CN1128012C - 以钴和钪为基的催化剂的制备方法 - Google Patents

以钴和钪为基的催化剂的制备方法 Download PDF

Info

Publication number
CN1128012C
CN1128012C CN98800891A CN98800891A CN1128012C CN 1128012 C CN1128012 C CN 1128012C CN 98800891 A CN98800891 A CN 98800891A CN 98800891 A CN98800891 A CN 98800891A CN 1128012 C CN1128012 C CN 1128012C
Authority
CN
China
Prior art keywords
catalyst
cobalt
scandium
temperature
inert
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN98800891A
Other languages
English (en)
Chinese (zh)
Other versions
CN1230901A (zh
Inventor
R·茨纳罗
A·古索
P·朔密特
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies nouvelles
Agip Petroli SA
Eni SpA
Original Assignee
IFP Energies nouvelles
Agip Petroli SA
Eni SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies nouvelles, Agip Petroli SA, Eni SpA filed Critical IFP Energies nouvelles
Publication of CN1230901A publication Critical patent/CN1230901A/zh
Application granted granted Critical
Publication of CN1128012C publication Critical patent/CN1128012C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/0445—Preparation; Activation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN98800891A 1997-06-26 1998-06-20 以钴和钪为基的催化剂的制备方法 Expired - Fee Related CN1128012C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI97A001510 1997-06-26
IT97MI001510A IT1292423B1 (it) 1997-06-26 1997-06-26 Procedimento per la preparazione di un catalizzatore a base di cobalto e scandio

Publications (2)

Publication Number Publication Date
CN1230901A CN1230901A (zh) 1999-10-06
CN1128012C true CN1128012C (zh) 2003-11-19

Family

ID=11377443

Family Applications (1)

Application Number Title Priority Date Filing Date
CN98800891A Expired - Fee Related CN1128012C (zh) 1997-06-26 1998-06-20 以钴和钪为基的催化剂的制备方法

Country Status (14)

Country Link
US (1) US6096790A (enExample)
EP (1) EP0934115B1 (enExample)
JP (1) JP4446130B2 (enExample)
CN (1) CN1128012C (enExample)
CA (1) CA2264697C (enExample)
DE (1) DE69812577T2 (enExample)
ES (1) ES2195369T3 (enExample)
ID (1) ID21346A (enExample)
IT (1) IT1292423B1 (enExample)
MY (1) MY129167A (enExample)
NO (1) NO317872B1 (enExample)
RU (1) RU2201801C2 (enExample)
SA (1) SA98190949B1 (enExample)
WO (1) WO1999000190A1 (enExample)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1237652A1 (en) * 1999-12-01 2002-09-11 Sasol Technology (Proprietary) Limited Cobalt catalysts
JP4139883B2 (ja) * 2002-02-08 2008-08-27 独立行政法人産業技術総合研究所 多種の固体触媒の迅速調製方法及びそのための装置
JP4857565B2 (ja) * 2005-01-27 2012-01-18 株式会社Ｉｈｉ フィッシャー・トロプシュ合成触媒とその製造方法
EP2055381A4 (en) 2006-08-25 2011-10-12 Nippon Steel Eng Co Ltd CATALYST FOR PRODUCING HYDROGEN CARBON HYDROGEN, METHOD FOR THE PRODUCTION OF CATALYST, METHOD FOR REGENERATING CATALYST AND METHOD FOR PRODUCING HYDROGEN CARBON FUEL FROM SYNTHETIC GAS
GB2482171B (en) 2010-07-22 2018-04-11 Gtl F1 Ag Catalyst treatment
AU2013336290B2 (en) * 2012-10-24 2016-11-17 Sasol Technology (Proprietary) Limited Process for preparing a Fischer-Tropsch catalyst
EA201791548A1 (ru) * 2015-02-25 2018-05-31 ЭсДжиСи ЭНЕРДЖИЯ С.А. (ФОРМЕЛИ-ДжиАй-ГАЗИФИКЕЙШН ИНТЕРНЭШНЛ С.А.) Системы, способы и устройства для каскада реакторов фишера-тропша
JPWO2017131231A1 (ja) * 2016-01-29 2018-11-22 Ｊｘｔｇエネルギー株式会社 フィッシャー・トロプシュ合成用触媒の製造方法及び炭化水素の製造方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU8543791A (en) * 1990-09-25 1992-04-15 Allied-Signal Inc. Production of complex cavities inside castings or semi solid forms
WO1993005000A1 (en) * 1991-08-28 1993-03-18 The Broken Hill Proprietary Company Limited Fischer tropsch catalyst comprising cobalt and scandium
WO1994004476A1 (en) * 1992-08-25 1994-03-03 The Broken Hill Proprietary Company Limited Producing blendstock
EP0756895A2 (en) * 1995-08-04 1997-02-05 AGIP PETROLI S.p.A. Process for the preparation of a catalyst useful for the conversion of synthesis gas

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4088671A (en) * 1976-03-19 1978-05-09 Gulf Research & Development Company Conversion of synthesis gas using a cobalt-ruthenium catalyst
US4585798A (en) * 1981-10-13 1986-04-29 Gulf Research & Development Company Synthesis gas conversion using ruthenium-promoted cobalt catalyst
US5227407A (en) * 1985-12-30 1993-07-13 Exxon Research And Engineering Company Water addition for increased CO/H2 hydrocarbon synthesis activity over catalysts comprising cobalt, ruthenium and mixtures thereof which may include a promoter metal
US4801573A (en) * 1987-10-23 1989-01-31 501 Den Norske Stats Oljeslenskap A.S. Catalyst for production of hydrocarbons

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU8543791A (en) * 1990-09-25 1992-04-15 Allied-Signal Inc. Production of complex cavities inside castings or semi solid forms
WO1993005000A1 (en) * 1991-08-28 1993-03-18 The Broken Hill Proprietary Company Limited Fischer tropsch catalyst comprising cobalt and scandium
WO1994004476A1 (en) * 1992-08-25 1994-03-03 The Broken Hill Proprietary Company Limited Producing blendstock
EP0756895A2 (en) * 1995-08-04 1997-02-05 AGIP PETROLI S.p.A. Process for the preparation of a catalyst useful for the conversion of synthesis gas

Also Published As

Publication number Publication date
ITMI971510A1 (it) 1998-12-26
CA2264697C (en) 2007-05-22
ITMI971510A0 (enExample) 1997-06-26
SA98190949B1 (ar) 2006-03-15
NO990880L (no) 1999-04-26
NO990880D0 (no) 1999-02-24
ID21346A (id) 1999-05-27
WO1999000190A1 (en) 1999-01-07
DE69812577D1 (de) 2003-04-30
JP2000516856A (ja) 2000-12-19
CA2264697A1 (en) 1999-01-07
DE69812577T2 (de) 2004-01-29
EP0934115A1 (en) 1999-08-11
JP4446130B2 (ja) 2010-04-07
EP0934115B1 (en) 2003-03-26
MY129167A (en) 2007-03-30
NO317872B1 (no) 2004-12-27
CN1230901A (zh) 1999-10-06
ES2195369T3 (es) 2003-12-01
US6096790A (en) 2000-08-01
IT1292423B1 (it) 1999-02-08
RU2201801C2 (ru) 2003-04-10

Similar Documents

Publication Publication Date Title
RU2161067C2 (ru) Способ получения катализатора для конверсии синтез-газа, композиция, катализатор и способ синтеза газа
RU2207188C2 (ru) Каталитическая композиция, пригодная для способа фишера-тропша
EP0977632B1 (en) Preparation of high activity catalysts and their use
CN1082458A (zh) 一种含有第3主族和第8族金属的选择加氢催化剂及用途
CN1187180A (zh) 制备烃的催化剂和方法
CN1024666C (zh) γ-丁内酯催化氢化制备四氢呋喃和丁二醇的方法
CN1440310A (zh) 使用掺杂的、热稳定的催化剂载体的高活性费－托合成
KR20100133766A (ko) 피셔-트롭쉬 합성 반응용 철계열의 촉매와 이의 제조방법
CN1015358B (zh) 有载体金属催化剂及其制法和应用
CN1069298C (zh) 将马来酸氢化成1,4-丁二醇的改进方法
CN1065261A (zh) 制备一氯三氟乙烯和三氟乙烯的方法以及用于该方法的催化剂组合物
CN1230901A (zh) 以钴和钪为基的催化剂的制备方法
CN108246313B (zh) 一种基于碳化处理方法的高分散重质烃费托合成催化剂及其制备方法
CN108654637B (zh) 一种钴基催化剂及制备方法和应用及费托合成方法
CN1100005A (zh) 可用于脱氢的催化剂的制备方法
CN1221776A (zh) 长链正构烷烃的加氢异构化方法和适用于该目的的催化剂
CN1044094C (zh) 将甲烷转化成较高级烃的催化剂及其用途
JP4911974B2 (ja) フィッシャー・トロプシュ合成用触媒および炭化水素の製造法
JPS61111139A (ja) 触媒の製造法
CN1142124C (zh) 一种负载型铜基催化剂用在烯烃环丙烷化反应中的应用
JP2004196874A (ja) フィッシャー・トロプシュ法による炭化水素類の製造方法
CN1774407A (zh) 二氧化钛与铝酸钴催化剂载体的制备及其在费－托合成中的用途
CN1428193A (zh) 合成气制乙烯、丙烯的纳米催化剂及其制备方法
JPH05212289A (ja) Ｍｆｉ構造を有する触媒、および炭素原子数２〜１２の炭化水素の芳香族化におけるこれの使用
CN1263714C (zh) 丁烯歧化制丙烯的方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20031119

Termination date: 20130620