CN1127474C - 可光固化的卤代氟丙烯酸酯 - Google Patents

可光固化的卤代氟丙烯酸酯 Download PDF

Info

Publication number
CN1127474C
CN1127474C CN98805977A CN98805977A CN1127474C CN 1127474 C CN1127474 C CN 1127474C CN 98805977 A CN98805977 A CN 98805977A CN 98805977 A CN98805977 A CN 98805977A CN 1127474 C CN1127474 C CN 1127474C
Authority
CN
China
Prior art keywords
cfx
cfcl
enough
generate
condition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN98805977A
Other languages
English (en)
Chinese (zh)
Other versions
CN1259933A (zh
Inventor
C·吴
B·徐
J·单
J·T·雅德莱
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell International Inc
Original Assignee
AlliedSignal Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by AlliedSignal Inc filed Critical AlliedSignal Inc
Publication of CN1259933A publication Critical patent/CN1259933A/zh
Application granted granted Critical
Publication of CN1127474C publication Critical patent/CN1127474C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/62Halogen-containing esters
    • C07C69/65Halogen-containing esters of unsaturated acids
    • C07C69/653Acrylic acid esters; Methacrylic acid esters; Haloacrylic acid esters; Halomethacrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00Ethers; Compounds having groups, groups or groups
    • C07C43/02Ethers
    • C07C43/03Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04Saturated ethers
    • C07C43/13Saturated ethers containing hydroxy or O-metal groups
    • C07C43/137Saturated ethers containing hydroxy or O-metal groups containing halogen
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/045Light guides
    • G02B1/046Light guides characterised by the core material

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Optical Integrated Circuits (AREA)
  • Overhead Projectors And Projection Screens (AREA)
CN98805977A 1997-04-17 1998-03-23 可光固化的卤代氟丙烯酸酯 Expired - Fee Related CN1127474C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/842,783 1997-04-17
US08/842,783 US6323361B1 (en) 1997-04-17 1997-04-17 Photocurable halofluorinated acrylates

Publications (2)

Publication Number Publication Date
CN1259933A CN1259933A (zh) 2000-07-12
CN1127474C true CN1127474C (zh) 2003-11-12

Family

ID=25288229

Family Applications (1)

Application Number Title Priority Date Filing Date
CN98805977A Expired - Fee Related CN1127474C (zh) 1997-04-17 1998-03-23 可光固化的卤代氟丙烯酸酯

Country Status (8)

Country Link
US (3) US6323361B1 (enExample)
EP (1) EP0975577B1 (enExample)
JP (1) JP4106095B2 (enExample)
CN (1) CN1127474C (enExample)
AT (1) ATE224354T1 (enExample)
CA (1) CA2288295A1 (enExample)
DE (1) DE69808066T2 (enExample)
WO (1) WO1998046556A1 (enExample)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6308001B1 (en) * 1998-12-22 2001-10-23 Alliedsignal Inc. Radiation curable fluorinated vinyl ethers derived from hexafluoropropene
US6166156A (en) * 1998-11-12 2000-12-26 Wu; Chengjiu Method for making photocurable halofluorinated acrylates
US6555288B1 (en) * 1999-06-21 2003-04-29 Corning Incorporated Optical devices made from radiation curable fluorinated compositions
US6306563B1 (en) 1999-06-21 2001-10-23 Corning Inc. Optical devices made from radiation curable fluorinated compositions
US6496637B2 (en) * 2000-12-21 2002-12-17 Corning Incorporated Low optical loss polymers
DE60121719T2 (de) * 2001-01-19 2007-07-05 Centre National De La Recherche Scientifique (Cnrs) Verfahren zur Herstellung einer Wellenleiterkomponente mit mehreren Schichten auf einem Substrat und damit versehene Komponente
US6929899B2 (en) * 2001-01-25 2005-08-16 E. I. Du Pont De Nemours And Company Fluorinated photopolymer composition and waveguide device
US20020115820A1 (en) * 2001-01-25 2002-08-22 Fang Wang Hyperbranched fluorinated multifunctional alcohols and derivatives
US7078445B2 (en) * 2001-02-01 2006-07-18 E. I. Du Pont De Nemours And Company Photosensitive acrylate composition and waveguide device
US6778753B2 (en) 2001-07-25 2004-08-17 E. I. Du Pont De Nemours And Company Halogenated optical polymer composition
US6902871B2 (en) * 2002-10-03 2005-06-07 Lumera Corporation Method for manufacturing polymer microstructures and polymer waveguides
US7374859B2 (en) * 2002-11-15 2008-05-20 E.I. Du Pont De Nemours And Company Protective layers compatible with thick film pastes
US6937811B2 (en) * 2002-11-19 2005-08-30 Lumera Corporation Polymer waveguide devices incorporating electro-optically active polymer clads
DE10255667B4 (de) * 2002-11-28 2006-05-11 Kodak Polychrome Graphics Gmbh Strahlungsempfindliche Elemente mit ausgezeichneter Lagerbeständigkeit
US20040170925A1 (en) * 2002-12-06 2004-09-02 Roach David Herbert Positive imageable thick film compositions
US20040191639A1 (en) * 2003-03-26 2004-09-30 Danliang Jin Micro-imprinting method and template for use in same
CN100427516C (zh) * 2003-11-21 2008-10-22 大日本油墨化学工业株式会社 含氟光固化性组合物
US7125949B2 (en) * 2004-01-21 2006-10-24 Lumera Corporation Fluorinated sol-gel electro-optic materials, process for producing same, and devices therefrom
US7250712B2 (en) * 2004-01-21 2007-07-31 Lumera Corporation Polymer sustained microelectrodes
US6852563B1 (en) 2004-01-21 2005-02-08 Lumera Corporation Process of fabricating electro-optic polymer devices with polymer sustained microelectrodes
US7241394B2 (en) * 2004-01-21 2007-07-10 Lumera Corporation Process of fabricating polymer sustained microelectrodes
US7402373B2 (en) * 2004-02-05 2008-07-22 E.I. Du Pont De Nemours And Company UV radiation blocking protective layers compatible with thick film pastes
ATE423676T1 (de) * 2004-08-16 2009-03-15 Fujifilm Corp Flachdruckplattenvorläufer
FR2878040B1 (fr) * 2004-11-15 2007-02-09 Nexans Sa Composition photoreticulable pour materiau de fibre optique plastique a saut d'indice
US7799885B2 (en) * 2005-11-30 2010-09-21 Corning Incorporated Photo or electron beam curable compositions
US7463417B2 (en) * 2006-02-13 2008-12-09 3M Innovative Properties Company Optical articles from curable compositions
JP5309436B2 (ja) 2006-10-16 2013-10-09 日立化成株式会社 樹脂製微細構造物、その製造方法及び重合性樹脂組成物
JP5449735B2 (ja) * 2008-09-30 2014-03-19 富士フイルム株式会社 含フッ素多官能化合物、反射防止膜及び反射防止フィルム
US8442360B2 (en) * 2008-11-05 2013-05-14 Gigoptix, Inc. Intrinsically low resistivity hybrid sol-gel polymer clads and electro-optic devices made therefrom
JP5654050B2 (ja) 2010-02-04 2015-01-14 エルジー・ケム・リミテッド 新規のフッ素化化合物、これを含む組成物、これを利用した成形体、及び成形体の製造方法
KR101369381B1 (ko) * 2011-11-04 2014-03-06 에스케이이노베이션 주식회사 함불소 화합물을 포함하는 저굴절 코팅 조성물, 이를 이용한 반사방지 필름, 이를 포함하는 편광판 및 표시장치
KR101811116B1 (ko) 2013-05-09 2017-12-20 캐논 가부시끼가이샤 화합물, 광경화성 조성물, 및 광경화성 조성물을 사용하여 패턴 형상을 갖는 막, 광학 부품, 회로 기판, 전자 부품을 제조하는 방법, 및 경화물
JP6542219B2 (ja) * 2013-12-03 2019-07-10 プレジデント アンド フェローズ オブ ハーバード カレッジ 妊娠性糖尿病の評価のための方法および試薬

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3055932A (en) * 1960-04-27 1962-09-25 Hooker Chemical Corp Unsaturated esters of fluorinated glycols
EP0128701A1 (en) * 1983-06-03 1984-12-19 Minnesota Mining And Manufacturing Company Acrylate and methacrylate monomers and polymers and process for thermoformed articles

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2806866A (en) 1957-09-17 Hoocxcfcix
US4346235A (en) * 1979-06-15 1982-08-24 Okamura Oil Mill Limited Fluorine-containing compounds
US5274174A (en) 1988-07-19 1993-12-28 Hoechst Celanese Corporation Process for the production of poly(4-hydroxystyrene)
WO1991009069A1 (fr) 1989-12-11 1991-06-27 Sumitomo Electric Industries, Ltd. Resine photopolymerisable et fibre optique l'utilisant
USRE35060E (en) 1991-12-11 1995-10-10 Alliedsignal Inc. Fluorinated photoinitiators and their application in UV curing of fluorinated monomers
US5231197A (en) 1992-06-01 1993-07-27 General Electric Company Method for producing ethylenically unsaturated graftable orthoesters
EP0820980B1 (en) 1996-02-14 2001-07-11 Nof Corporation Fluorinated polyfunctional (meth)acrylic esters, fluoromonomer composition, material with low refractive index, and lowly reflective film

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3055932A (en) * 1960-04-27 1962-09-25 Hooker Chemical Corp Unsaturated esters of fluorinated glycols
EP0128701A1 (en) * 1983-06-03 1984-12-19 Minnesota Mining And Manufacturing Company Acrylate and methacrylate monomers and polymers and process for thermoformed articles

Also Published As

Publication number Publication date
CA2288295A1 (en) 1998-10-22
US6323361B1 (en) 2001-11-27
US20010053502A1 (en) 2001-12-20
DE69808066T2 (de) 2003-02-06
WO1998046556A1 (en) 1998-10-22
EP0975577B1 (en) 2002-09-18
US20010044481A1 (en) 2001-11-22
CN1259933A (zh) 2000-07-12
ATE224354T1 (de) 2002-10-15
EP0975577A1 (en) 2000-02-02
JP2001521519A (ja) 2001-11-06
DE69808066D1 (en) 2002-10-24
JP4106095B2 (ja) 2008-06-25
US6534671B2 (en) 2003-03-18

Similar Documents

Publication Publication Date Title
CN1127474C (zh) 可光固化的卤代氟丙烯酸酯
CN1221861C (zh) 光致抗蚀剂组合物
JP4760868B2 (ja) 反射防止処理物品の製造方法
CN1476449A (zh) 卤代光学聚合物组合物
JP4285238B2 (ja) 含フッ素不飽和化合物、含フッ素重合体、およびそれらを用いた硬化性組成物
EP0616617A1 (en) UV CURING OF FLUORINATED MONOMERS.
TW200535147A (en) Fluorine containing photocurable composition
EP1227076B1 (en) Hyperbranched fluorinated multifunctional alcohols and derivatives
CN1890206A (zh) 多官能(甲基)丙烯酸酯及其制备方法
CN1285626C (zh) 低光损耗聚合物
JP4530565B2 (ja) モノアクリレートフルオレン化合物、該化合物を含有する組成物、及びその硬化物
WO1997047585A1 (en) Fluorinated polyfunctional (meth)acrylate esters, compositions, low-refraction materials, and antireflection films
JP4590703B2 (ja) 含フッ素ポリエーテルカルボン酸エステル
JPWO2002072706A1 (ja) 硬化性含フッ素ポリマーを含んでなる光学材料
JP3940086B2 (ja) フッ素置換脂環基含有(メタ)アクリル酸エステルおよびその硬化物
WO2003091343A1 (en) Fluorinated optical material comprising fluoropolymer having functional group capable of forming complex with rare earth metal ion
CN1219741C (zh) 制造光可固化的卤代氟化丙烯酸酯的新颖方法
CN1675268A (zh) 含氟化合物、含氟聚合物及其制备方法
JP4179306B2 (ja) 硬化性含フッ素ポリマー、それを用いた硬化性樹脂組成物および反射防止膜
JP5071612B2 (ja) 含フッ素硬化性組成物
JP4192600B2 (ja) 含フッ素光導波路用材料
JP2005336484A (ja) 硬化性含フッ素ポリマー、それを用いた硬化性樹脂組成物および反射防止膜
CN1490299A (zh) 一种新羟烷基苯酮光固化引发剂及其制备方法和应用
JP4442533B2 (ja) 含フッ素不飽和化合物
JP2008115106A (ja) 含フッ素ポリエーテルカルボン酸エステルおよびその製造法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20031112

Termination date: 20150323

EXPY Termination of patent right or utility model