CN115006285A

CN115006285A - Smoothie-like makeup remover composition and preparation method thereof

Info

Publication number: CN115006285A
Application number: CN202210555241.7A
Authority: CN
Inventors: 陈冬琦; 崔泽亮; 黄思旗; 马艺宸; 胡艳波; 陈欢; 周秋娜; 金荣熙; 金延埈
Original assignee: Shanghai Lizhi Brand Management Co ltd; Cosmax China Cosmetics Co Ltd
Current assignee: Shanghai Lizhi Brand Management Co ltd; Cosmax China Cosmetics Co Ltd
Priority date: 2021-06-28
Filing date: 2022-05-20
Publication date: 2022-09-06
Also published as: CN113440433A

Abstract

The invention relates to a composition for removing makeup and cleaning face in ice-cream shape. The color-changing facial make-up cream comprises thickening agents such as acrylic acid (ester) cross-linked polymer sodium-2 or sodium polyacrylate grafted starch and the like, forms unique mousse ice sand texture, can help to accelerate dissolving of color-changing make-up through gentle massage, and simultaneously reduces barrier damage caused by friction to skin; the composition of the invention contains a sebum-like ingredient, moisturizes and reduces skin dryness after makeup removal. The product provided by the invention has comfortable smoothie texture, excellent makeup removing capability, good moisturizing effect, safety and mildness.

Description

Smoothie-like makeup remover composition and preparation method thereof

Technical Field

The invention relates to a composition for removing makeup and cleaning face in ice-cream shape. Has comfortable smoothie texture, excellent makeup removing capability, good moisturizing effect, safety and mildness.

Background

With the improvement of living standard and the pursuit of beauty of modern people, the cosmetics products are more and more popular, and the makeup removal becomes an indispensable step for many modern people every day. Persistent cosmetic residue and soil from improper cleansing can be a significant injury to facial skin, especially long-lasting lip makeup, water-resistant mascaras, and long-lasting foundations, among others.

The makeup removing products which are mainstream on the market at present mainly comprise makeup removing water, makeup removing cream, makeup removing oil, makeup removing cream/cream, makeup removing gel and the like. The cleansing water does not contain an oil phase generally, and has the advantages of comfortable skin feel and no need of secondary water washing; however, the makeup remover is weak, difficult to remove lipstick or mascara, and easy to remain. Meanwhile, the makeup remover is inconvenient to use due to the fact that makeup cotton needs to be matched with the makeup remover; the makeup cotton needs to be rubbed back and forth on the face when being removed, so that the cuticle of the skin is easily damaged, and stimulation is caused. The makeup removing oil or the makeup removing cream usually comprises an oil phase and an emulsifier, and the makeup remover removes makeup by utilizing the principle of similar intermiscibility, has good makeup removing capability but oily skin, needs secondary cleaning and has poor use experience. The makeup removing cream/cream usually comprises three phases of an oil phase, a water phase and an emulsifier, and can remove grease, a film forming agent, a macromolecular polymer and the like, but the existing makeup removing cream/cream still has the problems of slow makeup melting and long makeup removing time.

Therefore, a makeup removing product which has strong makeup removing force, is mild, does not hurt the skin and has fresh and greasy skin feeling is still needed in the market at present.

Brief description of the invention

Based on this, the present invention provides, firstly in a first aspect, a makeup removing composition comprising the following components:

a) a surfactant;

b) skin care grease;

c) a thickener which accounts for 0.1 to 5 weight percent of the composition; wherein the thickening agent is selected from one or more of acrylic acid (ester) cross-linked polymer sodium-2, sodium polyacrylate grafted starch, gellan gum and agarose;

d) a humectant; and

e) water accounts for 60-90 wt% of the composition.

In some embodiments of the invention, the makeup removal composition of the invention comprises the following components:

a) surfactant accounting for 8-15 wt% of the composition;

b) skin care grease which accounts for 1-5 wt% of the composition;

c) a thickener, wherein the thickener accounts for 0.5 to 2 weight percent of the composition; the thickening agent is selected from one or more of cross-linked polymer sodium-2 of acrylic acid (ester) or sodium polyacrylate grafted starch;

d) a humectant accounting for 5 wt% -10 wt% of the composition; and

e) water; accounting for 70wt percent to 80wt percent of the composition.

In some embodiments, the makeup removal composition of the present invention further comprises a chelating agent and/or a humectant and/or an emulsifier and/or a preservative and/or a skin conditioner and/or a fragrance.

In particular embodiments, the chelating agent comprises 0.01 wt% to 0.05 wt% of the composition; the humectant accounts for 3-12 wt% of the composition; the emulsifier accounts for 0.2-5 wt% of the composition; the preservative accounts for 0.1-5 wt% of the composition; the skin conditioning agent comprises 0.1 wt% to 10 wt%, such as 0.1 wt% to 5 wt% or 5 wt% to 10 wt% of the composition; the essence accounts for 0.01-0.1 wt% of the composition.

In some embodiments, in the make-up remover composition of the present invention, the surfactant is selected from at least one or more of PEG-7 glyceryl cocoate, PEG-6 caprylic/capric glycerides, poloxamer 184, glyceryl polyether-7, PPG-30 buthyleth-30, polyglyceryl-2 oleate, polyglyceryl-10 dioleate, polyglyceryl-2 sesquicaprylate, polyglyceryl-10 stearate, potassium laurate; preferably poloxamer 184 and/or PEG-7 glyceryl cocoate and/or PEG-6 caprylic/capric glycerides.

In some embodiments, the skin care oil is selected from at least one or more of caprylic/capric triglyceride, hydrogenated polydecene, caprylic/capric/myristic/stearic triglyceride, octyldodecanol myristate, ethylhexyl palmitate, decyl cocoate, diisostearyl malate, pentaerythritol tetrakis (ethyl hexanoate), hydrogenated C6-14 alkene polymers, coconut oil, mango seed fat, jojoba seed oil, sunflower seed oil, meadowfoam seed oil, macadamia integrifolia seed oil, shea butter, sweet almond oil, squalane, tocopherol acetate, cetyl ethylhexanoate, polydimethylsiloxane; preferably caprylic/capric triglyceride and/or jojoba seed oil, more preferably caprylic/capric triglyceride and/or cetyl ethylhexanoate and/or olive oil and/or geranium oil and/or bergamot oil and/or jojoba seed oil, most preferably a combination of caprylic/capric triglyceride and cetyl ethylhexanoate and olive oil and geranium oil and bergamot oil and jojoba seed oil.

In some embodiments, in the make-up removal composition of the present invention, the thickener comprises, in addition to the above, one or more of PEG-240/HDI copolymer bis-decyltetradecanol polyether-20 ether, xanthan gum, cellulose ether, carboxymethyl cellulose, hydroxyethyl cellulose, gelatin, sodium alginate, dextrin, fatty acid polyglycol ester. In a preferred embodiment, in the makeup removing composition according to the invention, the thickener further comprises PEG-240/HDI copolymer bis-decyltetradecanol polyether-20 ether, in addition to the above.

In some embodiments, the cleansing composition of the present invention wherein the humectant is selected from at least one or more of glycerin, butylene glycol, 1, 2-pentanediol, 1, 2-hexanediol, polyethylene glycol-32, dipropylene glycol, octylene glycol, sorbitol, 1, 2-propanediol, 1, 3-propanediol, sucrose, octanediol; one or more of 1, 3-butanediol, dipropylene glycol, octylene glycol, 1, 2-pentanediol, or octanediol are preferred.

In some embodiments, in the make-up remover composition of the present invention, the chelating agent is selected from at least one or more of disodium EDTA, tetrasodium EDTA, sodium phytate; sodium phytate is preferred.

In some embodiments, in the make-up remover composition of the present invention, the emulsifier is selected from at least one or more of polysorbate-20, polysorbate-60, glyceryl stearate SE, PEG-100 stearate, polyglyceryl-3-methylglucose distearate, PEG-60 hydrogenated castor oil, ceteth-20, cetearyl glucoside, sorbitan stearate, sorbitan sesquioleate, cetearyl alcohol, cetearyl olive oleate, sorbitan olive oleate, C12-20 alkyl glucoside, octyldodecyl polyether-25; PEG-100 stearate, polysorbate-20 and/or glyceryl stearate are preferred.

In some embodiments, in the makeup removing composition of the present invention, the preservative is selected from at least one or more selected from phenoxyethanol, ethylhexyl glycerin, p-hydroxyacetophenone, and butylated hydroxytoluene.

In some embodiments, the makeup remover composition of the present invention, the skin conditioning agent is selected from the group consisting of a soybean seed extract, a lavender extract, an apple fruit extract, an aloe extract, a sweet orange fruit extract, a citron fruit extract, a bergamot fruit extract, a grapefruit skin extract, a mint extract, an albizzia bark extract, a sugar cane extract, one or more of peony flower extract, sea buckthorn fruit extract, horse chestnut extract, hollyhock flower extract, coconut fruit extract, silica, tocopherol, aesculus hippocastanum flower water, yeast fermentation product filtrate, saccharomyces diculus fermentation product lysate, preferably a glycine soja seed extract and/or aesculus hippocastanum flower water and/or yeast fermentation product filtrate and/or saccharomyces diculus fermentation product lysate, more preferably a combination of glycine soja seed extract and aesculus hippocastanum flower water and yeast fermentation product filtrate and saccharomyces diculus fermentation product lysate.

In a preferred embodiment, the composition according to the invention does not comprise silicone oil.

In another aspect, the present invention also relates to a method of preparing the make-up removing composition described herein above, comprising the steps of:

1) a, B, C, D, preparing phase components; wherein, water, chelating agent, humectant and makeup removing surfactant are mixed, heated and dissolved, and kept warm to obtain phase A; heating, dissolving and mixing emulsifier and skin care grease to obtain phase B; the thickener mixture is phase C; mixing antiseptic, skin conditioner and essence to obtain phase D;

2) weighing phase A, phase B, phase C and phase D according to the mass percentage of the composition;

3) adding the phase B pretreatment into the phase A, homogenizing for several minutes, and confirming the dispersion state;

4) cooling the content obtained in the step 3), slowly adding the phase C in portions, and homogenizing for a plurality of minutes;

5) cooling the content obtained in the step 4), adding the phase D, and homogenizing for a plurality of minutes to obtain the cleansing smoothie.

In some embodiments, wherein the phase A thermal dissolution temperature is 60-90 ℃, preferably 70-80 ℃; the phase B has a thermal dissolution temperature of 60-90 deg.C, preferably 70-80 deg.C.

In some embodiments, wherein in step 3), the homogenization temperature is 60 to 90 ℃, preferably 70 to 80 ℃, more preferably 72 to 75 ℃; the homogenizing time is 5-20 minutes, preferably 8-15 minutes; in the step 4), the cooling temperature is 30-80 ℃, preferably 40-70 ℃, and more preferably 50-55 ℃; the homogenizing time is 3-15 minutes, preferably 5-8 minutes; the cooling temperature in the step 5) is 25-60 ℃, preferably 30-50 ℃, and more preferably 40-45 ℃; homogenizing for 1-10 minutes, preferably 3-8 minutes, and more preferably 2-4 minutes; wherein the homogenizing rotation speed is 2500-.

In another aspect, the invention also relates to a smoothie-like makeup-removing gel comprising a makeup-removing composition according to the invention, and a cosmetically acceptable carrier or excipient.

The invention has the beneficial effects that: according to the smoothie cleansing gel, the product is in the form of smoothie gel by adding the acrylic acid (ester) cross-linked polymer sodium-2, has granular feel, and can assist the surface active ingredient to achieve a better cleansing effect. Because of its swelling action after absorbing water, it has a "water burst feeling" when removing makeup, providing a feeling of use. In addition, the cleansing cream has a film forming effect on the skin surface and realizes a synergistic moisturizing effect with the moisturizing component.

The smoothie cleansing gel disclosed by the invention is remarkable in moisturizing effect, excellent in cleansing capability, mild in texture, free of irritation, fresh and cool in skin feel, free of greasiness, good in user experience, simple in preparation process operation and suitable for large-scale production, and cleansing cotton does not need to be matched during use.

Detailed Description

Definition of

As used herein, the terms "comprises," "comprising," "includes," "including," "has," "having," "contains," "containing," or any other variation thereof, are intended to cover a non-exclusive inclusion. For example, a composition, process, method, article, or apparatus that comprises a list of elements is not necessarily limited to only those elements but may include other elements not expressly listed or inherent to such composition, process, method, article, or apparatus.

The term "consisting of … …," excludes any unlisted element, step or component. As used in the claims, shall render the claims closed, i.e. not containing materials other than the recited materials except for conventional impurities associated therewith. When the phrase "consisting of … …" appears in a clause of the subject matter of the claims and not immediately after the subject matter, it defines only the elements described in the clause; no other elements are excluded from the claims as a whole.

As used herein, any feature of the present invention described by "a" or "an" means one or more. "at least one" means one or more, i.e., comprising individual components, or mixtures/compositions.

Unless otherwise indicated, all numbers expressing quantities of ingredients and/or reaction parameters are to be understood as being modified by the term "about", i.e., within 10% of the number indicated (e.g., "about 10%" may mean 9% to 11%, "about 5%" may mean 4.5% to 5.5%).

Unless otherwise indicated, the percentages and ratios herein are based on the total weight of the composition; the percentages are based on the total composition. Generally, "weight" or "amount" as used herein with respect to a percentage of an ingredient refers to the amount of the raw material that includes the ingredient.

Unless otherwise defined or indicated, the measurement conditions of the present invention are understood to be ambient conditions, wherein ambient conditions refer to about 25 ℃, about one atmosphere of pressure, and at about 50% relative humidity.

The numerical ranges given herein include subranges using any endpoint value. For example, a range of "1% -10%, such as 2% -8%, such as 3% -5%" includes "1% -8%", "1% -5%" "2% -10%", "3% -10%" and the like. All numbers, amounts, ranges, etc. may be modified by the term "about". For example, a range given as "about 1% -10%" relates to "about" modifying the endpoints of 1% and 10%.

Any numerical value includes certain errors necessarily resulting from the standard deviation found in their respective testing measurements.

The terms "keratinous substrate" and "keratinous tissue" refer to a keratin-containing layer that is the outermost protective covering species for a mammal (e.g., a human, or other animal, such as a cat); including but not limited to skin, hair and nails, cuticles, lips, and the like.

The terms "apply" or "spread" and the like refer to the use or spreading of the compositions of the present invention on keratinous tissue, such as skin.

As used herein, the term "cosmetic" refers to compositions for use on the human body, such as skin compositions, sunscreen compositions, hair compositions, oral compositions, cosmetic compositions, make-up removal compositions, preservative compositions, and the like.

The term "cosmetically acceptable" refers to molecular entities or compositions that are generally considered safe, are approved by the appropriate governmental regulatory agency, or are listed in generally recognized pharmacopoeias as being useful in animals, particularly humans; in particular, as used herein, a carrier that is compatible in contact with any keratinous substrate or tissue does not produce toxicity, incompatibility, instability, or irritation.

As used herein, the term "fragrance" or "perfume" generally comprises components that react with the human olfactory locus to produce a so-called "aroma". Typical molecules comprised by perfumes or fragrances are linear and cyclic olefins such as terpenes, primary, secondary and tertiary alcohols, nitrites, ethers, saturated or unsaturated aldehydes, esters, ketones and mixtures thereof.

Makeup removing composition

The invention provides the makeup removing smoothie which can effectively remove makeup with water burst feeling by forming micelles by the surfactant and having the physical massage effect. It can effectively remove facial makeup and residual dirt, and has refreshing and non-greasy skin feeling.

The product of the invention comprises acrylic acid (ester) cross-linked polymer sodium-2, sodium polyacrylate grafted starch, gellan gum and/or agarose, forms unique mousse smoothie texture, assists soft massage, helps to accelerate dissolving of color cosmetics, and simultaneously reduces barrier damage caused by friction to skin; contains sebum-like components (jojoba oil and caprylic/capric triglyceride), is safe, mild, moisturized, and reduces skin dryness after makeup removal. Compared with the commercially available makeup removing products, the makeup removing cream has excellent makeup removing effect, good moisturizing effect, safety, mildness and better use experience.

First, in a first aspect of the present invention, there is provided a cleansing composition in the form of a slush comprising the following components:

a) a surfactant;

b) skin care grease;

c) a thickener, the thickener comprises 0.1 wt% to 5 wt% of the composition; the thickening agent is selected from one or more of acrylic acid (ester) cross-linked polymer sodium-2, sodium polyacrylate grafted starch, gellan gum or agarose;

d) a humectant; and

e) water accounts for 60-90 wt% of the composition.

In some embodiments, the makeup removal composition comprises the following components:

a) surfactant accounting for 8-15 wt% of the composition;

b) skin care grease which accounts for 1-5 wt% of the composition;

d) a humectant accounting for 5 wt% -10 wt% of the composition; and

e) water; accounting for 70wt percent to 80wt percent of the composition.

In some embodiments, the makeup removal composition further comprises a chelating agent, a humectant, an emulsifier, a preservative, a skin conditioning agent, and/or a fragrance. In some embodiments, the makeup removal composition does not comprise silicone oil.

In some embodiments, the surfactant is selected from at least one or more of PEG-7 glyceryl cocoate, PEG-6 caprylic/capric glycerides, poloxamer 184, glyceryl polyether-7, PPG-30 butyether-30, polyglyceryl-2 oleate, polyglyceryl-10 dioleate, polyglyceryl-2 sesquicaprylate, polyglyceryl-10 stearate, potassium laurate; preferably poloxamer 184 and/or PEG-7 glyceryl cocoate and/or PEG-6 caprylic/capric glycerides. In some embodiments, the surfactant is present in a proportion of 8% to 15%, preferably 10% to 12% by weight of the composition. In a particular embodiment, the surfactant comprises 2% to 10%, preferably 3% to 8%, more preferably 6% PEG-7 glyceryl cocoate; the surfactant comprises 2% -8%, preferably 3% -6%, more preferably 5% of PEG-6 caprylic/capric glycerides; the surfactant comprises 0.5-8%, preferably 1-5%, and more preferably 2% of poloxamer 184. Wherein the weight percentages are based on the total weight of the make-up removal composition.

In some embodiments, the skin care oil is selected from at least one or more of caprylic/capric triglyceride, hydrogenated polydecene, caprylic/capric/myristic/stearic triglyceride, octyldodecanol myristate, ethylhexyl palmitate, decyl cocoate, diisostearyl malate, pentaerythritol tetrakis (ethylhexanoate), hydrogenated C6-14 alkene polymers, coconut oil, mango seed fat, jojoba seed oil, sunflower seed oil, meadowfoam seed oil, macadamia ternifolia seed oil, shea butter, sweet almond oil, squalane, tocopherol acetate, cetyl ethylhexanoate, polydimethylsiloxane; preferably caprylic/capric triglyceride and/or jojoba seed oil, more preferably caprylic/capric triglyceride and/or cetyl ethylhexanoate and/or olive oil and/or geranium oil and/or bergamot oil and/or jojoba seed oil, most preferably a combination of caprylic/capric triglyceride and cetyl ethylhexanoate and olive oil and geranium oil and bergamot oil and jojoba seed oil. In some embodiments, the skin oil is present in a ratio of 1% to 5%, preferably 1.5% to 2.5% by weight of the composition. In particular embodiments, the skin care oil comprises 0.2% to 5%, preferably 0.5% to 2%, more preferably 1% caprylic/capric/triglyceride; the skin care grease comprises 0.05-2%, preferably 0.1-0.5%, more preferably 0.2% of jojoba seed oil. Wherein the weight percentages are based on the total weight of the make-up removal composition.

In particular embodiments, in addition to the above, the compositions of the present invention may further comprise one or more other suitable thickeners, suitable classes of which include, but are not limited to, carboxylic acid polymers, polyacrylamide polymers, sulfonated polymers, copolymers thereof, hydrophobically modified derivatives thereof, or mixtures thereof. Preferably, the additional thickener is selected from one or more of PEG-240/HDI copolymer bis-decyltetradecanol polyether-20 ether, xanthan gum, cellulose ether, carboxymethyl cellulose, hydroxyethyl cellulose, gelatin, sodium alginate, dextrin or fatty acid polyethylene glycol ester. In a preferred embodiment, the other thickener is selected from the group consisting of PEG-240/HDI copolymer bis-decyltetradecanol polyether-20 ether.

Further preferably, in the makeup remover composition, the thickener comprises acrylic acid (ester) crosslinked polymer sodium-2 and PEG-240/HDI copolymer bis-decyltetradecanol polyether-20 ether.

In some embodiments, the thickener is present in an amount of 0.1% to 5%, preferably 0.5% to 1.5%, more preferably 0.8% to 1%, and most preferably 0.95% by weight of the composition. In some embodiments, the thickener is preferably a combination of sodium acrylate crosspolymer, sodium-2, and PEG-240/HDI copolymer bis-decyltetradecylpolyether-20 ether; or a thickener, preferably a combination of sodium polyacrylate grafted starch and PEG-240/HDI copolymer bis-decyltetradecanol polyether-20 ether; or the thickening agent is preferably a composition of acrylic acid (ester) cross-linked polymer sodium-2, sodium polyacrylate grafted starch and PEG-240/HDI copolymer bis-decyltetradecylpolyether-20 ether; wherein the acrylic acid (ester) crosslinked polymer sodium-2 is preferably 0.1-1%, more preferably 0.25-1%, or further preferably 0.35-0.75%, the sodium polyacrylate grafted starch is preferably 0.05-0.8%, preferably 0.1-0.5%, more preferably 0.15-0.3%, the PEG-240/HDI copolymer bis-decyltetradecanol polyether-20 ether is preferably 0.1-0.5%, more preferably 0.1-0.3%, and most preferably 0.2% by weight of the composition. Wherein the weight percentages are based on the total weight of the make-up removal composition.

In some embodiments, the humectant is selected from at least one or more of glycerin, butylene glycol, 1, 2-pentanediol, 1, 2-hexanediol, polyethylene glycol-32, dipropylene glycol, octylene glycol, sorbitol, 1, 2-propanediol, 1, 3-propanediol, sucrose, octanediol; preferably one or more of 1, 3-butanediol, dipropylene glycol, octylene glycol, 1, 2-pentanediol or octanediol. In some embodiments, the humectant comprises from 3% to 12%, preferably from 5% to 10%, more preferably from 7% to 9% by weight of the composition. In particular embodiments, the humectant comprises 3% to 5%, preferably 4%, 1, 3-butanediol; the humectant comprises 2 to 5 percent, preferably 3 percent of dipropylene glycol; the humectant comprises 0.1-1%, preferably 0.2-0.5%, more preferably 0.3% of dioctyl glycol; the humectant comprises 0.1-2%, preferably 0.2-1%, more preferably 0.5% of 1, 2-pentanediol. Wherein the weight percentages are based on the total weight of the make-up removal composition.

In some embodiments, the chelating agent is selected from at least one or more of disodium EDTA, tetrasodium EDTA, sodium phytate; sodium phytate is preferred. In some embodiments, the chelating agent is present in an amount of 0.01 to 0.05%, preferably 0.02%, by weight of the composition.

In some embodiments, the emulsifier is selected from at least one or more of polysorbate-20, polysorbate-60, glyceryl stearate SE, PEG-100 stearate, polyglyceryl-3 methyl glucose distearate, PEG-60 hydrogenated castor oil, ceteareth-20, cetearyl glucoside, sorbitan stearate, sorbitan sesquioleate, cetearyl alcohol, cetearyl olive oleate, sorbitan olive oleate, C12-20 alkyl glucoside, octyldodeceth-25; PEG-100 stearate, polysorbate-20 and/or glyceryl stearate are preferred. In some embodiments, the emulsifier is present in an amount of 0.2% to 5%, preferably 0.5% to 2%; in a specific embodiment, the emulsifier comprises 0.05% to 1%, preferably 0.1% to 0.5%, more preferably 0.2% PEG-100 stearate; the emulsifier comprises 0.05% to 1%, preferably 0.1% to 0.5%, more preferably 0.3% polysorbate-20; the emulsifier comprises 0.05% to 1%, preferably 0.1% to 0.5%, more preferably 0.3% glyceryl stearate. Wherein the weight percentages are based on the total weight of the make-up removal composition.

In some embodiments, the preservative is selected from at least one or more of phenoxyethanol, ethylhexyl glycerol, p-hydroxyacetophenone, butylated hydroxytoluene, preferably ethylhexyl glycerol, phenoxyethanol, and/or p-hydroxyacetophenone. In some embodiments, the preservative is present at a level of 0.1% to 5%, preferably 0.5% to 2%, more preferably 0.8% by weight of the composition; in particular embodiments, the preservative comprises from 0.05% to 1%, preferably from 0.1% to 0.5%, more preferably 0.2% of ethylhexyl glycerol; the preservative comprises 0.05-1%, preferably 0.1-0.5%, more preferably 0.3% phenoxyethanol; the preservative comprises 0.05-1%, preferably 0.1-0.5%, more preferably 0.3% of p-hydroxyacetophenone. Wherein the weight percentages are based on the total weight of the make-up removal composition.

In some embodiments, the skin conditioner is selected from the group consisting of a Glycine soja seed extract, a lavender (Lavandula angustifolia) extract, an apple (Malus domestica) fruit extract, an Aloe (Aloe vera) extract, a sweet orange (Citrus aurantium dulcis) fruit extract, a citron (Citrus medica) fruit extract, a bergamot (Citrus aurantium bergamo) fruit extract, a grapefruit (Citrus grandis) bark extract, a mint (Mentha arvensis) extract, a Crataegus pinnatifida (Crataegus cuneata) fruit extract, an Albizia julibrissin (Albizia julibrissin) bark extract, a sugar cane (Saccharum ficum) extract, a Paeonia (Paoniella) alboflurana flower extract, a plantarena flower extract, a cyathula flower extract, a japonica flower extract, a mangifera (Phellodendron amurense) root extract, a officinalis (Phellodendron amurense) bark extract, a officinalis root extract, a officinalis (Phellodendron amurense) bark extract, and a officinalis (Phellodendron amurense) fruit extract, a officinalis extract, and a pinnatifida extract, One or more of horse chestnut (Aesculus chinensis) extract, hollyhock (Althaea Rosea) flower extract, coconut (Cocos nucifera) fruit extract, silica, tocopherol, Aesculus hippocastanum flower water, yeast fermentation product filtrate, saccharomyces bifidus fermentation product lysate, preferably a wild soybean seed extract, more preferably a wild soybean seed extract and/or Aesculus hippocastanum flower water and/or yeast fermentation product filtrate and/or saccharomyces bifidus fermentation product lysate, most preferably a combination of a wild soybean seed extract and Aesculus hippocastanum flower water and yeast fermentation product filtrate and saccharomyces bifidus fermentation product lysate. In some embodiments, the skin conditioning agent comprises 0.1% to 5%, preferably 0.5% to 2%, more preferably 1%, by weight of the total make-up removal composition.

In some embodiments, the essence is selected from (daily use) essences, such as cosmetic or skin care essences, selected from, for example, rose essence, jasmine essence, gardenia essence, lavender essence, osmanthus essence, cucumber essence, green tea essence, aloe essence, mint essence, and the like; the essence accounts for 0.01-0.1 percent of the total weight of the makeup removing composition, preferably 0.02-0.075 percent, and more preferably 0.05 percent.

The compositions of the present invention may also contain at least one additive for use in the composition, or other cosmetically acceptable components. Such additives or components are ingredients that do not affect the performance of the compositions of the present invention, for example, including but not limited to perfumes, pearlizing agents, silicas, preservatives, amino acids, peptides, proteins, protein hydrolysates, sugar amines, panthenol, silicones, odor absorbers, antioxidants or radical scavengers, minerals, anti-inflammatory agents, lubricants, penetrants, viscosity modifiers, colorants, film formers, volatiles, pH modifiers, buffering agents, gelling agents, hydrophilic or lipophilic active agents, reducing agents, light stabilizers, and the like; oil control agents, such as salicylic acid, dehydroacetic acid, benzoyl peroxide; vitamins, such as vitamin B (including B1, B2, B3 such as niacinamide, niacin, tocopherol nicotinate, C1-C18 nicotinate, and nicotinyl alcohol; B5 such as panthenol or "Pre-B5", pantothenic acid, panthenyl, B6 such as pyridoxine, pyridoxal, pyridoxamine, carnitine, thiamine, riboflavin), vitamin A and its natural and/or synthetic analogs, including retinoids, retinol, retinyl acetate, retinyl palmitate, retinoic acid, retinal, retinyl propionate, carotenoids, vitamin D, vitamin K, vitamin C including ascorbate, ascorbyl esters of fatty acids and ascorbic acid derivatives, such as ascorbyl phosphate such as magnesium ascorbyl phosphate and sodium ascorbyl phosphate, ascorbyl glucoside and ascorbyl sorbate, and vitamin F such as saturated or unsaturated fatty acids; antibacterial ingredients such as caprylyl glycine and sodium salicylate; essential oil; fruit extracts such as apple fruit extract, aloe extract, sweet orange fruit extract, citron fruit extract, bergamot fruit extract, grapefruit peel extract, etc.; plant extracts such as lavender extract, peppermint extract, wild soybean seed extract, albizia bark extract, sugar cane extract, peony flower extract, etc.; citric acid, sodium chloride; and combinations thereof.

Preparation method

On the other hand, the invention also provides a preparation method of the smoothie cleansing composition, which comprises the following steps:

1) mixing water, chelating agent, humectant and makeup removing surfactant, heating for dissolving, and keeping the temperature to obtain phase A; emulsifier and skin care grease are heated to be dissolved and mixed to be used as a phase B; the thickener mixture is phase C; mixing antiseptic, skin conditioner and essence to obtain phase D;

2) and weighing the phase A, the phase B, the phase C and the phase D according to the mass percentage.

3) The B phase was added to the A phase for homogenization for several minutes to confirm the dispersion state.

4) Cooling the content obtained in the step 3), slowly adding the phase C in portions, and homogenizing for a plurality of minutes.

5) Cooling the content obtained in the step 4), adding the phase D, and homogenizing for a plurality of minutes to obtain the makeup removing smoothie.

In some embodiments, the water is present in an amount of from 60 to 90%, preferably from 70 to 80%, more preferably about 75%, by weight of the composition; the chelating agent accounts for 0.01-0.05%, preferably 0.02%; the humectant accounts for 3% -12%, preferably 5% -10%, more preferably 7% -9%; the proportion of the surfactant is 8-15%, preferably 10-12%. In some embodiments, the phase a thermal dissolution temperature is from 60 to 90 ℃, preferably from 70 to 80 ℃.

In some embodiments, the emulsifier is present in an amount of 0.2% to 5%, preferably 0.5% to 2%; the skin care grease accounts for 1% -5%, preferably 1.5% -2.5%. In some embodiments, the phase B thermal dissolution temperature is from 60 to 90 deg.C, preferably from 70 to 80 deg.C.

In some embodiments, the thickener is present in an amount of 0.1% to 5%, preferably 0.5% to 1.5%, more preferably 0.8% to 1%, and most preferably 0.95% by weight of the composition. In some embodiments, the thickener is preferably a combination of sodium acrylate crosspolymer, sodium-2, and PEG-240/HDI copolymer bis-decyltetradecylpolyether-20 ether; or the thickener is preferably a combination of sodium polyacrylate grafted starch and PEG-240/HDI copolymer bis-decyltetradecanol polyether-20 ether; or the thickening agent is preferably a composition of acrylic acid (ester) cross-linked polymer sodium-2, sodium polyacrylate grafted starch and PEG-240/HDI copolymer bis-decyltetradecylpolyether-20 ether; wherein the acrylic acid (ester) crosslinked polymer sodium-2 is preferably 0.1-1%, more preferably 0.25-1%, or further preferably 0.35-0.75%, the sodium polyacrylate grafted starch is preferably 0.05-0.8%, preferably 0.1-0.5%, more preferably 0.15-0.3%, the PEG-240/HDI copolymer bis-decyltetradecanol polyether-20 ether is preferably 0.1-0.5%, more preferably 0.1-0.3%, and most preferably 0.2% by weight of the composition. Wherein the weight percentages are based on the total weight of the make-up removal composition.

In some embodiments, the preservative is present at a level of 0.1% to 5%, preferably 0.5% to 2%, more preferably 0.8% by weight of the composition; the skin conditioning agent comprises from 0.1% to 10%, such as from 0.1% to 5%, preferably from 0.5% to 2%, more preferably 1%, or from 5% to 10%, preferably from 5% to 9%, more preferably 8%; the essence accounts for 0.01-0.1%, preferably 0.02-0.075%, and more preferably 0.05%.

In some embodiments, wherein in step 3), the homogenization temperature is 60 to 90 ℃, preferably 70 to 80 ℃, more preferably 72 to 75 ℃; the homogenization time is 5 to 20 minutes, preferably 8 to 15 minutes.

In some embodiments, in step 4), the content obtained in step 3) is cooled to 30-80 ℃, preferably 40-70 ℃, and more preferably 50-55 ℃; homogenizing for 3-15 min, preferably 5-8 min.

In some embodiments, wherein in step 5), the content obtained in step 4) is cooled to 25-60 ℃, preferably 30-50 ℃, more preferably 40-45 ℃; homogenizing for 1-10 minutes, preferably 3-8 minutes, and more preferably 2-4 minutes to obtain the cleansing smoothie.

Further, in the preparation method of the moisturizing cleansing smoothie as described above, step 1):

the chelating agent is at least one or more of disodium EDTA, tetrasodium EDTA and sodium phytate.

The humectant is at least one or more selected from glycerol, butanediol, 1, 2-pentanediol, 1, 2-hexanediol, polyethylene glycol-32, dipropylene glycol, sorbitol, 1, 2-propanediol, 1, 3-propanediol, octanediol and sucrose.

The makeup removing surfactant is at least one or more selected from PEG-7 glyceryl cocoate, PEG-6 caprylic/capric glycerides, poloxamer 184, glyceryl polyether-7, PPG-30 butanol polyether-30, polyglycerol-2 oleate, polyglycerol-10 dioleate, polyglycerol-2 sesqui-caprylate, polyglycerol-10 stearate and potassium laurate.

Further, as described above for step 1), phase B:

the skin care oil is selected from at least one or more of caprylic/capric triglyceride, hydrogenated polydecene, caprylic/capric/myristic/stearic triglyceride, octyldodecanol myristate, ethylhexyl palmitate, decyl cocoate, diisostearyl malate, pentaerythritol tetrakis (ethyl hexanoate), hydrogenated C6-14 alkene polymers, coconut oil, mango seed fat, jojoba seed oil, sunflower seed oil, meadowfoam seed oil, macadamia ternifolia seed oil, shea butter, sweet almond oil, squalane, tocopherol acetate, cetyl ethyl hexanoate and polydimethylsiloxane.

The emulsifier is selected from at least one or more of polysorbate-20, polysorbate-60, glyceryl stearate SE, PEG-100 stearate, polyglyceryl-3-methylglucdistearate, PEG-60 hydrogenated castor oil, ceteth-20, cetearyl glucoside, sorbitan stearate, sorbitan sesquioleate, cetearyl alcohol, cetearyl olive oleate, sorbitan olive oleate, C12-20 alkyl glucoside, and octyl laureth-25.

Further, as described above for step 1), phase D:

the preservative is selected from at least one or more of phenoxyethanol, ethylhexyl glycerol, p-hydroxyacetophenone and butylated hydroxytoluene.

The skin conditioner is selected from active substances such as extract of semen glycines, extract of Lavender, extract of pericarpium Citri Grandis, extract of fructus Hippophae, extract of horse chestnut, extract of flos Althaeae Roseae, extract of coconut fruit, silica, tocopherol, water of Aesculus hippocastanum flower, yeast fermentation product filtrate, and lysate of yeast fermentation product, and at least one or more of them can be added according to requirement.

The essence is selected from (daily use) essences such as rose essence, jasmine essence, gardenia essence, lavender essence, osmanthus essence, cucumber essence, green tea essence, aloe essence, mint essence, etc.

Further, in the preparation method of the makeup removing smoothie, steps 3) -5) as described above, the homogenization speed is 2500-3500 RPM.

Further, in the preparation method of the cleansing smoothie as described above, in the step 3), the thickener mixture is added in portions, and the number of times of adding is preferably 2 to 4 times.

In another aspect, the present invention also relates to the use of the make-up removal composition described above in cosmetics; preferably a make-up removal or cleansing product. More preferably a makeup removal product, which is useful for removing makeup and moisturizing the skin.

The carrier or excipient, which may be a cosmetically acceptable additive, or other ingredient, does not affect the performance of the product of the invention when added. For example, including, but not limited to, perfumes, pearlescers, silicas, preservatives, amino acids, peptides, proteins, protein hydrolysates, sugar amines, panthenol, silicones, odor absorbers, antioxidants or radical scavengers, minerals, anti-inflammatory agents, lubricants, osmotic agents, viscosity modifiers, colorants, film formers, volatiles, pH modifiers, buffers, gelling agents, hydrophilic or lipophilic active agents, reducing agents, light stabilizers, and the like; oil control agents, such as salicylic acid, dehydroacetic acid, benzoyl peroxide, niacinamide or tocopherol niacinamide; vitamins, such as vitamin B (including B1, B2, B3 such as niacinamide, niacin, tocopherol nicotinate, C1-C18 nicotinate, and nicotinyl alcohol; B5 such as panthenol or "Pre-B5", pantothenic acid, panthenyl, B6 such as pyridoxine, pyridoxal, pyridoxamine, carnitine, thiamine, riboflavin), vitamin A and its natural and/or synthetic analogs, including retinoids, retinol, retinyl acetate, retinyl palmitate, retinoic acid, retinal, retinyl propionate, carotenoids, vitamin D, vitamin K, vitamin C including ascorbate, ascorbyl esters of fatty acids and ascorbic acid derivatives, such as ascorbyl phosphate such as magnesium ascorbyl phosphate and sodium ascorbyl phosphate, ascorbyl glucoside and ascorbyl sorbate, and vitamin F such as saturated or unsaturated fatty acids; antibacterial ingredients such as caprylyl glycine and sodium salicylate; essential oil; fruit extracts such as apple fruit extract, aloe extract, sweet orange fruit extract, citron fruit extract, bergamot fruit extract, grapefruit peel extract, etc.; plant extracts such as lavender extract, peppermint extract, wild soybean seed extract, albizia bark extract, sugar cane extract, peony flower extract, etc.; citric acid, sodium chloride, and the like.

Drawings

FIG. 1: the appearance of the type I cleansing smoothie product of the invention is as follows: it is white translucent ice-sand.

FIG. 2 is a schematic diagram: the invention discloses a type I cleansing smoothie moisturizing test result: the water content increase and decrease rate of stratum corneum is shown along with the time change.

FIG. 3: the invention discloses a type I cleansing smoothie cleansing ability test result: test example 1 product of the present invention compares makeup removal before and after makeup removal for each makeup product (air cushion, eye shadow, waterproof eyeliner, waterproof mascara, and lipstick).

FIG. 4: the invention discloses a type I cleansing smoothie cleansing ability test result: comparative example 1 product pre-and post-makeup removal comparison of each color cosmetic product (air cushion, eye shadow, waterproof eyeliner, waterproof mascara, and lipstick).

FIG. 5: the II type cleansing smoothie cleansing capability test result of the invention is as follows: test example 4 of the present invention the product was compared to each makeup product (air cushion, eye shadow, waterproof eyeliner, waterproof mascara, and lipstick) before and after makeup removal.

FIG. 6: the invention relates to a type II cleansing smoothie cleansing ability test result: comparative example 2 product before and after makeup removal comparison of each makeup product (air cushion, eye shadow, waterproof eyeliner, waterproof mascara, and lipstick).

Detailed Description

The following examples are intended to illustrate embodiments of the invention, but should be understood to be merely illustrative and not restrictive, with reference to the accompanying drawings. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. The components used in the present invention are commercially available.

Example 1: composition of type I makeup removing composition

Mixing the phase A components, heating to dissolve to 75 ℃, adding the phase B pretreatment into the phase A, homogenizing at 75 ℃ for 10 minutes at 3500rpm, and confirming the dispersion state; cooling the obtained content to 55 ℃, slowly adding the phase C in 3 times, homogenizing at 3500rpm for 6 minutes; and cooling the obtained contents to 45 ℃, adding the phase D, and homogenizing for 3 minutes to obtain the cleansing smoothie.

Test examples 1 to 3 and comparative example 1 were prepared according to the above preparation method and the formulation of table 1 below, and the moisture retention ability, makeup removal ability, and stability test after use were compared.

Table 1: the invention relates to a type I makeup removing composition product

Example 2: comparative testing of moisturizing Capacity of type I make-up remover composition

The immediate moisturizing test was performed on the test examples 1 to 3, the comparative example 1, and a commercially available moisturizing makeup removing gel (grapefruit makeup removing gel, the same applies below) in example 1.

Selecting the measurement area of forearm curvature of the subject to be 2 x 2cm ² Respectively coating the products on areas to be detected, adding an equivalent amount of appropriate water, coating 30 circles of the products with latex finger sleeves, and cleaning with clear water; the measurements were carried out using a Corneometer CM825(CK, Germany) before, 0min, 10min and 30min after use, respectively, and the same points were measured 5 times, and 3 averages were taken after excluding the maximum and minimum values and recorded.

The rate of increase and decrease in the moisture content of the stratum corneum was calculated and the data are shown in table 2 and fig. 2. The stratum corneum water increase and decrease rate calculation formula is as follows:

the experimental results are as follows: referring to Table 2 and FIG. 2, comparing the cleansing smoothies of the present invention in the preparation of test examples 1-3 with comparative example 1 and a commercially available grapefruit cleansing gel, it was found that the rate of water increase in the stratum corneum was higher after using the cleansing smoothies of the present invention and for a period of time than the comparative example 1 and the commercially available moisturizing cleansing gel. It can be seen that the makeup removing smoothie of the present invention has very excellent instant moisturizing effect and can maintain high skin moisture content for a while after makeup removal.

Table 2: comparison of moisturizing Capacity of inventive cleansing smoothies, comparative example 1, and commercial products

Example 3: comparative test for makeup removal effect of makeup removal composition type I

To test the makeup removing ability of the smoothie makeup removing gel product of the present invention, comparative evaluation of the makeup removing ability was performed using the product of test example 1 of the present invention together with comparative example 1. The specific evaluation steps are as follows:

1. selecting the subjects, using the skin of the curved side of the left and right forearms as the subjects, and the test area of each product to be removed is 2 x 2cm ² And respectively smearing 10 mu L of air cushion, eye shadow, waterproof eyeliner, waterproof mascara cream and lipstick on the area to be detected.

2. Waiting for 10 minutes; the makeup removing products of the invention, test example 1 and comparative example 1, were used to remove makeup from the test area to which the makeup removing product was applied; until the test area remained in the post makeup removal state for several minutes with no significant change.

3. The camera respectively takes pictures in the same position under the condition of illumination before, after and after the makeup color product is applied; the obtained photo pair before and after makeup removal is shown in fig. 3 and 4.

As can be seen from a comparison of FIGS. 3 and 4, when the same makeup remover gel of the smoothie was used for removing the same makeup product in the same position of the same subject, the skin makeup remover gel of the smoothie showed less traces of makeup residue and less obvious color residue after removing makeup. The makeup removing effect of the product is obviously better than that of a comparative example.

Example 4: stability testing of type I make-up removing compositions

Test examples 1-3 of example 1 were each packaged in a colorless ground glass jar (not open) simulating the environment and conditions under which makeup removing gels were routinely stored. Placing the glass bottles at-7, 4, 25, 27 and 45 ℃ respectively, placing for 2 months under the condition of illumination (room temperature is 25 ℃), and continuously observing the appearance; wherein the degree of change is represented by 0-3, 0 is no significant change in color and texture, 1 is a slight acceptable change (e.g., slight color change, slight thickening of texture), 2 is an unacceptable change (e.g., significant color change, uneven gummy texture), and 3 is a severe change (e.g., severely reduced volume of jelly, yellowish brown color). The observation results are shown in table 3.

Table 3: the storage stability of the smoothie cleansing gel

As can be seen from Table 3, under the conditions of low temperature, normal temperature, high temperature and/or light treatment, the makeup remover product of the present invention has stable color property state, no obvious change and excellent stability within 2 months of the experiment.

Example 5: user experience testing of type I make-up removal compositions

The test method comprises the following steps: 20 female volunteers with the average age of 32.10 +/-4.48 years are selected and provided with samples of the products of the test examples 1-3, the product of the comparative example 1 and the commercially available moisturizing makeup-removing gel (grapefruit makeup-removing gel) in the example 1 of the invention to be respectively tried.

The evaluation method comprises the following steps:

1. applying a proper amount of the powder on the face, gently massaging and rubbing with fingers to remove the color cosmetics, and repeating until the powder is completely clean;

2. then cleaning with clear water;

3. after 15 minutes, the product was scored and the form filled in.

Grading standard: the score is 1-5; the scoring profiles are shown in Table 4 below. Wherein:

satisfaction criteria: "1" means very unsatisfactory; "2" means unsatisfactory; "3" means general; "4" means relatively satisfactory; "5" means very satisfactory.

Pain scoring criteria: the '5' is mild and has no stimulation; "4" is slightly painful and can be tolerated; the pain of the 3 part slightly affects the work and can be still tolerated; "2" pain and affects normal work, cannot be tolerated; "1" is painful and unable to work normally.

Purchase propensity criteria: "1" does not consider purchases at all; "2" basically does not take into account purchases; a "3" possible purchase; "4" inclined to purchase; "5" is very willing to buy.

Table 4: the invention provides the condition of the phenotypic form and the use feeling score of the cleansing smoothie

As can be seen from the test results of randomly selected users, the smoothie makeup removal product of the invention has better score than the comparative product in terms of moisturizing experience, makeup removal experience and overall use experience.

The invention provides a smoothie-shaped makeup remover which is stable in property, mild, free of stimulation, excellent in moisturizing and makeup removing effects, fresh, cool, not sticky and good in use experience.

EXAMPLE 6 composition of make-up remover composition type II

Test examples 4 to 6 and comparative example 2 were prepared according to the above preparation method and the following formulation of table 5, and comparison of moisturizing ability, makeup removing ability, and stability test after use was performed (test criteria are exactly the same as those of examples 1 to 5).

Table 5: the type II cleansing composition product of the present invention

Example 7: comparative testing of moisturizing Capacity of type II make-up remover composition

The test examples 4 to 6 in example 6 and comparative example 2 were subjected to an immediate moisture retention test.

Selecting forearm curve of subjectThe lateral measurement region was 2X 2cm ² Respectively coating the products on areas to be detected, adding an equivalent amount of appropriate water, coating 30 circles of the products with latex finger sleeves, and cleaning with clear water; the measurements were carried out using a Corneometer CM825(CK, Germany) before, 0min, 10min and 30min after use, respectively, and the same points were measured 5 times, and 3 averages were taken after excluding the maximum and minimum values and recorded.

The rate of increase and decrease in the water content of the horny layer was calculated and the data are shown in Table 6. The stratum corneum water increase and decrease rate calculation formula is as follows:

the experimental results are as follows: referring to Table 6, when the cleansing smoothies of the present invention preparations of test examples 4 to 6 were compared with comparative example 2, it was found that the rate of increase of water in the horny layer was higher in the cleansing smoothies of the present invention and after a certain period of use than in the comparative example 2. It can be seen that the makeup removing smoothie disclosed by the invention has a very excellent instant moisturizing effect, and the moisturizing effect is more excellent within a period of time after makeup removal, so that the makeup removing smoothie is obviously superior to the I-type makeup removing smoothie disclosed by the invention.

Table 6: comparison of moisturizing Capacity of type II cleansing smoothie of the invention and comparative example 2

Example 8: comparative test for makeup removal effect of makeup removal composition type II

To test the makeup removing ability of the type II smoothie makeup removing gel product of the present invention, comparative evaluation of the makeup removing ability was performed using the product of test example 4 in example 6 of the present invention together with comparative example 2.

The specific evaluation steps are as follows:

2. Waiting for 10 minutes; the makeup removing products of the invention, test example 4 and comparative example 2, were used to remove makeup from the test area to which the makeup removing product was applied; until the test area remained in the post makeup removal state for several minutes with no significant change.

3. The camera respectively takes pictures in the same position under the condition of illumination before, after and after the makeup color product is applied; the obtained photo alignment before and after makeup removal is shown in fig. 5 and 6, fig. 5 being test example 4, and fig. 6 being comparative example 2.

As can be seen from the comparison of fig. 5 and fig. 6, when the same makeup product is removed at the same position of the same subject, the smoothie makeup removing gel of the invention has the same effect as that of the comparative example 2, and can effectively remove the common makeup.

Example 9: stability testing of type II make-up removing compositions

Test examples 4-6 of example 6 were each packaged in a colorless frosted glass jar (not open) simulating the environment and conditions under which makeup removing gels were routinely stored. Placing the glass bottles at-7, 4, 25, 27 and 45 ℃ respectively, placing for 2 months under the condition of illumination (room temperature is 25 ℃), and continuously observing the appearance; wherein the degree of change is represented by 0-3, 0 is no significant change in color and texture, 1 is a slight acceptable change (e.g., slight color change, slight thickening of texture), 2 is an unacceptable change (e.g., significant color change, uneven gummy texture), and 3 is a severe change (e.g., severely reduced volume of jelly, yellowish brown color). The observation results are shown in Table 7.

Table 7: the storage stability of the smoothie makeup-removing gel

As can be seen from Table 7, under the conditions of low temperature, normal temperature, high temperature and/or light treatment, the makeup remover product of the invention keeps stable color property state within 2 months of the experiment, has no obvious change and has excellent stability.

Example 9: user experience testing of type II make-up removal compositions

The test method comprises the following steps: 20 female volunteers with the average age of 32.10 +/-4.48 years are selected and provided for the products of the test examples 4-6 and the product of the comparative example 2 in the example 6 of the invention to be respectively tried.

The evaluation method comprises the following steps:

2. then cleaning with clear water;

3. after 15 minutes, the product was scored and the form filled in.

Grading standard: the score is 1-5; the scoring profiles are shown in Table 8 below. Wherein:

satisfaction criteria: "1" means very unsatisfactory; "2" means unsatisfactory; "3" means general; "4" indicates relatively satisfactory; "5" means very satisfactory.

Table 8: the invention provides the condition of the phenotypic form and the use feeling score of the cleansing smoothie

As can be seen from the results of tests conducted by randomly selected users, the type II makeup remover composition is superior in comfort and moisturizing feel, and is more popular with consumers.

The invention provides the ice-slush-shaped makeup removing products I and II which are stable in property, mild, free of stimulation, excellent in moisturizing and makeup removing effects, fresh, cool, not sticky and good in use experience, wherein the effect of the makeup removing products II is better.

The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is specific and detailed, but not to be understood as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.

Claims

1. A makeup removing composition characterized by comprising the following components:

a) a surfactant;

b) skin care grease;

c) a thickener, wherein the thickener accounts for 0.1-5 wt% of the composition; the thickening agent is selected from one or more of acrylic acid (ester) cross-linked polymer sodium-2, sodium polyacrylate grafted starch, gellan gum and agarose;

d) a humectant; and

e) water accounts for 60-90 wt% of the composition.

2. The makeup removing composition according to claim 1, comprising the following components:

a) surfactant accounting for 8-15 wt% of the composition;

b) skin care grease which accounts for 1 to 5 weight percent of the composition;

d) a humectant accounting for 5 wt% -10 wt% of the composition; and

e) water; accounting for 70wt percent to 80wt percent of the composition.

3. The makeup removing composition according to claim 1 or 2, further comprising a chelating agent and/or a humectant and/or an emulsifier and/or a preservative and/or a skin conditioner and/or a perfume.

4. The makeup removing composition according to claim 3,

the chelating agent accounts for 0.01-0.05 wt% of the composition;

the humectant accounts for 3 to 12 weight percent of the composition;

the emulsifier accounts for 0.2-5 wt% of the composition;

the preservative accounts for 0.1-5 wt% of the composition;

the skin conditioning agent comprises 0.1 wt% to 10 wt%, such as 0.1 wt% to 5 wt% or 5 wt% to 10 wt% of the composition;

the essence accounts for 0.01-0.1 wt% of the composition.

5. The makeup removing composition according to any one of claims 1-4, wherein the surfactant is selected from at least one or more of PEG-7 glyceryl cocoate, PEG-6 caprylic/capric glycerides, poloxamer 184, glyceryl polyether-7, PPG-30 butanoeth-30, polyglyceryl-2 oleate, polyglyceryl-10 dioleate, polyglyceryl-2 sesquicaprylate, polyglyceryl-10 stearate, potassium laurate; preferably poloxamer 184 and/or PEG-7 glyceryl cocoate and/or PEG-6 caprylic/capric glycerides.

6. The make-up removing composition according to any one of claims 1 to 5, wherein the skin care oil is selected from at least one or more of caprylic/capric triglyceride, hydrogenated polydecene, caprylic/capric/myristic/stearic triglyceride, octyldodecanol myristate, ethylhexyl palmitate, decyl cocoate, diisostearyl malate, pentaerythritol tetrakis (ethyl hexanoate), hydrogenated C6-14 alkene polymers, coconut oil, mango seed fat, jojoba seed oil, sunflower seed oil, meadowfoam seed oil, macadamia integrifolia seed oil, shea butter, sweet almond oil, squalane, tocopherol acetate, cetyl ethylhexanoate, polydimethylsiloxane, olive oil, geranium sunflower oil, bergamot oil; preferably caprylic/capric triglyceride and/or jojoba seed oil, more preferably caprylic/capric triglyceride and/or cetyl ethylhexanoate and/or olive oil and/or geranium oil and/or bergamot oil and/or jojoba seed oil, most preferably a combination of caprylic/capric triglyceride and cetyl ethylhexanoate and olive oil and geranium oil and bergamot oil and jojoba seed oil.

7. The makeup removing composition according to any one of claims 1 to 6, wherein said thickener further comprises one or more of PEG-240/HDI copolymer bis-decyltetradecyltetradecylpolyether-20 ether, xanthan gum, cellulose ether, carboxymethyl cellulose, hydroxyethyl cellulose, gelatin, sodium alginate, dextrin, fatty acid polyglycol esters, preferably PEG-240/HDI copolymer bis-decyltetradecyltetradecyltetradecyltetradecyltolyether-20 ether.

8. The makeup removing composition according to any one of claims 1 to 7, wherein the humectant is selected from at least one or more of glycerin, butylene glycol, 1, 2-pentanediol, 1, 2-hexanediol, polyethylene glycol-32, dipropylene glycol, octylene glycol, sorbitol, 1, 2-propanediol, 1, 3-propanediol, sucrose, octanediol; one or more of 1, 3-butanediol, dipropylene glycol, octylene glycol, octanediol, or 1, 2-pentanediol are preferred.

9. The makeup removing composition according to any one of claims 1 to 8, wherein the chelating agent is selected from at least one or more of disodium EDTA, tetrasodium EDTA, and sodium phytate; sodium phytate is preferred.

10. The makeup removing composition according to any one of claims 1 to 9, wherein the emulsifier is selected from at least one or more of polysorbate-20, polysorbate-60, glyceryl stearate SE, PEG-100 stearate, polyglyceryl-3-methylglucdistearate, PEG-60 hydrogenated castor oil, ceteth-20, cetearyl glucoside, sorbitan stearate, sorbitan sesquioleate, cetearyl alcohol, cetearyl olivate oleate, sorbitan olivate, C12-20 alkyl glucoside, octyldodecyl polyether-25; PEG-100 stearate, polysorbate-20 and/or glyceryl stearate are preferred.

11. The makeup removing composition according to any one of claims 1 to 10, wherein the preservative is selected from at least one or more selected from the group consisting of phenoxyethanol, ethylhexyl glycerol, p-hydroxyacetophenone, butylated hydroxytoluene.

12. The makeup removing composition according to any one of claims 1-11, wherein the skin conditioner is selected from one or more of a glycine soja seed extract, a lavender extract, an apple fruit extract, an aloe extract, a citrus sinensis fruit extract, a citrus medica fruit extract, a bergamot fruit extract, a grapefruit peel extract, a mint extract, an albizia bark extract, a sugarcane extract, a peony flower extract, a hippophae fruit extract, a horse chestnut extract, a hollyhock flower extract, a coconut fruit extract, silica, tocopherol, aesculus hippocastanum water, a yeast fermentation product filtrate, a saccharomyces diculus fermentation product lysate, preferably a glycine soja seed extract and/or aesculus hippocastanum water and/or a yeast fermentation product filtrate and/or a saccharomyces diculus fermentation product lysate, more preferably a glycine soja seed extract and a aesculus hippocastanum water and yeast fermentation product filtrate and a lysate of a saccharomyces diculus fermentation product And (4) combining.

13. The makeup removing composition according to claims 1-12, wherein said composition does not comprise silicone oil.

14. A method of preparing the make-up removing composition according to any one of claims 1 to 13, comprising the steps of:

1) preparing A, B, C, D phase components; wherein, water, chelating agent, humectant and makeup removing surfactant are mixed, heated and dissolved, and kept warm to obtain phase A; heating, dissolving and mixing emulsifier and skin care grease to obtain phase B; the thickener mixture is phase C; mixing antiseptic, skin conditioner and essence to obtain phase D;

15. The method of claim 14, wherein the phase a thermal dissolution temperature is 60-90 ℃, preferably 70-80 ℃; the phase B has a thermal dissolution temperature of 60-90 deg.C, preferably 70-80 deg.C.

16. The production method according to claim 14 or 15,

in the step 3), the homogenizing temperature is 60-90 ℃, preferably 70-80 ℃, and more preferably 72-75 ℃; the homogenizing time is 5-20 minutes, preferably 8-15 minutes;

in the step 4), the cooling temperature is 30-80 ℃, preferably 40-70 ℃, and more preferably 50-55 ℃; the homogenizing time is 3-15 minutes, preferably 5-8 minutes;

in the step 5), the cooling temperature is 25-60 ℃, preferably 30-50 ℃, and more preferably 40-45 ℃; homogenizing for 1-10 minutes, preferably 3-8 minutes, and more preferably 2-4 minutes;

wherein the homogenizing rotation speed is 2500-.

17. The smoothie-shaped cleansing gel is characterized in that: comprising the makeup removal composition according to any one of claims 1 to 13 and a cosmetically acceptable carrier or excipient.