the art.In the present invention, the target insect of the insect pheromone includes Semiptera
Stinkbug Superfamily insect.
In the present invention, the insect pheromone includes 1,13- tridecane diols, 2- hendecane epoxide -1- ethanol and trans-
One or more in 4- carbonyl -2- hexenoic aldehydes, described several specially two or three.When the insect pheromone is two kinds
Or at three kinds, each group is graded mass mixing.The present invention is not particularly limited to the source of mentioned reagent, using people in the art
Member routinely selects.In the present invention, the target insect of the insect pheromone includes coleoptera Cerambycoidea.
In the present invention, the insect pheromone also include trans -2- hexenoic aldehydes, 2- hendecane epoxide -1- ethanol, just oneself
Aldehyde, 3- methylthios isothiocyanates, isothiocyanates, isothiocyanates salt, leaf-alcohol, leaf-alcohol ester, phenylacetaldehyde, salicylic acid first
Ester, hexyl acetate, n-hexyl alcohol, phenylacetaldehyde dimethyl acetal, cis-blatter alcohol, D- limonenes, L-citrene, 1- hexenes-
It is 3- alcohol, linalool, australene, nopinene, α-carypohyllene, β-carypohyllene, γ-terpinenes, α-copaene, gaultherolin, anti-
Formula anethole, anethole, anise alcohol, methyl o-anisate, benzyl carbinol, butyl salicylate and by tree brain in one kind or
It is several, it is described it is several be specially two kinds, three kinds, four or more.When the insect pheromone is two kinds or more than four kinds
When, each group is graded mass mixing.When the insect pheromone is three kinds, preferably australene, beta pinene and 2- hendecane oxygen
Base -1- ethanol, the mass ratio of the australene, beta pinene and 2- hendecane epoxide -1- ethanol is preferably (20~50):(0.5~
1.5):(0.1~1.0), more preferably (30~45):(0.8~1.2):(0.4~0.8), most preferably 40:1.0:0.5.When
When the insect pheromone is four kinds, preferably trans -2- hexenoic aldehydes, n-hexyl aldehyde, 3- methylthios isothiocyanates and second
Sour hexadecylene ester, more preferably β-carypohyllene, linalool, D- limonenes and γ-terpinenes.When the insect pheromone is anti-
When formula -2- hexenoic aldehydes, n-hexyl aldehyde, 3- methylthios isothiocyanates and acetic acid hexadecylene ester, the trans -2- hexenoic aldehydes,
The mass ratio of n-hexyl aldehyde, 3- methylthios isothiocyanates and acetic acid hexadecylene ester is preferably (15~45):(5~15):(1
~5):(0.1~1.0), more preferably (25~35):(8~12):(2~4):(0.3~0.8), most preferably 30:10:3:
0.5.When the insect pheromone is β-carypohyllene, linalool, D- limonenes and γ-terpinenes, the β-carypohyllene, fragrant camphor tree
The mass ratio of alcohol, D- limonenes and γ-terpinenes is preferably (10~20):(1~10):(10~20):(15~25), more preferably
For (12~18):(3~8):(12~18):(18~22), most preferably 15:5:15:20.Source of the present invention to mentioned reagent
It is not particularly limited, is routinely selected using those skilled in the art.In the present invention, the insect pheromone is target
Insect host specialized plant volatile matter, it is main to attract target insect female individuals, mainly inhaled with making up other insect pheromones
Draw the deficiency of male.
Application of the Pesticidal combination obtained present invention also offers such scheme in insecticidal preparation is prepared, the desinsection
Preparation includes suspending agent, microcapsule suspending agent, oil-suspending agent, low capacity liquor or thermal fog.In the present invention, the microcapsule suspension
Agent, oil-suspending agent, low capacity liquor and thermal fog, which remove, contains the Insecticidal combinations beyond the region of objective existence, also acceptable auxiliary containing above-mentioned preparation
Material.The present invention is not particularly limited to the preparation method of the microcapsule suspending agent, oil-suspending agent, low capacity liquor and thermal fog,
Using those skilled in the art's customary preparation methods.
A kind of insecticides provided by the invention and its application are described in detail with reference to embodiment, but
It is that they can not be interpreted as limiting the scope of the present invention.
Embodiment 1
In terms of the mass percent of suspending agent total amount, along 6- heneicosene -11- ketone 0.2%, suitable 6, along 9- 21
Carbon -6,9- diene 0.8%, methyl-isorhodanate 4%, thiacloprid 10%, Rimon 40%, alkylaryl APEO phosphorus
Acid esters 3.5%, methylbenzene e pioic acid methyl ester graft copolymer 2.5%, ethylene glycol 4.5%, KF88 0.02%, organic silicon defoamer
0.3%th, xanthans 0.25%, water supply 100%.
Preparation method：Will be along 6- heneicosene -11- ketone, suitable 6, along the carbon -6,9- diene of 9- 21, isothiocyanic acid first
Ester, thiacloprid, Rimon, alkylaryl polyoxyethylene ether phosphate, methylbenzene e pioic acid methyl ester graft copolymer, ethylene glycol,
KF88, organic silicon defoamer, xanthans and water mixing, obtain mixed liquor, mixed liquor are sanded to grain diameter D90≤10 μm,
Obtain suspending agent.
Embodiment 2
In terms of the mass percent of suspending agent total amount, along 11- hexadecenes ester 1%, along 11- hexadecenals 1%, suitable
11- hexadecenols 0.1%, thiacloprid 3%, Rimon 18%, alkylaryl polyoxyethylene ether phosphate 3.5%, methyl
Benzene e pioic acid methyl ester graft copolymer 2.5%, ethylene glycol 4.5%, KF88 0.02%, organic silicon defoamer 0.3%, xanthans
0.25%th, water supplies 100%.
Preparation method：Will along 11- hexadecenes esters, along 11- hexadecenals, along 11- hexadecenols, thiacloprid, double
Benzene fluorine urea, alkylaryl polyoxyethylene ether phosphate, methylbenzene e pioic acid methyl ester graft copolymer, ethylene glycol, KF88, organosilicon disappear
Infusion, xanthans and water mixing, obtain mixed liquor, mixed liquor are sanded to grain diameter D90≤10 μm, obtains suspending agent.
Embodiment 3
In terms of the mass percent of oil-suspending agent total amount, acetic acid E-5- ubidecarenones 0.8%, E-5- decenols 0.2%, thiophene worm
Quinoline 8%, Rimon 32%, alkylaryl polyoxyethylene ether phosphate 20%, methyl oleate supply 100%.
Above-mentioned material is mixed to get mixed liquor, and mixed liquor is sanded to grain diameter D90≤10 μm, obtains oil-suspending agent.
Embodiment 4
In terms of the mass percent of suspending agent total amount, (5R, 6S) -6- acetate -5- hexadecanolides 1%, thiacloprid 15%,
Rimon 30%, alkylaryl polyoxyethylene ether phosphate 3.5%, methylbenzene e pioic acid methyl ester graft copolymer 2.5%, second two
Alcohol 4.5%, KF88 0.02%, organic silicon defoamer 0.3%, xanthans 0.25%, water supply 100%.
Preparation method：By (5R, 6S) -6- acetate -5- hexadecanolides, thiacloprid, Rimon, alkylaryl polyoxy second
Alkene ether phosphate, methylbenzene e pioic acid methyl ester graft copolymer, ethylene glycol, KF88, organic silicon defoamer, xanthans and water mixing,
Mixed liquor is obtained, mixed liquor is sanded to grain diameter D90≤10 μm, obtains suspending agent.
Embodiment 5
In terms of the mass percent of suspending agent total amount, butyl butyrate 1.5%, trans- 2- butyric acid hexene ester 0.25%, trans- 4-
Carbonyl -2- hexenoic aldehydes 1%, thiacloprid 10%, Rimon 25%, alkylaryl polyoxyethylene ether phosphate 3.5%, methylbenzene
E pioic acid methyl ester graft copolymer 2.5%, ethylene glycol 4.5%, KF88 0.02%, organic silicon defoamer 0.3%, xanthans
0.25%th, water supplies 100%.
Preparation method：By butyl butyrate, trans- 2- butyric acid hexene ester, trans- 4- carbonyls -2- hexenoic aldehydes, thiacloprid, double benzene fluorine
Urea, alkylaryl polyoxyethylene ether phosphate, methylbenzene e pioic acid methyl ester graft copolymer, ethylene glycol, KF88, organosilicon defoaming
Agent, xanthans and water mixing, obtain mixed liquor, mixed liquor are sanded to grain diameter D90≤10 μm, obtains suspending agent.
Embodiment 6
In terms of the mass percent of suspending agent total amount, 1,13- tridecane diols 5%, thiacloprid 30%, Rimon
15%th, alkylaryl polyoxyethylene ether phosphate 3.5%, methylbenzene e pioic acid methyl ester graft copolymer 2.5%, ethylene glycol 4.5%,
KF88 0.02%, organic silicon defoamer 0.3%, xanthans 0.25%, water supply 100%.
Preparation method：By 1,13- tridecane diols, thiacloprid, Rimon, alkylaryl polyoxyethylene ether phosphate,
Methylbenzene e pioic acid methyl ester graft copolymer, ethylene glycol, KF88, organic silicon defoamer, xanthans and water mixing, obtain mixed liquor,
Mixed liquor is sanded to grain diameter D90≤10 μm, obtains suspending agent.
Embodiment 7
In terms of the mass percent of thermal fog total amount, trans -2- hexenoic aldehydes 30%, n-hexyl aldehyde 10%, 3- methylthios
Isothiocyanates 10%, acetic acid hexadecylene ester 0.5%, thiacloprid 4%, the fatty alcohol oxygen vinethene 10% of Rimon 1%, octyl group
Sodium succinate 5%, benzoic acid leaf-alcohol ester complement to 100%.
Above-mentioned material is mixed to get transparent mixed liquor, obtains thermal fog.
Embodiment 8
In terms of the mass percent of low capacity liquor total amount, australene 40%, beta pinene 1%, 2- hendecane epoxide -1- second
Alcohol 0.5%, thiacloprid 10%, Rimon 5%, alkylaryl APEO 3.5%, alkyl benzene calcium sulfonate 0.5%, DMSO
15%, benzoic acid leaf-alcohol ester supplies 100%.
Above-mentioned material is mixed to get transparent mixed liquor, obtains low capacity liquor.
Embodiment 9
In terms of the mass percent of microcapsule suspending agent total amount, 1,13- tridecane diols 1.5%, 2- hendecane epoxide -1- second
Alcohol 1.5%, trans- 4- carbonyls -2- hexenoic aldehydes 2%, thiacloprid 5%, Rimon 5%, alkylaryl polyoxyethylene ether phosphate
4%th, urea-formaldehyde resin additive bag 20%, ethylene glycol 4.5%, KF88 0.02%, organic silicon defoamer 0.3%, xanthans 0.25%,
Water supplies 100%.
Urea-formaldehyde resin additive bag includes urea, formaldehyde, acetophenone, alkylaryl APEO and alkyl benzene calcium sulfonate,
The mass ratio of urea and formaldehyde, acetophenone, alkylaryl APEO, alkyl benzene calcium sulfonate is 1:1:3:1:0.5.
Preparation method：Acetophenone, thiacloprid, alkylaryl APEO, alkyl benzene calcium sulfonate and water are mixed, cut
Cut, then mixed with urea, formaldehyde, be down to room temperature after being heated to 45 DEG C of holding 1.5h, obtain clothianidin micro-capsule mother liquor；
Other raw materials in the present embodiment are mixed, then are sanded to grain diameter D90≤10 μm, obtain suspending agent mother liquor；
Clothianidin micro-capsule mother liquor and suspending agent mother liquor are mixed, obtain microcapsule suspending agent.
Comparative formulation 1：
In terms of the mass percent of suspending agent total amount, thiacloprid 10%, Rimon 40%, alkylaryl APEO
Phosphate 3.5%, ethylene glycol 4.5%, KF88 0.02%, organic silicon defoamer 0.3%, xanthans 0.25%, water is supplied
100%.
Preparation method：After above-mentioned material is well mixed, mixed liquor is obtained, mixed liquor is sanded to the μ of grain diameter D90≤10
M, obtain suspending agent.
The suspending agent of Assays Example 1 is to brown paddy plant hopper joint toxicity measuring
Suspending agent, 5% thiacloprid suspending agent and the 5% Rimon suspending agent that embodiment 1 is provided are diluted to acetone
Series concentration, and blank control is made with acetone, each 3 repetitions of concentration, 50 brown paddy plant hopper nymphs are each reprocessed, are often handled
It is repeated 5 times.Single head nymph worm is put into a diameter of 20cm plastic culture dish, with Hamilton syringes by 0.24 microlitre of medicine
Liquid drop is in every nymph pronotary.Handle in the insectary that culture dish is moved into 26 DEG C afterwards, with pot rice rice seedling
Raising, photoperiod 16:8 (illumination:It is dark), manually forage feed.Inspection result after 48h, Rimon check after needing 96h
As a result, polypide is flipped with tweezers, larva can not scrambler be normally death.
Synegism evaluation method surveys standard method NY/T1156.6-2006 with reference to raw, according to Sun＆Johnson (1960)
Co-toxicity coefficient method (CTC) evaluate the synergistic effect of pharmacy mix, i.e. CTC≤80 are antagonism, 80<CTC<120 be phase
Add effect, CTC >=120 are synergistic effect.It the results are shown in Table 1.
The calculation formula for surveying toxicity index is as follows：
Mixture theoretical toxicity index (TTI)=(percentage composition+medicament B of A medicaments in medicament A toxicity index * mixtures
The percentage composition of B medicaments in toxicity index * mixtures) × 100.
Co-toxicity coefficient calculation formula is as follows：
Indoor joint toxicity measuring result of the table 1 to brown paddy plant hopper
As it can be seen from table 1 thiacloprid and Rimon are 10:When being compounded in the range of (1~128), co-toxicity coefficient
(CTC) 110 are all higher than, but 10:When (4~64), co-toxicity coefficient (CTC) is big by 120, and synergy work is shown to brown paddy plant hopper
With.Wherein, thiacloprid and Rimon 10:16 ratio mixtures, to the co-toxicity coefficient highest of brown paddy plant hopper, it is seen that thiacloprid and double benzene
Fluorine urea compounding has reasonability and feasibility.
The suspending agent of Assays Example 2 is to diaphorina citri indoor pharmacodynamic test
Theory dead value (%) of the suspending agent to diaphorina citri of the offer of example of formulations 5 is provided according to Colby formula.When
When preventing and treating the numerical value of percentage higher than the theoretical value for preventing and treating percentage, it is believed that the suspending agent that embodiment 5 obtains obtains potentiating pesticidal
Activity.Colby calculation formula are as follows：
E=X+Y- (X × Y)/100, wherein
The death rates of the X=when using reactive compound A with mppm rate of application, it is expressed as the percentage of untreated control group
Than；
The death rates of the Y=when using reactive compound B with nppm rate of application, it is expressed as the percentage of untreated control group
Than；
The death rates of the E=when using reactive compound A and B with m+nppm rate of application, is expressed as untreated control group
Percentage.
Seven closed containers of a size of A, B, C, D, E, F and G are selected in experiment, and container size is 5m2, in each container
It is put into 50 diaphorina citris and one plant of potted plant mandarin tree A, B and C container and launches insecticide, target insect information in D containers
Element, the composition of insecticide and insect aggregation pheromone is launched in E, F and G container, is launched in A, B, C, D, E, F and G container
Reactive compound uses identical preparation type, and extension rate is identical 10000 times, and dilution is dropped on 5 citrus leaves,
And the dilution weight carried out mark of correlation and spent.
After required time 3 days, the death rate is determined, in terms of %.100% represents to kill all diaphorina citris；0% represents
It is killed without diaphorina citri.The identified death rate is substituted into Colby formula, result of the test is shown in Table 2：
The diaphorina citri indoor pharmacodynamic test of table 2
Note：Insect pheromone mixture is butyl butyrate, trans- 2- butyric acid hexene ester, trans- 4- carbonyls -2- hexenoic aldehydes, quality
Than for 5:1:4.
As can be drawn from Table 2, thiacloprid and Rimon compounding have synergistic effect, active ingredient to diaphorina citri preventive effect
Between synergistic effect be 125% or so；After being compounded with insect pheromone mixture, drug effect further obtains for thiacloprid, Rimon
To lifting, synergistic effect is more than 150% between active ingredient.As can be seen here, insect pheromone can more attract insect in dispenser leaf
Sucked on piece, so as to improve drug effect.
The suspending agent of Assays Example 3 is to grain aphid indoor pharmacodynamic test
Theory dead value (%) of the suspending agent to grain aphid of the offer of example of formulations 5 is provided according to Colby formula.When
When preventing and treating the numerical value of percentage higher than the theoretical value for preventing and treating percentage, it is believed that the suspending agent that embodiment 5 provides obtains potentiating pesticidal
Activity.Colby calculation formula are as follows：
E=X+Y- (X × Y)/100, wherein
The death rates of the X=when using reactive compound A with mppm rate of application, it is expressed as the percentage of untreated control group
Than；
The death rates of the Y=when using reactive compound B with nppm rate of application, it is expressed as the percentage of untreated control group
Than；
The death rates of the E=when using reactive compound A and B with m+nppm rate of application, is expressed as untreated control group
Percentage,
Seven closed containers of a size of A, B, C, D, E, F and G are selected in experiment, and container size is 0.5m2, each container
100 aptery grain aphids, and two basin wheat seedlings are inside put into, 50 Macrosiphus spps are put on every basin wheat seedling.A, thrown in B, C container
Put insecticide, target insect sex pheromone in D containers, the combination of insecticide and insect aggregation pheromone is launched in E, F and G container
Thing, the reactive compound launched in A, B, C, D, E, F and G container use identical preparation type.
After required time 3 days, the death rate is determined, in terms of %.100% represents to kill all grain aphids；0% represents
Grain aphid is killed.The identified death rate is substituted into Colby formula, result of the test is shown in Table 3.
The grain aphid indoor pharmacodynamic test of table 3
Note：Insect pheromone mixture is β-carypohyllene, linalool, D- limonenes, γ-terpinenes, mass ratio 3:1:
3:4。
As can be drawn from Table 3, thiacloprid and Rimon, which compound, also synergistic effect to grain aphid preventive effect, thiacloprid,
After Rimon compounds with insect pheromone, drug effect, which also has, further to get a promotion.
Assays Example 4
By suitable 11- hexadecenes ester, the use along 11- hexadecenals, suitable 11- hexadecenols and ethyl acetate in table 4
Amount, to prove the feasibility of the present invention program.
The biological information element dosage of table 4
Acetic acid second will be dissolved in proportion along 11- hexadecenes ester, along 11- hexadecenals, along 11- hexadecenols
Ester, the preparation 0.1g that embodiment 1-9 is obtained are dissolved in ethyl acetate 1g, and each formula is added in lml rubber lure, treated
After solvent volatilization completely, lure is fixed on to 400cmz insect-sticking plate trapper center.Select vegetable variety, growing way, rich water pipe
Manage in flakes vegetable plot of the consistent, area more than 10 mu and be tested field, it is central be uniformly arranged 10 it is above-mentioned containing sex attractant
Insect-sticking plate trapper, a lamp light trapping device (uviol lamp) and the trapper containing 30 female diamondback moths living, are traped 30 days altogether；Altogether
Set three to repeat, random alignment, the results are shown in Table 5.
The different formulations of table 5 and preparation lure diamondback moth to test
| Numbering | Total trapping amount/head | Average trapping amount/(head/day) |
| 1 | 1018 | 33.9 |
| 2 | 1177 | 39.2 |
| 3 | 1220 | 40.7 |
| 4 | 1262 | 42.1 |
| 5 | 1136 | 37.9 |
| 6 | 981 | 32.7 |
| 7 | 932 | 31.1 |
| 8 | 1016 | 33.9 |
| 9 | 1284 | 42.8 |
| 10 | 1141 | 38.0 |
| Embodiment 1 | 230 | 7.7 |
| Embodiment 2 | 1208 | 40.3 |
| Embodiment 3 | 6 | 0.2 |
| Embodiment 4 | 13 | 0.4 |
| Embodiment 5 | 12 | 0.4 |
| Embodiment 6 | 5 | 0.2 |
| Embodiment 7 | 1313 | 43.8 |
| Embodiment 8 | 6 | 0.2 |
| Embodiment 9 | 12 | 0.4 |
| Lamp light trapping device | 683 | 22.8 |
| Female diamondback moth living | 44 | 1.5 |
From second day, every morning investigated the diamondback moth quantity traped, and persistently investigated 30 days.
Result of the test shows:The total trapping amount and average trapping amount of 9 group of formula of attractant for diamondback moth are obviously higher than lamp
The trapping amount of light and female adult, wherein the effect of formula 9 is best, embodiment 2 is compared slightly lower with formula group 7, and embodiment 7 is than formula group
7 compared to slightly higher.This shows that the trapping activity of diamondback moth sex attractant will be apparently higher than other two kinds.Carried out using the attractant
Prediction and the trapping of phase occurs for vegetable plot diamondback moth, and it is accurate to observe and predict, and it is high to trap activity.As can be seen here, drawing using the present invention
It lure, can accurately be applied to diamondback moth detecting and reporting pest information, mass trapping, reach the ideal effect of comprehensive regulation diamondback moth, be adapted to big
Area popularization and application.
Performance activity test is lured by insect pheromone early stage and consults related data, the target of the embodiment of the present invention 1
Insect is designed as poison moth, and the target insect of embodiment 2 and 7 is designed as diamondback moth, and the target insect of embodiment 3 is designed as peach clearwing
Moth, the target insect of embodiment 4 are designed as mosquito, and the target insect of embodiment 5 is designed as fleahopper, the target insect of embodiment 6
To be designed as Monochamus alternatus, the target insect of embodiment 8 is designed as Monochamus alternatus Hope, and the target insect of embodiment 9 is designed as longicorn.
By in related activity tests, the activity test as Assays Example 4, it was demonstrated that above-described embodiment can reach well
To relevant design purpose.
It can be drawn thus according to table 5, use different insects pheromones for target diamondback moth, embodiment 1-10 is in chemistry
It is different to insect targets insect diamondback moth attraction power in the case of insecticide is substantially indiscriminate, so as to have to diamondback moth
Different desinsection preventive effects.The embodiment of the present invention 2 and the target insect of embodiment 7 are designed as diamondback moth, for diamondback moth, apply the He of example 2
Embodiment 7 also has higher preventive effect relative to other embodiment
Field test aviation plant protection shrub woods longicorn prevents and treats
The experiment Xinjiang Ji'an landscape ground carry out, beneficial effects of the present invention by following field test furtherly
It is bright.
The field efficacy pair for the preparation preventing and treating pine tree Cephus fumipennis that the embodiment of the present invention 3,5,6,8 and 9 is prepared
Than experiment.Test method：By helicopter aviation plant protection dispenser, each spraying area is 1000 for above-mentioned preparation and Comparative formulation 1
Mu；Blank control is no dispenser shrub woods.Each plot area is 1000 mu, is repeated 1 times, and 7 days after medicine, investigates within 15 days and prevents
Effect.Investigation drug effect method be：Each cell by east, south, west, north, in take 5 points, one black light lamp of every placement, underlying one
Bucket, the longicorn quantity lured is recorded, calculate correcting controling effect.Result of the test is shown in Table 6.
Calculation formula is as follows：
Table 6 prevents and treats the field test results of shrub woods longicorn
Note：Chemical agent active component includes thiacloprid and Rimon, because insect pheromone does not have direct desinsection to live
Property, therefore using thiacloprid and Rimon to carry out field activity test as normative reference has relative value
Table of field test results is bright:Embodiment 3,6,8 and 9 added with insect pheromone, preventive effect is not apparently higher than adding
Add the Comparative formulation embodiment 1 of insect pheromone, embodiment 5 is suitable with comparative example drug effect, wherein most preferably embodiment
8, and insect pheromone is specifically for obtained by being developed in longicorn in embodiment 8, this also demonstrates that the present invention in aviation plant protection,
Prevent and treat target insect the special preventing and treating of implementation and use space with huge.
As seen from the above embodiment, after thiacloprid, Rimon and insect pheromone compounding, there is increasing to the preventing and treating of insect pest
Effect acts on, and field experiment result shows, for having the target insect for ability of necessarily migrating as adult, especially in aviation plant protection
In, synergistic effect is even more than 50%.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (10)
1. a kind of Pesticidal combination, including insect pheromone, thiacloprid and Rimon.
2. Pesticidal combination according to claim 1, it is characterised in that the insect pheromone and thiacloprid, double benzene fluorine
The mass ratio of urea is (1~55):(1~30):(1~40).
3. Pesticidal combination according to claim 2, it is characterised in that the insect pheromone is included along the carbon of 6- 21
Alkene -11- ketone, suitable 6, along the carbon -6,9- diene of 9- 21 and along 6, along the one or more in the carbon -6,9- diene of 9- 23.
4. Pesticidal combination according to claim 2, it is characterised in that the insect pheromone is included along the carbon of 11- 16
One or more in alkene ester, suitable 11- hexadecenals and suitable 11- hexadecenols.
5. Pesticidal combination according to claim 2, it is characterised in that the insect pheromone includes acetic acid E-5- decene
Ester, E-5- decenols, E-9, Z11- hexadecadienoic aldehydes, acetic acid hexadecylene ester and along one kind or several in 11- hexadecenols
Kind.
6. Pesticidal combination according to claim 2, it is characterised in that the insect pheromone includes (5R, 6S) -6- second
It is acidic group -5- hexadecanolides, cis -9- 23 carbene, 10- methyl -9- 23 carbene, cis -2- methyl -8- 22 carbene, suitable
Formula -9- 22 carbene, cis -8- 22 carbene, cis -10- 23 carbene, the chloro- 6- methyl isophthalic acids-carboxylic acid tert-butyl esters of 2-, methyl
One or more in eugenol and the p- acetyl group phenyl -2- butanone of 4-.
7. Pesticidal combination according to claim 2, it is characterised in that the insect pheromone includes butyl butyrate, trans-
One or more in 2- butyric acid hexene esters and trans- 4- carbonyls -2- hexenoic aldehydes.
8. Pesticidal combination according to claim 2, it is characterised in that the insect pheromone includes 1,13- tridecanes
One or more in glycol, 2- hendecane epoxide -1- ethanol and trans- 4- carbonyls -2- hexenoic aldehydes.
9. the Pesticidal combination according to claim 3~8, it is characterised in that the insect pheromone also includes trans -2-
Hexenoic aldehyde, isothiocyanates, isothiocyanate, leaf-alcohol, leaf-alcohol ester, phenylacetaldehyde, gaultherolin, hexyl acetate, n-hexyl alcohol, benzene
Acetaldehyde dimethylacetal, cis-blatter alcohol, D- limonenes, L-citrene, 1- hexene-3-ols, linalool, australene, β-
Firpene, α-carypohyllene, β-carypohyllene, gaultherolin, trans-anethole, anethole, anise alcohol, o-methoxybenzoic acid first
Ester, benzyl carbinol, butyl salicylate and by tree brain in one or more.
10. application of the Pesticidal combination according to claim 1~9 any one in insecticidal preparation is prepared, described to kill
Worm preparation includes suspending agent, microcapsule suspending agent, oil-suspending agent, low capacity liquor or thermal fog.
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| CN111165234A (en) * | 2019-12-17 | 2020-05-19 | 湖南捷力洲有害生物防制有限公司 | Biological control method for fall webworms |
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| CN112239383A (en) * | 2020-10-28 | 2021-01-19 | 中诚国联（河南）生物科技有限公司 | Application of pesticide-fertilizer granules containing dinotefuran and monosultap to rice |
| CN113545346A (en) * | 2021-08-30 | 2021-10-26 | 广西壮族自治区亚热带作物研究所（广西亚热带农产品加工研究所） | Synergistic composition for preventing and treating papaya aphids |
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| CN113545346A (en) * | 2021-08-30 | 2021-10-26 | 广西壮族自治区亚热带作物研究所（广西亚热带农产品加工研究所） | Synergistic composition for preventing and treating papaya aphids |
| CN113545346B (en) * | 2021-08-30 | 2022-04-12 | 广西壮族自治区亚热带作物研究所（广西亚热带农产品加工研究所） | Synergistic composition for preventing and treating papaya aphids |
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