CN109966184A - A kind of suspension oil droplet makeup remover and preparation method thereof - Google Patents
A kind of suspension oil droplet makeup remover and preparation method thereof Download PDFInfo
- Publication number
- CN109966184A CN109966184A CN201910370397.6A CN201910370397A CN109966184A CN 109966184 A CN109966184 A CN 109966184A CN 201910370397 A CN201910370397 A CN 201910370397A CN 109966184 A CN109966184 A CN 109966184A
- Authority
- CN
- China
- Prior art keywords
- oil
- makeup remover
- makeup
- grease
- remover according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/044—Suspensions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/70—Biological properties of the composition as a whole
- A61K2800/72—Hypo-allergenic
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of suspension oil droplet makeup remover, the component including following mass percentage: grease 5-20%, thickener 0.15-1.0%；The grease includes silicone oil, vegetable oil, synthesizing ester and squalene extracting, wherein, their mass ratio is Sucrose Acetate acid sucrose: silicone oil: vegetable oil: squalene extracting=(3.5~4): (3~3.5): (1~2): (1~1.5)；The thickener is pectin and gellan gum.Oil phase can be steadily suspended in water phase by makeup remover of the invention, without rocking when use, greatly improve makeup removal efficiency, have many advantages, such as that irritation is low, skin sense is salubrious and makeup removing effect is good.In addition, makeup remover production cost of the invention is low, and preparation process is not related to complicated technology the present invention also provides the preparation method of the makeup remover, quality-high and inexpensive makeup removal products can be provided for consumer.
Description
Technical field
The invention belongs to daily chemicals fields, are related to a kind of makeup removal products, especially a kind of suspension oil droplet makeup remover and its preparation
Method.
Background technique
With the improvement of people's living standards, masses increasingly follow the fashion and beauty, the use of color make-up is also increasingly wider
It is general.With the rise of color make-up, demand of the people to makeup removal products is also more and more vigorous.After face makeup, if do not removed thoroughly,
Remaining cosmetics or the various dirts of absorption can cause the clogging of pores of skin of face, and the skin that gets off for a long time cannot exhale
It inhales, acne, acne and blackhead etc. can be caused to make us the skin problem of puzzlement.So makeup removing and makeup are same for skin nursing
Important, makeup removal products have become pith indispensable in daily skin nursing.
Commercially available low viscosity face makeup removal products, traditional has makeup remover and makeup remover, and appearance is all uniform liquid.In recent years
Come the also popular double-deck make up remover, the Double-layer liquid that usually upper layer is oil, lower layer is water.
Makeup remover quality is salubrious, does not stimulate mildly, but ability of removing ornaments and formal dress is weaker.Makeup remover makeup removing ability is stronger, still
Because it is with the characteristic of the molten oil of oil, the sebum film of human body itself can be also washed away while removal color make-up, long-time service is be easy to cause
Barrier is impaired, and skin sense sticks greasy makeup remover when in use, makes people unhappy.The double-deck makeup remover in combination with makeup remover with unload
The advantages of adornment water, makeup removing effect is better than makeup remover, when use the tender non-greasy of water salubriouser than makeup remover, and it is mild, non-stimulated, it is special
It Shi Yongyu not the use of the sensitive parts such as eye and lip.But the double-deck makeup remover is in use process that there are several distinct disadvantages: 1,
It must firmly be rocked before, some consumers may be because that the dynamics of rocking is inadequate, cause usage experience bad；2, oil, water two-phase
After shaking up can fast hierarchical, consumer is in the color make-up to more difficult removal, such as when waterproof eye-liner, mascara are removed ornaments and formal dress,
It repeated multiple times need to shake up, the makeup removing time is longer, and makeup removal efficiency is low；3, water in the make up remover got when each use is not can guarantee
Mutually as the ratio of oily phase, makeup removing effect is inconsistent when same bottle makeup remover being caused to use every time.
Summary of the invention
It is an object of the invention to good, the users that provides a kind of makeup removing effect in view of the deficiencies of the prior art mentioned above
Just, and after do not stick it is greasy, to the inirritative makeup removal products of skin.
To achieve the above object, the technical scheme adopted by the invention is as follows: a kind of makeup remover of suspension oil droplet, including following matter
Measure the component of percentage composition: grease 5-20%, thickener 0.15-1.0%, the grease include silicone oil, vegetable oil, synthesizing ester
And squalene extracting, in the silicone oil, vegetable oil, synthesizing ester and squalene extracting composition, the silicone oil, vegetable oil, conjunction
It is synthesizing ester: silicone oil: vegetable oil: squalene extracting=(3.5~4): (3~3.5) at the mass ratio of esters and squalene extracting:
(1~2): (1~1.5), the density of the grease are 0.9995~1.0100, and the synthesizing ester is Sucrose Acetate acid sucrose；
The thickener is pectin and gellan gum.
Sucrose acetoisobutyrate is typically used as food additives, with various types grease good compatibility, relative density
1.14-1.15 having wet dispersion force to pigment.In addition to adjusting oily phase density, its removal to color make-ups such as eye shadow, lipstick, foundation creams
Ability is very excellent.
Pectin is a kind of natural macromolecule amylose substance, usually with the pericarp of shaddock, lemon, citrus, apple etc. or fruit
Slag is raw material, food additives obtained by extracted, purification, can be used as thickener, gelling agent, stabilizer, tissue forming agent.Together
When, pectin has the function of autobalance pH, can form protective film in skin surface when it is applied to makeup remover, make facial flesh
Skin is adjusted to normal acid-base balance state.After pectin is compounded with gellan gum according to special ratios, it is crosslinked the synergistic effect of generation,
So that gellan gum has more excellent suspension stability；The stability of grease suspension can be effectively improved.
The makeup remover of suspension oil droplet, technical difficult points are the stability and makeup removing effect that oil droplet suspends, and grease
Two phase densities are close, are the key factors that oil droplet can suspend.The grease density range that the combination matching obtains is in 0.9995-
Between 1.0100, it is approximately equal to the density of water.
Mutually collocation is combination of the various types grease according to special ratios, product, silicone oil for vegetable oil system to the oil
The product of system and the product of dormant oil system have outstanding solvability, this is also to improve makeup removing effect key factor.Increase
Thick dose of addition can further increase stability, so that oil droplet preferably suspends.
Preferably, the density of the grease is 1.003.
Specifically, the silicone oil in the grease is at least one of following components: phenyl polymethyl siloxane, phenyl are poly-
Trimethicone, the poly- trimethicone of diphenyl silicon phenyl, trimethyl pentaphenyltrisiloxane, diphenyl are poly-
Dimethyl siloxane, ring five dimethyl silicone polymer, cyclohexasiloxane, dimethyl silicone polymer；Vegetable oil in the grease
For at least one of following components: olive oil, Sweet Almond Oil, macadimia nut oil, white pond flower seed oil, rice bran oil, cottonseed oil, small
Wheat germ oil, corn oil, jojoba oil, tea-seed oil；Squalene extracting in the grease is at least one of following components: liquid
Body paraffin, Nexbase 2004, isomery hexadecane, isomery dodecane, Parleam, saualane.
The selection of grease and makeup removing effect are closely related, therefore it is most important to reasonably select grease.
Preferably, the grease includes Sucrose acetoisobutyrate, phenyl trimethicone, white pond flower seed oil, liquid
Body paraffin, the mass ratio of each component are as follows: Sucrose acetoisobutyrate: phenyl trimethicone: white pond flower seed oil: liquid stone
Wax=3.5:3:1:1.
Specifically, the mass ratio of the gellan gum and pectin is 1:0.2~0.6.Preferably, the gellan gum and pectin
Mass ratio is 1:0.5.
Through testing, when gellan gum and pectin mass ratio are 1:0.2~0.6, the suspension effect of oil droplet is good, if exceeding the model
It encloses, suspension stability decline.
Further, the makeup remover further includes the component of following mass percentage: moisturizer 10-30%, preservative
0.2-1%, surfactant 0.1-1%, electrolyte 0.05-0.2%, antioxidant 0.01-0.5%, pigment 0.001-
0.3% and water surplus.
Specifically, the moisturizer includes at least one of following components: glycerol, diglycerol, dipropylene glycol, the third two
Alcohol, 1,3-BDO, PEG-6, isoprene；The preservative includes at least one of following components: Chlorphenesin, poly- ammonia
Propyl biguanides, parahydroxyacet-ophenone, imidazolidinyl urea, Phenoxyethanol, Sensiva SC50, pungent glycol, decoyl hydroximic acid；It is described
Surfactant include following components at least one of: PEG-7 glyceryl cocoate, poloxamer, PEG-6 caprylic/capric
Glyceride；The electrolyte includes but is not limited to calcium chloride；The antioxidant includes at least one of following components: fourth
Hydroxy toluene, pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamate), tocopherol acetate；The pigment includes following
At least one of component: solvent yellow 16, solvent green 3, German chamomile essential oil, Asian puccoon root extract, sunflower seed oil, kermes
Red, lemon yellow, light green, brilliant blue.
Pigment assigns the better appearance of make up remover, and the pleasure of the senses of user can be improved.Wherein, solvent yellow 16 (i.e. CI
12700), solvent green 3 (i.e. CI 61565), German chamomile essential oil, Asian puccoon root extract, sunflower seed oil are fat-soluble color
Element, famille rose, lemon yellow, light green, brilliant blue are water colo(u)r.
Preferably, the preservative is pungent glycol and Sensiva SC50；The surfactant is poloxamer；It is described
Pigment is German chamomile essential oil.
Pungent glycol is skin emollient, wetting agent, and existing good moisturizer also has anti-corrosion function, can prevent water-based
Bacterium and yeast are exceeded in formula, make an addition in product to play and assist moisturizing, softening and antibacterial application.Sensiva SC50 is tool
There is the moisturizer of antibacterial activity.
Poloxamer is polyoxyethylene poly-oxygen propylene aether block copolymer, is that a kind of novel macromolecule non-ionic surface is living
Property agent；It is safe and non-stimulating, assist removal color make-up.
The main component of German chamomile essential oil includes german chamomile azulene, α-bisabol and sesquiterpene lactone, is had excellent
Anti-inflammatory effects, on skin measles, itch, dry, exfoliant effect it is significant.In addition, being not necessarily to due to the presence of azulene
Addition pigment just can make oil mutually show graceful navy blue.De Gan is with slightly sweet spice taste, to calm equilibrium nerve system
System, eliminating anxiety also has good curative effect.
The present invention also provides the preparation methods of the makeup remover, and steps are as follows:
(1) water phase: main still is added in water, is added in room temperature water after thickener and moisturizer are premixed uniformly, agitating and heating
Sufficiently to 80-85 DEG C of swelling, surfactant is then added to stir evenly, is cooled to 70-75 DEG C of addition electrolyte, is cooled to 50
DEG C preservative is added stirs evenly, and standing is cooled to 30 DEG C or less and condenses into solid gum, uses homogenizer, speed 1000-
2000rpm homogeneous 3-5min smashes solid gum for uniform fluid glue；
(2) oily phase: mixing each grease, antioxidant, and is heated to 75 DEG C with transparent up to dissolving, and is cooled to 40 DEG C ± 5
DEG C, pigment is added, stirs evenly；
(3) finished product: under agitation, oily phase is added in main still water phase, until oil droplet suspension is in water phase, after stirring evenly
Discharging.
It is that can assemble to form double helix knot automatically between molecule after it is dissolved in water that gellan gum, which has the reason of levitation effect,
Structure, and the addition of electrolyte have caused the polymerization crosslinking between double helix.Further assemble when double helix and forms three-dimensional netted knot
Structure, hydrone, which is trapped, produces gelatin phenomenon.The fluid glue of traditional handicraft preparation is lasting stirring drop after electrolyte is added
Temperature is to gelling temp hereinafter, process and not formed tridimensional network, only provide suspending power by double-spiral structure at this time.And this hair
It is blended again after bright formation solid gel as fluid glue, the molecule hydrogen bond for forming tridimensional network still remains, molecule knot
Structure is secured, this suspending power for allowing for system greatly improves.
The oil phase of the double-deck makeup remover can be steadily suspended in water phase by suspension oil droplet makeup remover of the present invention
In, without rocking when use, no longer there is water-oil phase and takes uneven phenomenon, not only completely in grease uniform discharge when taking
Ground remains the advantages that double-deck makeup remover irritation is low, and skin sense is salubrious and makeup removing effect is good, also solves it in use process
In various inconvenience, greatly improve makeup removal efficiency；Oil of the invention, which is combined, further improves makeup removing effect, to various
Color make-up, the sunscreen product of type all have good removal effect；Completely new make up remover appearance can also be brought more to consumer
Pleasant makeup removing new experience.In addition, the present invention also provides the preparation method of the makeup remover, makeup remover production cost of the invention
Low, preparation process is not related to complicated technology, can be used for a large amount of steady productions makeup remover, provides quality-high and inexpensive unload for consumer
Complete outfit for newlyweds selection.
Detailed description of the invention
Fig. 1 is using the embodiment of the present invention 1, embodiment 3, the makeup remover of comparative example 4 and typical bilayer make up remover to eyelashes
The makeup removing effect test result of cream.
Fig. 2 is using the embodiment of the present invention 1, embodiment 3, the makeup remover of comparative example 4 and typical bilayer make up remover to non-sticky
The red makeup removing effect test result of rim of a cup.
Fig. 3 is the embodiment of the present invention 4, the makeup remover of comparative example 5-8 to the makeup removing effect test result of mascara.
The makeup removing effect test result that Fig. 4 is the embodiment of the present invention 4, the makeup remover of comparative example 5-8 is red to non-sticky rim of a cup.
Specific embodiment
To better illustrate the object, technical solutions and advantages of the present invention, below in conjunction with specific embodiment to the present invention
It is described further.
Embodiment 1
As a kind of embodiment of the invention, consisting of the component of following mass percentage: 20% isoprene,
5% dipropylene glycol, 5% butanediol, 0.08% pectin, 0.16% gellan gum, 0.12% calcium chloride, 0.3% it is pungent
Glycol, 0.2% Sensiva SC50,0.2% poloxamer, 8% Sucrose acetoisobutyrate, 2% the poly- front three of phenyl
Radical siloxane, 2% ring five dimethyl silicone polymer, 2% trimethyl pentaphenyltrisiloxane, 1% macadimia nut oil,
1% white pond flower seed oil, 2% olive oil, 0.5% atoleine, 1% Nexbase 2004,0.5% saualane,
0.3% tocopherol acetate, 0.02% German chamomile essential oil and water surplus.The preparation of makeup remover of the present invention
Method, steps are as follows:
(1) water phase: main still is added in water, is added in room temperature water after thickener and moisturizer are premixed uniformly, agitating and heating
Sufficiently to 80-85 DEG C of swelling, surfactant is then added to stir evenly, is cooled to 70-75 DEG C of addition electrolyte, is cooled to 50
DEG C preservative is added stirs evenly, and standing is cooled to 30 DEG C or less and condenses into solid gum, uses homogenizer, speed 1000-
2000rpm homogeneous 3-5min smashes solid gum for uniform fluid glue；
(2) oily phase: mixing each grease, antioxidant, and is heated to 75 DEG C with transparent up to dissolving, and is cooled to 40 DEG C ± 5
DEG C, pigment is added, stirs evenly；
(3) finished product: under agitation, oily phase is added in main still water phase, until oil droplet suspension is in water phase, after stirring evenly
Discharging.
Embodiment 2
As a kind of embodiment of the invention, the preparation method of the makeup remover is same as Example 1, consisting of below
The component of mass percentage: 20% dipropylene glycol, 5% butanediol, 0.05% pectin, 0.1% gellan gum, 0.05%
Calcium chloride, 0.1% pungent glycol, 0.1% Sensiva SC50,0.1% poloxamer, 5.25% Sucrose Acetate acid sugarcane
Sugar ester, 4.5% phenyl trimethicone, 1.5% white pond flower seed oil, 1.5% atoleine, 0.05% season penta
Tetrol four (double-tert-butyl hydroxy hydrocinnamic acid) ester, 0.1% German chamomile essential oil and water surplus.
Embodiment 3
As a kind of embodiment of the invention, the preparation method of the makeup remover is same as Example 1, consisting of below
The component of mass percentage: 10% isoprene, 10% dipropylene glycol, 10% butanediol, 0.2% pectin, 0.4%
Gellan gum, 0.3% calcium chloride, 0.1% pungent glycol, 0.3% Sensiva SC50,0.2% poloxamer, 2%
Sucrose acetoisobutyrate, 1% ring five dimethyl silicone polymer, 0.5% trimethyl pentaphenyltrisiloxane, 1% it is white
Pond flower seed oil, 0.5% atoleine, 0.5% tocopherol acetate, 0.0001% German chamomile essential oil, Yi Jishui
Surplus.
Embodiment 4
As a kind of embodiment of the invention, the preparation method of the makeup remover is same as Example 1, consisting of below
The component of mass percentage: 15% isoprene, 15% dipropylene glycol, 0.072% pectin, 0.12% gellan gum,
0.09% calcium chloride, 0.1% pungent glycol, 0.5% Sensiva SC50,0.2% poloxamer, 3.5% acetic acid are different
Butyric acid sucrose ester, 1% phenyl trimethicone, 1% ring five dimethyl silicone polymer, 1% five phenyl of trimethyl
Trisiloxanes, 0.5% macadimia nut oil, 0.5% white pond flower seed oil, 0.5% atoleine, 0.5% Nexbase 2004,
0.5% saualane, 0.1% tocopherol acetate, 0.3% German chamomile essential oil and water surplus.
Embodiment 5
As a kind of embodiment of the invention, the preparation method of the makeup remover is same as Example 1, consisting of below
The component of mass percentage: 10% isoprene, 0.04% pectin, 0.2% gellan gum, 0.15% calcium chloride,
0.2% pungent glycol, 0.2% Sensiva SC50,1% poloxamer, 3.5% Sucrose acetoisobutyrate, 3% benzene
The poly- trimethicone of base, 1% macadimia nut oil, 1% saualane, 0.01% pentaerythrite four (double-tert-butyl hydroxy hydrogen
Change cinnamic acid) ester, 0.2% tocopherol acetate, 0.2% German chamomile essential oil and water surplus.
Embodiment 6
As a kind of embodiment of the invention, the preparation method of the makeup remover is same as Example 1, consisting of below
The component of mass percentage: 20% butanediol, 0.2% pectin, 0.8% gellan gum, 0.2% calcium chloride, 0.3%
Pungent glycol, 0.2% Sensiva SC50,0.5% poloxamer, 2% Sucrose acetoisobutyrate, 0.25% ring five it is poly-
Dimethyl siloxane, 1.5% trimethyl pentaphenyltrisiloxane, 0.5% macadimia nut oil, 0.5% white pond flower seed oil,
0.5% atoleine, 0.25% Nexbase 2004,0.01% pentaerythrite four (double-tert-butyl hydroxy hydrocinnamoyl
Acid) ester, 0.05% German chamomile essential oil and water surplus.
Comparative example 1
As comparative example of the invention, the preparation method of the makeup remover is same as Example 1, consisting of following quality
The component of percentage composition: 20% isoprene, 5% dipropylene glycol, 5% butanediol, 0.016% pectin, 0.16%
Gellan gum, 0.12% calcium chloride, 0.3% pungent glycol, 0.2% Sensiva SC50,0.2% poloxamer, 8% second
Sour isobutyric acid sucrose ester, 2% phenyl trimethicone, 2% ring five dimethyl silicone polymer, 2% trimethyl five
Phenyl trisiloxanes, 1% macadimia nut oil, 1% white pond flower seed oil, 2% olive oil, 0.5% atoleine, 1%
Nexbase 2004,0.5% saualane, 0.3% tocopherol acetate, 0.02% German chamomile essential oil, Yi Jishui
Surplus.
Comparative example 2
As a kind of comparative example of the invention, the composition of the makeup remover is same as Example 1, but makeup removing of the present invention
The preparation method of water, steps are as follows:
(1) water phase: main still is added in water, is added in room temperature water after thickener and moisturizer are premixed uniformly, agitating and heating
Sufficiently to 80-85 DEG C of swelling, surfactant is then added to stir evenly, is cooled to 70-75 DEG C of addition electrolyte, is cooled to 50
DEG C preservative is added stirs evenly, and lasting stirring is cooled to 30 DEG C or less；
(2) oily phase: mixing each grease, antioxidant, and is heated to 75 DEG C with transparent up to dissolving, and is cooled to 40 DEG C ± 5
DEG C, pigment is added, stirs evenly；
(3) finished product: under agitation, oily phase is added in main still water phase, until oil droplet suspension is in water phase, after stirring evenly
Discharging.
Comparative example 3
As a kind of comparative example of the invention, the preparation method of the makeup remover is same as Example 1, consisting of below
The component of mass percentage: 20% isoprene, 5% dipropylene glycol, 5% butanediol, 0.08% pectin, 0.16%
Gellan gum, 0.12% calcium chloride, 0.3% pungent glycol, 0.2% Sensiva SC50,0.2% poloxamer, 6%
Sucrose acetoisobutyrate, 2% phenyl trimethicone, 2% ring five dimethyl silicone polymer, 2% trimethyl
Pentaphenyltrisiloxane, 1% macadimia nut oil, 1% white pond flower seed oil, 2% olive oil, 0.5% atoleine,
1% Nexbase 2004,0.5% saualane, 0.3% tocopherol acetate, 0.02% German chamomile essential oil, and
Water surplus.
Comparative example 4
As a kind of comparative example of the invention, the preparation method of the makeup remover is same as Example 1, consisting of below
The component of mass percentage: 20% isoprene, 5% dipropylene glycol, 5% butanediol, 0.08% pectin, 0.16%
Gellan gum, 0.12% calcium chloride, 0.3% pungent glycol, 0.2% Sensiva SC50,0.2% poloxamer, 8%
Caprylic/capric/amber acid glycerol three ester, 2% phenyl trimethicone, 2% ring five dimethyl silicone polymer, 2%
Trimethyl pentaphenyltrisiloxane, 1% macadimia nut oil, 1% white pond flower seed oil, 2% olive oil, 0.5% liquid
Body paraffin, 1% Nexbase 2004,0.5% saualane, 0.3% tocopherol acetate, 0.02% German chamomile essence
Oil and water surplus.
Comparative example 5
As a kind of comparative example of the invention, the preparation method of the makeup remover is same as Example 1, consisting of below
The component of mass percentage: 15% isoprene, 15% dipropylene glycol, 0.072% pectin, 0.12% gellan gum,
0.09% calcium chloride, 0.1% pungent glycol, 0.5% Sensiva SC50,0.2% poloxamer, 4.5% phenyl are poly-
Trimethicone, 1% ring five dimethyl silicone polymer, 1% trimethyl pentaphenyltrisiloxane, 0.5% Queensland nut
Oil, 0.5% white pond flower seed oil, 0.5% atoleine, 0.5% Nexbase 2004,0.5% saualane, 0.1%
Tocopherol acetate, 0.3% German chamomile essential oil and water surplus.
Comparative example 6
As a kind of comparative example of the invention, the preparation method of the makeup remover is same as Example 1, consisting of below
The component of mass percentage: 15% isoprene, 15% dipropylene glycol, 0.072% pectin, 0.12% gellan gum,
0.09% calcium chloride, 0.1% pungent glycol, 0.5% Sensiva SC50,0.2% poloxamer, 3.5% acetic acid are different
Butyric acid sucrose ester, 0.5% macadimia nut oil, 0.5% white pond flower seed oil, 3% olive oil, 0.5% atoleine,
0.5% Nexbase 2004,0.5% saualane, 0.1% tocopherol acetate, 0.3% German chamomile essential oil, with
And water surplus.
Comparative example 7
As a kind of embodiment of the invention, the preparation method of the makeup remover is same as Example 1, consisting of below
The component of mass percentage: 15% isoprene, 15% dipropylene glycol, 0.072% pectin, 0.12% gellan gum,
0.09% calcium chloride, 0.1% pungent glycol, 0.5% Sensiva SC50,0.2% poloxamer, 3.5% acetic acid are different
Butyric acid sucrose ester, 1% phenyl trimethicone, 1% ring five dimethyl silicone polymer, 1% five phenyl of trimethyl
Trisiloxanes, 1.5% atoleine, 0.5% Nexbase 2004,0.5% saualane, 0.1% tocopherol acetate,
0.3% German chamomile essential oil and water surplus.
Comparative example 8
As a kind of embodiment of the invention, the preparation method of the makeup remover is same as Example 1, consisting of below
The component of mass percentage: 15% isoprene, 15% dipropylene glycol, 0.072% pectin, 0.12% gellan gum,
0.09% calcium chloride, 0.1% pungent glycol, 0.5% Sensiva SC50,0.2% poloxamer, 3.5% acetic acid are different
Butyric acid sucrose ester, 1% phenyl trimethicone, 1% ring five dimethyl silicone polymer, 1% five phenyl of trimethyl
Trisiloxanes, 0.5% macadimia nut oil, 0.5% white pond flower seed oil, 1.5% olive oil, 0.1% tocopherol acetate,
0.3% German chamomile essential oil and water surplus.
Comparative example 9
As a kind of embodiment of the invention, the makeup remover is in addition to without pectin, remaining is at being grouped as and preparation method
It is same as Example 3.
Comparative example 10
As a kind of embodiment of the invention, the makeup remover is in addition to without gellan gum, remaining is at being grouped as and preparation side
Method is same as Example 6.
Comparative example 11
As a kind of embodiment of the invention, it is 0.04% containing mass percentage that the makeup remover, which is removed, which is free of pectin,
Outside xanthan gum, remaining is at being grouped as and preparation method is same as Example 5.
One, product stability can be evaluated
Stability test: to embodiment 1-6, the product of comparative example 1-11 is tested.1 Sucrose Acetate acid sucrose of embodiment
Ester and silicone oil, vegetable oil, hydro carbons are 4:3:2:1 in mass ratio, measure density 1.007.3 Sucrose acetoisobutyrate of comparative example with
Silicone oil, vegetable oil, hydro carbons are 3:3:2:1 in mass ratio, measure density 0.9982.Comparative example 4 is formulated referring to embodiment 1, still
Sucrose acetoisobutyrate is substituted for caprylic/capric/amber acid glycerol three ester, measuring comparative example grease density is 0.9999.
Comparative example 5-8 is the comparative example for being embodiment 4, and comparative example 5 does not contain Sucrose acetoisobutyrate, density 0.9999；Comparison
Example 6 does not contain silicone oil, density 1.0027；Comparative example 7 does not contain vegetable oil, density 1.0094；Comparative example 8 does not contain hydro carbons
Grease, density 0.9996.It is resisted cold (- 15 DEG C) to each embodiment, comparative example, the stability of heat-resisting (45 DEG C) examination
It tests, experimentation is as follows:
A) it resists cold and tests:
Instrument: refrigerator, accuracy of temperature control ± 1 DEG C
Operation sequence: adjusting refrigerator arrive (- 15 ± 1) DEG C in advance, real sample is placed in refrigerator, is taken out after 3 months, restores
It is observed after to room temperature.
B) heat-resistant experiment
Instrument: constant incubator, accuracy of temperature control ± 1 DEG C
Operation sequence: constant incubator is adjusted arrive (45 ± 1) DEG C in advance, real sample is placed in incubator, is taken after 3 months
Out, restore to room temperature to observe.
Test result such as table 1.It is found by trimestral test, embodiment 1-6 uniformly stablizes without significant change, oil droplet
Ground is suspended in system.Comparative example 1 because thickener ratio adjustment, comparative example 2 because technique change, all cause water phase outstanding
Floating stability dies down, and shows as oil droplet floating.The change of 3 grease ratio of comparative example causes relative density to become smaller, and oil droplet floats.It is right
The change of 4 grease of ratio selection causes oily mutually compatibility to be deteriorated, and separates between the grease of miscella phase, the big oil of density occurs
Sink, the small oil of density floats, and it is poor to stablize sex expression.It can be obtained by comparative example 5-8, under certain density, Sucrose Acetate acid
Sucrose ester plays a decisive role to the suspension for maintaining oil droplet, shows that single gellan gum or pectin are not enough to provide by comparative example 9,10
Compounding can be crosslinked the enough suspending powers of generation according to a certain percentage for suspending power steady in a long-term, only the two.By comparative example
11 as it can be seen that pectin, which is replaced with xanthan gum also, can make outstanding pearl stability decline.
1 stability test result of table
Two, the makeup removing performance evaluation of product
It in daily nursing, needs that facial color make-up and the anti-sweat sunscreen product of waterproof unload washing, color make-up is many kinds of, packet
Include a plurality of types of products such as foundation cream, sweet powder, lipstick, eye shadow, kermes, mascara；Color make-up product component is extremely complex.Wherein,
Vanishing cream, suncream majority are silicon oil packed water formulations, usually contain a large amount of silicone oil and organic silicon film forming agent, contain titanium white simultaneously
The inorganic particles such as powder, iron oxide, zinc oxide, and in order to achieve the effect that docile, most powders are carried out using organosilicon
Surface treatment；Containing plant components such as beeswax, Brazil wax, candelila waxes in lipstick, also containing hydrocarbons such as dormant oil, paraffin
Matter；Kermes, eye shadow, mascara contain the ingredients such as pigment, color ingot, silicone oil and film forming agent.Because non-sticky rim of a cup is red and mascara formulation
The ingredients such as pigment, silicone oil, film forming agent, mineral oil, vegetable wax are usually contained, it is relatively more representative, therefore the present invention chooses
It carries out makeup removing performance test.
Respectively using embodiment 1, embodiment 3, embodiment 4, the suspension oil droplet make up remover of comparative example 4-8 carry out makeup removing and
The conventional double-deck make up remover carries out mascara and the red makeup removing effect test of non-sticky rim of a cup: taking that the not viscous rim of a cup of equivalent is red, mascara
It is uniformly applied at arm, respectively takes 0.5g makeup removing water droplet will makeup removing after the cotton that on makeup removing cotton, will remove ornaments and formal dress applies 1min after adornment is dry
Cotton is wiped 3 times with same dynamics, observes makeup removing effect.Test result (A typical bilayer make up remover picture 1-4；B comparative example 4；C
Embodiment 3；D embodiment 1；1. comparative example 5；2. comparative example 6；3. comparative example 7；4. comparative example 8；5. embodiment 4).
By Fig. 1, Fig. 2 as it can be seen that embodiment makeup removing effect is preferable, the wherein highest embodiment of Sucrose acetoisobutyrate content
1 makeup removing effect is best；Sucrose acetoisobutyrate equivalent is replaced with other esters by comparative example 4, and makeup removing ability is declined；City
It sells the double-deck make up remover and there is the problems such as taking inconvenience, uneven, and makeup removing effect is most weak.
According to the similar principle that mixes, it just can be carried out and dissolve each other between the similar component of polarity, therefore can not only be unloaded by vegetable oil
It, only also can not the more kermes of removal toner content, eye shadow class by mineral oil except the color make-up or sun-proof class product of siliceous Chuck Steak
Product；Therefore the makeup removing effect for the makeup remover for lacking amount of grease in Fig. 3, Fig. 4 is remarkably decreased, only when grease is that acetic acid is different
The makeup removing effect of the combination of butyric acid sucrose ester and silicone oil, vegetable oil, squalene extracting, makeup remover is most excellent.
The present invention dispersibility splendid to pigment, toner using Sucrose acetoisobutyrate, by itself and silicone oil, plant
Oil, squalene extracting be combined, thus the makeup removal products being prepared have it is easy to use, take uniformly, and can simultaneously removal
Various types of color make-ups, sunscreen product.
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than protects to the present invention
The limitation of range is protected, although the invention is described in detail with reference to the preferred embodiments, those skilled in the art should
Understand, it can be with modification or equivalent replacement of the technical solution of the present invention are made, without departing from the essence of technical solution of the present invention
And range.
Claims (10)
1. a kind of makeup remover of suspension oil droplet, which is characterized in that the component including following mass percentage: grease 5-20%,
Thickener 0.15-1.0%；The grease includes silicone oil, vegetable oil, synthesizing ester and squalene extracting, the silicone oil, plant
The mass ratio of oil, synthesizing ester and squalene extracting is synthesizing ester: silicone oil: vegetable oil: squalene extracting=(3.5~4): (3~
3.5): (1~2): (1~1.5), the density of the grease are 0.9995~1.0100, and the synthesizing ester is Sucrose Acetate acid
Sucrose；The thickener is pectin and gellan gum.
2. makeup remover according to claim 1, which is characterized in that the density of the grease is 1.003.
3. makeup remover according to claim 1 or 2, which is characterized in that the silicone oil in the grease is in following components
It is at least one: the poly- trimethyl silicane oxygen of phenyl polymethyl siloxane, phenyl trimethicone, diphenyl silicon phenyl
Alkane, diphenyl dimethicone, ring five dimethyl silicone polymer, cyclohexasiloxane, gathers trimethyl pentaphenyltrisiloxane
Dimethyl siloxane；Vegetable oil in the grease is at least one of following components: olive oil, Sweet Almond Oil, Australia are hard
Fruit oil, white pond flower seed oil, rice bran oil, cottonseed oil, wheat-germ oil, corn oil, jojoba oil, tea-seed oil；In the grease
Squalene extracting is at least one of following components: atoleine, Nexbase 2004, isomery hexadecane, isomery dodecane, hydrogenation
Polyisobutene, saualane.
4. makeup remover according to claim 3, which is characterized in that the grease includes Sucrose acetoisobutyrate, phenyl
Poly- trimethicone, white pond flower seed oil, atoleine, and their mass ratio are as follows: Sucrose acetoisobutyrate: phenyl poly- three
Methylsiloxane: white pond flower seed oil: atoleine=3.5:3:1:1.
5. makeup remover according to claim 1, which is characterized in that the mass ratio of the gellan gum and pectin be 1:0.2~
0.6。
6. makeup remover according to claim 5, which is characterized in that the mass ratio of the gellan gum and pectin is 1:0.5.
7. makeup remover according to claim 1 or 2, which is characterized in that the makeup remover further includes that following quality percentage contains
The component of amount: moisturizer 10-30%, surfactant 0.1-1%, electrolyte 0.05-0.2%, preservative 0.2-1%, pigment
0.001-0.3%, antioxidant 0.01-0.5% and water surplus.
8. makeup remover according to claim 7, which is characterized in that the moisturizer includes at least one in following components
Kind: glycerol, diglycerol, dipropylene glycol, propylene glycol, 1,3-BDO, PEG-6, isoprene；The preservative includes with the following group
At least one of point: Chlorphenesin, polyaminopropyl biguanide, parahydroxyacet-ophenone, imidazolidinyl urea, Phenoxyethanol, ethyl hexyl
Base glycerol, pungent glycol, decoyl hydroximic acid；The surfactant includes at least one of following components: PEG-7 glycerol cocounut oil
Acid esters, poloxamer, PEG-6 caprylic/capric glyceride；The electrolyte includes but is not limited to calcium chloride；Described is anti-oxidant
Agent includes at least one of following components: Butylated Hydroxytoluene, pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamate), life
Educate phenol acetic acid esters；The pigment includes at least one of following components: solvent yellow 16, solvent green 3, German chamomile essence
Oil, Asian puccoon root extract, sunflower seed oil, famille rose, lemon yellow, light green, brilliant blue.
9. makeup remover according to claim 8, which is characterized in that the preservative is pungent glycol and Sensiva SC50；
The surfactant is poloxamer；The pigment is German chamomile essential oil.
10. the preparation method of any one makeup remover according to claim 1~9, which is characterized in that steps are as follows:
(1) water phase: main still is added in water, is added in room temperature water after thickener and moisturizer are premixed uniformly, is heated with stirring to 80-
85 DEG C of swellings sufficiently, are then added surfactant and stir evenly, be cooled to 70-75 DEG C of addition electrolyte, be cooled to 50 DEG C and add
Enter preservative to stir evenly, standing is cooled to 30 DEG C or less and condenses into solid gum, uses homogenizer, speed 1000-2000rpm
Homogeneous 3-5min smashes solid gum for uniform fluid glue；
(2) oily phase: mixing each grease, antioxidant, and is heated to 75 DEG C with transparent up to dissolving, and is cooled to 40 DEG C ± 5 DEG C, adds
Enter pigment, stirs evenly；
(3) finished product: under agitation, oily phase is added in main still water phase, until oil droplet suspension goes out after in water phase, stirring evenly
Material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910370397.6A CN109966184B (en) | 2019-04-30 | 2019-04-30 | Suspended oil bead cleansing water and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910370397.6A CN109966184B (en) | 2019-04-30 | 2019-04-30 | Suspended oil bead cleansing water and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109966184A true CN109966184A (en) | 2019-07-05 |
| CN109966184B CN109966184B (en) | 2021-09-14 |
Family
ID=67072879
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910370397.6A Active CN109966184B (en) | 2019-04-30 | 2019-04-30 | Suspended oil bead cleansing water and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109966184B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020233509A1 (en) * | 2019-05-17 | 2020-11-26 | 株式会社资生堂 | Oil-in-water composition |
| CN111991243A (en) * | 2020-08-31 | 2020-11-27 | 广州环亚化妆品科技有限公司 | Double-layer multi-effect coagulated bead and preparation method and application thereof |
| CN112999117A (en) * | 2021-03-04 | 2021-06-22 | 旌德县万方日用品有限公司 | Cleansing water with water phase and oil phase high-stability system, preparation method and application |
| CN113440433A (en) * | 2021-06-28 | 2021-09-28 | 上海丽知品牌管理有限公司 | Smoothie-like makeup remover composition and preparation method thereof |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1291885A (en) * | 1998-01-28 | 2001-04-18 | 宝洁公司 | Moisturizing personal cleansing compositions with improved lipid deposition |
| EP1149574A2 (en) * | 2000-04-21 | 2001-10-31 | Kao Corporation | Cleansing material |
| EP2042216A1 (en) * | 2007-09-28 | 2009-04-01 | ACO Hud Nordic AB | Body and hair cleansing formulations |
| CN102740827A (en) * | 2010-02-01 | 2012-10-17 | 荷兰联合利华有限公司 | Shampoo composition containing gel network |
| KR20130028480A (en) * | 2011-09-09 | 2013-03-19 | 주식회사 엘지생활건강 | Cosmetic composition comprising weighting agent |
| CN106333898A (en) * | 2016-10-08 | 2017-01-18 | 广州丹奇日用化工厂有限公司 | Multi-moisturizing double-layer makeup remover and preparation method thereof |
| CN107550743A (en) * | 2017-09-19 | 2018-01-09 | 天津郁美净集团有限公司 | A kind of three layers of make up remover and preparation method thereof |
| CN108042394A (en) * | 2017-12-20 | 2018-05-18 | 广州玮弘祺生物科技有限公司 | A kind of Soap-base facial cleanser and preparation method thereof |
| CN108721132A (en) * | 2018-05-30 | 2018-11-02 | 上海中翊日化有限公司 | A kind of suspension oil droplet toner and preparation method thereof containing Sucrose acetoisobutyrate |
| CN109125237A (en) * | 2018-09-18 | 2019-01-04 | 广州艾蓓生物科技有限公司 | A kind of food grade profit lip gel and preparation method thereof |
-
2019
- 2019-04-30 CN CN201910370397.6A patent/CN109966184B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1291885A (en) * | 1998-01-28 | 2001-04-18 | 宝洁公司 | Moisturizing personal cleansing compositions with improved lipid deposition |
| EP1149574A2 (en) * | 2000-04-21 | 2001-10-31 | Kao Corporation | Cleansing material |
| EP2042216A1 (en) * | 2007-09-28 | 2009-04-01 | ACO Hud Nordic AB | Body and hair cleansing formulations |
| CN102740827A (en) * | 2010-02-01 | 2012-10-17 | 荷兰联合利华有限公司 | Shampoo composition containing gel network |
| KR20130028480A (en) * | 2011-09-09 | 2013-03-19 | 주식회사 엘지생활건강 | Cosmetic composition comprising weighting agent |
| CN106333898A (en) * | 2016-10-08 | 2017-01-18 | 广州丹奇日用化工厂有限公司 | Multi-moisturizing double-layer makeup remover and preparation method thereof |
| CN107550743A (en) * | 2017-09-19 | 2018-01-09 | 天津郁美净集团有限公司 | A kind of three layers of make up remover and preparation method thereof |
| CN108042394A (en) * | 2017-12-20 | 2018-05-18 | 广州玮弘祺生物科技有限公司 | A kind of Soap-base facial cleanser and preparation method thereof |
| CN108721132A (en) * | 2018-05-30 | 2018-11-02 | 上海中翊日化有限公司 | A kind of suspension oil droplet toner and preparation method thereof containing Sucrose acetoisobutyrate |
| CN109125237A (en) * | 2018-09-18 | 2019-01-04 | 广州艾蓓生物科技有限公司 | A kind of food grade profit lip gel and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 李成海: "乙酸异丁酸蔗糖酯的合成和应用", 《广西化工》 * |
| 珠海市嘉琪精细化工有限公司: "网址：http://ftba.nmpa.gov.cn:8181/ftban/itownet/hzp_ba/fw/pz.jsp?processid=20150131102613ztsq9&nid=20150131102613ztsq9", 《赫丽姿瞬柔双层卸妆水》 * |
| 谢明勇，等: "《日用化学品实用生产技术与配方》", 30 June 2002, 江西科学技术出版社 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020233509A1 (en) * | 2019-05-17 | 2020-11-26 | 株式会社资生堂 | Oil-in-water composition |
| CN111991243A (en) * | 2020-08-31 | 2020-11-27 | 广州环亚化妆品科技有限公司 | Double-layer multi-effect coagulated bead and preparation method and application thereof |
| CN111991243B (en) * | 2020-08-31 | 2023-03-07 | 广州环亚化妆品科技股份有限公司 | Double-layer multi-effect coagulated bead and preparation method and application thereof |
| CN112999117A (en) * | 2021-03-04 | 2021-06-22 | 旌德县万方日用品有限公司 | Cleansing water with water phase and oil phase high-stability system, preparation method and application |
| CN113440433A (en) * | 2021-06-28 | 2021-09-28 | 上海丽知品牌管理有限公司 | Smoothie-like makeup remover composition and preparation method thereof |
| CN115006285A (en) * | 2021-06-28 | 2022-09-06 | 上海丽知品牌管理有限公司 | Smoothie-like makeup remover composition and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109966184B (en) | 2021-09-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109966184A (en) | A kind of suspension oil droplet makeup remover and preparation method thereof | |
| US6280746B1 (en) | Dry emollient compositions | |
| CN102366384B (en) | Skin-refreshing face-repairing cream composition and preparation method thereof | |
| CN106176321B (en) | A kind of lipstick and preparation method thereof rich in moisture | |
| JPH11130655A (en) | Thickened composition containing fused silica | |
| JP6181697B2 (en) | Dextrin fatty acid esters and cosmetics | |
| JP5878472B2 (en) | Cosmetic composition | |
| CN107510621A (en) | It is a kind of be used for remove ornaments and formal dress without Water blown aerosol | |
| FR2867065A1 (en) | SURFACE TREATED POWDER, DISPERSION CONTAINING THE SAME, AND COSMETIC PRODUCT PREPARED THEREFROM | |
| CN102348451A (en) | Cosmetic basic composition and its use | |
| CN104940121A (en) | Chlamydomonus nivalis cream and preparing method thereof | |
| US20040091435A1 (en) | Deodorant and antiperspirant controlled release system | |
| KR20180019082A (en) | Composition | |
| CN107362090A (en) | A kind of water class cosmetics that can produce the long-acting moisturizing of pearly-lustre | |
| KR20010072740A (en) | Solid aqueous gel comprising a hydrophilic gelling agent and starch, composition comprising same and uses | |
| JP2009179564A (en) | Oily solid cosmetic | |
| EP1926470A1 (en) | Preparation, in particular cosmetic preparation, production and use thereof | |
| KR101479689B1 (en) | Cosmetic composition to react with soap specifically | |
| JP3909828B2 (en) | Solid cosmetics | |
| FR3098113A1 (en) | Composition in the form of an oil-in-water emulsion with a fatty phase in the form of drops and aggregates | |
| CN107929099A (en) | It is long-acting to hold non-sticky cup lip gloss of adornment plant and preparation method thereof | |
| JP4136965B2 (en) | Hair cosmetics | |
| JPH09208483A (en) | Preparation composition for external use for skin and bath agent composition | |
| WO2019179775A1 (en) | A cosmetic composition comprising beads | |
| KR100553227B1 (en) | The cosmetic composition of jelly type for improving lips |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |