CN114277579A - 耐晒全涤仿棉面料的加工方法 - Google Patents

耐晒全涤仿棉面料的加工方法 Download PDF

Info

Publication number
CN114277579A
CN114277579A CN202111625461.4A CN202111625461A CN114277579A CN 114277579 A CN114277579 A CN 114277579A CN 202111625461 A CN202111625461 A CN 202111625461A CN 114277579 A CN114277579 A CN 114277579A
Authority
CN
China
Prior art keywords
fabric
temperature
sun
processing method
benzophenone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202111625461.4A
Other languages
English (en)
Other versions
CN114277579B (zh
Inventor
陈明贤
孙立新
曹竹青
谢萍萍
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Dongjin New Material Co ltd
Original Assignee
Zhejiang Dongjin New Material Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Dongjin New Material Co ltd filed Critical Zhejiang Dongjin New Material Co ltd
Priority to CN202111625461.4A priority Critical patent/CN114277579B/zh
Publication of CN114277579A publication Critical patent/CN114277579A/zh
Priority to US17/807,308 priority patent/US20230203722A1/en
Application granted granted Critical
Publication of CN114277579B publication Critical patent/CN114277579B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00—Woven fabrics designed to make specified articles
    • D03D1/0035—Protective fabrics
    • D03D1/007—UV radiation protecting
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/16—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds as constituent
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/292—Conjugate, i.e. bi- or multicomponent, fibres or filaments
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/54—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads coloured
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/56—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads elastic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B21/00—Successive treatments of textile materials by liquids, gases or vapours
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • D06B3/18—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • D06B3/20—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics with means to improve the circulation of the treating material on the surface of the fabric
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B5/00—Forcing liquids, gases or vapours through textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing impregnating
    • D06B5/12—Forcing liquids, gases or vapours through textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing impregnating through materials of definite length
    • D06B5/22—Forcing liquids, gases or vapours through textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing impregnating through materials of definite length through fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12—Aldehydes; Ketones
    • D06M13/127—Mono-aldehydes, e.g. formaldehyde; Monoketones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34—Material containing ester groups
    • D06P3/52—Polyesters
    • D06P3/54—Polyesters using dispersed dyestuffs
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
    • D06P5/2066—Thermic treatments of textile materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/06—Load-responsive characteristics
    • D10B2401/061—Load-responsive characteristics elastic
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/22—Physical properties protective against sunlight or UV radiation
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00—Wearing apparel
    • D10B2501/04—Outerwear; Protective garments

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Coloring (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明公开了一种耐晒全涤仿棉面料的加工方法，属纺织面料领域。加工步骤为：(1)PTT/PET双组份复合弹力丝织造成面料；(2)面料进行染色加工；(3)定型整理；定型整理具体流程为：a、配置整理液；整理液由交联剂与含二苯甲酮聚有机硅氧烷乳液混合而成；b、浸轧面料；c、高温定型烘干。本发明耐晒全涤仿棉面料的加工方法，将PTT/PET双组份复合弹力丝织造为全涤弹力面料，面料手感仿棉，弹力较好，性能优于传统的涤氨面料。同时，面料不含氨纶，因此不存在不耐酸碱，不耐氯，日晒易脆化的问题。

Description

耐晒全涤仿棉面料的加工方法
技术领域
本发明属于纺织面料领域，具体涉及一种耐晒全涤仿棉面料的加工方法。
背景技术
棉织物具有优良的吸湿性、柔软性、保暖性和舒适性，一直深受人们喜爱，但纯棉织物的抗皱、防污和防霉等方面存在不足，当棉纤维饱和吸收人体汗液后造成湿冷不适感觉时，其导湿性、吸湿快干性差的缺点显现。保形性和悬垂性良好的涤纶，被广泛用于仿棉面料的制作。现有的仿棉面料多为涤纶、氨纶制成，因含氨纶而存在不耐酸碱，不耐氯，不耐日晒的问题。
发明内容
本发明目的是提供一种耐晒全涤仿棉面料的加工方法。
为实现上述目的，本发明采用了以下技术方案。
一种耐晒全涤仿棉面料的加工方法，包括以下步骤：
(1)PTT/PET双组份复合弹力丝织造成面料；
(2)面料进行染色加工；
(3)定型整理；
所述的定型整理，具体流程为：
a、配置整理液；由交联剂与含二苯甲酮聚有机硅氧烷乳液混合成整理液；
b、浸轧面料；
c、高温烘干定型。
所述的含二苯甲酮聚有机硅氧烷乳液，制备方法为：
在装有电动搅拌器、温度计、回流冷凝管的三口烧瓶中加入D4 90g、含二苯甲酮硅氧烷5g和KH602 2g，搅拌混合均匀，升温至90℃以上；再加入0.2g四甲基氢氧化铵，保持温度在120℃反应6小时，在表压为0.8MPa的压力下减压蒸馏脱除低沸物，然后升温至140℃分解催化剂四甲基氢氧化铵，并再次在0.8MPa的表压下减压蒸馏脱除低沸物，获得无色透明粘稠液体，即含二苯甲酮聚有机硅氧烷；含二苯甲酮聚有机硅氧烷与乳化剂按质量比10:1混合，搅拌过程中添加水和乙酸的混合物，搅拌至溶液呈透明状，得含二苯甲酮聚有机硅氧烷乳液。乳化剂由异构十三醇聚氧乙烯醚1307、异构十三醇聚氧乙烯醚1309、AEO-9按质量比2:2:1组成。
交联剂为水性封端型聚氨酯。
步骤(1)所述的PTT/PET双组份复合弹力丝，为消光100D/108FPET/PTT复合丝，PET、PTT质量比1:1。
所述的染色加工，包括面料的精练、预定型、碱减量、染色工序。
精练：精练剂2g/L、纯碱浓度10g/L、浴比1:10，面料在100℃条件下处理30min。
预定型：温度190～195℃、时间30～4Os。
碱减量：NaOH质量浓度20g/L，浴比1:10，处理时间40min，处理温度110℃。
染色：常温下染浴中加入高温匀染剂和抗皱柔软剂→面料在染色机中处理10min→加入分散染料染，染液循环10min→升温至75℃→保温10min→升温至90℃→保温15min→升温至130℃→保温45min→降温至50℃→排液→水洗→还原清洗→水洗→出缸。
本发明耐晒全涤仿棉面料的加工方法，将PTT/PET双组份复合弹力丝织造为全涤弹力面料，面料手感仿棉，弹力较好，性能优于传统的涤氨面料。同时，面料不含氨纶，因此不存在不耐酸碱，不耐氯，日晒易脆化的问题。涤纶面料的耐晒牢度稍差，在面料的服用期间会发生褪色等不良现象，本发明在面料后整理时采用含二苯甲酮聚有机硅氧烷乳液，增强了面料的耐光牢度，也避免了常规有机防紫外线剂的迁移及有机氟的环保问题；交联剂可与涤纶纤维碱减量后产生的羟基及聚有机硅氧烷中的氨基反应，形成交联，提高面料定型整理的耐久性。
具体实施方式
一种耐晒全涤仿棉面料的加工方法，包括以下步骤：
(1)PTT/PET双组份复合弹力丝织造成面料；
(2)面料进行染色加工；
(3)定型整理。
步骤(1)中所述的PTT/PET双组份复合弹力丝为消光100D/108FPET/PTT复合丝，PET、PTT质量比1:1。织造工艺流程包括，经纱：原料-分条整经-分绞-穿综、穿筘-织造；纬纱：原料-织造。
步骤(2)中所述的面料染色加工，包括面料的精练、预定型、碱减量、染色工序。
精练：精练剂2g/L、纯碱浓度10g/L、浴比1:10，面料在100℃条件下处理30min；
预定型：温度190～195℃、时间30～4Os；
碱减量：NaOH质量浓度20g/L，浴比1:10，处理时间40min，处理温度110℃；
染色：常温下加入高温匀染剂和抗皱柔软剂→面料在染色机中处理10min→加入分散染料染，染液循环10min→升温至75℃(1.5℃/min)→保温10min→升温至90℃(0.5℃/min)→保温15min→升温至130℃(1℃/min)→保温45min→降温至50℃(1℃/min)→排液→水洗→还原清洗→水洗→出缸。
所述的定型整理，具体工艺流程为：
a、配置整理液；交联剂与含二苯甲酮聚有机硅氧烷乳液按质量比1:18-20混合成整理液；
b、浸轧面料，二浸二轧，轧液率80-90％；
c、高温定型烘干，120℃、40-60s烘干，180-190℃、30-40s焙烘。
所述的含二苯甲酮聚有机硅氧烷乳液，制备方法为：
在装有电动搅拌器、温度计、回流冷凝管的三口烧瓶中加入D4 90g、含二苯甲酮硅氧烷5g和KH602 2g，搅拌混合均匀，升温至90℃以上；再加入0.2g四甲基氢氧化铵，然后保持温度在120℃反应6小时，在表压为0.8MPa的压力下减压蒸馏脱除低沸物，然后升温至140℃分解催化剂四甲基氢氧化铵，并再次在0.8MPa的表压下减压蒸馏脱除低沸物，获得无色透明粘稠液体，即含二苯甲酮聚有机硅氧烷；含二苯甲酮聚有机硅氧烷与乳化剂按质量比10:1混合，搅拌过程中添加水和乙酸的混合物，搅拌至溶液呈透明状，得含二苯甲酮聚有机硅氧烷乳液。乳化剂由异构十三醇聚氧乙烯醚1307、异构十三醇聚氧乙烯醚1309、AEO-9按质量比2:2:1组成。乙酸调节乳液的pH值呈酸性、乳液的质量百分浓度约10％。KH602,N-(β-氨乙基)-γ-氨丙基甲基二甲氧基硅烷。
含二苯甲酮硅氧烷由三甲氧基氢硅烷与2-羟基-4-丙烯氧基二苯甲酮经加成反应制成；具体步骤为：将28.2g(0.1mol)2-羟基-4-丙烯氧基二苯甲酮(CAS号：2549-87-3)、80g甲苯和0.12g铂催化剂加入到装有机械搅拌器、回流冷凝管、恒压滴液漏斗和氮气导气管的四口圆底烧瓶中，在氮气氛围下升温至85℃并回流30min；称量14.7g(0.12mol)三甲氧基氢硅烷(CAS号：2487-90-3)和10g甲苯，充分混合后利用恒压滴液漏斗在2h内加入到四口烧瓶中，然后升温至100℃并保温6h，降温，0.01MPa减压蒸馏未反应单体，出料，即为含二苯甲酮硅氧烷。
交联剂为水性封端型聚氨酯，市售产品，如德国科思创的水性封闭型异氰酸酯固化剂BL5335。
实施例1：
一种全涤仿棉面料，包括经纱、纬纱，经纱和纬纱均为消光100D/108FPET/PTT复合丝，PET、PTT质量比1:1；织造工艺流程包括，经纱：原料-分条整经-分绞-穿综、穿筘-织造；纬纱：原料-织造。
整经工序的参数为：经丝规格100D/108F复合丝、150T/m.Z；总经丝数7416根；门幅206㎝；上排数618颗；条数12条；定幅条宽17㎝；18羽筘穿入2根；角度90°；络轴张力2kg。
织造工序的参数为：织机车速800r/min；停经架深度5；内经综平时间340°；开口动程24°；上机张力100KN；选纬1甲；上机纬密27根/cm。
全涤仿棉面料规格如下：
门幅：206cm
经纬密：36/27根/cm
筘号:18#
筘穿入:2
总经线数:7416根
边经数：60*2＝120根
经线：消光100D/108F PET/PTT复合丝，PET、PTT质量比1:1
纬线：消光100D/108F PET/PTT复合丝，PET、PTT质量比1:1
穿综：1-4顺穿
纹板：平纹
每米克重：154g/米
实施例2：
实施例1的全涤仿棉面料染色加工工艺，包括面料的精练、预定型、碱减量、染色工序：
1)精练
精练加工处方及工艺条件
精练剂2g/L
纯碱浓度10g/L
浴比1:10
面料室温浸入精练处理液中，1.5℃/min的速率升温至100℃，保温处理30min后，以2℃/min的速率降温至50℃以下，酸中和，再经两道水洗至布面呈中性；
2)预定形
预定形工艺条件
温度/℃190～195
时间/s 30～4O
车速/(m/min)30
3)碱减量
碱减量处方及工艺条件：
NaOH质量浓度20g/L，
浴比1:10，
处理时间40min，
处理温度110℃；
面料室温浸入碱液中，1℃/min的速率升温至110℃，保温处理40min后，以2℃/min的速率降温至50℃以下，酸中和，再以清水水洗至布面呈中性；
4)染色
染色处方
Figure BDA0003438635690000071
染色工艺条件及流程
常温下加入高温匀染剂和抗皱柔软剂→面料在染色机中处理10min→加入分散染料，染液循环10min→升温至75℃(1.5℃/min)→保温10min→升温至90℃(0.5℃/min)→保温15min→升温至130℃(1℃/min)→保温45min→降温至50℃(1℃/min)→排液→水洗→还原清洗→水洗→出缸；
染色完毕后进行还原清洗，可去除纤维表面的浮色，提高各项色牢度指标；
还原清洗处方及工艺条件
Figure BDA0003438635690000081
还原清洗后用醋酸中和，再分别以温热水和冷水清洗。
实施例3：
一种耐晒全涤仿棉面料的加工方法，包括以下步骤：
(1)PTT/PET双组份复合弹力丝织造成面料，具体见实施例1；
(2)面料进行染色加工，具体步骤见实施例2；
(3)定型整理
a、配置整理液；整理液为含二苯甲酮聚有机硅氧烷乳液；
b、浸轧面料，二浸二轧，轧液率80-90％；
c、高温烘干定型，120℃、40-60s烘干，180-190℃、30-40s焙烘。
防泼水洗前5级，5次洗后3级；弹性伸长率≥20％，弹性回复率≥85％；耐光色牢度等级4-5级。
实施例4：
一种耐晒全涤仿棉面料的加工方法，包括以下步骤：
(1)PTT/PET双组份复合弹力丝织造成面料，具体见实施例1；
(2)面料进行染色加工，具体步骤见实施例2；
(3)定型整理
a、配置整理液；整理液由质量比1:20的水性封闭型异氰酸酯固化剂BL5335与含二苯甲酮聚有机硅氧烷乳液混合而成；
b、浸轧面料，二浸二轧，轧液率80-90％；
c、高温烘干定型，120℃、40-60s烘干，180-190℃、30-40s焙烘。
防泼水洗前5级，5次洗后4级；弹性伸长率≥16％，弹性回复率≥83％；耐光色牢度等级4-5级。
实施例5：
一种耐晒全涤仿棉面料的加工方法，包括以下步骤：
(1)PTT/PET双组份复合弹力丝织造成面料，具体见实施例1；
(2)面料进行染色加工，具体步骤见实施例2；
(3)定型整理
a、配置整理液；整理液由质量比1:18的水性封闭型异氰酸酯固化剂BL5335与含二苯甲酮聚有机硅氧烷乳液混合而成；
b、浸轧面料，二浸二轧，轧液率80-90％；
c、高温烘干定型，120℃、40-60s烘干，180-190℃、30-40s焙烘。
防泼水洗前5级，5次洗后4级；弹性伸长率≥12％，弹性回复率≥80％；耐光色牢度等级4-5级。
本发明工艺制备的耐晒全涤仿棉面料，仿棉的效果是由纺织、染色、后整理综合形成的，织造时经纬线PET/PTT组分的质量比例及纤度、捻度、经纬密等参数是主要的影响因素；后续染色加工时，预定型条件、减量率的高低均直接影响面料成品的风格及手感；后整理的硅乳则形成面料柔软手感及防水、耐晒功能。
上述性能指标测试方法：防泼水性能测试测试参照GB/T 4745-2012《纺织品防水性能的检测和评价沾水法》；弹性测试参照FZ/T 01034-2008《纺织品机织物拉伸弹性试验方法》；耐光色牢度测试参照GB/T 8427-2019《纺织品色牢度试验耐人造光色牢度：氙弧》。

Claims (9)

1.一种耐晒全涤仿棉面料的加工方法，包括以下步骤：
(1)PTT/PET双组份复合弹力丝织造成面料；
(2)面料进行染色加工；
(3)定型整理；
所述的定型整理，具体步骤为：
a、配置整理液；整理液由交联剂与含二苯甲酮聚有机硅氧烷乳液混合而成；
b、浸轧面料；
c、高温定型烘干。
2.根据权利要求1所述的一种耐晒全涤仿棉面料的加工方法，其特征在于：所述的含二苯甲酮聚有机硅氧烷乳液，制备方法为：
在装有电动搅拌器、温度计、回流冷凝管的三口烧瓶中加入D4 90g、含二苯甲酮硅氧烷5g和KH602 2g，搅拌混合均匀，升温至90℃以上；再加入0.2g四甲基氢氧化铵，然后保持温度在120℃反应6小时，在表压为0.8MPa的压力下减压蒸馏脱除低沸物，然后升温至140℃分解催化剂四甲基氢氧化铵，并再次在0.8MPa的表压下减压蒸馏脱除低沸物，获得无色透明粘稠液体，即含二苯甲酮聚有机硅氧烷；含二苯甲酮聚有机硅氧烷与乳化剂按质量比10:1混合，搅拌过程中添加水和乙酸的混合物，搅拌至溶液呈透明状，得含二苯甲酮聚有机硅氧烷乳液。乳化剂由异构十三醇聚氧乙烯醚1307、异构十三醇聚氧乙烯醚1309、AEO-9按质量比2:2:1组成。
3.根据权利要求1所述的一种耐晒全涤仿棉面料的加工方法，其特征在于：交联剂为水性封端型聚氨酯。
4.根据权利要求1所述的一种耐晒全涤仿棉面料的加工方法，其特征在于：步骤(1)所述的PTT/PET双组份复合弹力丝，为消光100D/108F PET/PTT复合丝，PET、PTT质量比1:1。
5.根据权利要求1所述的一种耐晒全涤仿棉面料的加工方法，其特征在于：所述的染色加工，包括面料的精练、预定型、碱减量、染色工序。
6.根据权利要求5所述的一种耐晒全涤仿棉面料的加工方法，其特征在于：所述的精练，处方及工艺条件为精练剂2g/L、纯碱浓度10g/L、浴比1:10，面料在100℃条件下处理30min。
7.根据权利要求5所述的一种耐晒全涤仿棉面料的加工方法，其特征在于：所述的预定型，工艺条件为温度190～195℃、时间30～4Os。
8.根据权利要求5所述的一种耐晒全涤仿棉面料的加工方法，其特征在于：所述的碱减量，处方及工艺条件为NaOH质量浓度20g/L，浴比1:10，处理时间40min，处理温度110℃。
9.根据权利要求5所述的一种耐晒全涤仿棉面料的加工方法，其特征在于：所述的染色，具体步骤为常温下加入高温匀染剂和抗皱柔软剂→面料在染色机中处理10min→加入分散染料染，染液循环10min→升温至75℃→保温10min→升温至90℃→保温15min→升温至130℃→保温45min→降温至50℃→排液→水洗→还原清洗→水洗→出缸。
CN202111625461.4A 2021-12-28 2021-12-28 耐晒全涤仿棉面料的加工方法 Active CN114277579B (zh)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN202111625461.4A CN114277579B (zh) 2021-12-28 2021-12-28 耐晒全涤仿棉面料的加工方法
US17/807,308 US20230203722A1 (en) 2021-12-28 2022-06-16 Method for processing all-polyester fiber cotton-like fabric with sunlight resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202111625461.4A CN114277579B (zh) 2021-12-28 2021-12-28 耐晒全涤仿棉面料的加工方法

Publications (2)

Publication Number Publication Date
CN114277579A true CN114277579A (zh) 2022-04-05
CN114277579B CN114277579B (zh) 2023-07-25

Family

ID=80876911

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202111625461.4A Active CN114277579B (zh) 2021-12-28 2021-12-28 耐晒全涤仿棉面料的加工方法

Country Status (2)

Country Link
US (1) US20230203722A1 (zh)
CN (1) CN114277579B (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115058815A (zh) * 2022-07-04 2022-09-16 晋江市联盛舒坦科技有限公司 一种舒弹型生物基仿锦棉提花梭织外套面料及制备工艺

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN118087124B (zh) * 2024-04-22 2024-06-21 比音勒芬服饰股份有限公司 一种呼吸透湿散热的超薄面料及其应用

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4525426A (en) * 1982-04-30 1985-06-25 General Electric Company Ultraviolet light absorbing agents, method for making, compositions, and articles containing same
CN101914206A (zh) * 2010-08-13 2010-12-15 东华大学 一种季铵化改性氨基硅油柔软剂、其制备和应用
CN102529248A (zh) * 2010-09-06 2012-07-04 信越化学工业株式会社 用于汽车玻璃窗的塑料制品
CN102605530A (zh) * 2012-03-20 2012-07-25 福建凤竹纺织科技股份有限公司 一种弹性针织面料的生产工艺
JP2013190542A (ja) * 2012-03-13 2013-09-26 Shin Etsu Chem Co Ltd コーティング用組成物及びプラスチックレンズ
CN104711690A (zh) * 2015-02-08 2015-06-17 江苏江南高纤股份有限公司 高弹性中空毛型聚酯长纤维的制造方法
CN105294753A (zh) * 2015-11-19 2016-02-03 陕西省石油化工研究设计院 一种2-羟基二苯甲酮衍生物基硅烷的制备方法
CN105384768A (zh) * 2015-11-27 2016-03-09 陕西省石油化工研究设计院 一种含二苯甲酮基团硅烷的制备方法
CN105442326A (zh) * 2015-12-29 2016-03-30 陕西科技大学 一种纳米复合抗紫外有机涂层整理剂及其制备方法
CN107988801A (zh) * 2017-12-31 2018-05-04 南通纺织丝绸产业技术研究院 一种用于棉织物的反应型抗紫外柔软整理剂及制备方法
CN109021005A (zh) * 2018-08-22 2018-12-18 陕西能源职业技术学院 一种水溶性2-羟基二苯甲酮衍生物基硅烷的制备方法
CN111363199A (zh) * 2020-03-09 2020-07-03 国科广化(南雄)新材料研究院有限公司 一种具有光引发功能的二氧化硅复合材料及制备与应用
CN113718410A (zh) * 2021-09-28 2021-11-30 宁波大千纺织品有限公司 一种双组分聚酯仿棉弹性针织面料及其制备方法

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4525426A (en) * 1982-04-30 1985-06-25 General Electric Company Ultraviolet light absorbing agents, method for making, compositions, and articles containing same
CN101914206A (zh) * 2010-08-13 2010-12-15 东华大学 一种季铵化改性氨基硅油柔软剂、其制备和应用
CN102529248A (zh) * 2010-09-06 2012-07-04 信越化学工业株式会社 用于汽车玻璃窗的塑料制品
JP2013190542A (ja) * 2012-03-13 2013-09-26 Shin Etsu Chem Co Ltd コーティング用組成物及びプラスチックレンズ
CN102605530A (zh) * 2012-03-20 2012-07-25 福建凤竹纺织科技股份有限公司 一种弹性针织面料的生产工艺
CN104711690A (zh) * 2015-02-08 2015-06-17 江苏江南高纤股份有限公司 高弹性中空毛型聚酯长纤维的制造方法
CN105294753A (zh) * 2015-11-19 2016-02-03 陕西省石油化工研究设计院 一种2-羟基二苯甲酮衍生物基硅烷的制备方法
CN105384768A (zh) * 2015-11-27 2016-03-09 陕西省石油化工研究设计院 一种含二苯甲酮基团硅烷的制备方法
CN105442326A (zh) * 2015-12-29 2016-03-30 陕西科技大学 一种纳米复合抗紫外有机涂层整理剂及其制备方法
CN107988801A (zh) * 2017-12-31 2018-05-04 南通纺织丝绸产业技术研究院 一种用于棉织物的反应型抗紫外柔软整理剂及制备方法
CN109021005A (zh) * 2018-08-22 2018-12-18 陕西能源职业技术学院 一种水溶性2-羟基二苯甲酮衍生物基硅烷的制备方法
CN111363199A (zh) * 2020-03-09 2020-07-03 国科广化(南雄)新材料研究院有限公司 一种具有光引发功能的二氧化硅复合材料及制备与应用
CN113718410A (zh) * 2021-09-28 2021-11-30 宁波大千纺织品有限公司 一种双组分聚酯仿棉弹性针织面料及其制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
路德待,安秋凤,黄玲,程浩,何钦飞: "一种新型有机硅抗紫外整理剂的合成与应用", 针织工业, no. 07, pages 51 - 54 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115058815A (zh) * 2022-07-04 2022-09-16 晋江市联盛舒坦科技有限公司 一种舒弹型生物基仿锦棉提花梭织外套面料及制备工艺

Also Published As

Publication number Publication date
US20230203722A1 (en) 2023-06-29
CN114277579B (zh) 2023-07-25

Similar Documents

Publication Publication Date Title
CN106012214B (zh) 提花醋酸长丝家纺面料及其生产方法
CN107460602B (zh) 一种四面弹面料的生产工艺
CN102767083B (zh) 一种免烫服装面料的加工方法
CN114277579A (zh) 耐晒全涤仿棉面料的加工方法
CN113684584B (zh) 纯棉色织高支高密免烫面料的制备方法
CN110699826B (zh) 一种涤纶仿棉色织面料、及其制造方法和应用
CN103126140A (zh) 一种羊绒衬布的生产工艺
CN104294450A (zh) 一种轻薄羊毛混纺面料及其制备方法
CN106283352B (zh) 一种化纤超仿棉格子布的生产工艺
CN108049177B (zh) 一种珍珠防皱服装面料及其制备方法
CN108286104A (zh) 一种羊毛/羊驼毛/波斯纶混纺顺毛双面呢的生产工艺
CN111005230B (zh) 一种运动棉型面料及其生产方法
CN107022827B (zh) 一种经纱三套色小提花牛仔面料
CN111764036B (zh) 一种多次水洗不变形全棉面料及其制备方法
CN108728986A (zh) 棉涤混纺、棉涤交织四面弹面料及其长车染色生产方法
CN104278396B (zh) 用于家纺的真丝-羊毛交织提花面料及其制备方法
CN106012552A (zh) 丝麻交织面料
CN113046891B (zh) 一种提高高尔夫服装舒适性的面料及其制备方法
CN109023640B (zh) 一种搓球呢粗纺面料生产工艺
CN115961468A (zh) 抗紫外线防水涤纶面料
CN115323579A (zh) 一种高支高密导光面料的制备方法
CN109056151A (zh) 一种高支生态舒弹呢的制备方法
CN110205730A (zh) 一种零甲醛的雨露麻纺织面料
CN108532107A (zh) 一种混纺仿丝绸面料的制备方法
CN115323767A (zh) 一种高支高密透气面料的制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
PE01 Entry into force of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: The processing method of sun resistant polyester cotton like fabric

Effective date of registration: 20230925

Granted publication date: 20230725

Pledgee: Bank of Beijing Co.,Ltd. Shaoxing Keqiao Sub branch

Pledgor: ZHEJIANG DONGJIN NEW MATERIAL Co.,Ltd.

Registration number: Y2023330002170